Engineering Commons^™

Triboelectrostatic Separation Of Lunar Regolith, Hannah Peterson

Dissertations, Master's Theses and Master's Reports

Lunar regolith as a source of raw materials for a long-term human presence on the moon would need to be separated into single mineral fractions. To do this, triboelectric properties can be utilized to separate minerals without needing to add a working fluid, such as air and water, or expensive, consumable chemicals. A lightweight machine can be created to do this, one that also requires minimal electricity. A series of three prototypes for this machine were created and tested to determine if this concept would work, and what properties the machine would need. A mixture of magnetite and silica were …

Iron Ore Tailings Reprocessing By Electrostatic Separation Plus Two Stages Froth Flotation, Vincent Bailey Arohunmolase

Dissertations, Master's Theses and Master's Reports

The reprocessing of tailings is crucial for recovering valuable iron and reducing the environmental impact associated with tailings disposal. This study investigates the practicality of reprocessing tailings to enhance iron oxide content, combining electrostatic separation with a two-stage froth flotation process using oleic acid (direct flotation) and amine (reverse flotation). The primary goal is to efficiently recover valuable iron from tailings, thereby reducing waste and promoting sustainable resource utilization. The process aims to upgrade the iron oxide content to around 93-99% Fe₂O₃, making the recovered material suitable for the production of direct-reduced iron.

Electrostatic separation was …

Enhancement Of Intersystem Crossing In Asymmetrically Substituted Bodipy Photosensitizers, Mikhail Filatov, Tatsiana Mikulchyk, Maxine Hodee, Metodej Dvoracek, Venkata N.K. Mamillapalli, Aimee Sheehan, Craig Newman, Sergey M. Borisov, Daniel Escudero, Izabela Naydenova

Articles

We present a novel method to promote intersystem crossing (ISC) and triplet state formation in boron dipyrromethenes (BODIPYs) through the asymmetrical introduction of functional groups within the chromophore. This approach enables the development of new BODIPY photosensitizers without relying on the incorporation of heavy atoms or large electron-donating aromatic groups. Demonstrated on a series of 14 synthesized asymmetrical BODIPY (aBDP) compounds, it significantly enhances photosensitization efficiency compared to the reference symmetrical BODIPYs. In particular, the asymmetrical introduction of ethoxycarbonyl groups into pyrrolic rings of the BODIPY core lead to efficient ISC and singlet oxygen generation, with quantum yields reaching 0.76 …

Sensitivity Analysis Of Reservoir Characteristics And Flue Gas Composition For Enhanced Oil Recovery In Heterogeneous Reservoir, Mehdi Nassabeh, Zhenjiang You, Alireza Keshavarz, Stefan Iglauer

Research outputs 2022 to 2026

The success of enhanced oil recovery depends on optimizing various reservoir factors. While CO2 and flue gas injections are common methods, they encounter challenges that require a deep understanding of reservoir characteristics and thorough analysis of pertinent parameters for effective mitigation. This study aimed to explore the synergistic relationship between flue gas compositions, reservoir characteristics, and injection rates for optimal oil recovery. Unlike prior studies that primarily examined the isolated effects of CO2 or flue gas, this research uniquely investigates the combined impact of real-world flue gas compositions from industrial sources under heterogeneous reservoir conditions. Through extensive sensitivity analysis and …

Investigating The Potential Of Remote Ultraviolet Sensing For Real-Time Produced Water Monitoring: A Lab-Scale Study, M. Weir, T. Robertson, D. I. Maroef, M. L. Johns, M. Zargar

Research outputs 2022 to 2026

Traditional produced water discharge monitoring techniques involve ‘end of pipe’ sample collection and analysis, offering a snapshot of discharged fluid composition and predicting the marine environmental risk through dispersion models. This study presents a proof-of-concept analysis of using ultraviolet remote sensing for real-time produced water monitoring, enabling data capture directly within the marine environment. Ultraviolet imaging was used to quantify the sheen intensity of artificially prepared produced water standards and to evaluate the relationship between image signal intensity and total petroleum hydrocarbon concentration over time. A statistically significant relationship was observed between signal intensity and total petroleum hydrocarbon concentrations, with …

