Arts and Humanities Commons^™

Development Of Cadmium Selenide As An Absorber Layer For Tandem Solar Cells, Sathyaharish Jeedigunta

USF Tampa Graduate Theses and Dissertations

Cadmium Selenide is a binary compound. It has a band gap of 1.7 eV. This is one of the suitable materials for an absorber layer in the top cell of a tandem solar cell. CIGS with a low Gallium content has a band gap of 1 eV suits well as an absorber layer for the bottom cell. CIGS cells have already attained an efficiency of 15% [1,2]. Since years, research has been done in developing the bottom cell. The results of the bottom cell are promising. So the fabrication of an efficient top cell in a tandem solar cell is …

Personality And Motivational Characteristics Of The Successful Mentor, Lizzette Lima

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to investigate the relationship between mentor characteristics (i.e., motivational tendencies, personality traits), mentoring provided, and protégé outcomes. A motivational approach was taken, in the sense that motives to mentor, as well as personality characteristics of the mentor, were considered in regard to their ability to predict the type of mentoring provided and outcomes for the protégé. Specifically, the potential relationships between personality traits (Intrinsic Motivation, Learning Goal Orientation, Conscientiousness, Extraversion, Agreeableness, and Machiavellianism) and mentor motives, as well as the provision of career and psychosocial mentoring, were examined. In addition, the current study examined …

The Interaction Between Victim Race And Gender On Capital Sentencing Outcomes: An Exploration Of Previous Research, Amy Reckdenwald

USF Tampa Graduate Theses and Dissertations

This study is an exploration and extension of previous research on the interactive effects of victim-race and victim-gender on death sentence outcomes. Williams and Holcomb's (2004) study suggests that an interactive effect exists between victim-race and victim-gender on Ohio death sentencing outcomes, such that killers of White women are especially singled out for capital punishment. The current study analyzes a sample of death eligible cases at the trial level in North Carolina to determine if Williams & Holcomb's findings hold up for a different sample of cases and in a different state. Logistic regression is used to determine if there …

Supramolecular Metal-Organic And Organic Materials, Elisabeth Rather

USF Tampa Graduate Theses and Dissertations

The rational design of functional solids based upon the development of strategies for controlling intermolecular interactions and structural arrangement of simple molecular building units, represents a salient feature in the context of supramolecular chemistry and crystal engineering. Consideration of chemical functionality, geometrical capability and knowledge of the interplay between two or more sets of supramolecular interactions specific of preselected chemical components will facilitate further extension of crystal engineering towards the construction of supramolecular materials possessing valuable properties.

Calixarenes represent excellent building blocks for the design of solid-state architectures, in particular calix-4-arenes crystallize easily and the introduction of a wide range …

Alternative Formulations Of Joint Model Systems Of Departure Time Choice And Mode Choice For Non-Work Trips, Constantinos A. Tringides

USF Tampa Graduate Theses and Dissertations

Modeling travel demand by time of day is gaining increasing attention in travel demand forecasting practice. This is because time of day choice has important implications for mode choice and for quantifying potential modal and time of day shifts in response to traffic congestion and peak period travel demand management strategies. In this context, understanding the causal relationship between time of day (departure time) choice and mode choice behavior would be useful in the development of time of day based travel demand modeling systems both within the four-step modeling paradigm and within newer tour-based and activity-based microsimulation paradigms. This thesis …

Investigation Of Oxide Thickness Dependence Of Fowler-Nordheim Parameter B, Shashank Bharadwaj

USF Tampa Graduate Theses and Dissertations

During recent years the thickness of the gate oxide has been reduced considerably. The progressive miniaturization of devices has caused several phenomena to emerge such as quasi-breakdown, direct tunneling and stress induced leakage currents. Such phenomena significantly modify the performance of the scaled-down MOSFETs. As a part of this research work, an effort has been made to study the performance and characteristics of the thin Gate oxide for MOSFETs and Tunnel Oxide for Floating Gate (FG) MOS devices. The exponential dependence of tunnel current on the oxide-electric field causes some critical problems in process control. A very good process control …

Development Of Structural Equations Models Of Statewide Freight Flows, Siva S. Jonnavithula

