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Articles 11101 - 11130 of 14130

Full-Text Articles in Engineering

A Mathematical Model For A Lithium-Ion Battery/Electrochemical Capacitor Hybrid System, Godfrey Sikha, Ralph E. White, Branko N. Popov Jan 2005

A Mathematical Model For A Lithium-Ion Battery/Electrochemical Capacitor Hybrid System, Godfrey Sikha, Ralph E. White, Branko N. Popov

Faculty Publications

A one-dimensional model for predicting the performance of a battery/electrochemical capacitor-hybrid system has been developed. Simulation results are presented for a LiCoO2|LiPF6 ethylene carbonate/dimethyl carbonate|carbon battery system and a Maxwell PC 10F carbon double-layer electrochemical capacitor. The current shared between the battery and the electrochemical capacitor at very short times depends on the ohmic resistances of the battery and the capacitor. As the discharge proceeds, the operating conditions such as frequency, duty ratio, and peak pulse discharge current control the current shared among parallel circuits. These parameters also determine the extent of the run time increase of …

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Fundamental Chemistry Of U And Pu In The Tbp-Dodecane-Nitric Acid System: Quarterly Report, Kenneth Czerwinski, Cynthia-May Gong, Amber Wright Jan 2005

Fundamental Chemistry Of U And Pu In The Tbp-Dodecane-Nitric Acid System: Quarterly Report, Kenneth Czerwinski, Cynthia-May Gong, Amber Wright

Separations Campaign (TRP)

The speciation of hexavalent U and tetravalent Pu will be examined in the TBPdodecane- nitric acid systems. This topic is chosen based on data needs for separation modeling identified by the AFCI. Emphasis will be placed on studying the influence of nitrate and acetohydroxamic acid on U and Pu speciation as well as conditions where a third phase forms in the organic phase. The organic phase will be 30 % TBP in dodecane. Equal volumes of aqueous and organic phase will be used. The speciation of the actinides in the aqueous and organic phase will be determined by a number …

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Large Pyroelectric Response From Reactively Sputtered Aluminum Nitride Thin Films, Everett E. Crisman, John S. Derov, Alvin J. Drehman, Otto J. Gregory Jan 2005

Large Pyroelectric Response From Reactively Sputtered Aluminum Nitride Thin Films, Everett E. Crisman, John S. Derov, Alvin J. Drehman, Otto J. Gregory

Chemical, Biomolecular, and Materials Engineering Faculty Publications

We report the pyroelectric response of c-axis oriented, undoped, wurtzite, aluminum nitride reactively sputtered onto polished silicon wafers. The voltage between a metallic contact on the AlN surface and the n+ -doped silicon substrate was monitored during pulsed infrared, radiant heating. From analysis of the data, a pyroelectric voltage coefficient, PV, in excess of 0.5 x 106 V/m/K was extracted for films in the 600 to 2500 Å thickness range.

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Characterization Of Fluoropolymer Powders Made By Supercritical Assisted Mixing With Crystalline Additives, Ntoh Atem-Tambe Jan 2005

Characterization Of Fluoropolymer Powders Made By Supercritical Assisted Mixing With Crystalline Additives, Ntoh Atem-Tambe

Theses and Dissertations

This research project investigates a new technique to efficiently mix crystalline solid additives with polymers by gentle ball milling with steel balls in the presence of carbon dioxide (C02) at 17 to 30°C and 1300 to 2500 psig. As the ball milling system is agitated, the steel balls transfer mechanical energy to the fluoropolymer and additive thereby converting them to powders. C02 is added into the chamber to expand the polymer and make it amenable to impregnation by the additive. At the end of the mixing process, a free flowing powder is produced consisting of the additive coated with fluoropolymer. …

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Experimental Investigation Of Drilling Fluid Formulations And Processing Methods For A Riser Dilution Approach To Dual Density Drilling, John Shelton Jan 2005

Experimental Investigation Of Drilling Fluid Formulations And Processing Methods For A Riser Dilution Approach To Dual Density Drilling, John Shelton