A Comparative Study Of Aluminium Properties Manufactured Using Additive Friction Stir Deposition (Afsd) And Wire Arc Additive Manufacturing (Waam), Numan Habib, Ana Vafadar, Ferdinando Guzzomi

Research outputs 2022 to 2026

Wire arc additive manufacturing (WAAM) has recently gained considerable attention due to its capability to manufacture large-size metal with a length of one meter or above, with good microstructural and mechanical properties. However, the manufacture of critical components exposed to extreme environmental conditions, such as high stresses, remains the focus of most research studies. The applications of WAAM in high-tech industries, such as aerospace and marine modes, remain limited due to metallurgical challenges such as oxidation, porosity, cracking, and deformation, especially for high-strength aluminium alloys, including 6XXX and 7XXX series. The aforementioned metallurgical challenges in WAAM are minimized to some …

3d Printing Parameter Optimisation Combined With Heat Treatment For Achieving High Density And Enhanced Performance In Refractory High-Entropy Alloys, Deyu Jiang, Miao Luo, Changxi Liu, Yashuo Zhang, Lai Chang Zhang, Kuaishe Wang, Wen Wang, Lechun Xie, Liqiang Wang, Weijie Lu, Di Zhang

Research outputs 2022 to 2026

In this study, a Ti1.5Nb1Ta0.5Zr1Mo0.5 (TNTZM) high-entropy alloy was fabricated using laser powder bed fusion (LPBF). By integrating 63 sets of parameter trials with machine learning (ML) models, an optimised process window was identified, achieving a density of up to 99.9%. The combination of relatively high laser power and low scanning speed resulted in the formation of a stable cellular structure. Subsequent heat treatments at 700, 850, and 1000°C showed that while small-angle misorientations developed at cell-wall interfaces and medium-entropy (Ti–Zr–Mo) second-phase particles precipitated preferentially in the cell walls, the overall cellular architecture remained intact. Mechanical testing showed that these …

Fatigue Properties Of 3d-Printed Polymeric Metamaterials: A Review, Ani Daniel, Hamed Bakhtiari, Alireza Nouri, Barun K. Das, Muhammad Aamir, Majid Tolouei-Rad

Research outputs 2022 to 2026

The present article provides an in-depth review of the fatigue properties of polymeric metamaterials, with particular emphasis on those manufactured using 3D printing techniques. Despite the significant potential of 3D-printed metamaterial polymers in the biomedical field, there has been limited studies dedicated to their fatigue behaviour. The article highlights the significance of fatigue behaviour in determining the reliability and longevity of polymeric materials under cyclic loading, which is crucial for biomedical applications. The effects of different 3D printing parameters, metamaterial designs, and polymer properties on fatigue life are explored. The fatigue response of metamaterials depends on material properties, geometric factors, …

From Fabrication To Function: Mechanical Insights Into Gelma Microneedle Arrays, Moloud Amini Baghbadorani, Masoumeh Zargar, Asghar Eskandarinia, Majid Tolouei-Rad

Research outputs 2022 to 2026

Gelatin methacryloyl (GelMA) has emerged as a highly suitable material for microneedle (MN) fabrication, offering exceptional biocompatibility and cost-effectiveness. Despite significant advances introduced by GelMA hydrogels, research on GelMA MNs dates back to 2019, yet no review has specifically focused on the manufacturing techniques and mechanical properties of GelMA MNs. For the first time, this review aims to examine the manufacturing methods and mechanical characteristics of GelMA microneedles across various medical applications. Additionally, it discusses different approaches to mechanical characterization and identifies gaps in current manufacturing technologies. The review also explores the potential implications of GelMA MNs in drug delivery …

Corrosion Behavior Of Niti Alloys Fabricated By Laser Powder Bed Fusion In Relation To The Formed Passive Films In Hank's Solution, Yi Fan Zhang, Liang Yu Chen, Yong Liu, Hong Yu Yang, Jin Hua Peng, Chuanbo Zheng, Lina Zhang, Lai Chang Zhang

