Arts and Humanities Commons^™

N-Thiolated Β-Lactams: Chemistry And Biology Of A Novel Class Of Antimicrobial Agents For Mrsa, Timothy E. Long

USF Tampa Graduate Theses and Dissertations

N-Methylthio beta-lactams represent a promising new family of antibacterial agents whose in vitro activity is confined largely to Staphylococcus species, including multidrug-resistant forms of S. aureus. Originally developed in the 1980's for use as synthetic intermediates, N-methylthio beta-lactams have recently been shown in these laboratories to possess intriguing biological properties which are addressed in Chapters I-IV. In terms of the antibacterial activities, the structural features and species specificities exhibited by these compounds are unlike those of any existing family of beta-lactam drugs. The lactams seem to exert their effects intracellularly, requiring passage of the bioactive species through the …

Design And Construction Of Plasma Enhanced Chemical Vapor Deposition Reactor And Directed Assembly Of Carbon Nanotubes, Joshua David Schumacher

USF Tampa Graduate Theses and Dissertations

The goals of this research project were the design and construction of a carbon nanotube (CNT) reactor based on the plasma enhanced chemical vapor deposition (PECVD) principle and the development of a method for directed assembly of CNTs by catalyst patterning. PECVD was selected as the growth method due to the requirement of a catalyst for the growth process, thereby facilitating directed assembly and controlled diameter CNT growth at well-defined locations.

The reactor was built in accord with horizontal flow design using standard ultra high vacuum components. The controllable parameters of the reactor include sample temperature, DC plasma intensity, chamber …

Psychological Factors Associated With Skin Cancer Detection Behaviors In Individuals With A Family History Of Melanoma, Lora M. Azzarello

USF Tampa Graduate Theses and Dissertations

Current ACS guidelines recommend routine screening for cancer (ACS, 2002). Motivation to adhere to guidelines may be different for individuals with and without a family history of melanoma (Jonna, et al., 1998). Prior research examining the relationship between family history and skin cancer detection behaviors (Berwick et al., 1996; Friedman et al., 1993; Oliveria et al., 1999) have failed to utilize a theoretical framework to derive hypotheses. The purpose of the present study was to examine the utility of Protection Motivation Theory (PMT) in explaining intentions to engage in skin cancer screening (SCS) and skin self-examination (SSE). In addition, the …

Radiation Induced Degradation Pathways For Poly (Methyl Methacrylate) And Polystyrene Polymers As Models For Polymer Behavior In Space Environments, Kenneth Henry Heffner

USF Tampa Graduate Theses and Dissertations

Modeling methods are required for predicting the chemical stability of macromolecular materials used in critical spacecraft components of satellites orbiting in the high-energy radiation environment of near earth and deep space planetary magnetic belts. Methods for establishing degradation mechanisms and predicting and simulating the total absorbed dose and ionization for long term space missions are presented herein. This investigation evaluates cross-linking, main-chain scission and elimination products in a linear series of narrowly dispersed poly(methyl methacrylate) (PMMA) and polystyrene (PS) polymers. A comparison is made of the scission radiation yield (G_s) and crosslinking (G_x) predicted for the …

Substrate-Based Inhibitors Of Peptidylglycine Á-Amidating Monooxygenase (Pam) As Anti-Proliferative Drugs For Cancer, Geoffrey H. Chew

USF Tampa Graduate Theses and Dissertations

C-Terminal glycine-extended prohormones are enzymatically converted to á-amidated peptides, by peptidylglycine á-amidating monooxygenase (PAM). PAM is a bifunctional enzyme with two catalytic domains: peptidylglycine á-hydroxylating monooxygenase (PHM) and peptidylglycine peptidylglycineaminoglycolate lyase (PAL).

PAM has a significant role in the proliferation of androgen-independent prostate cancer. Thus, the inhibition of PAM could halt cancer growth. Hippurate and hippurate analogs were used as lead compounds for developing inhibitors for PAM. The hippurate analogs exhibiting the highest affinity to PAM (lowest inhibition constant) did inhibit the growth of human androgen-independent prostate cancer DU 145 cells.

