Engineering Commons^™

The Synergy Of Recombinant Xylanolytic Enzyme On Xylan Hydrolysis, One Asmarani, Bambang Prajogo Eko Wardojo, Ni Nyoman Tri Puspaningsih

Makara Journal of Technology

Microbial xylanases or xylanolytic enzyme have received considerable attention over the last years owing to a multitude of possible applications. These enzymes have potential in the biodegradation of lignocellulosic biomass to fuels, chemicals, fruit juice, animal feed and in improving rumen digestion. More recently, the use of xylanases as bleaching agent in the pulp and paper industry has been suggested to replace of some of the chemicals presently used for this purpose. Such applications could have an important positive impact on the environment. The purpose of this research was determining the synergy of 3 recombinant xylanolytic enzymes (β-xylosidase, exo-xylanase and …

Cradle To Gate Simple Life Cycle Assessment Of Biodiesel Production In Indonesi, Akhmad Hidayatno, Teuku Yuri M. Zagloel, Widodo Wahyu Purwanto, Carissa Carissa, Lindi Anggraini

Makara Journal of Technology

The focus of this research is to analyze potential environmental impact in the supply chain of palm oil biodiesel industries. Simple Life Cycle Assessment (LCA) is applied to analyze impacts, produced by the three main units in the supply chain of Palm-Oil-based Biodiesel, which are Palm Plantation, CPO mill, and Biodiesel Plant. We developed LCA calculation model using spreadsheet software, used to assess a number of input scenarios to evaluate the best scenario, in variation of: land quality, land area and the rate of clearing, land clearing technique and type of the original land. The biggest potential environmental impact is …

Characterization Of Surface Active Shell Charcoal Nyamplung Seeds (Calophyllum Inophyllum Linn), Santiyo Wibowo, Wasrin Syafi, Gustan Pari

Makara Journal of Technology

Characterization of Surface Active Shell Charcoal Nyamplung Seeds (Calophyllum inophyllum Linn). Chemical and physical activation of nyamplung shell with 0%, 5%, and 10% H3PO4 for 60 and 120 minutes has been carried out to prepare activated charcoal. The purpose of this experiment was to look into the characteristic of nyamplung shell activated charcoal surface. Nyamplung shell was carbonized into charcoal, then activated by immersion in H3PO4 solution using 0%, 5% and 10%, for 24 hours, and heated in retort at two temperatures (700 and 800 oC) and two duration (60 and 120 minutes). The material were characterized by fourier transform …

An Investigation Into The Resistance/Powering And Seakeeping Characteristics Of River Catamaran And Trimarana, Murdijanto Murdijanto, I Ketut Aria Pria Utama, Andi Jamaluddin

Makara Journal of Technology

The increase of fuel price has caused fleet operational and shipping business to be in danger situation. The fuel consumption of a ship is influenced by ship volume or wetted area which contributes directly to the increase of ship resistance and the size of main engine. In order to find out the appropriate answers, a series of investigation into river transportation using monohull, catamaran and trimaran types of vessel was carried out. The work focused on the estimation of total resistance and powering as well as seakeeping characteristics and carried out experimentally using tank test and numerically using a ship …

Determining The Standard Value Of The Oily Distortion Of Acquisition The Fingerprint Images, Rahmat Syam, Mochamad Hariadi, Mauridhi Hery Purnomo

Makara Journal of Technology

Determining the Standard Value of the Oily Distortion of Acquisition the Fingerprint Images. This research describes a novel procedure for determining the standard value of the oily distortion of acquisition the fingerprint images based on the score of clarity and ridge-valley thickness ratio. The fingerprint image is quantized into blocks size 32 x 32 pixels. Inside each block, an orientation line, which perpendicular to the ridge direction, is computed. The center of the block along the ridge direction, a two-dimension (2-D) vector V1 (slanted square) with the pixel size 32 x 13 pixels can be extracted and transformed to a …

Are Ieee 754 32-Bit And 64-Bit Binary Floating-Point Accurate Enough?, Bernaridho Hutabarat, I Ketut Eddy Purnama, Mochamad Hariadi, Mauridhi Hery Purnomo

Makara Journal of Technology

This paper describes a research toward the accuracy of floating-point values, and effort to reveal the real accuracy. The methods used in this research paper are assignment of values, assignment of value of arithmetic expressions, and output the values using floating-point value format that helps reveal the accuracy. The programming-tool used are Visual C# 9, Visual C++ 9, Java 5, and Visual BASIC 9. These tools run on top of Intel 80 x 86 hardware. The results show that 1*10-x cannot be accurately represented, and the approximate accuracy ranges only from 7 to 16 decimal digits.

