Engineering Commons^™

Challenges In Optimization For The Performance On Sustainability Dimensions In Reverse Logistics Social Responsibility, Sumarsono Sudarto, Katsuhiko Takahashi, Mochammad Dewo

Makara Journal of Technology

Reverse logistics social responsibility is preferred as the most acceptable solution for addressing the challenges in stakeholders’ debate regarding social responsibility in supply chains because it involves as many actors as possible in the supply chain to perform social responsibility to achieve sustainability. This paper explores the challenges in achieving optimal policies in sustainability dimensions for collection and recycling facilities in reverse logistics. Sustainability dimensions include economic, environmental, and social aspects. The reverse logistics is modeled on System Dynamics, and a simplified statistical analysis using a contour chart is employed in numerical experiments. Results show a narrow area of optimal …

Mathematical Model Of An Industrial Robot Built On The Basis Of Linear Motion Mechatron Modules, Matyokubov Nurbek Rustamovich, Rakhimov Temurbek Omonboyevich

Chemical Technology, Control and Management

The use of Industry 4.0 technologies in modern production serves to increase production efficiency. Robots and robotic complexes with innovative intelligent control are widely used in industrial production. However, studying their mechanical part, linear motion mechatronic modules and control system is a complex object. The variety and complexity of control methods and operating modes negatively affects the operator's working time and production productivity. In such cases, it is necessary to improve control methods and develop technologies used in industry, including robots and robotic manipulators, which allow to perform short movements with high accuracy and speed. In the article, the mathematical …

Systematic Analysis Of Methods Of Control Of Dynamic Objects In Conditions Of Non-Measurable Disturbances, Mamirov Farkhodovich Uktam, Buronov Mamurjon Ugli Bunyod

Chemical Technology, Control and Management

The article presents a systematic analysis of control methods of dynamic objects under non-measurable disturbances. It is important to study all the factors affecting the control object in order to increase the efficiency of the control system. Due to the immeasurable nature of disturbances affecting control objects, it is shown that they cause negative effects and increase the complexity of control systems in this case. In the control of dynamic objects of this type, the possibilities of control by indirect measurement of disturbances or by estimation of object position and disturbances have been explored. The use cases, shortcomings and achievements …

Development Of The Computer Model Of The Waste Water Treatment Process Using Ion-Exchange Resins In The Matlab Program, Jaloliddin Abdurazzakovich Eshbobaev, Bakhodir Tajiddinovich Khamidov, Adham Tilovovich Norkobilov, Orifjon Sharipovich Kodirov

Chemical Technology, Control and Management

In this work, a mathematical model of industrial wastewater treatment technology was formed. First, wastewater treatment technologies were analyzed and the technology of ion-exchange resin treatment was selected. A water purification device using ion-exchange resins was made, and tested on the Kungrad soda plant and the results were obtained. According to these results, it was determined that the cleaning coefficient of the device is up to 98-99%. In this article, a mathematical model of a wastewater treatment device using ion-exchange resins was developed using the stoichiometric matrix method. After the mathematical model of the process was found, a graph of …

Investigating The Rheological Behavior Of A Simple Yield Stress Fluid Under Shear Flows, Francesco Accetta

Theses

Many soft materials display unique and complex rheological behavior characterized by a transition from a solid-like to a fluid-like state upon the application of a force that exceeds the threshold to flow, known as the yield stress. Yield stress fluids are found in a wide range of commonly encountered materials including microgels, emulsions, and foams, and have been widely studied by rheologists over the last several decades. Carbopol is a popular polymeric microgel system as it displays simple, non-thixotropic rheological behavior and is typically seen as an ideal yield stress fluid. Previous research has demonstrated the reproducible behavior of shear …

Optimization Of A Bioreactor, Ali Alshami

AI Assignment Library

The primary objective of this assignimentis to learn to work effectively as a team, and to design an experiment where optimization is essential.

Bacterial Extraction And Concentration From Blood Through Filtration Processes, Ryan L. Wood, Rebecca Prymak, Evelyn Welling, Alayna Bedwell, Jordan T. Wood, Damian E. Teasley, Magdalena Crofts, Hope Callister Anderson, Clifton M. Anderson, W Cameron Beard, Jacob Stepan, Alexandra Carter, William G. Pitt

Faculty Publications

Blood stream infections (BSIs) are challenging to rapidly and precisely diagnose. Current clinical diagnostic methods for BSI identification require culturing the blood sample for many hours prior to identifying the bacteria and possible antibiotic resistance. Removing the culturing step from the bacterial identification process of a BSI provides a significant reduction in the processing time, but shifts the rate-limiting step from the growth time to the concentration procedure, since CFU levels in clinical blood samples can be as low as 10 CFU/mL in blood. This study developed a novel whole blood filtration method to concentrate bacteria from a BSI without …

