Engineering Commons^™

Synthesize Of Emulsion Polymer Latex For Sub-Grade Cbr Improvement In The Road Construction, Keba Moto, V. Julian, Syamsudin Syamsudin, T. A. Wiradi, S. R. Wijaya

Makara Journal of Technology

Synthesize of emulsion polymer latex for sub-grade CBR improvement in the road construction. Latex polymer for California Bearing Ratio (CBR) enhancement in sub-grade soil of road building has been prepared by emulsion polymerizations technique. The prepared polymer then characterize by Fourier Transform Infrared (FTIR). For application purpose, CBR test was done to the compacted polymer added-soil. The CBR test is done also for both soaked and unsoaked samples. It is found that our latex polymer is better then other imported latex polymer. For the latex polymer, which is design to have Temperatur glass (Tg) around 9.8-19.6o, indicating the formation of …

Induced Defects In Carbonaceous Materials For Hydrogen Storage, Angela D. Lueking, Caroline E. Burgess Clifford, Deepa L. Narayanan

Chemical and Biochemical Engineering Faculty Research & Creative Works

The induced defects in carbonaceous materials for hydrogen storage were studied. The effect of exfoliation was studied and the graphite nanofibers (GNF) diameter before and after exfoliation was quantified. Thermal decomposition of the GNF before and after sulfuric/nitric acid exfoliation indicated a clear loss of thermal stability. GNF exfoliation enhanced the hydrogen uptake by a factor of five compared to the untreated GNF. The amorphous carbon was reactive than GNF, and decomposed before the GNF. The higher pretreatment temperature was intended to preferentially remove amorphous carbon leaving a higher purity of exfoliated GNF.

Investigation Into The Ultrasonic Setting Of Glass Ionomer Cements : Part Ii Setting Times And Compressive Strengths, E. Twomey, Mark R. Towler, C. M. Crowley, J. Doyle, S. Hampshire

Chemical and Biochemical Engineering Faculty Research & Creative Works

The ultrasonic setting of glass ionomer cements (GIC) was discussed. It was observed that the ultrasonic setting resulted in improvements of compressive strength. An increase in the PAA molecular weight from PAA50 to PAA200 resulted in an increase in the strength, but with a further increase in the PAA molecular weight to PAA450, there was a reduction in the strength. Results show that the strength of the ultrasonically set materials after 1 day were close to the values for the 7 days chemically set samples.

Onset Of Tethered Chain Overcrowding, William Y. Chen, Joseph X. Zheng, Stephen Z. D. Cheng, Christopher Y. Li, Ping Huang, Huiming Xiong, Qing Ge, Ya Guo, Roderic P. Quirk, Bernard Lotz, Lingfeng Deng, Chi Wu, Edwin L. Thomas

College of Polymer Science and Polymer Engineering

We proposed an approach to precisely control the density of tethered chains on solid substrates using PEO-b-PS and PLLA-b-PS. As the crystallization temperature T-x increased, the PEO or PLLA lamellar crystal thickness d(L) increased as well as the reduced tethering density (σ) over tilde of the PS chains. The onset of tethered PS chains overcrowding in solution occurs at (σ) over tilde*similar to3.7-3.8 as evidenced by an abrupt change in the slope between (d(L))(-1) and T-x. This results from the extra surface free energy created by the tethered chain that starts to affect the growth barrier of the crystalline blocks.

Final Report: Engineering Design Of Stable Immobilized Enzymes For The Hydrolysis And Transesterification Of Triglycerides, Dr.Hossein Noureddini, Gustavo F. Larsen

Department of Chemical and Biomolecular Engineering: Funded Proposals

Enzyme Immobilization. Work will continue in the area of enzymatic transesterification reaction (biodiesel). Both methyl and ethyl esters will be used in this study. Unlike the chemical reaction where methanol has a clear advantage over ethanol, ethanol can be used as easily as methanol in the enzymatic reaction.
Sol/Gel Structure Modification. Work will concentrate on the effect of the vacuum procedure on pore size and distribution for the transesterification reaction. Additives such as glucose have been very effective in the hydrolysis reaction and will be explored further in the transesterification reaction.
Characterization. The developed material will be characterized for the …

Review Of The Product Development Process And Information Flow In The Manufacturing Industry: Problems And A Possible Wav Forward, E Opiyo

Tanzania Journal of Engineering and Technology (TJET)

No abstract provided.