Research outputs 2022 to 2026

Laser powder bed fusion (L-PBF) produced NiTi alloys have significant potential in biomedical applications. Varying the parameters of the L-PBF process may result in the NiTi alloys with different ratios of B2 and B19′ phases, thereby, the different corrosion performance in the human body. However, a dearth of research efforts remains dedicated to resolving this issue. This work employed three different but comparable sets of parameters in the L-PBF process to produce NiTi alloys with different ratios of B2 and B19′ phases. The corrosion behavior of samples in Hank's solutions with the addition of lactic acid and their evolution of …

Photo-Thermal Conversion Properties Of Hybrid Nh2-Mil-125/Tin/Eg Nanofluids For Solar Energy Harvesting, Seyedeh Zahra Haeri, Mehdi Khiadani, Bahram Ramezanzadeh, Hamed Kariman, Masoumeh Zargar

Research outputs 2022 to 2026

Nanofluids, engineered by dispersing nanoparticles into base fluids, have demonstrated significant potential in enhancing the performance of solar collectors. Their superior thermal conductivity and improved heat transfer properties lead to more efficient energy absorption and utilization in solar thermal systems. This study comprehensively investigated and compared the performance of ethylene glycol (EG)-based NH2-MIL-125/TiN (MIL/TiN) composite nanofluids, fabricated by a two-step method, with single-component nanofluids in photothermal utilization. The results illustrated that incorporating NH2-MIL-125 (MIL) nanoparticles enhances the stability of TiN nanofluids in EG. Additionally, the thermal conductivity and optical absorption properties of the hybrid nanofluids exhibited a positive correlation with …

A Critical Review On Parameters Affecting The Feasibility Of Underground Hydrogen Storage, Chiradip Bagchi, Samarth D. Patwardhan, Stefan Iglauer, Hisham Ben Mahmud, Muhammad Fazil Jaffar Ali

Research outputs 2022 to 2026

The need and demand for energy are ever increasing with the rapid urbanization of the global population. Near-future economic development and consequent expected industrialization are the strongest indicators of the rising energy requirement. Though fossil fuel and coal are catering toward a major chunk of energy demand, their negative or adverse impact in terms of emission of greenhouse gases (GHGs) and carbon dioxide (CO2) is causing global warming and imbalance in environmental conditions, leading to a search for commercially viable alternate energy types. As renewable energies like solar and wind are weather-dependent, the search for an alternate energy supply needs …

Determination Of Electrochemical Parameters For Predicting Reaction Mechanism And Algorithmic Approaches To Pain Assessment, Huize Xue

Dissertations

This dissertation introduces novel advancements in electrochemical kinetics and pain assessment, structured into two main parts. The first part focuses on the comprehensive analysis of the kinetic and mechanistic aspects of electrochemical reactions, utilizing a combination of experimental techniques and simulation methods. A new software tool, Envismetrics, was developed using Python to facilitate the analysis of complex electrochemical data, including cyclic voltammetry (CV), chronoamperometry (CA), and hydrodynamic voltammetry (HDV). The software was rigorously tested and validated with well-characterized redox systems such as the ferricyanide/ferrocyanide couple, dimethylamine borane (DMAB), and Per- and Polyfluoroalkyl Substances (PFAS). It was successfully used to determine …

Gas-Generating Reactive Materials: Design, Evaluation And Effect Of Morphology On Their Ignition And Combustion, Purvam Mehulkumar Gandhi

Dissertations

This work investigates optimizing gas-generating reactive materials, focusing on particle morphology's effect on ignition and combustion behavior. Metal-based gas-generating energetic materials (EMs) are promising alternatives to replace traditional CHNO compounds. Design of advanced metal-based EMs requires consistent ways of evaluating how their characteristics affect their ignition and combustion. Many relevant evaluation approaches exist; however, the results may be difficult to compare directly across different studies. Commonly, experimentalists ignite metal-based EMs in enclosed chambers and report pressures, P. However, direct comparison of these pressures is hindered by variations in the chamber volume, V, and the EM mass, m. To standardize the …

Decomposition Of Diisopropyl Methylphosphonate (Dimp) Exposed To Elevated Temperatures And Combustion Products Of Reactive Materials, Elif Irem Senyurt

Dissertations

The safe and efficient destruction of chemical weapon agents (CWAs) stockpiles remains a critical global challenge. Understanding the thermophysical properties, decomposition mechanisms, and interactions of CWAs with their environment is crucial for developing effective strategies to mitigate their threats. Diisopropyl methylphosphonate (DIMP) and Dimethyl methylphosphonate are commonly used nerve agent surrogates. This dissertation focuses on DIMP and DMMP, investigates their properties and behavior under conditions relevant to prompt defeat scenarios.