LSU Master's Theses

Oil and natural gas resources in the deepwater Gulf of Mexico are important for the U.S. economy, but development is limited by high costs. Dual density drilling concepts that result in wellbore pressure gradients similar to the natural subsurface gradients can simplify well designs and reduce costs. Riser dilution may be an economical means of achieving such a system. This system would use a low density fluid to dilute the weighted wellbore fluid and give an intermediate density fluid in the riser. Two key concerns addressed in this study are whether a drilling fluid can be formulated that will suspend …

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Zeolite And Metal Oxide Catalysts For The Production Of Dimethyl Sulfide And Methanethiol, Craig Plaisance Jan 2005

Zeolite And Metal Oxide Catalysts For The Production Of Dimethyl Sulfide And Methanethiol, Craig Plaisance

LSU Master's Theses

Metal oxide and zeolite catalysts were examined to determine their suitability for the production of methanethiol and dimethyl sulfide from the condensation of methanol and hydrogen sulfide. Fixed bed reactor experiments were used to test the catalysts in these processes. The acid sites of these catalysts were characterized by investigating the thermal desorption of 1-propanamine from these sites. It was found that WO3/ZrO2, La2O3/Al2O3, g-Al2O3, and HZSM-5 catalysts were active and selective in the production of dimethyl sulfide. On these four catalysts, the reaction converting methanol to dimethyl ether and the methanethiol disproportionation reaction were fast and close to equilibrium. …

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Mechanism Of Targeted Chemotherapeutic Delivery Using Ultrasound, Thaidra A. Gaufin, Byron K. Murray, Seiga Ohmine, Kim L. O'Neill, William G. Pitt, Briant S. Stringham Jan 2005

Mechanism Of Targeted Chemotherapeutic Delivery Using Ultrasound, Thaidra A. Gaufin, Byron K. Murray, Seiga Ohmine, Kim L. O'Neill, William G. Pitt, Briant S. Stringham

Faculty Publications

Ultrasound (US) is used to enhance and target delivery of drugs and genes to cancer tissues. The advantages of focused delivery to select tissues are manifold, but the exact mechanisms are largely unknown and need clarification to optimize delivery. The present study further defined the role of collapse cavitation in US-induced permeabilization of cell membranes and subsequent drug or gene uptake by the cell. Cavitation, defined as the collapse of micro-bubbles, produces high shear stresses and shock waves that may transiently puncture cell membranes and has been suggested as the cause of increased permeability. The hypothesis that collapsing bubbles permeabilize …

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Effects Of Pressure On Coal Pyrolysis And Char Morphology, Dong Zeng, Thomas H. Fletcher Jan 2005

Effects Of Pressure On Coal Pyrolysis And Char Morphology, Dong Zeng, Thomas H. Fletcher

Faculty Publications

A better understanding of high-pressure coal pyrolysis is needed to design advanced coal gasification combined-cycle systems. High-temperature, high-heating-rate, and high-pressure pyrolysis experiments were conducted on three bituminous coals and a lignite, to more fully understand the effects of pressure on resultant char properties. A flat-flame burner was designed and used inside a high-pressure drop-tube reactor to provide a high-temperature, high-heatingrate environment that is representative of industrial processes. Chars were prepared at four different pressures, ranging from 0.85 atm to 15 atm. The measured total volatiles yields compared well with predictions of the Chemical Percolation Devolatilization (CPD) model. The physical properties …

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Simulated Land-Based Turbine Deposits Generated In An Accelerated Deposition Facility, Jared W. Jensen, Sean W. Squire, Jeffrey P. Bons, Thomas H. Fletcher Jan 2005

Simulated Land-Based Turbine Deposits Generated In An Accelerated Deposition Facility, Jared W. Jensen, Sean W. Squire, Jeffrey P. Bons, Thomas H. Fletcher

