Digital Commons Network^™

The Cosolvent And Association Effect On Polymer Behaviors, Xiangyu Zhang

Theses and Dissertations

The blending or mixing is extensively utilized in diverse processes of polymers to bring about advantageous properties, but the behavior becomes intriguing when associations are involved and multi-solvents are used. Explanations based on chemistry-specific arguments are less than satisfactory in abstracting essential features, and lack the general applicability across various systems. So, this work focuses on capturing the physical force governing the phenomenon of interest by using a generic model. Highly non-trivial behaviors of polymers are often observed in multi-solvent solutions. It is known that polymers swell and dissolve in good solvents, while they tend to collapse and aggregate in …

Ruggedness Test Of A New Standardized Test Method For Abrasion Resistance Of E-Textiles, Erin Parker

Theses and Dissertations

Standard test methods provide product developers with information regarding materials' suitability for different purposes. Typically, current standards are suitable for determining the mechanical properties of new materials. However, in the case of electronic textiles (E-Textiles) and wearable technology (wearables), adding conductive components with added functionality makes utilizing textile standards difficult, and these standards will not provide information on mechanical and electrical properties of conductive elements. New standards for E-Textile and wearables testing are needed to ensure product developers can obtain the information necessary to make informed decisions about new products. Standards organizations such as the American Society for Testing and …

Re(Engineering) Student Success: Constructing Knowledge On Students’ Experiences In Engineering Education Programs To Encourage Holistic Student Success, Shaylin Williams

Theses and Dissertations

If a group of engineering deans were asked whether students at their institutions were successful and why, what information might they immediately or subconsciously use to measure or gauge the engineering students’ success? If only academic performance outcomes like GPA, individual course grades, or graduation rate race to their minds, then their rationale aligns with the majority of researchers. My research seeks to shift the mindset that frames engineering student success mainly within the boundaries of academic performance measures. By measuring students’ perceived autonomy, competence, social integration and relatedness within their programs, and aspirations after graduation, one can more accurately …

Faculty Experiences Facilitating Study Abroad, Francis Edmond Dechert

Theses and Dissertations

Faculty who teach at the college level are often responsible for their own pedagogical training and development, and leading a short-term study abroad program may be one strategy for helping faculty with this development. This study explores the experiences of faculty who have led short-term study abroad programs and provides insight into how the experiences align with experiential learning models and ways that they can lead to pedagogical development. Nine faculty members were interviewed and asked questions about their teaching backgrounds, their introduction to study abroad, and their experiences related to teaching and learning while abroad. The findings show that …

Determining Student Attentiveness By Use Of Heart Rate Measurement Using A Wearable Device, Erik Rhodes Brown

Theses and Dissertations

Distraction from personal technology is a widely recognized problem in the modern classroom. Further, instructors have limited abilities to determine when students are waxing or waning in attentiveness. This evaluative experiment leverages the Apple Watch’s heart rate sensors to capture signs of attentiveness in participants simulating remote university lectures of differing interest levels as determined by YouTube commenters. Once captured, the heart rate data separated and analyzed to determine the effect of the lecture treatment on the participants’ heart rates. Twenty-seven students from Mississippi State University’s Electrical and Computer Engineering and Computer Science and Engineering departments elected to participate in …

Heat And Mass Transfer Modeling Of High-Temperature Moving-Bed Thermochemical Reactors, David Korba

Theses and Dissertations

With the global deployment of renewable energy generation at record rates, clean energy is steadily becoming competitive with its fossil-fuel counterparts. However, further expansion is limited by the inherent intermittency of renewable energy sources (solar, wind, wave, etc.), which typically do not match with daily and seasonal variations of global (and local) energy demand. Thermochemical energy storage (TCES) has demonstrated strong potential in being a technological pathway to provide on-demand process heat and handle the intrinsic variations in renewable energy generation and energy demand. TCES works on the premise of excess renewable heat driving an endothermic reduction reaction, in which …

Ide-Based Learning Analytics For Assessing Introductory Programming Skill, Phyllis J. Beck

Theses and Dissertations

Providing a sufficient level of personalized feedback on students' current level of strategic knowledge within the context of the natural programming environment through IDE-based learning analytics would transform learning outcomes for introductory programming students. However, providing sufficient insight into the programming process was previously inaccessible due to the need for more complex and scalable data collection methods and metrics with a wider variety for understanding programming metacognition and the full programming process.