Ergonomic Analysis Of Garment Industry Using Posture Evaluation Index (Pei) In Virtual Environment, Erlinda Muslim, Boy Nurtjahyo, Romadhani Ardi

Makara Journal of Technology

Ergonomic Analysis of Garment Industry using Posture Evaluation Index (PEI) in Virtual Environment. This research tried to study, in a virtual environment, the ergonomics of four divisions in garment industry: cutting division, sewing division, button division, and finishing division. Variables that influence the working conditions in each division are different; depend on the real situations that happened. The purpose is to assess the real working conditions based on ergonomics study using Posture Evaluation Index (PEI). PEI integrates the scores of low back analysis (LBA), ovako working posture (OWAS), and rapid upper limb assessment (RULA). Analysis phase was done using digital …

Formation Of Caco3 Particle And Conductivity Of Na2co3 And Cacl2 Solution Under Magnetic Field On Dynamic Fluid System, Nelson Saksono, Setijo Bismo, Roekmijati Widaningroem, Azwar Manaf

Makara Journal of Technology

Hard water causes the CaCO3 scale formation on the pipe walls and heat exchanger equipments in industrial or domestic water processes. A great number of experimental researches on the prevention of the CaCO3 precipitation process by magnetic field have been carried out. In this research, Na2CO3 and CaCl2 solutions was magnetized in the circulated flow condition (dynamic fluid system). The velocity of fluid and the circulation time was modified to examine its influences to the magnetization process. CaCO3 content was measured by titration method of EDTA complexometry. Conductivity test was conducted to find out hydrate ion bonding. The results showed …

Two-Class Classification With Various Characteristics Based On Kernel Principal Component Analysis And Support Vector Machines, Ivanna Kristianti Timotius, Iwan Setyawan, Andreas Ardian Febrianto

Makara Journal of Technology

Two class pattern classification problems appeared in many applications. In some applications, the characteristic of the members in a class is dissimilar. This paper proposed a classification system for this problem. The proposed system was developed based on the combination of kernel principal component analysis (KPCA) and support vector machines (SVMs). This system has been implemented in a two class face recognition problem. The average of the classification rate in this face image classification is 82.5%.

Chemical Potential Perturbation: A Method To Predict Chemical Potentials In Periodic Molecular Simulations, Stan G. Moore, Dean R. Wheeler

Faculty Publications

A new method, called chemical potential perturbation (CPP), has been developed to predict the chemical potential as a function of density in periodic molecular simulations. The CPP method applies a spatially varying external force field to the simulation, causing the density to depend upon position in the simulation cell. Following equilibration the homogeneous (uniform or bulk) chemical potential as a function of density can be determined relative to some reference state after correcting for the effects of the inhomogeneity of the system. We compare three different methods of approximating this correction. The first method uses the van der Waals density …

Pyrolysis Kinetics And Chemical Structure Considerations Of A Green River Oil Shale And Its Derivatives, James L. Hillier

Theses and Dissertations

This work had the objective of determining both the kinetic parameters for the pyrolysis of oil shale and kerogen as well as using analytical techniques coupled with pyrolysis to shed light on the structure of a specific Green River oil shale. Because of the problems with linearized methods and disagreement among literature values and methods, a new method was developed tofit kinetic parameters to non linearized data. The method was demonstrated to determine the "correct" answer for mathematically generated data within a few percent error and was shown to have a lower sum squared error than the linearized methods. The …

Sawdust Pyrolysis And Petroleum Coke Co2 Gasification At High Heating Rates, Aaron D. Lewis

Theses and Dissertations

Clean and efficient electricity can be generated using an Integrated Gasification Combined Cycle (IGCC). Although IGCC is typically used with coal, it can also be used to gasify other carbonaceous species like biomass and petroleum coke. It is important to understand the pyrolysis and gasification of these species in order to design commercial gasifiers and also to determine optimal conditions for operation. High heating-rate (100,000 K/s) pyrolysis experiments were performed with biomass (sawdust) in BYU's atmospheric flat-flame burner reactor at conditions ranging from 1163 to 1433 K with particle residence times ranging from 23 to 102 ms. Volatile yields and …

Genomic Library Screens For Genes Involved In N-Butanol Tolerance In Escherichia Coli, Luis Reyes, Maria Almario, Katy Kao