Mathematical Simulation Of The Influence Of Volatile Ma•Rrer Cloud On Heterogeneous Ignition Of Single Coal Particles, Hassan Ratal Ambula

Tanzania Journal of Engineering and Technology (TJET)

Asimple model has been developed to predict the heterogeneous ignition temperature for single coal particles under conditions of negligible, natural and forced convections. These conditions cause different sizes Of volatile matter cloud that surround the coal particle. The model is based on the ignition Of a single coal particle heated by irradiation from spot heaters in a cold (ambient) surrounding. Energy from the particle surface oxidation, volatile matter combustion and physical heating from the spot heaters are all included in rhe particle energv balance. General ignüion criterion is used to determine the ignition point. The agreement between the experimental and …

Development Of A Multidisciplinary Engineering Foundation Spiral, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura

Engineering and Applied Science Education Faculty Publications

To operate effectively in today’s workforce engineers need to have a muti-disciplinary perspective along with substantial disciplinary depth. This broad perspective cannot be achieved by merely taking 2 or 3 engineering courses outside of the major, but rather will require a radical change in the way we educate engineers. The faculty of the School of Engineering and Applied Science at the University of New Haven have developed a new approach: the Multidisciplinary Engineering Foundation Spiral. This curricular model provides the needed mix of breadth and depth, along with the desired professional skills, by providing carefully crafted, well-coordinated curricular experiences in …

Project-Based Introduction To Engineering -- Course Assessment, Samuel Bogan Daniels, Michael Collura, Bouzid Aliane, Jean Nocito-Gobel

Engineering and Applied Science Education Faculty Publications

The School of Engineering and Applied Science at the University of New Haven has a newly developed project-based Introduction to Engineering course. This new course plays a central role in the new Multi-Disciplinary Engineering Foundation Spiral curriculum as the first semester course for all engineering freshmen. An assessment process was developed to determine the effectiveness of this project-based course, specifically with attention towards assessing attitudes, impact on retention, problem-solving and engineering foundation topics. This paper addresses the particular portion of the assessment process for the individual course projects and their contribution to the last two assessment categories.

Project-Based Introduction To Engineering - A University Core Course, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura

Engineering and Applied Science Education Faculty Publications

This paper describes a first year engineering course that is taken by both engineering and non-engineering students. The project-based Introduction to Engineering course, EAS107P, fulfills a university core curriculum elective. Although engineering students take the course during their first year, students from other majors typically elect to take the course later in their curriculum. The focus of EAS107P is to have students experience the engineering design and problem solving process in a multi-disciplinary, team-based setting. In addition to learning about design, students develop an interest in the engineering profession and build a foundation of skills for future work. An additional …

Project Planning & Development For Engineering Freshmen, Bouzid Aliane, Michael Collura, Samuel Bogan Daniels, Jean Nocito-Gobel

Engineering and Applied Science Education Faculty Publications

The nature and background of students seeking an engineering education has changed drastically in the last decade, as has the expectations of industrial employers. Many students lack the organizational skills needed for academic success. Similar organizational skills, although more advanced, are required for managing engineering projects. A new course was developed by the faculty at the School of Engineering and Applied Science at the University of New Haven. Through this course, a key component of the Multidisciplinary Engineering Foundation Spiral, seeks to promote higher retention rates, increase student motivation and begin a confidence-building transition to professional practice. Project management concepts …

Optimization Of Cell Density And Dilution Rate In Pichia Pastoris Continuous Fermentations For Production Of Recombinant Proteins, Wenhui Zhang, Chih-Ping Liu, Mehmet Inan, Michael M. Meagher

Papers in Biomolecular Engineering

This paper provides an approach for optimizing the cell density (X_c) and dilution rate (D) in a chemostat for a Pichia pastoris continuous fermentation for the extracellular production of a recombinant protein, interferon τ (INF-τ). The objective was to maximize the volumetric productivity (Q, mg INF-τ I^-1 h^-1), which was accomplished using response surface methodology (RSM) to model the response of Q as a function of X_c and D within the ranges 150 ≤ X_c ≤ 450 g cells (wet weight) l^-1 and 0.1 μm ≤ D …

Hydrazine/Nitrogen Dioxide Fiber Optic Sensor, Alfred S. Andrawis, Josephine B. Santiago, Rebecca Young, Clayton J. Baum

