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2023

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Average Or Outlier? Introductory Statistics Adjunct Instructors’ Beliefs, Practices, And Experiences, Samantha Estrada, Erica Martinez Jan 2023

Average Or Outlier? Introductory Statistics Adjunct Instructors’ Beliefs, Practices, And Experiences, Samantha Estrada, Erica Martinez

Psychology Faculty Publications and Presentations

In recent years, the adjunct faculty phenomenon has grown steadily. This research focused on adjunct instructors teaching introductory statistics courses. The purpose of the study was to give a voice to adjunct instructors by allowing them to describe their experiences teaching statistics. We conducted a qualitative study with 15 adjunct instructors of introductory statistics through semi-structured interviews. The participants came from several fields: psychology, nursing, and business, among others. Thematic analysis was used to find themes of statistical anxiety, use of technology in the classroom, lack of curriculum flexibility, and connection to the host institution. Our findings can inform institutions …


The Impact Of Post-Dobbs Abortion Bans On Prenatal Tort Claims, Aviva K. Diamond Jan 2023

The Impact Of Post-Dobbs Abortion Bans On Prenatal Tort Claims, Aviva K. Diamond

Michigan Law Review

In June 2022, the Supreme Court revoked Americans’ fundamental right to abortion in Dobbs v. Jackson Women’s Health Organization. However, the Court said nothing about how its decision would impact tort claims related to reproductive care. Many states have since adopted near-total or early-gestational- age abortion bans, which has not only diminished access to reproductive care, but has also incidentally impaired the ability of plaintiffs to bring long-recognized prenatal tort claims. Prenatal tort claims—wrongful pregnancy, birth, and life—allow victims to recover when a medical professional negligently performs reproductive or prenatal care. This Note identifies the impact that post-Dobbs …


Teaching Beyond Trans-Competency: Exploring Trans-Affirming Pedagogy Through Applied Case Studies, Sam Harrell, Sarah Mountz, Hazel (Bobbi) Ali Zaman Jan 2023

Teaching Beyond Trans-Competency: Exploring Trans-Affirming Pedagogy Through Applied Case Studies, Sam Harrell, Sarah Mountz, Hazel (Bobbi) Ali Zaman

The Journal of Sociology & Social Welfare

In this paper, we share two applied case studies social work instructors can use to teach trans-affirming, anti-oppressive practice. These cases span two practice arenas, child welfare and low-barrier shelter services, and are derived from practice in the authors’ personal and professional experiences in the Northeastern and Midwestern regions of the United States. For each case, we describe the accompanying class context, share our pedagogical approach, name the underlying assumptions and structures that facilitate harm, explore relevant practice skills, and identify theoretical, philosophical, and ethical commitments essential for trans-affirming practice. Our approach to social work education on transgender and gender …


The Myth Of Programmatic Intervention To Tackle Intergenerational Poverty In Post-Industrial Societies: A Longitudinal Study In Hong Kong As A Vantage Point, Wing Chung Ho Jan 2023

The Myth Of Programmatic Intervention To Tackle Intergenerational Poverty In Post-Industrial Societies: A Longitudinal Study In Hong Kong As A Vantage Point, Wing Chung Ho

The Journal of Sociology & Social Welfare

Through tracking the educational and career trajectories of the young adult members (aged 24–26) of 154 families over 13–15 years, this study suggests that the problem of intergenerational poverty is serious in Hong Kong. Quantitative data indicates that adolescents with poor parents have a 104 percent higher chance of being poor in young adulthood, and nearly 60 percent (58.4%) of the samples follow “the-poor-begets-the-poor; therich- begets-the-rich” pattern across generations. However, the explanatory power of the logistic regression models consisting of confounding factors are weak (R2=0.15). Subsequent focus group discussions with 30 mothers from the samples point to myriad forms of …


Repair Of Complex Ovine Segmental Mandibulectomy Utilizing Customized Tissue Engineered Bony Flaps, Emma Watson, Hannah A Pearce, Katie J Hogan, Natasja W M Van Dijk, Mollie M Smoak, Sergio Barrios, Brandon T Smith, Alexander M Tatara, Timothy C Woernley, Jonathan Shum, Craig B Pearl, James C Melville, Tang Ho, Issa A Hanna, Nagi Demian, Jeroen J J P Van Den Beucken, John A Jansen, Mark E Wong, Antonios G Mikos Jan 2023

Repair Of Complex Ovine Segmental Mandibulectomy Utilizing Customized Tissue Engineered Bony Flaps, Emma Watson, Hannah A Pearce, Katie J Hogan, Natasja W M Van Dijk, Mollie M Smoak, Sergio Barrios, Brandon T Smith, Alexander M Tatara, Timothy C Woernley, Jonathan Shum, Craig B Pearl, James C Melville, Tang Ho, Issa A Hanna, Nagi Demian, Jeroen J J P Van Den Beucken, John A Jansen, Mark E Wong, Antonios G Mikos

