Engineering Commons^™

Vibrations For Improving Multiphase Contact, Yogesh G. Waghmare

LSU Doctoral Dissertations

Present work demonstrates the use of vibrations to enhance performance of two multi-phase contacting systems: a bubble column for gas-liquid contacting (physical absorption) and a Piston Oscillating Monolith Reactor (POMR) for gas-liquid-solid contacting (catalytic reactions). In a bubble column reactor, enhancements of mass transfer coefficient and gas hold up were experimentally studied for the air-water system. Mass transfer coefficient enhancements up to 500% and gas hold-up improvements up to 200% were achieved under the application of low amplitude (0.5-2.5 mm) vibration at low frequencies (0-25 Hz). A fundamental theory was developed from first principles to explain these enhancements. The theory …

Fog-Smog Reactor And Photooxidation Of Naphthalene Within The Fog Condensate In A Uv Light Setup, Neha Shrikant Damle

LSU Master's Theses

Polycyclic aromatic hydrocarbons (PAHs) form a major class of air pollutants. Naphthalene is a commonly found PAH in the atmosphere. Atmospheric fog water contains naphthalene absorbed from surrounding air. The partition coefficient of naphthalene is defined as the ratio of total naphthalene concentration in fog water to total naphthalene concentration in air. The purpose of this research was to determine the partition coefficients of naphthalene for varying reactor temperature. Fog was artificially formed in a predesigned reactor. NaCl aerosols were used as condensation nuclei for fog formation. Fog droplets were exposed to naphthalene vapors in the reactor. The reactor provided …

Experimental Study Of A Foam Flow In Horizontal Pipes: Two Flow Regimes And Its Implications, Miodrag Bogdanovic

LSU Master's Theses

Although foam has been widely used in many scientific and engineering applications, the current understanding of foam rheology in pipes is still very limited because of its complex nature. This experimental study, for the first time, investigates the flow rheology of foams in pipes by placing a special emphasis on two distinct foam flow regimes. A wide range of experimental conditions are examined in this study, which include five different surfactant formulations (Cedepal FA-406, Petrostep CG-50, Stepanform 1050, Aquet TD-600, and Ultra-Palmolive), three different surfactant concentrations (0.1, 1, and 5 wt %), two different pipe diameters (0.5 and 1 inch …

Structure Property Relationships In Electron Donating Systems For Potential Photovoltaic Applications., Jonathan Moghal

Doctoral

Conjugated polymers are considered to be one-dimensional semiconductors. In conjugated polymers single and double bonds alternatively bond the carbon atoms along the polymer chain. The loosely bound electrons determine the electronic properties of conjugated polymers. In order to utilise the properties of conjugated polymers in terms of a photovoltaic (PV) device application an acceptor material must be added. The acceptor material used in this study is used in buckminsterfullerence (C60). C60 was selected for this purpose due to its size and the fact that it can accept up to six additional electrons. Ultrafast charge transfers from a conducting polymer onto …

Process For Formation Of Cationic Poly (Lactic-Co-Glycolic Acid) Nanoparticles Using Static Mixers, Yamuna Reddy Charabudla

University of Kentucky Master's Theses

Nanoparticles have received special attention over past few years as potential drug carriers for proteins/peptides and genes. Biodegradable polymeric poly (lactic-co-glycolic acid) (PLGA) nanoparticles are being employed as non-viral gene delivery systems for DNA. This work demonstrates a scalable technology for synthesis of nanoparticles capable of gene delivery. Cationic PLGA nanoparticles are produced by emulsiondiffusion- evaporation technique employing polyvinyl alcohol (PVA) as stabilizer and chitosan chloride for surface modification. A sonicator is used for the emulsion step and a static mixer is used for dilution in the diffusion step of the synthesis. A static mixer is considered ideal for the …

Identification Of Polycyclic Aromatic Hydrocarbons In The Supercritical Pyrolysis Products Of Synthetic Jet Fuel S-8 And Methylcyclohexane, Jorge Oswaldo Ona Ruales

LSU Doctoral Dissertations

Inside the pre-combustor fuel lines of future high-speed aircraft, at supercritical conditions, hydrocarbon fuels react to form polycyclic aromatic hydrocarbons (PAH) and eventually solid deposits. These deposits can block fuel lines and lead to undesirable effects for the aircraft operation. To elucidate the pathways that lead to the formation of PAH (and ultimately, solids formation), the identification of the PAH products generated by the reactions is critical. In this context, two fuels have been analyzed: synthetic jet fuel S-8 and methylcyclohexane. Synthetic jet fuel S-8 is important due to its non-petroleum origin. Methylcyclohexane is important due to its endothermic behavior. …