The thermophysical properties of DIMP and DMMP were experimentally characterized, including vapor-liquid surface tension (3-60 °C) and viscosities of neat and aqueous solutions. Results revealed significant non-ideal behavior in aqueous …

Development Of A Spray Pipe Evaporator For Application On Unproductive Salt Farm Land In Indonesia, Srie Muljani, Ketut Sumada, Alfian Rizki Pradana, Caecilia Pujiastuti

ASEAN Journal of Community Engagement

This article discusses the development of a prototype spray pipe evaporator and its efficiency in producing salt in Indonesia. Due to the length of the salt harvesting season in Indonesia, many salt farmers have closed their business doors, leaving many salt ponds abandoned. The spray pipe evaporator prototype was designed to produce a brine solution with a salinity of 23–24 Be from seawater, which has a salinity of 2.5–3.5 Be, in less than 3 days. This is faster than the conventional process of a brine solution salinity of 24 Be. The prototype spray pipe evaporator was assessed in a 20 …

Black Soldier Fly Larvae (Bsfl) Bioconversion For Circular Economy: A Study In Polaman Village, Siswo Sumardiono, Rizka Amalia, Syaikha Butsaina Dhiya’Ulhaq, Nurika Nazilatul Ilmi, Hermawan Dwi Ariyanto

ASEAN Journal of Community Engagement

Conventional organic waste management methods often lead to environmental degradation and underutilization of valuable resources. In rural areas, such as Polaman Village, limited awareness and inefficient disposal systems exacerbate these issues, thus necessitating innovative and sustainable solutions. This study explores black soldier fly larvae (BSFL) bioconversion as a community-based solution for organic waste management, addresses environmental challenges, and promotes economic empowerment by converting waste into valuable by-products. The study employed a mixed-methods approach, beginning with baseline assessments of waste generation and existing management practices to identify community needs. Educational workshops and hands-on training sessions introduced BSFL bioconversion techniques to local …

Single-Step Synthesis Of Activated Carbon From Arabica Spent Coffee Ground Using K2co3 As Activator Agent, Ghina Ivana Mieldan, Yuliusman Yuliusman

Journal of Materials Exploration and Findings

Activated carbon is a nanomaterial that is often used as an effective adsorbent. Activated carbon raw materials can use biomass, such as coffee grounds, which can be found along with the growth of public interest in coffee drinks. Chemical activators are used for activation to increase biomass carbon's adsorption capacity. Using K₂CO₃ activator to increase the specific surface area of activated carbon is more harmless than KOH. The use of spent coffee grounds as carbon source and food additive K₂CO₃ as an activator can make food-grade activated carbon that can be used for food. …

Strategic Site Selection For Bio-Lng Plant In Indonesia: A Multi-Criteria Scoring Method Approach, Edma Nadhif Oktariani, Yuliusman Yuliusman

Journal of Materials Exploration and Findings

In Indonesia, the energy sector is still predominantly reliant on fossil fuels, with renewable energy, including liquefied biomethane (Bio-LNG), playing a limited role. Nonetheless, Indonesia has significant potential for Bio-LNG development due to its abundant organic waste resources such as Palm Oil Mill Effluent (POME) from palm oil mills. Having approximately 891 Palm Oil Mills in Indonesia and being spread mostly in Sumatra, this study aims to select a strategic location for a Bio-LNG plant that can enhance logistical efficiency and economic viability for the plant. This study uses Multi-Criteria Decision Making (MCDM) methodologies to assess potential sites based on …

Effect Of Alkyd And Polyester Resin Compositions On Corrosion Resistance, Blistering, And Adhesion In Utilization Of Oily Sludge As Anti-Rust Coating Material, Gerets Land Kakalang, Yohanes David Kristianto, Johny Wahyuadi Mudaryoto