This research developed a custom-built web-based IDE and event compression system to investigate two of the five components of a five-dimensional model of cognition for programming skill estimation …

Assessing And Predicting The Students’ Systems Thinking Preference: Multi-Criteria Decision Making And Machine Learning, Siham Tazzit

Theses and Dissertations

The 21st century is marked by a technological revolution that features digital implementation and high interconnectivity between systems across different domains, such as transportation, agriculture, education, and health. Although these technological changes resulted in modern systems capable of easing individuals’ lives, these systems are increasingly complex, and that increased complexity is only expected to continue. The increased system complexity is due to the rapid exchange of information between subsystems, which creates high interconnectivity and interdependence between the subsystems and their elements. Workforce skill sets, as a result, must be modified appropriately to ensure the systems’ success. Systems Thinking is an …

Investigating The Role Of Plant Traits And Interactions In Emergent Wetland Nutrient Removal, Andrew Ryan Sample

Theses and Dissertations

Increasing wetland restoration in the Lower Mississippi Alluvial Valley has been identified as a method to reduce nutrient loading in the Gulf of Mexico. Wetlands have historically been used to treat water through processes facilitated by wetland plants, and relatively few species and plant traits have been identified as important in carrying out these processes. This study focuses on some of those species and traits and aims to identify species differences and plant traits that may be important for wetland nutrient mitigation. Chapter I provides background information on nutrient pollution, wetland biogeochemical mechanisms for nutrient sequestration, and the focal species …

Comparison Of Aging Techniques In Wild Bottlenose Dolphins (Tursiops Truncatus) Of Unknown Age From The Mississippi Sound., Christa Elizabeth Barrett

Theses and Dissertations

Age determination of bottlenose dolphins (Tursiops truncatus) is a critical tool in understanding their health. There are many methods of aging dolphins including morphometrics, counting growth layer groups (GLGs) of teeth, comparing dentin to pulp cavity ratio on dental radiographs, analysis of the pectoral flipper radiographs, and epigenetic testing. The most common method for aging toothed cetaceans is the counting of GLGs in the teeth. Since there are many challenges associated with aging dolphins based on the counting of GLGs, a processing technique that results in better resolution of GLGs is needed. This is a two-part study that …

Non-Destructive Evaluation Of White Striping And Microbial Spoilage Of Broiler Breast Meat Using Structured-Illumination Reflectance Imaging, Ebenezer O. Olaniyi

Theses and Dissertations

Manual inspection is a prevailing practice for quality assessment of poultry meat, but it is labor-intensive, tedious, and subjective. This thesis aims to assess the efficacy of an emerging structured illumination reflectance imaging (SIRI) technique with machine learning approaches for assessing WS and microbial spoilage in broiler breast meat. Broiler breast meat samples were imaged by an in house-assembled SIRI platform under sinusoidal illumination. In first experiment, handcrafted texture features were extracted from direct component (DC, corresponding to conventional uniform illumination) and amplitude component (AC, unique to the use of sinusoidal illumination) images retrieved from raw SIRI pattern images build …

Tuning The Metal/Acid Functionalities In Hzsm-5 For Efficient Dehydroaromatization, Genwei Chen

Theses and Dissertations

The increasing production of natural gas liquids attracts both academia and industry to develop on-purpose techniques converting those light alkanes to value-added chemicals. Dehydroaromatization is an alternative path for light alkane conversion to produce aromatics but still lacks active and stable catalysts. This work aims at the development of efficient dehydroaromatization catalysts by tuning the metal/acid bifunctionality of the Pt/HZSM-5 catalyst. Additionally, through co-processing light alkane with ammonia during the dehydroaromatization process, this study also proposes a new reaction system that could directly link the C-N bond for nitrile synthesis.

