Engineering Commons^™

Improving Corrosion Resistance Of 3d Printed Ti-6al-4v By Tin Coating, Surada Nisaimun, Phitsanu Poolcharuansin, Patama Visuttipitukul, Pitichon Klomjit

Journal of Metals, Materials and Minerals

TiN thin films were deposited on biomaterial 3D printed Ti-6Al-4V substrates using two methods including direct current magnetron sputtering (DCMS) and high-power impulse magnetron sputtering (HiPIMS). The coating times were compared between 5 min and 25 min. HiPIMS was developed based on DCMS by increasing degree of ionization in plasma and power densities in the order of kWcm-2 compared to Wcm-2 of DCMS. The film characteristics and mechanical properties were investigated by glancing incident x-ray diffractometer (GIXRD), field emission scanning electron microscope (FE-SEM), and atomic force microscope (AFM). Electrochemical behavior was analyzed by electrochemical impedance spectroscopy (EIS) in 1 M …

Characteristic Of Fluorescence Spectroscopy Response Of Tetrakis (4-Sulfonatophenyl) Porphyrin Doped Polyaniline Toward Fe3+ Ion, Chatr Panithipongwut Kowalsk, Meatawadee Buntee, Prasit Pattananuwat

Journal of Metals, Materials and Minerals

Here, we report a selective colorimetric chemosensor toward Fe3+ ion detection by the combination of sensitizer and hole transport consisting of polyaniline and tetrakis (4-sulfonatophenyl) porphyrin. Interestingly, the presence of tetrakis (4-sulfonatophenyl) porphyrin moiety on polyaniline can enhance the optical limiting properties of polyaniline, allowing the fluorophore signal for chemical sensor. The performance sensing behaviors toward metal ion are observed by the ultraviolet-Visible and fluorescence properties. The sensing of polyaniline-tetrakis (4-sulfonatophenyl) porphyrin toward Fe3+ ion exhibits a linear response in the concentration range of 0.01 M to 1.0 × 10-4 M over the other transition metals (Cu2+, Ni2+, Zn2+, Pb2+, …

The Study On Un-Doped/Boron Doped/Un-Doped Triple Seg In Vertical Nand Flash Memory, Woong Lee, Chaeho Kim, Joonsuk Lee, Sehun Park, Yonghan Roh

Journal of Metals, Materials and Minerals

Selective epitaxial growth (SEG) plays a critical role in vertical NAND flash memory because it serves as a ground select line (GSL) transistor, which is used to control the cell current in the vertical channel. In this study, different channel hole sizes between the adjacent hole and away hole from the common source line (CSL) were detected after vertical channel etch (VCE). This discrepancy severely impacts the boron concentration of SEG applied through ex-situ boron implantation, and results in large GSL Vth variations. Novel in-situ boron-doping of triple-layered un-doped/boron doped/un-doped SEG was developed to solve the high variation of the …

Microwave-Assisted Ecofriendly Silver Nanoparticle Synthesis By Varieties Of Chrysanthemum Morifolium Ramat: Assessing Their Antioxidant, Photocatalytic And Antibacterial Activities, Mathivathani Kandiah, Laknee Nawamali De Silva

Journal of Metals, Materials and Minerals

Based on recent developments in the field of Nanobiotechnology, this study is aimed at the assessment of antioxidant, photocatalytic and antibacterial activities of silver nanoparticles (AgNPs) synthesized using Chrysanthemum morifolium Ramat varieties (brown, yellow, purple, pink, salmon pink and white), where five varieties produced AgNPs except white. Antioxidant assays such as total flavonoid content, total phenolic content and total antioxidant capacity and free radical scavenging assays such as ferric reducing antioxidant power and DPPH radical scavenging assays were performed. Photocatalytic activity was assessed by the degradation of the model dye methylene blue. Anti-bacterial activity was determined on Staphylococcus aureus and …