USF Tampa Graduate Theses and Dissertations

The modeling of freight travel demand has gained increasing attention in the recent past due to the importance of efficient and safe freight transportation to regional economic growth. Despite the attention paid to the modeling of freight travel demand, advances in modeling methods and the development of practical tools for forecasting freight flows have been limited. The development of freight demand models that incorporate the behavioral aspects of freight demand face significant hurdles, partially due to the data requirements, which are a consequence of the inherent complexity of the mechanisms driving freight demand. This research attempts to make a contribution …

Phase Imaging Digital Holography For Biological Microscopy, Daniel Parshall

USF Tampa Graduate Theses and Dissertations

We apply the techniques of digital holography to obtain microscopic 3D images of biological cells. Both the amplitude and phase images are obtained from a single hologram, with approximately 1 [mu]m lateral and 10 nm longitudinal resolution. The results are combined with previous experiments resolving the 2 [pi] ambiguity to produce continuous phase images of the samples.

Distribution, Metabolism And Trophic Ecology Of The Antarctic Cydippid Ctenophore, Callianira Antarctica, West Of The Antarctic Peninsula, Kerri M. Scolardi

USF Tampa Graduate Theses and Dissertations

The distribution, abundance, chemical composition, metabolism, and feeding ecology of the tentaculate ctenophore, Callianira antarctica (Chun 1897), were investigated during austral winter 2001and autumn & winter 2002, in the vicinity of Marguerite Bay west of the Antarctic Peninsula. Callianira antarctica had a widespread distribution during autumn and winter, and variable abundance (0.02 to 2.6 ind. m-2) during winter 2001 associated with specific circulation features. Size frequency distributions for autumn and winter suggest that more than half of the C. antarctica population may have experienced 'degrowth' during winter due to low food availability. Callianira antarctica is a fairly robust ctenophore with …

Risk Factors For Pediatric Community Acquired Methicillin Resistant Staphylococcus Aureus, Melissa Gail Kessler

USF Tampa Graduate Theses and Dissertations

Methicillin-Resistant Staphylococcus aureus (MRSA) began as a nosocomial infection due to overuse of antibiotics. Several previous studies have reported an increase in this infection in adult patients who have not been hospitalized. It has also been reported that there is an increase in MRSA in children. Some of these children became infected even though they were not at high risk for the infection. After approval from the All Children's Hospital Institutional Review Board (IRB), a cross sectional study was conducted with pediatric admissions and pediatric emergency room visits to determine the characteristics of Methicillin-Sensitive Staphylococcus aureus and MRSA. During this …

Synthesis And Characterization Of Potential Drug Delivery Systems Using Nonionic Surfactant “Niosome”, Sukit Leekumjorn

USF Tampa Graduate Theses and Dissertations

Niosomes are synthetic microscopic vesicles consisting of an aqueous core enclosed in a bilayer consisting of cholesterol and one or more nonionic surfactants. They are made of biocompatible, biodegradable, non-toxic, non-immunogenic and non-carcinogenic agents which form closed spherical structures (self assembly vesicles) upon hydration. With high resistance to hydrolytic degradation, niosomes are capable of entrapping many kinds of soluble drugs while exhibiting greater vesicle stability and longer shelf life.

In this work, a potential drug delivery system has been designed, synthesized and characterized. For the synthesis of niosomes, a hydration process was developed with varying design parameters such as mass …

Indium Oxide As A High Resistivity Buffer Layer For Cdte/Cds Thin Film Solar Cells, Umamaheswari Balasubramanian

USF Tampa Graduate Theses and Dissertations

Transparent conductive oxides are an essential part of technologies that require both large-area electrical contact and optical access in the visible portion of the light spectrum.