Synthesis And Evaluation Of Organic Additives For Copper Electroplating Of Interconnects, Yue-Hui Zhai, Yi-Xiao Peng, Yan Hong, Yuan-Ming Chen, Guo-Yun Zhou, Wei He, Peng-Ju Wang, Xian-Ming Chen, Chong Wang

Journal of Electrochemistry

Copper interconnects are essential to the functionality, performance, power efficiency, reliability, and fabrication yield of electronic devices. They are widely found in chips, packaging substrates and printed circuit boards, and are often produced by copper electroplating in an acidic aqueous solution. Organic additives play a decisive role in regulating copper deposition to fill microgrooves, and micro-vias to form fine lines and interlayer interconnects. Generally, an additive package consists of three components (brightener, suppressor, and leveler), which have a synergistic effect of super-filling on electroplating copper when the concentration ratio is appropriate. Many works of literature have discussed the mechanism of …

Transferrin-Targeted Liposomes In Glioblastoma Therapy: A Review, Paul Kawak, Nour M Al Sawaftah, William G. Pitt, Ghaleb A. Husseini

Faculty Publications

Glioblastoma (GBM) is a highly aggressive brain tumor, and its treatment is further complicated by the high selectivity of the blood–brain barrier (BBB). The scientific community is urgently seeking innovative and effective therapeutic solutions. Liposomes are a promising new tool that has shown potential in addressing the limitations of chemotherapy, such as poor bioavailability and toxicity to healthy cells. However, passive targeting strategies based solely on the physicochemical properties of liposomes have proven ineffective due to a lack of tissue specificity. Accordingly, the upregulation of transferrin receptors (TfRs) in brain tissue has led to the development of TfR-targeted anticancer therapeutics. …

Hydrodynamic Voltammetry Of Fe2+/3+ In Aqueous Deep Eutectic Solvents Towards Redox Flow Batteries, Desiree Mae Prado, Xiaochen Shen, Robert Savinell, Clemens Burda

Faculty Scholarship

Deep eutectic solvents (DESs) have recently attracted much attention as potential green electrolyte solvents for redox flow batteries. DESs are considered not only as environmentally sustainable but also economically attractive electrolytes because they can be resourced from biological feedstock (alcohols, urea, choline) and are earth-abundant and of low toxicity. Despite these advantages, DESs still have limitations in important aspects such as reactant and ion transport, which is inhibited due to hydrogen-bonding-induced viscosity. Thus, improving the transport properties of redox species in DESs is essential. In addition, we explore the quantitative addition of water to ethaline (a 1:2 choline chloride: ethylene …

Recommended Separation Distances For 1.3 Ammunition And Explosives, Clint Guymon, Ming Liu, Josephine Covino

Faculty Publications

Separation Distances are used throughout the world to protect people and assets from the potential hazardous effects from propellants, explosives, and pyrotechnics. The current separation distances for Hazard Division (HD) 1.3 substances and articles used in the United States, in some cases, may not adequately protect against the effects from heat flux and debris when those substances and articles are ignited in a confined structure. Multiple tests in such a confined scenario with HD 1.3 substances have shown that the heat flux and debris hazards could result in injury at distances beyond the current specified explosives safety separation distance (ESSD). …

The Fabrication Of Nearly Monodisperse Chiral And Achiral Plasmonic Nanostructures And Their Applications, Macayla J. Caso

LSU Doctoral Dissertations

An object is chiral when it holds no lines of symmetry. This quality naturally occurs in chemistry and biology. When an object is chiral it has a unique handedness and objects of opposite chirality are called enantiomers. The importance of handedness was brought to light in the 1960’s when a racemic mixture of thalidomide enantiomers was given to pregnant women. One enantiomer was able to treat morning sickness while the other caused severe birth defects. This case brought to light how enantiomers have unique properties from each other even though they are similar materials. With this knowledge chiral nanomaterials must …

Retracted: Fabrication And Characterization Of Wood Fiber Reinforced Polymer Composites, Firoz Ahmed, Omar Faroque, Saif Hasan, Khan Rajib Hossain, Rezaul Karim Sheikh