Improvement Of The Superconducting Properties Of Carbon Addition On Bi1.6pb0.4sr2 Ca2cu3o10+Δ Prepared Through The Two-Step Sintering Process, Dini Rizqi Dwikunti Siregar, Sigit Dwi Yudanto, Septian Adi Chandra, Eka Feby Ronauli Lubis, Syahrul Humaidi, Nono Darsono

Journal of Metals, Materials and Minerals

The effects of the addition of carbon nanoparticles and nanotubes on the Bi1.6Pb0.4Sr2Ca2Cu3O10+δ (BPSCCO) have been reported. BPSCCO samples were synthesized using the sol-gel method. BPSCCO with nominal composition was sintered at 840°C for 30 h, then grounded and added an amount of carbon. Pure and carbon added BPSCCO were sintered at 840°C for 30 hours. Resistivity measurements were carried out to determine the superconducting properties of the samples. We found that the addition of carbon nanoparticles and nanotubes increased the critical zero temperature (Tc-zero) of BPSCCO from 94.67 K to 97.8 K and 102.03 K for the pure BPSCCO, …

Stress Softening Characteristics Of Thin Monoholar Rubber Flat Slab, Kulyuth Boonseng, Chatchai Waiyapattanakorn, Prayoon Surin

Journal of Metals, Materials and Minerals

Thin monoholar rubber flat slab gives rise to unconventional mechanical properties under tension loading not found in thin solid rubber flat slab. However there has been no proper report on its stress softening characteristics. Stress softening is an important phenomenon occurring in all elastomeric materials under cyclic tension loading. Parameters pertinent to stress softening investigated in this research are stress-strain characteristics, permanent set strain and hysteresis loss energy of the thin monoholar rubber flat slab in comparison with the thin solid rubber fat slab when undergoing 7 cycles of stretching. Noticeable differences of stress-strain hysteresis loops diminution of the thin …

Photoelectrochemical Cathodic Protection Of Amorphous Zinc Oxide Coating On Hot Rolled Steel Ss400 In A 3 Wt% Nacl Solution And A Na2s-Naoh Solution, Phatchara Wipataphan, Worapot Sripianem, Naw Blessing Oo, Thanate Na Wichean, Boossayamas Dachbumroong, Oratai Jongprateep, Gasidit Panomsuwan, Naray Pewnim, Ratchatee Techapiesancharoenkij

Journal of Metals, Materials and Minerals

The photoelectrochemical cathodic protection of amorphous ZnO thin-film coating on hot rolled steel SS400, in the 3 wt% NaCl environment, was investigated. The ZnO thin film was coated on a SS400 substrate at 200℃ using the spray pyrolysis technique. The x-ray diffractometry analysis confirmed the amorphous ZnO coatings. Two different types of the electrochemical cells were used: a single-cell and a double-cell system. Two different types of the photoelectrolytic solutions were compared: (i) 0.1 M Na2S + 0.2 M NaOH and (ii) 3 wt% NaCl solution. The ZnO-coated SS400 samples were subjected to potentiostatic polarization testing under dark and UV …

Influence Of Graphite Feedstock On The Characteristics Of Silver-Decorated Graphene Oxide And Antimicrobial Property, Ebrahim Mahmoudi, Wei Lun Ang, Gasidit Panomsuwan, Oratai Jongprateep, Abdul Wahab Mohammad, Law Yong Ng, Muneer M. Ba-Abbad

Journal of Metals, Materials and Minerals

Graphite from different sources has significant influence on the properties of graphene oxide (GO) and reactivity of GO towards further modification with other nanoparticles. However, such effect has not yet been properly explored. This study aims to investigate the characteristics and antimicrobial property of GO decorated with silver nanoparticles (known as Ag-GO composite) where the GO is synthesized via modified Hummer’s method from various graphite feedstock, namely natural graphite flake (NGF), natural graphite powder (NGP), and synthetic graphite powder (SGP). The Ag-GO nanocomposite was then synthesized using chemical reduction methods. Antimicrobial properties of the Ag-GO were tested using the standard …