The results suggested that the activity, selectivity, and stability of …

Physical Layer Security With Unmanned Aerial Vehicles For Advanced Wireless Networks, Aly Sabri Abdalla

Theses and Dissertations

Unmanned aerial vehicles (UAVs) are emerging as enablers for supporting many applications and services, such as precision agriculture, search and rescue, temporary network deployment, coverage extension, and security. UAVs are being considered for integration into emerging wireless networks as aerial users, aerial relays (ARs), or aerial base stations (ABSs). This dissertation proposes employing UAVs to contribute to physical layer techniques that enhance the security performance of advanced wireless networks and services in terms of availability, resilience, and confidentiality. The focus is on securing terrestrial cellular communications against eavesdropping with a cellular-connected UAV that is dispatched as an AR or ABS. …

Impacts Of Cover Crop, Soil Steaming, And Plastic Mulch On Field-Grown Tomato Production And Virus-Induced Gene Silencing In Antirrhinum, Penstemon, Petunia, Rosa, And Rudbeckia, Brenton Andrew Earl Breland

Theses and Dissertations

Weeds and soil-borne diseases can cause large yield losses in field-grown tomato (Solanum lycopersicum) production. Techniques have been developed to reduce soil-based problems. In this study, we evaluated the impacts of cover crops, soil steaming, and plastic mulch to reduce weed and disease pressure in field-grown tomatoes. Four cover crop treatments were grown in the fall and winter before spring planting. Soils were steamed to a target temperature of 71.1 °C for 0, 5, or 20 minutes. Plastic mulch was also used on half of the rows. Yield, weed densities, and disease incidence were recorded.

Reduced flowering time …

Reflecting On Design: A Study Of The Relationship Between Beginning Landscape Architecture Students’ Graphic Skills And Self-Efficacy Through Hybrid Assessments And Reflective Writing, Rachel Michelle Nobles

Theses and Dissertations

The purpose of this study is to examine the connection between self-efficacy, reflective writing, and graphic quality inside a first-year Landscape Architecture design studio. Reflective writing and self-efficacy can be studied to better understand how to motivate students within a design studio. Bandura (1977) defines self-efficacy as the belief in one’s own capabilities relating to motivation, behavior, and environment. Reflective writing is overlooked as a mode of advancing knowledge in the design process (Lousberg, 2019). The data were collected with pre- and post-semester Likert scale questionnaires, graphic skill-building tests, and reflective writing. To determine growth, the pre-and post-Likert-type questionnaires and …

Exploring Bistatic Scattering Modeling For Land Surface Applications Using Radio Spectrum Recycling In The Signal Of Opportunity Coherent Bistatic Simulator, Dylan R. Boyd

Theses and Dissertations

The potential for high spatio-temporal resolution microwave measurements has urged the adoption of the signals of opportunity (SoOp) passive radar technique for use in remote sensing. Recent trends in particular target highly complex remote sensing problems such as root-zone soil moisture and snow water equivalent. This dissertation explores the continued open-sourcing of the SoOp coherent bistatic scattering model (SCoBi) and its use in soil moisture sensing applications. Starting from ground-based applications, the feasibility of root-zone soil moisture remote sensing is assessed using available SoOp resources below L-band. A modularized, spaceborne model is then developed to simulate land-surface scattering and delay-Doppler …

Synthesis Of Sustainable Polyethylene Mimics Through Ring-Opening Metathesis Polymerization, Brandon Zhang

Theses

Polyethylene is the most produced plastic in the world due to its versatility and ubiquitous applications. The production and use of polyethylene however pose sustainability issues such as using petroleum resources and the persistence of its waste in landfills and oceans. Though not every issue can be addressed simultaneously, the more critical issue is to develop a polyethylene that can degrade within a few months instead of hundreds of years. A possible solution is to synthesize a polyethylene mimic, consisting of long chain of methylene groups with an occasional input of a functional group while maintaining similar properties as that …