Characterization And Generation Of Streaming Video Traces, John N. Shahbazian

USF Tampa Graduate Theses and Dissertations

This thesis describes two methods collectively called Time Series Generation (TSG) that can be used to generate time series inputs modeling packet loss to test IP-based streaming video software. The TSG methods create packet loss models that recreate the mean, variance, and autocorrelation signatures of an actual trace. The synthetic packet loss traces can have their inherent statistics altered, thus allowing for thorough testing of video software in ways that could not be done on actual networks. The two methods comprising TSG, which are individually called the primary and secondary method, use the principle of iterated uniformity to create a …

A Model For The Benefits Of Electronic Toll Collection System, Rajesh H. Chaudhary

USF Tampa Graduate Theses and Dissertations

Due to the degree of complexity related to measuring the advantage of establishing Electronic Toll Collection (ETC) systems, literature generally stops short of modeling an all-inclusive set of benefits of the system. In this research, a model that incorporates the impact on both the users and the society as a whole and evaluates the financial benefits over the lifespan of the ETC investment is developed.

Most of the values for the parameters used for calculating the benefits are taken from Federal Highway Administration (FHWA) and from similar studies conducted by transportation agencies, which is the setting that has motivated the …

Scheduling Of 2-Operation Jobs On A Single Machine To Minimize The Number Of Tardy Jobs, Radhika M. Yeleswarapu

USF Tampa Graduate Theses and Dissertations

This study focuses on the study of a unique but commonly occurring manufacturing problem of scheduling of customized jobs consisting of two operations on a single multi-purpose machine with the performance objective of minimizing the number of tardy jobs (jobs that are not completed by their due dates). Each customized job to be complete needs one unique operation and one common operation performed on it. We considered a static case in this work. The objective of minimizing the number of tardy jobs is considered where all jobs have equal weights and the maximum tardiness has no effect on the performance. …

Physiological Responses Of Thalassia Testudinum And Ruppia Maritima To Experimental Salinity Levels, Donna M. Berns

USF Tampa Graduate Theses and Dissertations

Thalassia testudinum, a stenohaline seagrass species, and Ruppia maritima, a euryhaline submerged aquatic vegetation species, were subjected to the same seven salinity levels (0 - 60) in a controlled environment. The response variables examined were the occurrence of leaf discoloration, plant growth rates, photosynthetic characteristics of blade segments (P_max, respiration, alpha, and I_k), and osmolality changes within the plant tissues. These response variables were measured at exposure times of one, seven, and 28 days.

Greater than 75% leaf discoloration occurred in Thalassia testudinum blades placed in 0, and 60 psu, while Ruppia maritima blades …

Design And Fabrication Of Multi – Dimensional Rf Mems Variable Capacitors, Hariharasudhan T. Kannan

USF Tampa Graduate Theses and Dissertations

In this work, a multi dimensional RF MEMS variable capacitor that utilizes electrostatic actuation is designed and fabricated on a 425um thick silicon substrate. Electrostatic actuation is preferred over other actuation mechanisms due to low power consumption. The RF MEMS variable capacitor is designed in a CPW topology, with multiple beams supported (1 - 7 beams) on a single pedestal. The varactors are fabricated using surface micromachining techniques. A 1um thick silicon monoxide (Er - 6) is used as a dielectric layer for the varactor. The movable membrane is suspended on a 2.5um thick electroplated gold pedestal. The capacitance between …

Comida Sin Frijoles No Es Comida: Evaluation Of A Type 2 Diabetes Education Program For Latinos, Danielle R. O'Connor

USF Tampa Graduate Theses and Dissertations

This thesis describes an internship for the Department of Anthropology that was part of the Florida Health Literacy Study (FHLS) conducted at the University of South Florida College of Public Health, Department of Community and Family Health in the spring and summer of 2003. The FHLS implemented Pfizer Inc.'s For Your Health program, a type 2 diabetes and hypertension education programs, at 14 community health clinics across the state of Florida. The internship was designed to elicit the experiences of 10 bilingual health educators about their experiences and their perceptions of the experiences of their Latino patients with type 2 …

Vibrofluidized Bed Drying Of Citrus Processing Residue For Byproduct Recovery, Eric A. Roe

USF Tampa Graduate Theses and Dissertations

Approximately 44% of the citrus that is processed becomes processing residue. The residue consists of the non-juice components of a citrus fruit, primarily peel and pulp, and is recovered by conversion to animal feed. The material is hygroscopic, agglomerating, has a wide particle size distribution, and must be carefully dried to avoid thermal damage to nutrients and flavors. This dissertation evaluates the possibility of utilizing a vibrofluidized bed dryer for citrus processing residue. Results demonstrate that it is possible to overcome the agglomeration difficulties associated with this material, offering an economically viable alternative processing methodology.