Preparation Of A Mixed Al/Sc Nano-Oxide Derived From The Bauxite Residue (Red Mud) Via The Sulfuric Acid Roasting–Leaching–Precipitation Process, Razieh Habibpour, Eslam Kashi, Mehdi Janfada

Journal of Metals, Materials and Minerals

In this study, three methods were used and compared for the selectable extraction of aluminum/ scandium with the least amount of iron in red mud (RM) samples from the Iran alumina plant in Jajarm as follows: 1) RM direct acid leaching with H2SO4, 2) RM washing with hydrochloric acid and oxalic acid before leaching with H2SO4, and 3) RM sulfuric acid roasting-leaching-precipitation.  The aim was to extract the highest amount of scandium while preventing the leaching of other metals, especially iron. Due to any discriminative features, the selective separation of Al/Sc with …

Interface Characterization In Tungsten Fiber/Zr-Based Bulk Metallic Glass Matrix Composite, Mohammad Ammar Mofid, Mostafa Jafarzadegan

Journal of Metals, Materials and Minerals

In this research, Zr55Cu30Al10Ni5 bulk metallic glass (BMG) alloy is used as the base material to form tungsten fiber reinforced BMG composites. The composites are synthetized using melt infiltration casting method and their microstructure and compressive properties are investigated. Two different infiltration times of 10 min and 15 min are used to produce the composites. The microstructural evaluation of the interface between tungsten fiber and BMG matrix reveals that a narrow reaction band emerges between the tungsten wires and BMG alloy. Some portions of this layer are broken into the fine Zr/W-rich particles …

Timber Bridge Pile Splicing With Fiber Reinforced Polymer Wraps, Drew L. Damich

Graduate Theses, Dissertations, and Problem Reports (ETD)

Timber pile repair using splicing is widely used but little research has been done to determine their strength capacity after repair using this method. Current timber pile splicing mechanisms utilize various steel or wooden components. Fiber Reinforced Polymer (FRP) wraps can be utilized as replacement to conventional materials in splicing of timber piles. This study evaluated the strength capacities of traditional splicing mechanisms in relation to FRP wrap splice mechanisms. Traditional splicing mechanisms consisted of flat steel plate, C-channel steel plate, and wooden plate splices. The FRP wrap splice consisted of unidirectional glass/epoxy composite with three layers of fabric as …

Topological Design Of Pentamode Lattice Metamaterials Using A Ground Structure Method, Zuyu Li, Zhen Luo, Lai-Chang Zhang, Chun-Hui Wang

Research outputs 2014 to 2021

Pentamode metamaterials are a new class of artificially engineering three-dimensional lattice composites. There exist a few types of pentamode metamaterials that are dominated by ad hoc design motifs, while a systematic design approach is still missing. This paper will present an efficient topological optimization methodology to discover a series of novel pentamode lattice microarchitectures over a range of effective material properties. Firstly, the necessary and sufficient condition that is required for elasticity constants of pentamode micro lattices with at least elastically orthotropic symmetry is derived. Secondly, a general mathematical formulation for design optimization of such pentamode micro lattices is developed. …

Advancement Of Full-Vector Variable-Temperature Magnetometry For Rock-Magnetic And Paleointensity Applications, Leonid Surovitskii

Dissertations, Master's Theses and Master's Reports

Data on the variation of the direction and strength of Earth’s ancient magnetic field (absolute paleointensity) provide crucial information into the mechanisms of the geodynamo and the Earth’s thermal history. However, the use of conventional methods and instrumentation for absolute paleointensity determination has been hampered by physicochemical alteration of the samples caused by multiple high-temperature cycles and long experiment durations. The reliability and efficiency of the measurement process can be improved by the measurement of the full remanent magnetization vector simultaneously with the temperature cycling of a sample. Such as approach can also substantially expand the scope of materials available …

Relationship Between Pressure And Output Parameters In Belt Grinding Of Steels And Nickel Alloy, Nelli V. Syreyshchikova, Danil Y. Pimenov, Munish K. Gupta, Krzysztof Nadolny, Khaled Giasin, Muhammad Aamir, Shubham Sharma