Journal of Materials Exploration and Findings

Oil sludge is a waste derived from upstream and downstream activities of the oil and gas industry which is estimated at 10,000 tonnes generated from all PERTAMINA downstream activities spread across various fields, processing units and depots throughout Indonesia. Oil sludge has the same characteristics as asphalt, where asphalt in previous studies can be used as an anti-rust coating, so that the handling of oily sludge can be topped up by reusing and having its own added value. The purpose of this research is to utilise waste oily sludge as an alternative anti-rust coating material and compare alkyd resin and …

Synergic Efficiency Of Organophosphonates In The Synthesis And Corrosion Inhibition Of Zinc Complexonates, Shoyunus Botir Ugli Obidov, Xusniddin Nurboboyevich Raximov, Xasan Irgashevich Kadirov, Satridin Maxamatdinovich Turabdjanov

Technical science and innovation

In this article, the processes of metal complex synthesis are studied in detail. Zinc OEDF+NTF complexation reactions were carried out in the presence of polyhydric alcohols, ethylene glycol, glycerol, and citric acid. For the first time, the synergistic efficiency of a mixture of zinc OEDF+NTF complexes with methyldiethanolamine, used as an inhibitor of mineral salt accumulation, was studied. It was found that when selecting the components in equivalent amounts, the inhibition efficiency of the composition is at least 90%. The high efficiency of inhibiting mineral salt accumulation in the composition is due to the presence of methyldiethanolamine, alkylimidazoline, and their …

All-Solid-State Sodium-Ion Batteries: A Leading Contender In The Next-Generation Battery Race, Rui-Jie Zhu, Ze-Chen Li, Wei Zhang, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui

Journal of Electrochemistry

All-solid-state lithium-ion batteries (LIBs) using ceramic electrolytes are considered the ideal form of rechargeable batteries due to their high energy density and safety. However, in the pursuit of all-solid-state LIBs, the issue of lithium resource availability is selectively overlooked. Considering that the amount of lithium required for all-solid-state LIBs is not sustainable with current lithium resources, another system that also offers the dual advantages of high energy density and safety— all-solid-state sodium-ion batteries (SIBs) —holds significant sustainable advantages and is likely to be the strong contender in the competition for developing next-generation high-energy-density batteries. This article briefly introduces the research …

Contributions To Journal Of Electrochemistry, The Flagship Journal Of Chinese Chemical Society Electrochemical Committee, Will Be Listed As A New Recommendation Policy For China Youth Awards Of Electrochemist, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Dendrite-Free Strategies For Aqueous Zinc-Ion Batteries: Structure, Electrolyte, And Separator, Gang Wu, Wu-Hai Yang, Yang Yang, Hui-Jun Yang

Journal of Electrochemistry

Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently. The development and utilization of renewable, sustainable, and clean energy sources, such as wind and solar, are crucial. However, the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent. Aqueous zinc-ion batteries (AZIBs) have received widespread attention due to their unique advantages, such as high energy density, cost-effectiveness, environmental friendliness, and safety. However, AZIBs face significant challenges, mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries, leading to battery …

Electrochemical-Method-Induced Strong Metal-Support Interaction In Pt-Cnt@Sno2 For Co-Tolerant Hydrogen Oxidation Reaction, Shen-Zhou Li, Zi-Jie Lin, Qi-An Chen, Zhao Cai, Qing Li

Journal of Electrochemistry

Inducing the classic strong metal-support interaction (SMSI) is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles (NPs) with supports. Conventional thermal reduction method for inducing SMSI processes is often accompanied by undesirable structural evolution of metal NPs. In this study, a mild electrochemical method has been developed as a new approach to induce SMSI, using the cable structured core@shell CNT@SnO₂ loaded Pt NPs as a proof of concept. The induced SnO_x encapsulation layer on the surface of Pt NPs can protect Pt NPs from the poisoned of CO impurity in …

Enriched Microbial Consortia From Natural Environments Reveal Core Groups Of Microbial Taxa Able To Degrade Terephthalate And Terphthalamide, Laura G. Schaerer, Sulihat Aloba, Emily Wood, Allison Olson, Isabel B. A. Valencia, Rebecca Ong, Stephen Techtmann