Chemistry and Chemical Engineering Faculty Publications

This paper outlines the development of a dual hydrazine/nitrogen dioxide (HZ/NO2) prototype fiber optic sensor utilizing an acid-base indicator that undergoes color changes depending on which gas is present. Bromothymol blue bromocresol green mixture (1/1) in hydrogel (1/1), produces a blue-green indicator for HZ and/or NO2. The sensor was tested several times over a period of eight weeks and the response was consistent and proved the feasibility of dual HZ/NO2 leak detection. Prototype sensor construction, the hardware, and the software of the electronic interrogator circuitry are briefly explained. The paper presents a summary of sensor response when exposed to 52 …

Role Of Curvature Elasticity In Sectorization And Ripple Formation During Melt Crystallization Of Polymer Single Crystals, Rujul Mehta, Wirunya Keawwattana, Andrew L. Guenthner, Thein Kyu

College of Polymer Science and Polymer Engineering

The present article focuses on theoretical elucidation of possible effect of mechanical deformation on spatio-temporal emergence of unusual polymer morphology subjected to quiescent isothermal crystallization conditions. The present theory developed is based on a phase field model consisted of non-conserved time dependent Ginzburg-Landau equation having an asymmetric double well potential in the crystal order parameter signifying metastability for crystallization, coupled with the chain tilt angle involving curvature elasticity and strain recovery potentials. Under quiescent crystallization conditions, the curvature elasticity term is needed to discern the emergence of sectorized single crystals. Upon coupling with the strain recovery potential, the numerical calculation …

Modification Of Statistical Threading In Two-Component Pseudorotaxane Melts Using The Amphiphilic Approach And Variations In The Confinement Geometry, Sagar S. Rane, Wayne L. Mattice, Coleen Pugh

College of Polymer Science and Polymer Engineering

Recently we described a coarse-grained model of poly(ethylene oxide) and then employed that model to study the amount of spontaneous threading of cyclic molecules by linear chains in the melt [C. A. Helfer, G. Xu, W. L. Mattice, and C. Pugh, Macromolecules 36, 10071 (2003)]. Since the amount of statistical threading at equilibrium is small, there is interest in identifying physical changes in the system that will increase the threading. We now use that coarse-grained model to investigate the effect on threading of various hypothetical (but feasible) modifications to the two-component system of macrocycles and linear chains in the melt, …

Novel Internally-Staged Ultrafiltration For Protein Purification, Meredith Ann Feins

Dissertations

A new ultrafiltration technique based on a multimembrane stack has been developed to fractionate proteins closer in molecular weight than conventionally possible. The technique is illustrated here by obtaining a pure protein product from a binary protein mixture. By employing membranes in series using the same membrane without any gaskets or spacers in-between, ultrafiltration is carried out to separate two proteins relatively close in molecular weight. Flat membranes, of the same molecular weight cutoff (MWCO) 30,000 or 100,000, are stacked together in the desired number, and ultrafiltration takes place. The membrane rejection of a protein is amplified with each additional …

Mathematical Modeling Of Transient State Transdermal Drug Delivery, Alison Nickol Weltner

Theses

In this work, a two-pathway mathematical model for transdermal drug delivery with iontophoresis is presented. The partial differential equations are described and then solved. An alternative, two-pathway, three-layer model is also presented, and the implications of the coefficients within the equation are discussed. Using Franz cell iontophoretic delivery data from three drug substances (amitriptyline HCl, clomipramine HCl, and nortriptyline HCl), the two-pathway model is regressed to determine the diffusion coefficient and the concentration within the skin at the drug reservoir interface. ANOVA analysis indicates a correlation between iontophoretic current and concentration of drug within the stratum corneum.

Investigation Of Adsorption And Oxidation Behavior Of Isosafrole On A Smooth Pt, Xiao-Hong Zhang, Xiao-Jing Su, Qi-Ling Zhong, Lei Zhang, De-Sheng Mei, Bin Ren, Zhong-Qun Tian

Journal of Electrochemistry

The electro-oxidation of isosafrole on a smooth platinum electrode was investigated in the non-aqueous solution. The CV curve shows two oxidation peaks and one reduction peak in the potential region between -0.5 V and 1.95 V. The relation between the oxidation and reduction peaks has been determined also by CV. The adsorption behavior of isosafrole on Pt was also investigated.