Emulsification And Dispersant Properties Of Sugar Ester Glycolipid In Water In Oil And Oil In Water Emulsion., Azrah Abdul Aziz

Student Works (2010-2019)

The influence of different dispersing agent on the rheological behaviors of paraffin oil-water emulsion with addition of TiO2 for uv-protect and moisturizing active ingredient was studied. While making creams with minimal structural defects and longer storage stability, it is important that preparation conditions be optimized. Settle volume properties, Zeta potential, effective diameter and settle volume of TiO2 suspension were studied in the presence of glycolipid (DDM and Carrageenan), nonionic (PEG 10,000 and Brij 35P) as well as anionic surfactants (sodium dodecyl sulfate, SDS). In the experiments, the higher concentration of dispersing agents shows higher settle volume percentage, higher zeta potential …

Evolution Of Surface Deposits On A High-Pressure Turbine Blade—Part I: Physical Characteristics, James Edward Wammack, Jared M. Crosby, Daniel Fletcher, Jeffrey P. Bons, Thomas H. Fletcher

Faculty Publications

Turbine blade coupons with three different surface treatments were exposed to deposition conditions in an accelerated deposition facility. The facility simulates the flow conditions at the inlet to a first stage high-pressure turbine (T=1150 C, M=0.31). The combustor exit flow is seeded with dust particulate that would typically be ingested by a large utility power plant. The three coupon surface treatments included: (1) bare polished metal; (2) polished thermal barrier coating with bondcoat; and (3) unpolished oxidation resistant bondcoat. Each coupon was subjected to four successive 2 h deposition tests. The particulate loading was scaled to simulate 0.02 parts per …

Synthesis Of Iron Oxide Nanoparticles In A Counterflow Diffusion Flame Reactor, Hector Enrique Ruiz

Masters Theses

"A Counterflow Diffusion Flame (CDF) reactor was used to produce iron oxide nanoparticles. The experimental work was performed to study synthesis conditions and characterize the iron oxide nanoparticles. The parameters studied are those that control the flame structure, namely, gas flow rates and vacuum; other parameters include the precursor volume flow rate, and the relative location and temperature of the collecting probe inside the flame. Hexagonal nanoparticles were the most commonly observed shape. Hexagonal-shaped nanoparticles are mainly formed under stoichiometric conditions and with a high temperature profile in the flame. Cubic nanoparticles were also observed. The main parameter for the …

Characterization Of A Polymer Surface With Sequentially Immobilized Proteins, Anuradha Subramanian, Tarlan Mammedov, Karl E. Kador

Anuradha Subramanian Publications

To overcome the procoagulant processes on the surfaces of biomaterials, surface modifications have been undertaken to achieve hemocompatability characteristics that are comparable to the native endothelium. Our immediate goal in this paper is to design and develop strategies to inhibit thrombin activation on biomaterial surfaces. We will use biodurable polyurethane (PU) as the background polymer and synthesize biomaterial surfaces containing two immobilized recombinant proteins. To attain our objective, we have first undertaken the surface modification of biodurable polyurethane (chronoflex- AR) to enable the sequential immobilization of proteins via a bi-dentate bridge, a novel modification strategy. We have verified the creation …

Durability Of Perfluorosulfonic Acid And Hydrocarbon Membranes: Effect Of Humidity And Temperature, Vijay A. Sethuraman, John W. Weidner, Andrew T. Haug, Lesia V. Protsailo

Faculty Publications

The effect of humidity on the chemical stability of two types of membranes [i.e., perfluorosulfonic acid type (PFSA, Nafion 112) and biphenyl sulfone hydrocarbon type, (BPSH-35)] was studied by subjecting the membrane electrode assemblies (MEAs) to open-circuit voltage (OCV) decay and potential cycling tests at elevated temperatures and low inlet-gas relative humidities. The BPSH-35 membranes showed poor chemical stability in ex situ Fenton tests compared to that of Nafion membranes. However, under fuel cell conditions, BPSH-35 MEAs outperformed Nafion 112 MEAs in both the OCV decay and potential cycling tests. For both membranes, (i) at a given temperature, …

Enhanced Dielectric Properties In Single Crystal-Like Bifeo3 Thin Films Grown By Flux-Mediated Epitaxy, S.-H. Lim, M. Murakami, J. H. Yang, S.-Y. Young, Jason R. Hattrick-Simpers, M. Wuttig, L. G. Salamanca-Riba, I. Takeuchi

Faculty Publications

We have fabricated single crystal-like BiFeO₃ (BFO) thin films by flux-mediated epitaxy using pulsed laser deposition(PLD). The Bi–Cu–O flux composition and its thickness were optimized using composition spread, thickness gradient, and temperature gradient libraries. The optimized BFO thin films grown with this technique showed larger grain size of ∼2μm and higher dielectric constant in the range of 260–340 than those for standard PLD grown films. In addition, the leakage current density of the films was reduced by two orders of magnitude compared to that of standard PLD grown films.