Faculty Publications

Backgroundn-Butanol is a promising emerging biofuel, and recent metabolic engineering efforts have demonstrated the use of several microbial hosts for its production. However, most organisms have very low tolerance to n-butanol (up to 2% (v/v)), limiting the economic viability of this biofuel. The rational engineering of more robust n-butanol production hosts relies upon understanding the mechanisms involved in tolerance. However, the existing knowledge of genes involved in n-butanol tolerance is limited. The goal of this study is therefore to identify E. coli genes that are involved in n-butanol tolerance.Methodology/Principal FindingsUsing a genomic library enrichment strategy, we identified approximately 270 genes …

Effects Of Damköhler Number On Flame Extinction And Reignition In Turbulent Non-Premixed Flames Using Dns, David O. Lignell, Jacqueline H. Chen, Hans A. Schmutz

Faculty Publications

Results from a parametric study of flame extinction and reignition with varying Damköhler number using direct numerical simulation are presented. Three planar, non-premixed ethylene jet flames were simulated at a constant Reynolds number of 5120. The fuel and oxidizer stream compositions were varied to adjust the steady laminar extinction scalar dissipation rate, while maintaining constant flow and geometric conditions. Peak flame extinction varies from approximately 40% to nearly global blowout as the Damköhler number decreases. The degree of extinction significantly affects the development of the jets and the degree of mixing of fuel, oxidizer, and combustion products prior to reignition. …

Verification And Validation Of Cfd Simulations For Local Flow Dynamics In A Draft Tube Airlift Bioreactor, Hu Ping Luo, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Airlift Reactors Have Been Recognized as One of the Promising Photobioreactors for Biomass/bio-Energy Production, Where Mixing Has Significant Impact on the Reactor Performance. in Recent Years, using CFD Simulations to Track Microorganism Cells and to Generate their Trajectories in the Reactor for Reactor Performance Evaluations Becomes More Common. However, there is a Lack of Systematic and Rigorous Verifications and Validations of the Reliability of CFD Models in Particle Tracking Against Experimental Measurements in the Open Literature, Which is Vital for the Faithful Application of CFD in Reactor Design and Scale-Ups. in This Work, We Attempt to Evaluate the Reliability of …

Synthesis Of Mesoporous Nickel Oxide For Supercapacitor Application, Xuan-Xuan Chen, Zhen-Zhen Zhao, Deng-Chao Wang, Zhong-Jie Huang, Wen-Bin Ni, Li Yu, Jian-Wei Zhao

Journal of Electrochemistry

Mesoporous nickel oxide has been synthesized by calcining metal-organic coordination precursor.Transmission electron microscopy and BET test showed that the prepared NiO had a regular morphology and displayed a narrow size distribution.Electrochemical tests revealed that such mesoporous NiO had a specific capacity of 72 F·g^-1 at the current of 2.0 A·g^-1.Futhermore,the material showed excellent cycle-life stability.There was no degradation of capacitance after 1000 cycles.

A Titanium-Supported Nanoporous Pd Electrocatalyst For Methanol Oxidation, Feng-Juan Niu, Qing-Feng Yi

Journal of Electrochemistry

Titanium-supported nanoporous palladium electrode(nanoPd /Ti) was prepared by a hydrothermal process in the presence of the ligand EDTA and using formaldehyde as reducing agent.SEM images showed that the size of Pd particles was about 60 nm and the Pd particles were connected with each other to form a three-dimensional network structure.Cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) were applied to evaluate the electrocatalytic activity of the nanoPd/Ti electrode towards methanol oxidation in alkaline solution.CV results showed that the nanoPd /Ti electrode presented high anodic peak densities and a low onset potential for methanol oxidation.Also nanoPd /Ti electrode showed excellent CO tolerance …

Electrocatalytic Oxidation Of Hydrazine At Rutin Carbon Nanotubes Modified Electrode, Hong-Fang Zhang, Qing-Lin Sheng, Jian-Bin Zheng

Journal of Electrochemistry

The electrochemical behavior and electrocatalytic oxidation of hydrazine on rutin multiwall carbon nanotubes modified glassy carbon electrode were studied by cyclic voltammetry.The experimental results indicated that the electrode exhibits good electrocatalytic activity to hydrazine at a reduced oxidation potential of 262 mV.The amperometric response of the modified electrode showed linear increase after successive addition of hydrazine in the concentration range of 2.5×10^-6~1.0×10^-4 mol·L-1 with a detection limit of 5×10^-7 mol·L^-1.