Electrocatalytic And Lifetime Studies Of Commercial Catalystsin A Pemfc, Cheng Xuan, Yan-Yun Ma, Li Qi, Cheng Peng, Ling Chen, Jun Zhao, Ying Zhang, Qin-Bai Fan

Journal of Electrochemistry

A particularly designed H-type cell was used to simulate the operating condition of a hydrogen-air proton exchange membrane fuel cell (PEMFC). The electrocatalytic activity, morphology, structure and lifetime of commercially available catalysts, carbon support platinum (Pt/C) and unsupported platinum-ruthenium (Pt-Ru), were preliminary studied by carrying out electrochemical measurements and by SEM, XRD techniques. The catalysts were simultaneously tested in the H-cell under operation, and also separately tested in a conventional electrochemical cell for comparison. It was found that the characteristic peaks of hydrogen adsorption/desorption on cyclic voltammograms shifted considerably to a more positive direction for Pt/C, while a more negative …

Study On Reduction Process Of Electrolyic Manganese Dioxide In Situ By Ultraviolet-Visible Absorption Spectroscopy, Li-Cai Zhu, Zhong-Zhi Yuan, Wei-Shan Li

Journal of Electrochemistry

The concentrationsof soluble Mn(Ⅲ) species, during the reduction ofelectrolytic MnO₂ (EMD) in alkaline solution,have been monitored in situ by UV-visible spectroscopy. The concentration of Mn(Ⅲ) ion in solution changes with discharge time. The first electron discharge process of EMD can be described by three different steps: 1) the reduction of Mn⁴⁺ ions on the surface of EMD particles and the structural defect regions within the EMD, 2) the reduction of Mn⁴⁺ ions in ramsdellite, 3)the reduction of Mn⁴⁺ ions in pyrolusite. During the second electron discharge of EMD, the soluble Mn(Ⅲ) is reduced to Mn(Ⅱ) , …

The Influence Of Strontium Substitution In Fluorapatite Glasses And Glass-Ceramics, R. G. Hill, A. Stamboulis, R. V. Law, A. Clifford, Mark R. Towler, C. Crowley

Chemical and Biochemical Engineering Faculty Research & Creative Works

Strontium is often substituted for calcium in order to confer radio-opacity in glasses used for dental cements, Biocomposites and bio glass-ceramics. The present paper investigates the influence of substituting strontium for calcium in a glass of the following composition: 4.5SiO₂3Al₂O ₃1.5P₂O₅3CaO2CaF₂, having a Ca:P ratio of 1.67 corresponding to calcium fluorapatite (Ca5(PO 4)3F). The glasses were characterized by magic angle spinning nuclear magnetic resonance (MAS-NMR), by differential scanning calorimetry (DSC) and X-ray powder diffraction (XRD). The ²⁹Si, ²⁷Al and ³¹P NMR spectra for the glasses with …

Fundamental Chemistry Of U And Pu In The Tbp-Dodecane-Nitric Acid System, Kenneth Czerwinski, Byron Bennett

Separations Campaign (TRP)

The speciation of hexavalent U and tetravalent Pu will be examined in the TBP-dodecane-nitric acid systems. This topic is chosen based on data needs for separation modeling identified by the AFCI. Emphasis will be placed on studying the influence of nitrate and acetohydroxamic acid on U and Pu speciation as well as conditions where a third phase forms in the organic phase. The organic phase will be 30% TBP in dodecane. Equal volumes of aqueous and organic phase will be used. The speciation of the actinides in the aqueous and organic phase will be determined by a number of different …

Growth And Transport Properties Of Complementary Germanium Nanowire Field Effect Transistors, Andrew B. Greytak, Lincoln J. Lauhon, Mark S. Gudiksen, Charles M. Lieber

Faculty Publications

n- and p-type Ge nanowires were synthesized by a multistep process in which axial elongation, via vapor–liquid–solid (VLS) growth, and doping were accomplished in separate chemical vapor deposition steps. Intrinsic, single-crystal, Ge nanowires prepared by Au nanocluster-mediated VLS growth were surface-doped in situ using diborane or phosphine, and then radial growth of an epitaxial Ge shell was used to cap the dopant layer. Field-effect transistors prepared from these Ge nanowires exhibited on currents and transconductances up to 850 µA/µm and 4.9 µA/V, respectively, with device yields of >85%.