The Role Of Filler-Matrix Interaction On Viscoelastic Response Of Biomimetic Nanocomposite Hydrogels, Alireza S. Sarvestani, Xuezhong He, Esmaiel Jabbari

Faculty Publications

The effect of a glutamic acid (negatively charged) peptide (Glu6), which mimics the terminal region of the osteonectin glycoprotein of bone on the shear modulus of a synthetic hydorgel/apatite nanocomposite, was investigated. One end of the synthesized peptide was functionalized with an acrylate group (Ac-Glu6) to covalently attach the peptide to the hydrogel phase of the composite matrix. The addition of Ac-Glu6 to hydroxyapatite (HA) nanoparticles (50 nm in size) resulted in significant reinforcement of the shear modulus of the nanocomposite (~100% increase in elastic shear modulus). The reinforcement effect of the Glu6 peptide, a sequence in the terminal region …

Parameter Estimation And Life Modeling Of Lithium-Ion Cells, Shriram Santhanagopalan, Qi Zhang, Karthikeyan Kumaresan, Ralph E. White

Faculty Publications

Lithium-ion pouch cells were cycled at five different temperatures (5, 15, 25, 35, and 45°C ), and rate capability studies were performed after every hundred cycles. The data were used with a simple physics-based model to estimate parameters that capture the capacity fade in the cell, with cycling. The weight of active material within each electrode was estimated as a function of time, using rate capability data at the C/33 rate. The C-rate for these cells is 1.656 A. The capacity fade due to the loss of active material and that due to the loss of cyclable lithium …

Thermal Model For A Li-Ion Cell, Karthikeyan Kumaresan, Godfrey Sikha, Ralph E. White

Faculty Publications

A thermal model for a lithium-ion cell is presented and used to predict discharge performance at different operating temperatures. The results from the simulations are compared to experimental data obtained from lithium-ion pouch cells. The model includes a set of parameters (and their concentration and temperature dependencies) that has been obtained for a lithium-ion cell composed of a mesocarbon microbead anode, LiCoO₂ cathode in 1 M LiPF₆ salt, in a mixture of ethylene carbonate, propylene carbonate, ethyl-methyl carbonate, and diethyl carbonate electrolyte. The parameter set was obtained by comparing the model predictions to the experimental discharge profiles obtained …

Analytical Expression For The Impedance Response For A Lithium-Ion Cell, Godfrey Sikha, Ralph E. White

Faculty Publications

An analytical expression to predict the impedance response of a dual insertion electrode cell (insertion electrodes separated by an ionically conducting membrane) is presented. The expression accounts for the reaction kinetics and double-layer adsorption processes at the electrode-electrolyte interface, transport of electroactive species in the electrolyte phase, and insertion of species in the solid phase of the insertion electrodes. The accuracy of the analytical expression is validated by comparing the impedance response predicted by the expression to the corresponding numerical solution. The analytical expression is used to predict the impedance response of a lithium-ion cell consisting of a porous LiCoO …

A Mathematical Model For A Lithium–Sulfur Cell, Karthikeyan Kumaresan, Yuriy Mikhaylik, Ralph E. White

Faculty Publications

A mathematical model is presented for a complete lithium–sulfur cell. The model includes various electrochemical and chemical (precipitation) reactions, multicomponent transport phenomena in the electrolyte, and the charge transfer within and between solid and liquid phases. A change in the porosity of the porous cathode and separator due to precipitation reactions is also included in the model. The model is used to explain the physical reasons for the two-stage discharge profiles that are typically obtained for lithium–sulfur cells.

Multiscale Dynamic Monte Carlo / Continuum Modeling Of Drying And Curing In Sol-Gel Silica Films, Xin Li

University of Kentucky Doctoral Dissertations

Modeling the competition between drying and curing processes in polymerizing films is of great importance to many existing and developing materials synthesis processes. These processes involve multiple length and time scales ranging from molecular to macroscopic, and are challenging to fully model in situations where the polymerization is non-ideal, such as sol-gel silica thin film formation. A comprehensive model of sol-gel silica film formation should link macroscopic flow and drying (controlled by process parameters) to film microstructure (which dictates the properties of the films).