Michigan Tech Publications

Millions of tons of polyethylene terephthalate (PET) are produced each year, however only ~30% of PET is currently recycled in the United States. Improvement of PET recycling and upcycling practices is an area of ongoing research. One method for PET upcycling is chemical depolymerization (through hydrolysis or aminolysis) into aromatic monomers and subsequent biodegradation. Hydrolysis depolymerizes PET into terephthalate, while aminolysis yields terephthalamide. Aminolysis, which is catalyzed with strong bases, yields products with high osmolality, which is inhibitory to optimal microbial growth. Additionally, terephthalamide, may be antimicrobial and its biodegradability is presently unknown. In this study, microbial communities were enriched …

Influence Of Fused Deposition Modeling Process Parameters On The Constitutive Model Of Hyperelastic Thermoplastic Polyurethane, Lucas Gallup, Mohamed Trabia, Brendan O'Toole, Youssef Fahmy

Mechanical Engineering Faculty Research

Thermoplastic polyurethanes (TPUs) are suited for fused deposition modeling (FDM) of parts that require high levels of flexibility and strength. Predicting the deformation of TPU parts produced using FDM may be difficult, especially under large deformations, as their constitutive models depend on the printing process parameters. The lack of understanding led to the absence of constitutive models for TPU parts produced using FDM. This work aims to identify accurate hyperelastic constitutive models. Six groups of uniaxial tensile specimens were produced using FDM. These groups were made with variations in two process parameters, which were infill geometry and extrusion nozzle temperature. …

Determination Of The Kinetic Parameters Of Cholesterol Oxidation Using Cholesterol Oxidase From Streptomyces Sp., Meka Saima Perdani, Heri Hermansyah, Muhamad Sahlan, Dwini Normayulisa Putri, Teguh Pambudi, Anggi Khairina Hanum Hasibuan

Makara Journal of Technology

Cholesterol oxidase (CO) was successfully produced from Streptomyces sp. via the submerged fermentation method, and 69 U/mL enzyme activity was obtained. This study aimed to determine cholesterol oxidation kinetics and the production of CO as a catalyst. The enzyme was diluted to 0.15, 0.075, and 0.00375 U/mL for the oxidation reaction. The substrate was also prepared in three concentrations: 3.23, 6.46, and 12.93 mM. The optimization of conditions for enzymatic cholesterol oxidation was investigated through measurement of the effect of initial cholesterol and enzyme concentrations. Cholesterol concentration was rapidly measured via high-performance liquid chromatography (HPLC). The kinetics of CO were …

Physics-Informed Heterogeneous Spatiotemporal Graph Neural Network For Reservoir Simulation, Ahmed A.M.A. Abdullah

LSU Master's Theses

Reservoir simulation is the state-of-the-art method for predicting the flow of petroleum reservoir fluids in porous media. It provides an accurate and unbiased prediction of the performance of petroleum reservoirs under different operating conditions. Despite its advantages, reservoir simulation is computationally expensive; with typical full-field simulation models running for several hours. This limitation is worsened when simulating reservoirs with several equations for each cell, such as multiphysics or compositional reservoir simulation. The goal of this research is to provide a fast and accurate spatiotemporal machine-learning model that incorporates discretized governing mass balance equations for training. To achieve this, we propose …

Investigating Catalytic Conversion Of Lignin To Valuable Products, Jialiang Zhang

McKelvey School of Engineering Graduate Student Theses & Dissertations

Lignin is a complex, random, and heterogeneous biopolymer in lignocellulosic biomass. It has significant potential for conversion into valuable chemicals and fuels. However, its natural recalcitrant structure has made selective depolymerization challenging. This dissertation presents a detailed investigation into the mechanisms of lignin disassembly and structural evolution under various catalytic and solvent conditions. The research spans three key studies. In Chapter 2, operando magic-angle spinning (MAS) solid-state nuclear magnetic resonance (NMR) spectroscopy was employed to study reaction pathways and kinetics of lignin model polymers during catalytic hydrogenolysis. We used a Ni-Al2O3 catalyst in methanol under high temperature and pressure, and …