To properly analyze this proposed …

Self-Interference Handling In Ofdm Based Wireless Communication Systems, Tevfik Yücek

USF Tampa Graduate Theses and Dissertations

Orthogonal Frequency Division Multiplexing (OFDM) is a multi-carrier modulation scheme that provides efficient bandwidth utilization and robustness against time dispersive channels. This thesis deals with self-interference, or the corruption of desired signal by itself, in OFDM systems. Inter-symbol Interference (ISI) and Inter-carrier Interference (ICI) are two types of self-interference in OFDM systems. Cyclic prefix is one method to prevent the ISI which is the interference of the echoes of a transmitted signal with the original transmitted signal. The length of cyclic prefix required to remove ISI depends on the channel conditions, and usually it is chosen according to the worst …

Learning Average Reward Irreducible Stochastic Games: Analysis And Applications, Jun, Li

USF Tampa Graduate Theses and Dissertations

A large class of sequential decision making problems under uncertainty with multiple competing decision makers/agents can be modeled as stochastic games. Stochastic games having Markov properties are called Markov games or competitive Markov decision processes. This dissertation presents an approach to solve non cooperative stochastic games, in which each decision maker makes her/his own decision independently and each has an individual payoff function. In stochastic games, the environment is nonstationary and each agent's payoff is affected by joint decisions of all agents, which results in the conflict of interest among the decision makers.

In this research, the theory of Markov …

Using The Ablls With English Language Learners: Implications For Students And Teachers, Lorie G. Schultz

USF Tampa Graduate Theses and Dissertations

English language learners are traditionally behind in academics such as reading, math and science. Hispanics, who make up the vast majority of English language learners, tend to not enroll in pre-school or higher education, have higher dropout rates and as adults earn less than whites. Common instructional strategies used in public schools are not meeting the needs of these students. The field of TESOL (Teachers of English to Speakers of Other Languages) has typically offered a wide variety of poorly defined teaching strategies that are not based on empirical research. Within public schools, assessment tends to serve the purpose of …

Toward An Integrated Communication Theory For Celebrity Endorsement In Fund Raising, Tracie M. Domino

USF Tampa Graduate Theses and Dissertations

Throughout the history of the United States, Americans customarily have given away their money, as well as their time to serve the common good. Americans will give "to build something, to fight something, or to save something" (Fink, 1990, p. 136). They make gifts to causes, or the societal problems represented by organizational missions, that are important to them. Individuals give not only to advance a common good, but also to receive private goods, or benefits that are internal, intangible, and in some cases, tangible (Steinberg, 1989).

To create this feeling of reciprocity for prospective donors who have not actually …

Distributed Supervisory Control Of Workflows, Pranav Deshpande

USF Tampa Graduate Theses and Dissertations

The need for redesigning existing business processes to improve their efficiency makes it essential to adequately represent, study, and automate them. The WFMC defines "workflow" as computerized facilitation or automation of a business process in whole or part. It is actually a representation of the given process, which is made up of well-defined collection of activities called tasks.

Modeling and specification of a workflow involves the following steps: 1) Provide formalism for modeling and specification of workflow 2) specify the tasks together with the associated information and 3) enter the applicable business rules in form of inter-task dependencies.

Earlier …

A Vlsi Architecture For Rijndael, The Advanced Encryption Standard, Naga M. Kosaraju

USF Tampa Graduate Theses and Dissertations

The increasing application of cryptographic algorithms to ensure secure communications across virtual networks has led to an ever-growing demand for high performance hardware implementations of the encryption/decryption methods. The inevitable inclusion of the cryptographic algorithms in network communications has led to the development of several encryption standards, one of the prominent ones among which, is the Rijndael, the Advanced Encryption Standard. Rijndael was chosen as the Advanced Encryption Standard (AES) by the National Institute of Standard and Technology (NIST), in October 2000, as a replacement for the Data Encryption Standard (DES). This thesis presents the architecture for the VLSI implementation …

Kinematic Analysis And Evaluation Of Wheelchair Mounted Robotic Arms, Edward Jacob Mccaffrey

USF Tampa Graduate Theses and Dissertations

The goal of this thesis is the kinematic analysis and evaluation of wheelchair mounted robotic arms. More specifically, to address the kinematics of the wheelchair mounted robotic arm (WMRA) with respect to its ability to reach positions commonly required by an assistive device in activities of daily living (ADL).