Al-Bahir

Wood-polymer composites (WPCs) combine the properties of wood and polymers. Creating composites involves adding plant or wood fibers as fillers to a polymer matrix. This study used mahogany and mango wood sawdust as reinforcement materials, while high-density polyethylene (HDPE) and polyvinyl chloride (PVC) were used as matrices. The investigated data in this study comprises four different (10, 20, 30, and 40) weight percentages (wt%) of mahogany and mango sawdust paired with corresponding wt% (90, 80, 70, and60) of HDPE and PVC matrices. The extrusion method produced composites with different amounts of sawdust and polymer matrices. Wood polymer composites were characterized …

Ph Gradients In Spatially Non-Uniform Ac Electric Fields Around The Charging Frequency; A Study Of Two Different Geometries And Electrode Passivation, Azade Tahmasebi, Sanaz Habibi, Jeana Collins, Ran An, Esmaeil Dehdashti, Adrienne Minerick

Michigan Tech Publications

Dielectrophoresis (DEP), a precision nonlinear electrokinetic tool utilized within microfluidic devices, can induce bioparticle polarization that manifests as motion in the electric field; this phenomenon has been leveraged for phenotypic cellular and biomolecular detection, making DEP invaluable for diagnostic applications. As device operation times lengthen, reproducibility and precision decrease, which has been postulated to be caused by ion gradients within the supporting electrolyte medium. This research focuses on characterizing pH gradients above, at, and below the electrode charging frequency (0.2–1.4 times charging frequency) in an aqueous electrolyte solution in order to extend the parameter space for which microdevice-imposed artifacts on …

Simultaneous Multistep Transformer Architecture For Model Predictive Control, Junho Park, Mohammad Reza Babaei, Samuel Arce Munoz, Ashwin N. Venkat, John Hedengren

Faculty Publications

Transformer neural networks have revolutionized natural language processing by effectively addressing the vanishing gradient problem. This study focuses on applying Transformer models to time-series forecasting and customizing them for a simultaneous multistep-ahead prediction model in surrogate model predictive control (MPC). The proposed method showcases improved control performance and computational efficiency compared to LSTM-based MPC and one-step-ahead prediction models using both LSTM and Transformer networks. The study introduces three key contributions: (1) a new MPC system based on a Transformer time-series architecture, (2) a training method enabling multistep-ahead prediction for time-series machine learning models, and (3) validation of the enhanced time …

Engineering Multifunctional Adhesive Hydrogel Patches For Biomedical Applications, Aishik Chakraborty, Shana Alexander, Wei Luo, Narisse Al-Salam, Mia Van Oirschot, Sudhir H. Ranganath, Subrata Chakrabarti, Arghya Paul

Chemical and Biochemical Engineering Publications

Traditional patches, such as sticking plaster or acrylic adhesives used for over a hundred years, lack functionality. To address this issue of poor functionality, adhesive hydrogel patches have emerged as an efficient bioactive multifunctional alternative. Hydrogels are three-dimensional, water-swellable, and polymeric materials closely resembling the native tissue architecture. The physicochemical properties of hydrogels can be modified easily, allowing them to be suitable for various biomedical applications. Moreover, adhesive properties can be imparted to hydrogels through physicochemical manipulations, making them ideal candidates for supplementing or replacing traditional sticking plaster. As a result, sticky hydrogel patches are widely used for transdermal drug …

Determination Of A Surrogate For Plutonium Electrorefining, Greg Chipman, Bryant Johnson, Suhee Choi, Chao Zhang, Michael Simpson, Devin Rappleye

Faculty Publications

Conducting research experiments on plutonium electrorefining is difficult due to the significant hazards and regulations associated with nuclear materials. Finding a surrogate for plutonium electrorefining studies would enable more fundamental research to be conducted. Potential surrogates were first identified by determining the physical properties required to conduct electrorefining at the same conditions commonly used in plutonium electrorefining, a molten metal and molten CaCl₂ at 1123 K. Ce-CeCl₃, In-InCl₃, and Pb-PbCl₂ were the only potential surrogates identified using these constraints. Sn-SnCl₂ was also tested at these same conditions. More potential surrogates were identified by …

Origin Of Capacitance In Perovskite Solar Cells: Insight Vision On The Energy Band Diagram, Ziad Khalifa, Sameh Abdellatif, Monica Roman

Chemical Engineering

In recent years, perovskite solar cells (PSCs) have made significant progress, with fast improvements in energy conversion. Although they have become incredibly efficient in a short amount of time, they still face several obstacles before becoming a viable commercial technology. Researchers spent time looking for an equivalent circuit that could describe the J-V curves of PSCs and demonstrate the physical processes of optical absorption and carrier transit. In this paper, we proposed a model of perovskite solar cells (PSCs) using SCAPS software to determine the parasitic elements and show the solar cell's behavior. A previous model of a perovskite solar …