This dissertation describes a multiscale model in which dynamic Monte Carlo (DMC) polymerization simulations are coupled …

Treatment Of Aqueous Waste Streams At Eli Lilly - Alternatives To Incineration, Barry Hennessy

Theses

The aim of this project was to investigate the potential to treat liquid waste (secondary) from production processes at Eli Lilly with the emphasis on minimising the volume of waste sent for thermal oxidation. In addition, the project aimed to investigate if the chosen technology was diverse and potentially capable of handling waste streams from different processes. Membrane technology was identified as one of the most suitable technologies and trials were carried out on secondary waste from three production processes. The literature review and practical thrials aswell as assessment of trial results ran from October 2003 to June 2005.

All …

Effects Of Temperature And Particle Size On Deposition In Land Based Turbines, Jared M. Crosby, Scott Lewis, Jeffrey P. Bons, Weiguo Ai, Thomas H. Fletcher

Faculty Publications

Four series of tests were performed in an accelerated deposition test facility to study the independent effects of particle size, gas temperature, and metal temperature on ash deposits from two candidate power turbine synfuels (coal and petcoke). The facility matches the gas temperature and velocity of modern first stage high pressure turbine vanes while accelerating the deposition process. Particle size was found to have a significant effect on capture efficiency with larger particles causing significant thermal barrier coating (TBC) spallation during a 4 h accelerated test. In the second series of tests, particle deposition rate was found to decrease with …

Characteristics Of Black Liquor Sprays From Gas-Assisted Atomizers In Hightemperature Environments, Andrew J. Mackrory, Dale Tree, Larry L. Baxter

Faculty Publications

Black liquor droplets in an entrained-flow gasifier that are too large or too small can cause problems in the chemical recovery process. It is therefore important in gasifier design to understand the nature of the atomized-gas spray. We used high-speed imaging to study black liquor sprays in cold and hot environments. Significant conclusions are that: 1. the droplet size distribution width is linked to the mean droplet size as for other sprays in the literature, necessitating a gasifier design that is tolerant of the distribution width associated with the target droplet size; 2. the shape of black liquor droplets is …

Evolution Of Surface Deposits On A High-Pressure Turbine Blade—Part Ii: Convective Heat Transfer, Jeffrey P. Bons, James Edward Wammack, Jared M. Crosby, Daniel Fletcher, Thomas H. Fletcher

Faculty Publications

A thermal barrier coating (TBC)-coated turbine blade coupon was exposed to successive deposition in an accelerated deposition facility simulating flow conditions at the inlet to a first stage high pressure turbine (T=1150 C, M=0.31). The combustor exit flow was seeded with dust particulate that would typically be ingested by a large utility power plant. The turbine coupon was subjected to four successive 2 h deposition tests. The particulate loading was scaled to simulate 0.02 parts per million weight (ppmw) of particulate over 3 months of continuous gas turbine operation for each 2 h laboratory simulation (for a cumulative 1 year …

Catalytic Wet Air Oxidation Of Mono Azo Dye Orange Ii: Catalyst Selection, Reaction Kinetics, And Modeling, Pinar Ozdural

Civil & Environmental Engineering Theses & Dissertations

Wastewaters generated as byproducts of dyeing processes are not treatable with conventional methods. It has been estimated that among the 900,000 tons of different dyes produced annually in the world, approximately 10–15% are lost in wastewater streams during manufacturing and processing operations. Once in rivers and streams, dyes cause major problems, such as reducing light penetration, or displaying toxic effects on aquatic life. Therefore, it is essential that dyes are removed from wastewaters before being discharged into the environment.

This study focuses on the catalytic wet air oxidation (CWAO) of Orange II, a mono azo dye used in large amounts …

Effect Of Sparger Design On Hydrodynamics Of A Gas Recirculation Anaerobic Bioreactor, Rajneesh Varma, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

The Effects of Sparger Design and Gas Flow Rate On, Gas Holdup Distribution and Liquid (Slurry) Recirculation Velocity Have Been Studied in a Surrogate Anaerobic Bioreactor Used for Treating Bovine Waste with a Conical Bottom Mixed by Gas Recirculation. a Single Orifice Sparger (SOS) and a Multi-Orifice Ring Sparger (MORS) with the Same Orifice Open Area and Gas Flow Rates (Hence the Same Process Power Input) Are Compared in This Study. the Advanced Non-Invasive Techniques of Computer Automated Tomography (CT) and Computer Automated Radioactive Particle Tracking (CARPT) Were Employed to Determine Gas Holdup, Liquid Recirculation Velocity, and the Poorly Mixed …