Faculty Publications

This report presents a validation of the design and operation of an accelerated testing facility for the study of foreign deposit layers typical to the operation of land-based gas turbines. This facility was designed to produce turbine deposits in a 4-h test that would simulate 10,000 h of turbine operation. This is accomplished by matching the net foreign particulate throughput of an actual gas turbine. Flow Mach number, temperature and particulate impingement angle are also matched. Validation tests were conducted to model the ingestion of foreign particulate typically found in the urban environment. The majority of this particulate is ceramic …

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Observations Of Flame Behavior In A Laboratory-Scale Premixed Natural Gas/Air Gas Turbine Combustor From Planar Laser Induced Fluorescence Measurements Of Oh, Laser Doppler Anemometer Velocity Measurements, And Coherent Anti-Stokes Roman Spectrometer Temperature Measurements, Thomas H. Fletcher Jan 2005

Observations Of Flame Behavior In A Laboratory-Scale Premixed Natural Gas/Air Gas Turbine Combustor From Planar Laser Induced Fluorescence Measurements Of Oh, Laser Doppler Anemometer Velocity Measurements, And Coherent Anti-Stokes Roman Spectrometer Temperature Measurements, Thomas H. Fletcher

Faculty Publications

Instantaneous planar laser induced fluorescence (PLIF) images of OH, simultaneous axial/radial and axial/tangential velocity measurements with an LDA (laser Doppler anemometer), and instantaneous gas temperature measurements using a coherent anti- Stokes Raman spectrometer (CARS) were obtained in a pre-mixed, swirl-stabilized laboratory-scale combustor, fired with natural gas. Four operating conditions were examined (two swirl conditions and equivalence ratios of 0.80 and 0.65). The instantaneous PLIF images of OH illustrate the chaotic nature of the turbulent flame eddies. Mean and standard deviations of each variable were measured at different locations in the flame, along with probability density functions. Stability of the flame …

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Polymerization Kinetics Of Peo-B-Pnipaam Block Copolymers, William G. Pitt, Yi Zeng Jan 2005

Polymerization Kinetics Of Peo-B-Pnipaam Block Copolymers, William G. Pitt, Yi Zeng

Faculty Publications

Our research in ultrasonic activated drug delivery motivated us to develop polymeric micelles that sequester hydrophobic drugs (Fig. 1) until they are sheared open by cavitation events produced by low frequency ultrasound (Fig. 2). [1] Using this type of drug delivery system, micelles sequestering drug can circulate freely without releasing their drug until they flow through a tumor or other tissue insonated by low frequency ultrasound. There they release part of their drug (Fig. 3). [2,3] This drug delivery technology was used to reduce tumors in a rat model [4] using block copolymers of PEO and PPO. However, we are …

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Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole Jan 2005

Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole

Civil & Environmental Engineering Theses & Dissertations

Halonitromethanes (HNMs) are low molecular weight halogenated disinfection-by-products (DBPs) found to be formed during ozonation, chlorination, or chloramination of waters containing natural bromide ion and nitrogenous organic matter. This work identifies the absolute rate constants for the oxidative hydroxyl radical (•OH) and reductive hydrated electron e- aq extinction of HNM compounds. Three forms of HNMs included in this study are the chlorinated, brominated, and mixed halogenated compounds. Electron pulse radiolysis and transient absorption spectroscopy were used to measure •OH and e- aq radical absolute reaction rate constants for a total of nine HNMs. To elucidate the decomposition reaction …

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Participatory Evaluation And Improvement Of Cassava Processing Machines For The Eastern Zone Of Tanzania, V Silayo Dec 2004

Participatory Evaluation And Improvement Of Cassava Processing Machines For The Eastern Zone Of Tanzania, V Silayo

Tanzania Journal of Engineering and Technology (TJET)

Cassava processing machines previously introduced in Tanzania were chippers and graters of the International Institute Of Tropical Agriculture (IITA) design. Popularization of such machmes in Tanzania required thorough participatory testing with stakeholders. When tested with farmers in Muheza and Kibaha districts average throughputs were 11-18 kg/h, 752 kg/h and 270 kg/hfor the manual chipper, engine-powered chipper and the engine-powered grater, respectively. Despite their low throughputs the manual chipper and the grater were Veo difficult to operate, and therefore demanded improvement. Improvement on these machines included modifications on the design for increased throughput, ease of operation and safety. The improved machines …