Novel Anion Exchange Membranes Base On Copolymer Of 2-(Diethylamino) Ethyl Methacrylate And Fluoro-Polyacrylate For Alkaline Direct Methanol Fuel Cells, Yan-Mei Zhang, Jun Fang, Ge Yan, Yong-Ze Zhuang

Journal of Electrochemistry

Anion exchange membrane fuel cells,which use anion exchange membranes as polyelectrolytes,have attracted more and more research interests recently.In this work,a series of hydroxyl-conducting anion-exchange membranes based on the copolymer of 2-(Diethylamino)ethyl methacrylate and fluoro-polyacrylate were prepared by radical polymerization,and their potential applications in alkaline fuel cells were assessed.It was shown that the ionic conductivity of the membranes reached 10^-2 S·cm^-1 at room temperature,while the methanol permeability was lower than 10^-7 cm²·s^-1.The maximum power density of fuel cell assembled with this membrane was achieved to be 43.2 mW·cm^-2 at room temperature,indicating possible application …

Electrooxidation Of Methanol On Multilayer Films Of Polypyrrole-Platinum Electrode, Ling Zhang, Long-Zhen Zheng

Journal of Electrochemistry

Multilayer films of polypyrrole-platinum electrode were fabricated by cyclic voltammetric technique.Electro-oxidation of methanol on this electrode was investigated with the aid of cyclic voltammetry and chronoamperometry.Results demonstrated that the multilayer of polypyrrole-platinum electrode behaved better electrocatalytic performance for electro-oxidaton of methanol and better poison resistant.Furthermore,with the increase of deposited platinum loadings,the rate controlling step on electro-oxidation reaction of methanol was changed from CO oxidation to sorption-desorption of hydrogen.

Electrochemical Deposition Of Zinc Oxide Crystal Whiskers, Peng-Zeng Lu, Su Li, Jin-Qian Jia, Zhen-Hai Liang

Journal of Electrochemistry

Pine needle ZnO crystal whiskers were electrodeposited by anodization of zinc foil.The crystal whiskers were characterized by scanning electron microscopy(SEM) and X-ray diffraction(XRD) spectroscopy.The results show that the lengths and diameters of ZnO crystal whiskers are 200~300 nm and 20~50 nm,respectively,with the ratio of the length to diameter ranging from 10~15.The whiskers belong to wurtzite ZnO(JCPDS 36-1451) with good crystallinity and high purity.The crystalization behavior of ZnO was studied by cyclic voltammetry.The effects of the surface oxide layer at the zinc substrates and the [Zn(OH)₄]^2-concentration of the aqueous electrolyte on the formation of zinc oxide whiskers …

Cobalt Fischer-Tropsch Catalyst Preparation: Overview Of Preparation Techniques On Alumina Pellets, Brad M. Hancock, Kari M. Cook, William C. Hecker

Student Works

Fischer-Tropsch (FT) synthesis is a reaction used to convert carbon monoxide and hydrogen into high-quality liquid fuels. The FT process has been considered a promising alternative route for producing diesel fuel to meet an increasing demand for oil around the world and more strict limits to regulate auto tailpipe emissions. The U.S. Environmental Protection Agency has demanded a reduction in diesel fuel sulfur content to 15 ppm. While crude oil contains finite amounts of sulfur that needs further removal or treatment before it could be used as a commercial fuel, FT synthesis produces sulfur-free diesel fuel. The reaction takes place …

Thermodynamic, Sulfide, Redox Potential, And Ph Effects On Syngas Fermentation, Peng Hu

Theses and Dissertations

Recently, work in ethanol production is exploring the fermentation of syngas (primarily CO, CO2, and H2) following gasification of cellulosic biomass. The syngas fermentation by clostridium microbes utilizes the Wood-Ljungdahl metabolic pathway. Along this pathway, the intermediate Acetyl-CoA typically diverges to produce ethanol, acetic acid, and/or cell mass. To develop strategies for process optimization, a thermodynamic analysis was conducted that provided a detailed understanding of the favorability of the reactions along the metabolic pathway. Thermodynamic analysis provided identification of potentially limiting steps. Once these limiting reactions were identified, further thermodynamic analysis provided additional insights into the ways in which reaction …

Aerosol Synthesis And Electrochemical Analysis Of Niobium Mixed-Metal Oxides For The Ethanol Oxidation Reaction In Acid And Alkaline Electrolyte, Daniel Konopka

Chemical and Biological Engineering ETDs

Direct ethanol fuel cells are especially important among emerging electrochemical power systems with the potential to offset a great deal of the energy demand currently met through the use of fossil fuels. Ethanol can be refined from petroleum sources or attained from renewable biomass, and is more easily and safely stored and transported than hydrogen, methanol or gasoline. The full energy potential of ethanol in fuel cells can only be realized if the reaction follows a total oxidation pathway to produce CO2. This must be achieved by the development of advanced catalysts that are electrically conductive, stable in corrosive environments, …