Research outputs 2014 to 2021

Belt grinding of flat surfaces of typical parts made of steel and alloys, such as grooves, shoulders, ends, and long workpieces, is a good alternative to milling. Several factors can influence the belt grinding process of flat surfaces of metals, such as cutting speed and pressure. In this work, the importance of pressure in the belt grinding was investigated in terms of technological and experimental aspects. The grinding experiments were performed on structural alloy steel 30KhGSN2/30KhGSNA, structural carbon steel AISI 1045, corrosion-resistant and heat-resistant stainless steel AISI 321, and heat-resistant nickel alloy KHN77TYuR. The performance of the grinding belt was …

Review On Machining Of Additively Manufactured Nickel And Titanium Alloys, Navneet Khanna, Kishan Zadafiya, Tej Patel, Yusuf Kaynak, Rizwan Abdul, Rahman Rashid, Ana Vafadar

Research outputs 2014 to 2021

The machining of nickel and titanium-based superalloy components is very expensive and involves unusually high lead times compared with other engineering metals such as steels and aluminum. This has led to the development of most suitable additive manufacturing (AM) processes to fabricate these difficult-to-machine metals into near-net shape parts, thereby reducing the lead time and material waste, and significantly increasing productivity. Nonetheless, finish machining is still required on the AMed metal components to meet the dimensional and surface requirements of the application. Several research studies have investigated the machinability of AMed nickel and titanium alloy workpieces and have compared the …

Editorial: Hexagonal Close-Packed Metals And Alloys: Processing, Microstructure And Properties, Liang-Yu Chen, Linjiang Chai, Lai-Chang Zhang

Research outputs 2014 to 2021

In comparison with face-centered cubic (FCC) and body-centered cubic (BCC) metals and alloys, hexagonal close-packed (HCP) metals and alloys show distinct characteristics, such as atomic site occupation, anisotropic microstructure, and fewer slip systems, owing to their HCP lattice structure. Therefore, HCP metals and alloys have distinguished processing, microstructure, and properties. Several types of HCP metals and alloys, involving titanium, zirconium, magnesium, and so on, are extensively used in a variety of industrial and military sectors. Up to date, an increased requirement is still needed to improve the understanding of the relationships among processing, microstructures, and the resultant properties of HCP …

Corrosion Behavior And Characteristics Of Passive Films Of Laser Powder Bed Fusion Produced Ti-6al-4v In Dynamic Hank’S Solution, Liang-Yu Chen, Hong-Yue Zhang, Chuanbo Zheng, Hong-Yu Yang, Peng Qin, Cuihua Zhao, Sheng Lu, Shun-Xing Liang, Linjiang Chai, Lai-Chang Zhang

Research outputs 2014 to 2021

The corrosion behavior of laser powder bed fusion produced (L-PBF-produced) titanium alloys involving flowing body fluid is still unclear. Therefore, this work investigates in vitro corrosion behavior and the characteristics of passive films formed on L-PBF-produced Ti–6Al–4V in both static and dynamic Hank’s solutions. Electrochemical measurements, immersion tests, X-ray photoelectron spectroscopy and scanning electron microscopy were conducted. In comparison to the L-PBF-produced Ti–6Al–4V in static Hank’s solution, the samples showed lower charge transfer resistance and higher passivation current density (anodic current density as well) in dynamic Hank’s solution. Meanwhile, a more apparent deposition of apatite and hydroxyapatite is found on …

Static And Dynamic Analysis Of Composite Plates Using The Monna Finite Element, Mohamed Emadeldin Omar Abdelhadi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Composite materials are replacing metals in many fields due to their favorable qualities such as strength-to-weight ratio, fatigue characteristics, and corrosion resistance. An efficient, versatile, and accurate composite plate element applicable to the dynamic analysis of composite plates would help the advancement of composites tremendously.