Elucidating Self-Assembly Of Semiconducting Polymers In The Presence Of A Low Molecular Weight Gelator, Madhubhashini Lakdusinghe

Theses and Dissertations

Semiconducting polymers with a conjugated backbone are important for energy storage, conversion, and biomedical field applications. The self-assembly process of these polymers in solutions depends on the polymer concentration and quality of the solvent. The electrical properties of thin films obtained from the solution phase depend on the self-assembled process. Thin films of conjugated polymer gels with percolating networks of self-assembled structures display improved electrical conductivities. In this dissertation, we studied the impact of the secondary gel matrix formed by a low molecular weight gelator, on the self-assembly of conjugated polymers, the preservation of assembled structures in dried gel films …

Nanoscale Modeling Of Membrane Systems Under Mechanical Deformation In Traumatic Brain Injury Using Molecular Dynamics, Anh Thi Ngoc Vo

Theses and Dissertations

Neuronal membrane disruption and mechanoporation are nanoscale damage mechanisms that critically affect brain cell viability during traumatic brain injury (TBI). These nanoscale cellular impairments are elusive in experiments and necessitate in silico approaches such as molecular dynamics (MD) simulations. Implementing MD, this research aims to investigate the effects of different key factors related to membrane deformation and damage, including force field resolutions, lipid compositions, and loading conditions.

To examine the impact of force field resolution, MD deformation simulations were conducted on 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphatidylcholine (POPC) lipid bilayer membranes, using all-atom (AA), united-atom (UA), and coarse-grained Martini (CG-M) force fields. The mechanical responses …

Designing Bioinspired Materials With Tunable Structures And Properties From Natural And Synthetic Polymers, Anandavalli Varadarajan

Theses and Dissertations

Biological systems are composed of complex materials which are responsible for performing various functions, such as providing structural support, mobility, functional adaptation to the environment, damage repair, and self-healing. These complex materials display excellent mechanical properties and can rapidly adapt to external stimuli. Thus, nature inspires in terms of source materials, functions, and designs to develop new-generation structural and functional materials. Polymers (natural or synthetic) are excellent sources of developing materials to mimic the functions of soft segments in biological systems. This dissertation focuses on synthesizing and characterizing two different materials with tunable structures and properties: complexes from natural polysaccharides …

The Cosolvent And Association Effect On Polymer Behaviors, Xiangyu Zhang

Theses and Dissertations

The blending or mixing is extensively utilized in diverse processes of polymers to bring about advantageous properties, but the behavior becomes intriguing when associations are involved and multi-solvents are used. Explanations based on chemistry-specific arguments are less than satisfactory in abstracting essential features, and lack the general applicability across various systems. So, this work focuses on capturing the physical force governing the phenomenon of interest by using a generic model. Highly non-trivial behaviors of polymers are often observed in multi-solvent solutions. It is known that polymers swell and dissolve in good solvents, while they tend to collapse and aggregate in …

Tuning The Metal/Acid Functionalities In Hzsm-5 For Efficient Dehydroaromatization, Genwei Chen

Theses and Dissertations

The increasing production of natural gas liquids attracts both academia and industry to develop on-purpose techniques converting those light alkanes to value-added chemicals. Dehydroaromatization is an alternative path for light alkane conversion to produce aromatics but still lacks active and stable catalysts. This work aims at the development of efficient dehydroaromatization catalysts by tuning the metal/acid bifunctionality of the Pt/HZSM-5 catalyst. Additionally, through co-processing light alkane with ammonia during the dehydroaromatization process, this study also proposes a new reaction system that could directly link the C-N bond for nitrile synthesis.

The results suggested that the activity, selectivity, and stability of …

Discovering The Kinetic Behaviors Of Zeolites Of Mordenite, Ferrierite, Faujasite, Beta, Weixuan Huang

Theses - ALL

Fossil fuels have played a significant role in the development of nations. However, they have also given rise to various societal problems. In this context, Gamma-Valerolactone (GVL) emerges as a potential solution as a fuel additive and feedstock for the production of gasoline, jet fuel, and other products. GVL can undergo decarboxylation reactions facilitated by zeolite catalysts. Surprisingly, it has been observed that reactions taking place on different zeolites, despite having similar Brønsted acid site densities, exhibit distinct simulated initial rates. This research aims to compare the initial rate trends of mordenite and its poisoned derivatives with those of the …

Discovering The Kinetic Behaviors Of Zeolites Of Mordenite, Ferrierite, Faujasite, Beta, Weixuan Huang