Biofuel Cell Anode For Nad-Dependent Enzymes, Ovalles Rosalba Rincón

Chemical and Biological Engineering ETDs

Enzymatic biofuel cells are a very attractive young technology based on utilization of natural, renewable and plentiful resources that offer an alternative energy source. Most fuel cells run on hydrogen; but it is extremely expensive and difficult to obtain, which is why research has moved to target fuels that are already available in nature, avoiding high costs of production, both economically and environmentally. Several biofuels with very high energy densities are available to us in abundance, but the challenges to make use of them are plenty. These biofuels contain several carbon-to-carbon bonds which make their oxidation processes significantly more complex …

Printable Lithium Batteries, Kyle Fenton

Chemical and Biological Engineering ETDs

Printable lithium iron phosphate (LiFePO4) cathodes and porous aerogel / polymer separators have been designed, constructed, and tested. The cathodes consist of LiFePO4, PVDF binder, and conductive carbon which was developed for robocast deposition (printing) onto carbon coated aluminum substrates to form 60 \uf06dm thick cathodes. Electrochemical and physical evaluation of these printed cathodes was performed to determine capacity, rate capability, and lifetime performance of the printed cathodes. Cells were constructed using a standard 2032 coin cell to ensure uniform electrode size and pressure on the layers of the battery. Cathodes printed exhibited up to 115 mAh/g capacity with a …

The Structural Role Of Titanium In Ca-Sr-Zn-Si/Ti Glasses For Medical Applications, A. W. Wren, F. R. Laffir, A. Kidari, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Glasses for medical applications are used in particulate form or as a cement component. This work was undertaken to determine structural changes in 0.48SiO₂-0.36ZnO-0.12CaO-0.04SrO glass when the SiO₂ is substituted with 5 mol% increments of TiO2. X-ray Diffraction (XRD) was used to determine the presence of crystallinity. This occurred after additions of 20 mol% TiO₂. Differential Thermal Analysis (DTA) and Network connectivity (NC) calculations determined that by increasing the TiO₂ content, the T_g and NC reduced (T_g 670 °C to 632 °C, NC 1.83 to -1.14) suggesting that TiO₂ acts as …

Flow Regime Identification In A Bubble Column Via Nuclear Gauge Densitometry And Chaos Analysis, S. Nedeltchev, A. Shaikh, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

The Bubble Column Performance Can Change Significantly as a Result of Flow Regime Change. Since Reactor Volume Productivity, Mass and Heat Transfer as Well as Mixing Are Affected by the Prevailing Flow Regime, It is Very Important to Know How to Identify It. in This Work, Flow Regime Identification Was Performed on the Basis of the Kolmogorov Entropy (KE) Algorithm Applied to Nuclear Gauge Densitometry Data. in Addition, the Average Cycle Time Was Used for Validation of the Results. Three Transition Velocities Were Identified that Delineated the Boundaries of the Three Main Hydrodynamic Regimes. the First Two Transition Points Were …

Study Of Controlled Release Of Active Pharmaceutical Ingredients From Functionalized Nanoclays And Polymer Matrices, Jin Uk Ha

Dissertations

This dissertation contains the results of three related novel investigations in the field of structure-property-processing relationships of pharmaceutical polymer-based products. They are: a) modification of a pharmaceutical anionic nanoclay with two different Active Pharmaceutical Ingredients (APIs) to produce nanohybrid API carriers intended to be used alone or in acrylic polymer matrices, b) comparison of binary systems containing the above APIs in the selected acrylic polymers in terms of their miscibilities with the polymer, but in the absence of nanoclay, and c) comparison of the polymer/API binary systems with ternary polymer/API/Clay systems.

For the first study, the calcination method which can …

Study Of Controlled Release Of Dapsone From Modified Montmorillonite And Polymer Matrices, Jia Fan

Theses

This thesis focuses on the controlled release system of Dapsone (DAP) as the Active Pharmaceutical Ingredient (API) intercalated into sodium montmorillonite (MMT-Na+) and their combination with an anionic copolymer (Eudragit® S100). The effects of the excipients on the API dissolution rate were studied from their release profile in simulated intestinal fluid (pH=7.4) at 37±0.5°C. In the first part of the research, ionizable Dapsone was intercalated in the interlayers of MMT-Na+ to produce a nanohybrid. In the second part of the research, the nanohybrid was melt dispersed in the polymer to produce ternary (API/ Clay/ Polymer) composites. For comparison, API-polymer solid …