Draft Final 2023 Residential Metals Abatement Program (Rmap) Stodden Park Soil Remedial Action Work Plan (Rawp), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Re: Approval Letter For The Request For Change (Rfc) To The Butte Priority Soils Operable Unit (Bpsou) Request For Change (Rfc)-Brw-2023-03 To The Final Butte Reduction Works (Brw) Smelter Area Mine Waste Remediation And Contaminated Groundwater Hydraulic Control Site Phase Iii Quality Assurance Project Plan (Qapp) (Phase Iii) (Dated June 29, 2023)., Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Cancer: The Burden Of Treatments Eased By Recent Developments In The Field: A Review Of The Literature, Zachary J. Seim

Masters Projects

Cancer is a very prevalent disease that has affected most of the population. Treatment options that have been used for decades are beginning to be outcompeted by newer developments in the field. Newer developments allow a more specific response to cancers that have proven to be very difficult for traditional treatment. Immune specific treatments also give the ability to specifically target areas affected by the cancer, to reduce potential risk of systemic damage and autoimmunity. Developing cancer treatments that are highly specific brings forth a new age of medicine, hoping to prolong the life expectancy of those affected with cancers, …

Behavior Of Ultrahigh-Performance Concrete Plates Encasing Steel H-Piles, Mohamed Elgawady, Binod Shrestha

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Steel H-piles are exposed during their service life to wet-dry cycles in combination with salts, such as deicing, that may result in corrosion, leading to cross-sectional loss and reduction in axial load-carrying capacity. This paper proposes an innovative repair method for corroded steel H-piles using ultrahigh-performance concrete (UHPC) plates. The UHPC plates are reinforced with carbon fiber-reinforced polymer (CFRP) grids. The UHPC plates bridge the corroded segment so that the axial force bypasses the corroded segment. The UHPC are bolted to the steel H-pile using high-strength bolt connectors (HSBCs). Eleven steel H-piles bolted with UHPC plates were investigated experimentally under …

Utilizing Waste Latex Paint Toward Improving The Performance Of Concrete, Mohamed Leithy, Eslam Gomaa, Ahmed A. Gheni, Mohamed Elgawady

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

In this paper, incorporating the waste latex paint (WLP) into the conventional concrete as a partial replacement of sand to improve its durability was investigated. The fresh and hardened characterizations, in addition to the durability of concrete, were examined. The slump test was used to evaluate the fresh properties, while the hardened properties were evaluated through the volume of voids and absorption rate, in addition to the compressive, splitting tensile, and flexural strengths tests. The durability performance was evaluated by the surface resistivity, bulk electrical resistivity, as well as freeze and thaw resistance tests. The results showed a reduction in …

Genteel Culture, Legal Education, And Constitutional Controversy In Early Virginia, Matthew J. Steilen

Journal Articles

This article focuses on the movement to reform legal education in early national Virginia, offering a fresh perspective by examining the connection between legal education and society and culture. It challenges the notion that constitutional ideas were the primary driving force behind reforms and argues that social status and “manners” played a more significant role. Wealthy elites in Virginia associated manners with education, sending their sons to college to become gentlemen, as it secured their aspirations to gentility and their influence over society and politics. Reformers sought to capitalize on this connection by educating a generation of university-trained, genteel lawyers …

Elucidating Self-Assembly Of Semiconducting Polymers In The Presence Of A Low Molecular Weight Gelator, Madhubhashini Lakdusinghe

Theses and Dissertations

Semiconducting polymers with a conjugated backbone are important for energy storage, conversion, and biomedical field applications. The self-assembly process of these polymers in solutions depends on the polymer concentration and quality of the solvent. The electrical properties of thin films obtained from the solution phase depend on the self-assembled process. Thin films of conjugated polymer gels with percolating networks of self-assembled structures display improved electrical conductivities. In this dissertation, we studied the impact of the secondary gel matrix formed by a low molecular weight gelator, on the self-assembly of conjugated polymers, the preservation of assembled structures in dried gel films …

Effect Of Environmental And Geometrical Factors On Microstructure, Desiccation Cracking, And Carbon Dioxide Flux In Clays, Charles Clayton Goodman