SnO₂ doped with Fluorine (SnO₂: F) and In₂O₃ doped with tin (ITO) are the most popular choices of front contacts for CdTe solar cells. In this thesis, CdS/CdTe devices were fabricated with SnO₂: F (MOCVD) and ITO (sputtering) as front contacts without a high resistivity (resistivity relatively greater than front contact) buffer layer. The device characteristics of these devices were low but improved considerably after the …

Important Extrema Of Time Series: Theory And Applications, Harith Suman Gandhi

USF Tampa Graduate Theses and Dissertations

We describe techniques for fast compression of time series and hierarchical indexing of compressed series based on the assignment of importance levels to the extrema of time series and their derivatives. We formalize the distance functions used in compression and retrieval techniques. We describe retrieval techinques that use the developed compression and indexing techniques for fast retreval of series from a database that match a given pattern.

A Vhdl Implemetation Of The Advanced Encryption Standard-Rijndael Algorithm, Rajender Manteena

USF Tampa Graduate Theses and Dissertations

The National Institute of Standards and Technology (NIST) has initiated a process to develop a Federal information Processing Standard (FIPS) for the Advanced Encryption Standard (AES), specifying an Advanced Encryption Algorithm to replace the Data Encryption standard (DES) the Expired in 1998. NIST has solicited candidate algorithms for inclusion in AES, resulting in fifteen official candidate algorithms of which Rijndael was chosen as the Advanced Encryption Standard.

The Advanced Encryption Standard can be programmed in software or built with pure hardware. However Field Programmable Gate Arrays (FPGAs) offer a quicker, more customizable solution. This research investigates the AES algorithm with …

The Antidepressant Drug Tianeptine Blocks Working Memory Errors: Pharmacological And Endocrine Manipulations Of Stress-Induced Amnesia In Rats, Adam Marc Campbell

USF Tampa Graduate Theses and Dissertations

Stress has been shown to influence learning and memory in humans and rats (Diamond et al, 1996; Diamond et al, 1999; Krugers et al, 1997; Kirschbaum et al, 1996; Lupien et al, 1997). The hippocampus and is an area of the brain involved in memory function in humans and rats (Kirschbaum et al, 1996; Lupien et al, 1997) and is highly susceptible to stress (Diamond et al, 1990). Research has indicated that a number of stressors such as exposure to a predator (Diamond et al, 1999) can lead to stress effects. Recently efforts have been made to counteract the effects …

The Social Construction Of Workplace "Diversity", Brenda G. Shawver

USF Tampa Graduate Theses and Dissertations

This is a study of "workplace diversity" from a social constructionist perspective. The perspective holds that while human meaning is socially created, it is the social order which gives us resources for making this meaning. There is much literature about workplace diversity from objectivist standpoints that takes for granted the term "diversity." What is missing is a comprehensive understanding of diversity: what does this term mean? What does it conceal? I attempt to contribute to a better understanding of diversity by interrogating its construction in popular culture.

I analyze the content of an advertising supplement called "Diversity Works," published in …

Synthesis Of Nanoscale Structures In Single Crystal Silicon Carbide By Electron Beam Lithography, Jay A. Bieber

USF Tampa Graduate Theses and Dissertations

Nanostructures were formed on diced specimens of several silicon carbide polytypes and silicon using electron beam lithography. A general introduction to nanostructure synthesis and electron beam lithography,are presented. A scanning electron microscope was retrofitted with a commercially available electron beam lithography package and an electrostatic beam blanker to permit nanoscale lithography to be performed.

A process was first developed and optimized on silicon substrates to expose, poly-methyl-methacrylate (PMMA) resist with an electron beam to make nanoscale nickel masks for reactive ion etching. The masks consist of an array of nickel dots that range in size from 20 to 100 nm …

Effects Of Two-Way Left-Turn Lane On Roadway Safety, Haolei Peng

USF Tampa Graduate Theses and Dissertations

Two-way left-turn lane (TWLTL) is one of the common median treatments on the roadway. It is found that a number of crashes reported in Florida State are related to TWLTLs. This research focused on evaluating the effect of TWLTLs on these crashes by using the statistical crash prediction model that can estimate the expected number of crashes on TWLTLs. The crash database for analysis was extracted from the Florida Traffic Crash Database based on the TWLTL section list provided by FDOT and combined with some traffic characteristics. It consisted of totally 1688 sample sections within a three-year period from 1996 …

Effects Of Hydrodynamic Regime On Photosynthesis In The Green Alga Caulerpa., Mark D. Driscoll