The objective of this research is to analyze composite plates using the classical laminated plate theory (CLPT), first-order deformation theory (FSDT), and higher-order deformation theory (HSDT) with the applicable finite element modeling (FEM) for each theory. This thesis investigates which theory is more efficient and accurate and evaluates the benefits of using an h-p-version …

Valorization Of Xylan In Agroforestry Waste Streams, Harrison Appiah

Graduate Theses, Dissertations, and Problem Reports (ETD)

Valorization of Xylan in Agroforestry Waste Streams.

Harrison Appiah

Microwave-assisted deep eutectic solvent and gamma-valerolactone metallic chloride catalyzed conversion of xylan to furfural were investigated using a 2x3 factorial experimental design at two levels of percent microwave power, reaction time, and catalyst concentration. The levels of each factor studied were (20%, 60% microwave power, 2, 4 minutes, and 10, 20mg) respectively. The effect of three metallic chloride catalysts (LiCl, FeCl3.6H20, CuCl2) on the conversion of xylan to furfural was also investigated. The gamma-valerolactone-ferric chloride sent system exhibited the highest mean yield of furfural (56.50%). The next highest furfural yield of …

In-Situ Process Monitoring For Metal Additive Manufacturing (Am) Through Acoustic Technique, Md Shahjahan Hossain

College of Graduate Studies: Theses & Dissertations

Additive Manufacturing (AM) is currently a widely used technology in different industries such as aerospace, medical, and consumer products. Previously it was mainly used for prototyping of the products, but now it is equally valuable for commercial product manufacturing. More profound understanding is still needed to track and identify defects during the AM process to ensure higher quality products with less material waste. Nondestructive testing becomes an essential form of testing for AM parts, where AE is one of the most used methods for in situ process monitoring. The Acoustic Emission (AE) approach has gained a reputation in nondestructive testing …

The Role Of Structure Evolution For Prbaco2o6-Δ In Oxygen Reduction Reaction Kinetics At Sofc Cathode, Nan Zhang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Mixed ion and electron conductive materials especially those with perovskite-related structures have been widely used as cathode and anode of solid oxide fuel cells (SOFC). Double perovskite LnBaCo₂O_6-δ (Ln=Pr, Nd, Sm, Nd, Y) cathodes have been shown better performance than single perovskite Ln_0.5Ba_0.5CoO_3-δ in SOFC cathode studies. However, the effect of different double perovskite phases on oxygen transport properties has not been investigated. In this study, the electrochemical performance of different double perovskite materials PrBaCo₂O_6-δ (PBCO), NdBaCo₂O_6-δ (NBCO), YBaCo₂O_6-δ (YBCO), and single perovskite …

Dual-Adaptive Camouflage For The Hyperstealth Corperation, Keith J. Carlock Mr.

The Transdisciplinary STEAM+ Journal

Dual-Adaptive Camouflage, though still a concept that I've had for 28 years, seems to me, more promising that the bulk and brain power and needed energy supply of a computer-driven network of optical electronic harnesses that would be the basis for any suit that proclaims to render its wearer invisible.

Prospects For Solving The Problem Of Rational Use Of Water Resources Using The Tiiame-1 Sprinkling Machine, M.Kh. Khamidov, A.R. Muratov

Irrigation and Melioration

The information published by the International Commission on Irrigation and Drainage, and the intermediate results of many years of research carried out by scientists from TIIAME on the development, research and implementation of water-saving technologies in agriculture are presented. The acute shortage of water resources in Central Asia, the problems of increasing the efficiency of the use of water-saving technologies around the world have led to the careful use of available water resources in the region, including the prospects and advantages of using irrigation of crops by sprinkling, as well as the design and technical parameters of the sprinkler developed …

Inadequacy Of Current Water Use Planning At The Level Of Water Users And Wuas, A.A. Alimdjanov, A.Kh. Karimov, B.R. Nasibov

Irrigation and Melioration

This paper studies the main issues of water use planning at the level of water consumers and water user associations (WUA). The study carried out in Bulakbashi district of Andijan province of Uzbekistan, where the main source of irrigation water is the Southern Fergana Main Canal. The study followed two-stage procedure. During the first stage we compiled water use plans for the WUA and water consumers based on the applied methodology of water use planning. Then, at the second stage, we analyzed the results of the actual implementation of the farm water consumption plans and WUA water use plan, and …

Technology And Technical Device Used In The Efficient Use Of Water Resources In Irrigated Agriculture, А.U. Аtajanov

Irrigation and Melioration

The economical use of water resources, the improvement and development of new technology and technical means for its implementation, ensuring the saving of irrigation water is one of the most important issues of today. This article is devoted to the issues of improving the technology of irrigation of furrows and the creation of technical means,also recommended technology and using from created technical device in selected per experiment fields and analyzing their results.