Theses and Dissertations

Studying the effects of extreme conditions, such as high temperatures and low humidity, on soil properties is important to various disciplines, including geotechnical engineering, soil science, waste management, crop management, and ceramics. The goal of this research is to investigate the effect of environmental and geometrical factors on microstructure, desiccation cracking, and CO₂ flux in clays. The objectives of this research are threefold. (1) Understand the effects of temperature on the microstructure of clay soils; (2) develop a standardized procedure for studying desiccation cracking in a laboratory setting with reliable and repeatable results; and (3) develop an environmental chamber …

Gas Permeability Of 3d Stitched Composites For Cryogenic Applications, Shuvam Saha

Theses and Dissertations

This research aims to investigate the influence of 3D through-thickness stitching on the gas permeability and transverse microcracking of cryogenically cycled carbon/epoxy composites. 3D through-thickness stitching can be used to improve the interlaminar properties of polymer matrix composites (PMCs) and produce lightweight, unitized structures for cryogenic storage tanks. To fully utilize stitched composite structures for these applications, their inherent gas permeability challenges must be understood. Therefore, in this study, the stitched composites' damage evolution and gas permeability was experimentally characterized under a) pure thermal stress, b) thermal and uniaxial mechanical stress, and c) thermal and biaxial mechanical stress. Helium gas …

Multi-Objective Design Optimization Of Two Configurations Of Ventricular Shunts For Hydrocephalus, Will Kirkpatrick

Theses and Dissertations

Hydrocephalus is developed when the flow of cerebrospinal fluid is obstructed in the ventricles and a pressure build-up is generated within the brain. Ventricular shunts are used to remove excess fluid from the brain, but these shunts have a common problem of failure due to the shunt being obstructed by the build-up of astrocytes. To address this, two sets of 27 designs of ventricular shunts were identified and analyzed with parameters that could potentially reduce obstruction risks. The performance of these designs was examined using fluid simulations on these two sets of 27 designs. One set explored close-tipped shunt designs, …

Gene Expression Effects On Productivity And Stress Tolerance In Polyclonal Plantings Of Populus Deltoides, Macy Gosselaar

Theses and Dissertations

Polyclonal plantings of Populus deltoides are expected to display increased site resource use, productivity, and tolerance to stress through plasticity changes leading to niche differentiation (i.e changes to crown/canopy structures). In the present study, P. deltoides Clones S7C8, 110412, and polyclonal plots were tested for differentially expressed genes and enriched biological pathways between planting schemes. Transcriptomic analysis of leaves revealed upregulation of an active growth gene and gene family members that play important roles in plant stress and stress tolerance in polyclonal plantings. A gene associated with oxidative stress was upregulated in polyclonal plantings across all treatments. Secondary metabolic pathways …

An Analysis Of Moisture Environments Associated With Mature North Atlantic Tropial Cyclones, Katherine Berislavich

Theses and Dissertations

Tropical cyclone (TC) intensity and structure are affected by their environments, including sea surface temperature, vertical wind shear, and atmospheric moisture. Analyses of TC environments often rely on area-averaged quantities, yet the spatial variability of these fields can affect TC behavior, such as moisture distribution impacting where and how much rain falls. This study identifies spatial patterns of environmental moisture surrounding mature North Atlantic TCs during 2000-2021 in shear of less than 20 knots. Empirical orthogonal function analysis of total column water vapor reveals six dominant patterns. These patterns account for nearly 67% of the variance in the dataset and …

The Effects Of Mechanical Strain On Vascular Calcification And The Canonical Wnt Pathway, Hannah E. Douglas

Theses and Dissertations

Cardiovascular disease is a significant health crisis, representing 32% of deaths worldwide in 2019. Vascular calcification (VC), a major contributor to cardiovascular disease, is a regulated biomineralization process whose exact mechanisms are unknown. Additionally, vascular smooth muscle cells (VSMCs) significantly contribute to VC by undergoing a phenotypic switch and differentiating into osteoblast-like cells. When factors like hypertension cause disturbed laminar flow in the body’s vasculature, the mechanical stress promotes the phenotypic switch and calcification of VSMCs via mechanotransduction. VC is also induced by the Wnt pathway, which is activated via mineral imbalance and mechanical stimulation. However, the exact mechanisms behind …