A robotic manipulator attached to a power wheelchair could enhance the manipulation functions of an individual with a disability. In this thesis, a procedure is developed for the kinematic analysis and evaluation of a wheelchair mounted robotic arm. In addition to developing the analytical procedure, the manipulator is evaluated, and design …

The Fleeting Effects Of Retrieval Cue Attributes In The Pier2 Memory Model, Amie L. Wilbanks

USF Tampa Graduate Theses and Dissertations

Processing Implicit and Explicit Representations (PIER2) is a model of memory that makes predictions about memory performance based on the interaction of known and newly acquired information by studying how implicitly activated associates affect episodic memory. Nelson and Zhang (2000) found a significant effect of cue connectivity in a multiple regression analysis of the variables known to affect cued recall, but at that time no manipulational experiments had studied the cue connectivity effect in the laboratory. The present paper presents a series of three experiments designed to investigate the effect of cue connectivity in the context of the PIER2 memory …

Simple Models For Predicting Dune Erosion Hazards Along The Outer Banks Of North Carolina, Lauren Mckinnon Wetzell

USF Tampa Graduate Theses and Dissertations

Hurricane hazards result from the combined processes of wind, waves, storm surge, and overwash (Lennon et al., 1996). Predicting the severity of these hazards requires immense effort to quantify the processes and then predict how different coastal regions respond to them. A somewhat simpler, but no less daunting task is to begin to predict the hazards due to potential erosion of barrier islands. A four-part scale has been developed by Sallenger (2000) to provide a framework for understanding how barrier islands might respond during extreme storm events. These four regimes describe how beach and dune elevations interact with surge and …

Characterization Of Large Area Cadmium Telluride Films And Solar Cells Deposited On Moving Substrates By Close Spaced Sublimation, Vishwanath Kumar

USF Tampa Graduate Theses and Dissertations

With CdTe based photovoltaics developed by close spaced sublimation reaching efficiencies of over 16%, commercialization of this technology draws serious attention. Today large area industrial modules have not been able to produce the same performance of their laboratory counterparts. This work provides a means for understanding the various technical challenges in developing an effective deposition technology for large area processing.

The submodule process investigated provides a model for continuous and sequential processing of subsequent films. The system has a unique design and constructed with the provision for a moving transport module for the substrate transport. The process was developed to …

Characterization Of Cadmium Zinc Telluride Solar Cells, Gowri Sivaraman

USF Tampa Graduate Theses and Dissertations

Currently thin film solar cells have efficiencies in the range of 16-18%. Higher efficiencies of 20% or more can be achieved by two junction solar cells in which two p-n junctions are connected in series one on top of the other in a tandem structure. The ideal bandgaps for optimum efficiency in a tandem structure are about 1eV for the top cell and 1.7 eV for the bottom cell. Copper Indium Gallium di-Selenide (CIGS) with a bandgap of 1 eV is a suitable candidate for the bottom cell and Cadmium Zinc Telluride (CZT) with a tunable bandgap of 1.44-2.26 eV …

An Assessment Of Paired Similarities And Card Sorting, Theodore James Dwyer

USF Tampa Graduate Theses and Dissertations

Alcohol expectancies have been shown to be predictive of risk for alcohol problems. Experimental research studies have challenged participants' expectancies with the end result demonstrating a mediational effect on participant drinking. Cognitive research using priming and word recognition tasks have led to the theory that expectancies operate in an associative network. Using dissimilarities information this network has been mapped using multidimensional scaling. The current techniques for collecting dissimilarities information directly in alcohol expectancy research has been limited to the use of the paired comparisons tasks. In order to investigate the utility of a different similarities task a comparison was made …