Empirical Assessment Of Climate Change Impacts On Agriculture In Samarkand Region, Sh.B. Babakholov

Irrigation and Melioration

Agricultural production is highly sensitive to climate factors like other endogenous factors, and the expected climate change projections may have a negative impact on the efficiency and income of agricultural producers. Therefore, this study aims to analyze the impact of changes in climatic factors (average air temperature and precipitation) on the technical efficiency of cotton growing farmers as its determinants in Samarkand region. Empirical analyzes were performed on the cases of 1141 cotton-growing farms using panel-based Time-Invariant Inefficiency model. According to the results of the analysis, cotton farms in the region have an average technical efficiency of 76%, which in …

Car Wash Complex – Object Of Harmful Impact On Water Resources, M. Radkevich, K. Shipilova, M. Abdukodirova, O. Pochugevski

Irrigation and Melioration

Deals with the problem of the impact of car wash complexes in the city of Tashkent on water resources. The analysis of the technological process of washing and a sociological survey of car owners and employees of car washes revealed the average amount of water used per car wash per year, as well as the amount of harmful substances entering the sewer network of the city of Tashkent. Calculations have shown that the annual water consumption only for passenger cars in Tashkent is about 4.34 million m³, and the wastewater is not properly treated. From one car wash …

Agrochemical Indicators Of New Irrigated Graph-Meadow Soils Formed On The Iii Underfladder Terrace Of Syrdarya, J.M. Kuziev

Irrigation and Melioration

Presents material on the geographical location, geomorphological and geological structure, as well as the agrochemical state of irrigated serozem-meadow soils, common in the Mirzaabad district of the Syrdarya region. According to the data obtained on the chemical analysis of soils, the studied soils are medium- and heavily loamy in texture, where particles of coarse sand predominate (0.05-0.01%). In the arable horizon of these soils, the humus content is 1.088-1.214%, total nitrogen 0.079-0.089%, total phosphorus 0.109-0.124%, and total potassium within 1.15-1.24%, and on the basis of these data, a regularity of the underlying horizon of these soils. The degree of provision …

Water Efficient Technology Of Drip Irrigation In Intensive Gardens, F.U. Juraev, G.H. Karimov

Irrigation and Melioration

The studies were carried out in 2017-2019 at the Zodabek farm on a 6 hectare garden plot with seedlings of half-tall apple trees “Golden Delicious”. Experimental research work was carried out at a groundwater level in the experimental area of 1.5-2.0 m, mineralization 1.0-1.2 g/l in alluvial, mechanical, medium sandy soils with the following irrigation options. The first option is irrigation, at the start of the second - drip irrigation; third, the use of specially designed soil pegs. The following results were obtained: in the control option, the average irrigation rate for three years was 1125.7 m3/ha, with drip irrigation …

Forecasting The Dynamics Of Cotton Yield In The Ferghana Region, V. Vakhobov, А.А. Faiziev

Irrigation and Melioration

Observations of a certain phenomenon, the nature of which changes over time, give rise to an ordered sequence, which is called a time series. In the article, using the method of statistical time series analysis, statistical pattern of time series Y₁ – average yield of cotton in Fergana region of the Republic of Uzbekistan(on materials of CSB of the Republic of Uzbekistan for 1991-2018 years). Point and interval estimates for the average cotton yield were constructed with a 95% guarantee, explicit types of trends were determined, and the yield in the region was predicted for subsequent years. Using statistical …