USF Tampa Graduate Theses and Dissertations

The delivery of nutrients to the surface of marine algae can be controlled by the local hydrodynamic regime: in higher flow velocities, the Diffusive Boundary Layer (DBL) at the uptake surface is thinner, which can increase the flux of dissolved chemicals to the algal surface. If the primary productivity of an alga is controlled by the availability of a dissolved chemical, increased water flow should result in greater primary productivity due to increased chemical flux. To test the hypothesis that increased water flow will increase Photosystem II kinematics (PSII) in the green alga Caulerpa we used a Diving Pam Fluorometer …

Improving The Environment In Distance Learning Courses Through The Application Of Aesthetic Principles, Darryl J. Hancock

USF Tampa Graduate Theses and Dissertations

The primary goal of this project has been to research and create aesthetic visual environments in distance-learning media through the application of expert criteria and to explore the effects of those environments on student satisfaction and motivation. To accomplish this three instructors with distinct courses were selected to apply aesthetic criteria within the process of analysis, design, development, implementation, and evaluation. Courses selected were Art Appreciation -- ARTS 1100, Advanced Surveying -- ENGR 2502, and Introduction to Sociology -- SOCI 1101.

The project goal was subdivided into four objectives.

1) Develop criteria for the inclusion of visual aesthetics in the …

Chemical Investigation Of Three Antarctic Marine Sponges, Young Chul, Park

USF Tampa Graduate Theses and Dissertations

This thesis describes the chemical investigation of three marine sponges from Antarctica and the total syntheses of natural products erebusinone (12) and its derivative, erebusinonamine (52). Investigation of the yellow Antarctic marine sponge Isodictya setifera resulted in the isolation of two secondary metabolites, purine analog (32) and 3-hydroxykynurenine (24). Chemical investigation of Isodictya setifera led to the isolation of six secondary metabolites which included 5-methyl-2-deoxycytidine (25), uridine (28), 2-deoxycytidine (31), homarine (37), hydroxyquinoline (33), 3-hydroxykynurenine (24). The latter two compounds …

Secondary Students Using Expert Heuristics In The Analysis Of Digitalized Historical Documents, Daniel W. Stuckart

USF Tampa Graduate Theses and Dissertations

In time, more historical documents have become accessible through various technological modes including the Internet, CD-ROMs, and local databases. Teachers are now able to infuse a rich variety of resources into lessons with relative ease. This study measured expert historian heuristics in secondary students engaged in analysis of technologically-enhanced historical documents relating to women in the early United States republic. Nine 10th grade Advanced Placement world history students from an urban high school in the southeastern United States were assigned randomly to one of three conditions: paper historical documents, HTML historical documents, and HTML historical documents with simulated, limited Internet …

Human Topoisomerase Ii Alpha Nuclear Export Is Mediated By Two Crm-1 Dependent Nuclear Export Signals, Joel G. Turner

USF Tampa Graduate Theses and Dissertations

Resistance to chemotherapeutic drugs is a major obstacle in the treatment of leukemia and multiple myeloma. We have previously found that myeloma and leukemic cells in transition from low-density log phase conditions to high-density plateau phase conditions exhibit a substantial export of endogenous topoisomerase II alpha from the nucleus to the cytoplasm. In order for topoisomerase-targeted chemotherapy to function, the topoisomerase target must have access to the nuclear DNA. Therefore, the nuclear export of topoisomerase II alpha may contribute to drug resistance, and defining this mechanism may lead to methods to preclude this avenue of resistance. In the current report, …

Parameterization Of The Light Models In Various General Ocean Circulation Models For Shallow Waters, Hari Warrior

USF Tampa Graduate Theses and Dissertations

Solar energy is incident on the earth's surface in both short-wave and long-wave parts of the spectrum. The short-wave part of the spectrum is of special interest to oceanographers since the vertical distribution of temperature in the top layer of the ocean is mostly determined by the vertical attenuation of short-wave radiation. There are numerous studies regarding the temperature evolution as a function of time (see Chapter 2 for details). The diurnal and seasonal variation of the heat content (and hence temperature) of the ocean is explored in this thesis. The basis for such heat budget simulation lies in the …

Efforts Toward The First Enantioselective Total Synthesis Of Praziquantel And Synthetic Model Studies On Ecteinascidin 743 By Novel Aromatic C-H Insertion Methodology, Chiliu Chen

USF Tampa Graduate Theses and Dissertations

The thesis is composed of three chapters. The aim of this thesis is to apply the novel dirhodium perfluorobutyrate-catalyzed intramolecular aromatic C-H insertion methodology to the enantioselective total synthesis of praziquantel and synthetic model studies on ecteinascidin 743, which belongs to the important tetrahydroisoquinoline family.