Theses - ALL

Fossil fuels have played a significant role in the development of nations. However, they have also given rise to various societal problems. In this context, Gamma-Valerolactone (GVL) emerges as a potential solution as a fuel additive and feedstock for the production of gasoline, jet fuel, and other products. GVL can undergo decarboxylation reactions facilitated by zeolite catalysts. Surprisingly, it has been observed that reactions taking place on different zeolites, despite having similar Brønsted acid site densities, exhibit distinct simulated initial rates. This research aims to compare the initial rate trends of mordenite and its poisoned derivatives with those of the …

Activation Of The Renin–Angiotensin–Aldosterone System Is Attenuated In Hypertensive Compared With Normotensive Pregnancy, Robin C. Shoemaker, Marko Poglitsch, Hong Huang, Katherine Vignes, Aarthi Srinivasan, Cynthia Cockerham-Morris, Aric Schadler, John Anthony Bauer, John O'Brien

UK CARES Faculty Publications

Hypertension during pregnancy increases the risk of adverse maternal and fetal outcomes, but the mechanisms of pregnancy hypertension are not precisely understood. Elevated plasma renin activity and aldosterone concentrations play an important role in the normal physiologic adaptation to pregnancy. These effectors are reduced in patients with pregnancy hypertension, creating an opportunity to define the features of the renin–angiotensin–aldosterone system (RAAS) that are characteristic of this disorder. In the current study, we used a novel LC-MS/MS-based methodology to develop comprehensive profiles of RAAS peptides and effectors over gestation in a cohort of 74 pregnant women followed prospectively for the development …

Genesis Of The 1.45 Ga Kratz Spring Iron Oxide-Apatite Deposit Complex In Southeast Missouri, Usa: Constraints From Oxide Mineral Chemistry, Brandon Sullivan, Marek Locmelis, Bolorchimeg N. Tunnell, Cheryl M. Seeger, Marilena Moroni, Sarah Dare, Ryan Mathur, Thomas Schott

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Seven major and numerous lesser Fe oxide occurrences within the 1.47 Ga St. Francois Mountains terrane in Missouri (USA) have previously been described as iron oxide-apatite (IOA) and iron oxide-copper-gold (IOCG) deposits. Researchers speculate that these contain significant amounts of critical minerals, most notably rare earth elements and cobalt. One of the less-studied deposits in the region is the 1.455 Ga Kratz Spring deposit. The deposit consists of two steeply dipping magnetite bodies beneath 450 m of sedimentary cover. The genesis of the Kratz Spring deposit and its relationship to nearby IOA-IOCG deposits remains poorly constrained. To better understand the …

Novel Breath Collection Techniques For Detection Of Covid-19., James Morris

Electronic Theses and Dissertations

Volatile Organic Compounds (VOC) generated endogenously in the human body can be used to detect diseases that induce oxidative stress and inflammation. Breath analysis has been used for the detection of diseases such as COPD, Depression, Lung Cancer and most recently COVID-19. Methods such as Exhaled Breath Condensate (EBC), Sorbent Tubes, Solid Phase Microextraction (SPME), and silicon microreactors have shown considerable capability in extracting and concentrating trace VOC’s present in human breath. Silicon microreactors functionalized with capture agents to derivatize carbonyl compounds are effective but the overall maximum flow rate of breath sample possible during analysis is low, making direct …

Experimental And Numerical Investigation Of Fluid Flow Behavior Through Fractured Wellbore Cement, Mahya Hatambeigi

Civil Engineering ETDs

Leakage from wellbores has been a major challenge in the energy industry, leading to groundwater contamination, reduced productivity, safety hazards, and increased operating costs. Cemented annulus fractures are a common type of leakage pathway in wellbores that can form due to various physical and chemical conditions. The number of wellbore leaks continues to increase globally, making it imperative to develop a better understanding of the complex mechanisms governing fluid flow through fractured wellbore cement. Understanding the behavior of fluid flow through a leaky cemented annulus is crucial for evaluating the leakage potential and risk assessments in wellbore systems, as well …

Design And Simulation Of A Utility Oilfield Flare In Iraq/Kurdistan Region Using Cfd And Api-521 Methodology, Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper aims at reviewing and analyzing the operation and design of a utility flare in an oilfield in the Iraq/Kurdistan region. The flare supports a gas separation unit that separates 100 MMSCFD of natural gas from other liquid compounds in petroleum refining. The actual flare dimensions are 50 m high and 0.6 m diameter and works in summer where the crosswind speed is 9 m/s and a flow of 1.2 MMSCFD of treated natural gas is flaring through it. At the beginning, the flare design was performed using the API-521 recommended approach based on full operating capacity of the …