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Comparative Study Of The Dynamics Of Circulating Fluidized Bed Riser And Downer Of Equal Diameters, Samwel V. Manyele Dec 2004

Comparative Study Of The Dynamics Of Circulating Fluidized Bed Riser And Downer Of Equal Diameters, Samwel V. Manyele

Tanzania Journal of Engineering and Technology (TJET)

The microscopic flow dynamics of the 100-mm internal diameter riser/downer circulating fluidized bed (CFB) unit were monitored using a solids concentration fiber optic probe. The comparison was conducted by comparing radial profiles Of the dynamic parameters derived from time-series analysis techniques (statistical and chaos analyses). The solids concentration signals used were recorded under similar operating conditions (gas velocity of 8.0 m/s and solids flux of 100 kg/m2s). Similar axial elevations were compared (entrance and fully developed sections of die reactors). A1 each loca!ion, the signals were sampled a! afrequency of 970 Hz for duration of 30 seconds. It was observed …

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Aeration Efficiency Of A Three-Phase Fluidized Bed Bioreactor During Food Industry Wastewater Treatment, S Manyele Dec 2004

Aeration Efficiency Of A Three-Phase Fluidized Bed Bioreactor During Food Industry Wastewater Treatment, S Manyele

Tanzania Journal of Engineering and Technology (TJET)

The implementation Of a three-phase fluidized bed bioreaclor (TPFBB) in food- processing wastewater (FPW'W) treatment is reported. This study includes the modification Of the air distributor (plate design and gas-liquid mixing) for the bioreactor and resting of its aeration efficiency under different liquids. The aeration efficiency for wastewater samples collected from a soft drink processing industry and tannin processing industry (TANWA T) and tap water were compared. The aeration efficiency parameters studied include bed expansion, air holdup. volumetric oxygen mass transfer coefficient, and alpha factors. The variation of these parameters With air flow rates were studied at different liquid heights, …

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Ranque–Hilsch Vortex Tube Thermocycler For Fast Dna Amplification And Real-Time Optical Detection, Ryan J. Ebmeier, Scott E. Whitney, Amitabha Sarkar, Michael Nelson, Nisha Padhye, George Gogos, Hendrik J. Viljoen Dec 2004

Ranque–Hilsch Vortex Tube Thermocycler For Fast Dna Amplification And Real-Time Optical Detection, Ryan J. Ebmeier, Scott E. Whitney, Amitabha Sarkar, Michael Nelson, Nisha Padhye, George Gogos, Hendrik J. Viljoen

Papers in Biochemical Engineering

An innovative polymerase chain reaction (PCR) thermocycler capable of performing real-time optical detection is described below. This device utilizes the Ranque–Hilsch vortex tube in a system to efficiently and rapidly cycle three 20 mL samples between the denaturation, annealing, and elon-gation temperatures. The reaction progress is displayed real-time by measuring the size of a fluo-rescent signal emitted by SYBR green/double-stranded DNA complexes. This device can produce significant reaction yields with very small amounts of initial DNA, for example, it can amplify 0.25 fg (,5 copies) of a 96 bp bacteriophage l-DNA fragment 2.731011-fold by performing 45 cycles in less than …

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A Finite Element Simulation Of Temperature And Material Flow In Fricton Stir Welding, Mark J. Lasley Dec 2004

A Finite Element Simulation Of Temperature And Material Flow In Fricton Stir Welding, Mark J. Lasley

Theses and Dissertations

The purpose of this research was to use the Transvalor S.A. product, Forge3, to develop a finite element simulation of the friction stir welding process that improves the predictability of temperature evolution and material flow within the plunge portion of the process. Previous modeling created more heating within the billet than experimental results, probably due to the simplification of the simulation with adiabatic boundary conditions. More realistic tooling temperatures were included in this model as these affect heat evolution which is a determining factor in microcrystalline growth. These results were validated by experimental efforts using a billet and tooling instrumented …