An Experimental And Numerical Study Of The Film Casting Process, Kenneth Aniunoh

All Dissertations

Film casting is a common industrial process used to produce polymeric films. During film casting, a polymer melt is extruded through a flat die before rapid cooling on a chill roll. The chill roll velocity is faster than the velocity at which the melt exits the die, thus the polymer melt is stretched and oriented in an extensional flow. The material properties and processing conditions have a significant impact on the process and the final thermal/mechanical properties of the film produced.
Optimization of industrial scale film casting processes is still greatly dependent on trial and error methods. Therefore, this work …

Effect Of Carbon Nanofibers On Microstructure And Properties Of Polymer Nanocomposites, Sungho Lee

All Dissertations

Nano-modifiers are typically three orders of magnitude smaller in size than their micro-counterparts. At this scale, interactions between matrix molecules and the nano-modifiers can lead to novel physical and chemical properties of the resulting nanocomposites. Carbon nanofibers (CNFs) are a class of nano-modifiers that has received significant attention recently because they have superior electrical conductivity and mechanical properties with a high aspect ratio (length over diameter). Several recent research studies have focused on enhancing electrical and mechanical performance of composites in the presence of CNFs. However, the influence of CNFs on the structure of the polymer matrix is important in …

Numerical Simulation Of Gas-Solid Dynamics In A Circulating Fluidized-Bed Riser With Geldart Group B Particles, S. Vaishali, Shantanu Roy, Satish Bhusarapu, M. (Muthanna) H. Al-Dahhan, M. P. Dudukovic

Chemical and Biochemical Engineering Faculty Research & Creative Works

Circulating Fluidized-Bed (CFB) Risers with Geldart Group B Particles Have Found Significant Application in Combustion Reactions. the Present Work Attempts to Study the Solids Flow Dynamics in a CFB Riser that is Operated with Group B Particles, using Computational Fluid Dynamics (CFD) Techniques. the Key Feature in the Present Study is that the Various Closure Schemes in the CFD Model Have Been Evaluated Against Data from Non-Invasive Experimental Techniques: Computer Automated Radioactive Particle Tracking (CARPT) for Solids Velocity Field and Computed Tomography (CT) for Solids Holdup. Since Solids Flow in a Riser is Multiscale in Character, in Addition to the …

Elastic Breakup In Uniaxial Extension Of Entangled Polymer Melts, Yangyang Wang, Pouyan Boukany, Shi-Qing Wang, Xiaorong Wang

College of Polymer Science and Polymer Engineering

Five entangled melts, with the number of entanglements per chain ranging from 25 to 160, have been studied to illustrate how cohesive strength can be overcome in either continuous or interrupted extension (i.e., during or after uniaxial stretching). The internal elastic stress due to chain deformation from imposed strain appears to be the cause of the observed yielding behavior that reveals scaling laws. The visual signature of the elastic breakup is the occurrence of nonuniform extension. The yield phenomena may be understood at a force level.

Using Science, Engineering, And Education To Address Water Supply Challenges In The Highlands Of Guatemala, Andrew Curtis Elmore, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

The Guatemalan Highlands is a Popular Destination for Non-Government Organizations Interested in Performing Relief Projects. U.S.-Based Organizations Such as Rotary International, Engineers Without Borders, and Various Religious Organizations Travel to Guatemala to Conduct Humanitarian Activities Which May Be Effective for the Short Term, But It is Not Clear that the Efforts Have a Systematic Impact. Students and Faculty at the University of Missouri-Rolla Have Systematically Studied Water Supply Issues Including Undergraduate and Graduate Research Projects and Undergraduate Engineering Courses Such as International Capstone Design. Materials Engineers Have Been Involved in the Study of Ceramic-Based Water Treatment Devices. These Microfilters Have …

The Tri-Frame Model, Elsje Pienaar, Hendrik J. Viljoen

Hendrik J. Viljoen Publications

The tri-frame model gives mathematical expression to the transcription and translation processes, and considers all three reading frames. RNA polymerases transcribe DNA in single nucleotide increments, but ribosomes translate mRNA in pairings of three (triplets or codons). The set of triplets in the mRNA, starting with the initiation codon (usually AUG) defines the open reading frame (ORF). Since ribosomes do not always translocate three nucleotide positions, two additional reading frames are accessible. The -1RF and the +1RF are triplet pairings of the mRNA which are accessed by shifting one nucleotide position in the 5’ and 3’ directions respectively. Transcription is …