The first introductory chapter deals with the biological significance and previous synthetic methodologies. Our novel methodology is based on dirhodium perfluorobutyrate-catalyzed intromolecular aromatic C-H insertion reaction, which is crucial in the pivotal carbon-carbon bond formation when constructing isoquinolone moiety, which is ubiquitous in numerous natural products of significant biological and pharmacological activities.

The second chapter …

Feedback In Distance Learning: Do Student Perceptions Of Corrective Feedback Affect Retention In Distance Learning?, Lori S. Kielty

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to determine if there was a correlation between students' perception of corrective feedback and retention in online classes. A total of 134 community college students were enrolled in six online classes taught by three full-time instructors. The research questions addressed were as follows:

RQ1. How are the students' perception of corrective feedback and student retention related?

RQ2. Are students who attend course orientation meetings more likely to complete the course?

RQ3. Are students who attend distance learning technical workshops more likely to complete the course?

RQ4. Are students who have taken other online classes …

Are Preservice Instructional Designers Adequately Prepared For Tomorrow’S Diverse Learning Audiences?—A Cultural Content Analysis Of Textbooks (1993-2003) Used For Instructional Design, Sujie Man

USF Tampa Graduate Theses and Dissertations

This study used content analysis to examine the coverage of cultural issues in the five phases of instructional design within ID/ISD textbooks published between 1993 and 2003. The results indicated that not all the ID/ISD textbooks examined in this study covered cultural issues. Among the textbooks that did cover cultural issues, none of them reached more than 10% coverage of the total pages of any one book. The phase of Analysis and the Other category received the highest amount of coverage in both the 53 books sample and 36 books sample; whereas the phase of Implementation received the least amount …

Laboratory Statnamic Testing, Michael Jeffrey Stokes

USF Tampa Graduate Theses and Dissertations

Despite advancements in the analysis of statnamic load testing data, there exists uncertainty with underlying procedural assumptions. Two such assumptions are that the system mass and soil-related damping coefficient remain constant throughout the loading event. These assumptions are the culprit of aberrant predictions of the static capacity at small displacements when the overall displacement is large. An exploration of the assumptions may validate prior existing test results as well as solidify the current analysis process. However, an exploration could also reveal an overestimation or underestimation of portions of the predicted static load responses.

The testing program outlined herein consists of …

Prediction Of Commuter Choice Behavior Using Neural Networks, Aaron L. Gregory

USF Tampa Graduate Theses and Dissertations

In order to reduce air pollution and reduce the amount of traffic on highways in the western United States, certain states have set up worksite trip reduction programs. Employers in these states must comply with worksite trip reduction laws and submit trip reduction plans to their respective regulatory agency each year. These plans are currently evaluated manually, and are either rejected or accepted by the agency. There are two major flaws in this system; the first is the amount of time required by the agency to review a plan could be a matter of months, and the second is that …

A Model To Create Bus Timetables To Attain Maximum Synchronization Considering Waiting Times At Transfer Stops, Anitha Eranki

USF Tampa Graduate Theses and Dissertations

Due to the steady increased in public transportation demand, there is a need to provide more desirable and user-friendly transit systems. Typically, the public transportation timetables are modeled as an assignment problem, which often has objectives such as reducing the cost of operation, minimizing waiting time between transfer points or improving the quality of performance. This research considers the problem of developing synchronized timetables for bus transit systems with fixed routes when a waiting time limit exist at each transfer stops, for the passengers making connections. The objective of this research is to have maximum number of simultaneous arrivals.

Different …