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The Effects Of Influent Debit On Hydrodynamic Characteristic Of Bojongsoang Facultative Pond: Without Wind Effects, Rositayanti Hadisoebroto, Suprihanto Notodarmojo Dec 2004

The Effects Of Influent Debit On Hydrodynamic Characteristic Of Bojongsoang Facultative Pond: Without Wind Effects, Rositayanti Hadisoebroto, Suprihanto Notodarmojo

Makara Journal of Technology

The Effects of Influent Debit on Hydrodynamic Characteristic of Bojongsoang Facultative Pond: Without Wind Effects. The performance of facultative pond in Bojongsoang WWTP have reported to be unstable. One of the cause of the unstable performance is the hydrodynamic characteristics that not met the criterion. The improper hydrodynamic characteristics are included the existence of dead-zone, the short-circuiting, and the turbulence due to eddy current. The study was to analyze the effect of the influent debit variation on the hydrodynamic characteristics of the pond using mathematical model. The two-dimensional hydrodynamic model was built from two hydrodynamic equations which are continuity and …

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Fuel Injection System For One Cylinder Motor Cycle Engine, Bambang Sugiarto Dec 2004

Fuel Injection System For One Cylinder Motor Cycle Engine, Bambang Sugiarto

Makara Journal of Technology

Fuel Injection System for One Cylinder Motor Cycle Engine. Fuel injection has been developed for many years. But its common application is limited on car’s engine. With many reason fuel injection systems in motorcycle one cylinder engine has not been widely used yet. Fuel Injection System allows the amount of fuel, injected to be controlled appropriate to engine parameters such as engine speed, amount of air inducted to cylinder, temperature, for each cycle, over the entire engine operating conditions. This fuel injection research is done to find out the Volumetric Efficiency of the intake manifold system, the amount of fuel …

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Influence Of Connection Placement To The Behavior Of Precast Concrete Exterior Beam-Column Joint, Elly Tjahjono, Heru Purnomo Dec 2004

Influence Of Connection Placement To The Behavior Of Precast Concrete Exterior Beam-Column Joint, Elly Tjahjono, Heru Purnomo

Makara Journal of Technology

Influence of Connection Placement to the Behavior of Precast Concrete Exterior Beam-Column Joint. This paper presents an experimental study on the influence of connection placement to the behaviour of exterior beamcolumn joint of precast concrete structure under semi cyclic loading. Four half-scale beam-column specimens were investigated. Three beam-columns were jointed through connection that are placed in beam-column joint region and the forth is connected at the plastic hinge potensial region of the beam. Crack patterns, strength, stiffness and ductility of the test specimens have been evaluated. The test result indicated that all beam-column specimens show good ductility behavior.

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Modelling And Simulation Of Packed Bed Catalytic Converter For Oxidation Of Soot In Diesel Powered Vehicles Flue Gas, Mohammad Nasikin, Praswasti P.D.K. Wulan, Vita Andrianty Dec 2004

Modelling And Simulation Of Packed Bed Catalytic Converter For Oxidation Of Soot In Diesel Powered Vehicles Flue Gas, Mohammad Nasikin, Praswasti P.D.K. Wulan, Vita Andrianty

Makara Journal of Technology

Modelling and Simulation of Packed Bed Catalytic Converter for Oxidation of Soot in Diesel Powered Vehicles Flue Gas. Diesel vehicle is used in Indonesia in very big number. This vehicle exhausts pollutants especially diesel soot that can be reduces by using a catalytic converter to convert the soot to CO2. To obtain the optimal dimension of catalytic converter it is needed a model that can represent the profile of soot weight, temperature and pressure along the catalytic converter. In this study, a model is developed for packed bed catalytic converter in an adiabatic condition based on a kinetic study that …