A Mathematical Model For Colloidal Aggregation, Colleen S. O'Brien

USF Tampa Graduate Theses and Dissertations

The characterization of fine particles is an area of immense significance to many industrial endeavors. It has been estimated that 70% of all industrial processes deal with fine particles at some point in the process. A natural phenomenon occurring in these processes is colloidal aggregation. This study examines aggregation in colloidal systems in order to characterize, examine, and control this occurrence in industrial processes. The study of particle aggregation has been broken into many different areas, such as collision mechanisms, interaction energy etc, but a complete model that integrates these different aspects has never been fully realized. A new model …

Development And Testing Of A Haptic Interface To Assist And Improve The Manipulation Functions In Virtual Environments For Persons With Disabilities, Rohit Tammana

USF Tampa Graduate Theses and Dissertations

Robotics in rehabilitation provides considerable opportunities to improve the quality of life for persons with disabilities. Computerized and Virtual Environment (VE) training systems for persons with disabilities, many of which utilize the haptic feedback, have gained increasing acceptance in the recent years. Our methodology here is based on creating virtual environments connected to a haptic interface as an input device. This robotic setup introduces the advantages of the haptic rendering features in the environment and also provides tactile feedback to the patients.

This thesis aims to demonstrate the efficacy of assistance function algorithms in rehabilitation robotics in virtual environments. Assist …

Fishing-Dependent Communities On The Gulf Coast Of Florida: Their Identification, Recent Decline And Present Resilience, Yu, Huang

USF Tampa Graduate Theses and Dissertations

U.S. fisheries legislation requires National Marine Fisheries Service (NMFS) to attend to the critical social and economic issues surrounding the definition and identification of fishing communities, and to the effects that changes to the physical environment and regulatory decisions can have on such communities. To fulfil their mandate, National Marine Fisheries Service (NMFS) sponsored the research entitled "Identifying Fishing Communities in the Gulf of Mexico" to study the economic, social and cultural status of potential fishing communities along the Gulf of Mexico.

NMFS contracted the research project to Impact Assessment, Inc. to study 80 plus potential fishing communities in the …

Three Dimensional Finite Element Model For Lesion Correspondence In Breast Imaging, Yan Qiu

USF Tampa Graduate Theses and Dissertations

Predicting breast tissue deformation is of great significance in several medical applications such as surgery, biopsy and imaging. In breast surgery, surgeons are often concerned with a specific portion of the breast, e.g., tumor, which must be located accurately beforehand. Also clinically it is important for combining the information provided by images from several modalities or at different times, for the planning and guidance of interventions. Multi-modality imaging of the breast obtained by mammography, MRI and PET is thought to be best achieved through some form of data fusion technique. However, images taken by these various techniques are often obtained …

Transport And Survival Of Water Quality Indicator Microorganisms In The Ground Water Environment Of Florida: Implications For Aquifer Storage And Waste Disposal, David E. John

USF Tampa Graduate Theses and Dissertations

Ground water resources are heavily used for drinking water supply and often as a receptacle for waste water. One concern is the possible contamination of wetland areas by ground water receiving septic system infiltration. To investigate this, two tracer studies were performed using the bacteriophage PRD-1 by seeding septic systems adjacent to wetlands with the phage and monitoring migration towards wetland areas. Transport velocities were evaluated based on appearance of tracer in sampling wells at various distances from the injection point. Velocities were estimated to be 0.25 m/d and 0.4 m/d at the two sites. Some retardation with respect to …

Homosocial, Homoerotic, Bisexual, And Androgynous Bonds In Shakespeare’S Comedies, Klarisa Sokolovic-Cizmek

USF Tampa Graduate Theses and Dissertations

In the thesis I inquire into the nature of the same-sex bonds in Shakespeare’s comedies. I discuss seven pairs of characters and demonstrate how in his comedies, Shakespeare first created homosocial relationships, later homoerotic relationships, then bisexual relationships, and, finally, a couple that may be described as androgynous. I demonstrate that in the early comedies the relationships are primarily homosocial and serve the purpose of self-realization. The self-realization includes reaching of a balance between a “feminine,” and a “masculine” self, with the goal of becoming a mature, androgynous human being. Although there are some homoerotic undercurrents in both the male …