Characterisation Of The Glass Fraction Of A Selection Of European Coal Fly Ashes, J. Henry, Mark R. Towler, K. T. Stanton, X. Querol, N. Moreno

Chemical and Biochemical Engineering Faculty Research & Creative Works

Fly ash largely consists of the inorganic content of coal that remains after combustion. The crystalline phases present in fly ash may form upon cooling of a molten alumino-silicate glass. This view is supported by the spherical shape of many fly ash particles, inferring that they have gone through a viscous fluid state. The amorphous content in fly ash is believed to dominate reactivity behaviour, under both alkaline and acid conditions, because glasses have a higher potential energy than the equivalent crystal structure and the variation of bond angles and distances in a glass makes the bond breakage easier. It …

A Sequential Approach To Modeling Catalytic Reactions In Packed-Bed Reactors, Jing Guo, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

A Sequential Modeling Approach is Proposed to Simulate Catalytic Reactions in Packed-Bed Reactors. the Hydrogenation of Alpha-Methylstyrene and Wet Oxidation of Phenol Are Selected as Studied Cases. the Modeling Scheme Combines a Reactor Scale Axial Dispersion Model with a Pellet Scale Model. Without Involving Any Fitting Parameters, Such an Approach Accounts for the Non-Linear Reaction Kinetics Expression and Different Types of Pellet-Liquid Wetting Contact. to Validate the Developed Modeling Scheme and the Parallel Approach Reported in the Literature, the Experimental Observations for Hydrogenation of Alpha-Methylstyrene to Cumene Have Been Employed. the Predicted Results by Both Approaches Agree Reasonably with the …

Heat Transfer In A Thin Liquid Film In The Presence Of An Electric Field, Rama Subba Reddy Gorla, Jorge E. Gatica, Bahman Ghorashi, Pijarn Ineure, Larry W. Byrd

Chemical & Biomedical Engineering Faculty Publications

Heat transfer enhancement in an evaporating thin liquid film utilizing a electric field under isothermal interfacial condition is presented. A new mathematical model subjected to van der Waals attractive forces, capillary pressure, and an electric field is developed to describe the heat transfer enhancement in the evaporating thin liquid film. The effect of the electrostatic field on the curvature of the thin film, evaporative flux, pressure gradient distribution, heat flux, and heat transfer coefficient in the thin film is presented. The results show that applying an electric field can enhance heat transfer in a thin liquid film significantly. in addition, …

Design And Simulation Of An Induction Skull Melting System, Taide Tan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Incorporating volatile actinides, mainly americium into a metallic fuel pin (MFP) has been a serious problem due to americium’s high vapor pressure. An Induction Skull Melting (ISM) system was identified by Argonne National Laboratory (ANL) as a potential furnace design to cast MFPs. Through the development of the ISM system, the nuclear waste feedstock can be melted and injected into the mold for fabricating MFPs in the advanced nuclear fuel cycles. The main phenomena in this system include: induction melting process, casting process and mass transfer process of americium. Issues related to ISM system design for casting MFPs are discussed …

Developing A Sensing System For The Measurement Of Oxygen Concentration In Liquid Pb-Bi Eutectic, Bingmei Fu, Yingtao Jiang, Jian Ma

Mechanical Engineering Faculty Research

Although liquid lead-bismuth eutectic (LBE) is a good candidate for the coolant in the subcritical transmutation blanket, it is known to be very corrosive to stainless steel, the material of the carrying tubes and the containers. Such a corrosion problem can be prevented by producing and maintaining a protective oxide layer on the exposed surface of stainless steel. The proper formation of this oxide layer critically depends on the accurate measurement and control of the oxygen concentration in the liquid LBE. YSZ (Yttria Stabilized Zirconia) oxygen sensors, using molten bismuth saturated with oxygen as the reference, have been utilized to …

Molecular-Dynamics Simulation Of The Effect Of Ions On A Liquid–Liquid Interface For A Partially Miscible Mixture, Richard L. Rowley, Kent E. Wardle, Eric Carlson, Douglas Henderson

Faculty Publications

Molecular-dynamics simulations were performed to model the effect of added salt ions on the liquid-liquid interface in a partially miscible system. Simulations of the interface between saturated phases of a model 1-hexanol + water system show a bilayer structure of 1-hexanol molecules at the interface with OH heads of the first layer directed into the water phase and the opposite orientation for the second layer. The alignment of the polar OH groups at the interface stabilizes a charge separation of sodium and chloride ions when salt is introduced into the aqueous phase, producing an electrical double layer. Chloride ions aggregate …

Silicon Based Micro Components For Use In Chemical Agent Detection, Scott R. Forrest

Doctoral Dissertations

The objective of this work was to model, fabricate and test silicon based micro components for applications in chemical agent detection. Part I deals with research done on tunable micro Fabry-Perot interferometers. These devices are designed for use in identifying chemicals that absorb radiation in the infrared range of the spectrum. Part II deals with research done on novel Layer by Layer (LbL) assembled enzyme microreactors. These devices are designed for use in identifying chemicals that absorb radiation in the ultraviolet and visible range of the spectrum.

The emphasis of Part I is on the design and modeling of Fabry-Perot …