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Optic Properties On Aggase2 Polycristal Fabrication, A. Harsono Soepardjo, I Dewa Made Janusetiawan Dec 2004

Optic Properties On Aggase2 Polycristal Fabrication, A. Harsono Soepardjo, I Dewa Made Janusetiawan

Makara Journal of Technology

Optic Properties on AgGaSe2 Polycristal Fabrication. Polycristal AgGaSe2, is compound (I-III-VI2) a semiconductor as basic material for thin film for solar cell. Polycristal was succesfully grown using Bridgmann Method, heated on sequential temperature treatment until 850°C and cooled down slowly until room temperature. Results observed were in the form of ingot (bars) with more or less 3 cm length and 13 mm in diameter. By using X-Ray Fefraction, composition obtained of each element (weight %) was Ag = 29,3996 %, Ga = 36,8123 % and Se = 30,29 % while using X-Ray Difraction lattice parameter obtained/calculated a = 4,4112 Å, …

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Causes Of Proteolytic Degradation Of Secreted Recombinant Proteins Produced In Methylotrophic Yeast Pichia Pastoris: Case Study With Recombinant Ovine Interferon-T, Jayanta Sinha, Bradley A. Plantz, Mehmet Inan, Michael Meagher Dec 2004

Causes Of Proteolytic Degradation Of Secreted Recombinant Proteins Produced In Methylotrophic Yeast Pichia Pastoris: Case Study With Recombinant Ovine Interferon-T, Jayanta Sinha, Bradley A. Plantz, Mehmet Inan, Michael Meagher

Papers in Biotechnology

It was observed that during fermentative production of recombinant ovine interferon-H (r-oIFN-H ) in Pichia pastoris, a secreted recombinant protein, the protein was degraded increasingly after 48 h of induction and the rate of degradation increased towards the end of fermentation at 72 h, when the fermentation was stopped. Proteases, whose primary source was the vacuoles, was found in in-creasing levels in the cytoplasm and in the fermentation broth after 48 h of induction and reached maximal values when the batch was completed at 72 h. Protease levels at various cell fractions as well as in the culture supernatant …

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Fast Measurements Of Flow Through Mitral Regurgitant Orifices With Magnetic Resonance Phase Velocity Mapping, Haosen Zhang, Sandra S. Halliburton, Richard D. White, George P. Chatzimavroudis Dec 2004

Fast Measurements Of Flow Through Mitral Regurgitant Orifices With Magnetic Resonance Phase Velocity Mapping, Haosen Zhang, Sandra S. Halliburton, Richard D. White, George P. Chatzimavroudis

Chemical & Biomedical Engineering Faculty Publications

Magnetic-resonance (MR) phase velocity mapping (PVM) shows promise in measuring the mitral regurgitant volume. However, in its conventional nonsegmented form, MR-PVM is slow and impractical for clinical use. The aim of this study was to evaluate the accuracy of rapid, segmented k-spaceMR-PVM in quantifying the mitral regurgitant flow through a control volume (CV) method. Two segmented MR-PVM schemes, one with seven (seg-7) and one with nine (seg-9) lines per segment, were evaluated in acrylic regurgitant mitral valve models under steady and pulsatile flow. A nonsegmented (nonseg) MR-PVM acquisition was also performed for reference. The segmented acquisitions were …

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Thermodynamic Analysis Of Separation Systems, Yaşar Demirel Dec 2004

Thermodynamic Analysis Of Separation Systems, Yaşar Demirel

Papers in Thermal Mechanics

Separation systems mainly involve interfacial mass and heat transfer as well as mixing. Distillation is a major separation system by means of heat supplied from a higher temperature level at the reboiler and rejected in the condenser at a lower temperature level. Therefore, it resembles a heat engine producing a separation work with a rather low efficiency. Lost work (energy) in separation systems is due to irreversible processes of heat, mass transfer, and mixing, and is directly related to entropy production according to the Gouy-Stodola principle. In many separation systems of absorption, desorption, extraction, and membrane separation, the major irreversibility …

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The Effect Of Gas Pressure On No Conversion Energy Efficiency In Nonthermal Nitrogen Plasma, Morris D. Argyle, Gui-Bing Zhao, S.V.B. Janardhan Garikipati, Xudong Hu, Maciej Radosz Nov 2004

The Effect Of Gas Pressure On No Conversion Energy Efficiency In Nonthermal Nitrogen Plasma, Morris D. Argyle, Gui-Bing Zhao, S.V.B. Janardhan Garikipati, Xudong Hu, Maciej Radosz

Faculty Publications

This work explores the effect of gas pressure on the rate of electron collision reactions and energy consumption for NO conversion in N2 in a pulsed corona discharge reactor. A previous study showed that the rate constant of electron collision reactions, multiplied by the electron concentration, can be expressed as k[e] = βα−0.5P−0.5W0.75exp(−αP/W). The model parameter α remains constant with increasing gas pressure, which verifies the previous assumption that the electron temperature is inversely proportional to gas pressure. However, the model parameter β decreases with increasing gas pressure, which indicates that the rate constant of electron collision reactions decreases with …

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Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang Nov 2004

Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang

Journal of Electrochemistry

The electrochemical behaviours of DDAB-Hb-PME were studied in this paper. The (apparent) surface concentration of Hb was enhanced greatly by using the powder microelectrode (technique). NO reacts with Hb and absorbs on the surface of the modified carbon powder. Therefore, the output of the electrode was enhanced greatly by employing PME with higher reaction surface (area). The sensitivity of DDAB-Hb-PME is 3.1 mA/μmol·L-1·cm2, which is much larger than the values obtained with the traditional electrodes. The detection limit is 9 nmol·L-1 and the linear response range is 9～100 nmol·L-1.

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Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma Nov 2004

Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma

Journal of Electrochemistry

The air electrodes with different mass ratio of Pt/active carbon or carbon nanotube as catalyst layer material have been prepared. The electrocatalytic performances for oxygen reduction were evaluated by means of polarization curve and electrochemical impedance spectroscopy (EIS). The results disclosed that carbon nanotubes dealt with nitric acid in the catalyst layer had been improved obviously on the electrocatalytic activity. After the surface of carbon nanotube was oxygenated and aggraded with platinum, the catalyst had obviously effects on the electrocatalytic activity. The air electrode with the mass ratio of active carbon to Pt/carbon nanotube in 4∶1 showed better electrocatalytic activity, …

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Effect Of Fe3+ Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang Nov 2004

Effect Of Fe3+ Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang

Journal of Electrochemistry

Photo-catalytic titanium dioxide film in nano crystalline has been prepared by electrochemical oxidation process and adding different amount of ferric ion into the electrolyte during the anodic oxidation.The effects of Fe3+ dopen on absorption spectra and photo-catalytic of the titanium dioxide films have been studied. It shows that the Fe3+ dopen caused the red shife of the absorption edge for the incoming light and exhibited the improved photocatalytic reactivity.

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Anodic Dissolution Of Aluminum In Koh-Ethanol Solutions, Hai-Bo Shao, Jian-Ming Wang, Xiao-Yan Wang, Yi Zheng, Jian-Qing Zhang Nov 2004

Anodic Dissolution Of Aluminum In Koh-Ethanol Solutions, Hai-Bo Shao, Jian-Ming Wang, Xiao-Yan Wang, Yi Zheng, Jian-Qing Zhang

Journal of Electrochemistry

The feasibility of employing aluminum in KOH ethanol solution as a battery anode system was discussed. Weight loss measurement showed that the corrosion rate of Al is low enough to be used in sealed batteries. Through the measurements done by anodic polarization, EIS and galvanostatic discharge, it was found that Al is electrochemical active in a wide potential range in this system, and its discharge mechanism is similar to that of Al in aqueous solution. The discharge potential increased rapidly after a period of time, which might be caused by the discharge products depositing on the electrode surface.

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