Faculty, Staff and Student Publications

Craniofacial defects require a treatment approach that provides both robust tissues to withstand the forces of mastication and high geometric fidelity that allows restoration of facial architecture. When the surrounding soft tissue is compromised either through lack of quantity (insufficient soft tissue to enclose a graft) or quality (insufficient vascularity or inducible cells), a vascularized construct is needed for reconstruction. Tissue engineering using customized 3D printed bioreactors enables the generation of mechanically robust, vascularized bony tissues of the desired geometry. While this approach has been shown to be effective when utilized for reconstruction of non-load bearing ovine angular defects and …


Identification Of Microbiological Factors Associated With Periodontal Health Disparities, Bing-Yan Wang, Aize Cao, Meng-Hsuan Ho, Derek Wilus, Sally Sheng, Hsiu-Wan Meng, Elissa Guerra, Jianming Hong, Hua Xie Jan 2023

Identification Of Microbiological Factors Associated With Periodontal Health Disparities, Bing-Yan Wang, Aize Cao, Meng-Hsuan Ho, Derek Wilus, Sally Sheng, Hsiu-Wan Meng, Elissa Guerra, Jianming Hong, Hua Xie

Faculty, Staff and Student Publications

The present study aimed at identifying risk factors associated with periodontitis development and periodontal health disparities with emphasis on differential oral microbiota. The prevalence of periodontitis is recently rising dentate adults in the US, which presents a challenge to oral health and overall health. The risk of developing periodontitis is higher in African Americans (AAs), and Hispanic Americans (HAs) than in Caucasian Americans (CAs). To identify potentially microbiological determinations of periodontal health disparities, we examined the distribution of several potentially beneficial and pathogenic bacteria in the oral cavities of AA, CA, and HA study participants. Dental plaque samples from 340 …


Assessing Erosion Improvement In Beach Sand Treated With Bioslurry, Peter E. Schmillen Jan 2023

Assessing Erosion Improvement In Beach Sand Treated With Bioslurry, Peter E. Schmillen

UNF Graduate Theses and Dissertations

Over the last 10 years microbially induced calcite precipitation (MICP) has emerged as a possible solution to reduce shoreline erosion. To date, most MICP soil treatments that have been studied involve column injection using a pump. In recent years, MICP application through surface percolation has gained traction as an alternative technique, but data using this technique are limited. More recently, a new treatment recipe/technique was developed, and this technique was termed “bioslurry”. Like most MICP studies research with bioslurry concentrated on the column injection method, and surface percolation has received very limited attention. This paper discusses the treatment of Florida …


Child Psychological Well-Being And Adult Health Behavior And Body Mass Index, Julia Boehm, Farah Qureshi, Laura D. Kubzansky Jan 2023

Child Psychological Well-Being And Adult Health Behavior And Body Mass Index, Julia Boehm, Farah Qureshi, Laura D. Kubzansky

Psychology Faculty Articles and Research

Objective: Psychological well-being (PWB) is linked with health behaviors among adults, but it is unclear if childhood PWB prospectively predicts healthy adulthood biobehavioral profiles. Such evidence may identify developmental windows for establishing positive health trajectories across the lifespan. Using data spanning 30 years, we investigated whether PWB at age 11 was associated with health behaviors and body mass index (BMI) at ages 33 and 42. We hypothesized children with higher versus lower PWB would engage in healthier behaviors, have lower BMI in adulthood, and be more likely to maintain optimal levels over time. Method: Data were from 4,728 participants of …


Non-Traditional Adult Learners After Covid-19: Applying National Standards For Online Teaching In Human Service Education, Chaniece Winfield, Kathryn Hughes, Jessica L. Huffman Jan 2023

Non-Traditional Adult Learners After Covid-19: Applying National Standards For Online Teaching In Human Service Education, Chaniece Winfield, Kathryn Hughes, Jessica L. Huffman

Counseling & Human Services Faculty Publications

After the COVID-19 pandemic, the field of higher education increased its attention on quality distance learning for traditional and non-traditional adult learners. While the world saw an increase in online education enrollment as a result of the pandemic, non-traditional adult learners have historically relied on this method of education delivery to support their success in the collegiate setting. As the field of human service education supports the offering of distance learning instruction, it is vital for human service educators to consider the National Standards for Quality Online Teaching when educating adult learners. The authors of this article provide an overview …


A Population Level Examination Of The Incredible Fruit Diversity In Astragalus Lentiginosus, Quinn Thomas Jan 2023

A Population Level Examination Of The Incredible Fruit Diversity In Astragalus Lentiginosus, Quinn Thomas

Master's Theses

Astragalus lentiginosus is the most taxomically diverse species in the North American flora with over 40 recognized varieties. The incredible diversity within A. lentiginosus, particularly in respect to its fruit morphology, makes it an exceptional model to study adaptation and evolution. However, it remains unknown whether fruit morphology is an adaptation and, if so, the extent to which selection or neutral evolutionary processes shape the striking diversity in this trait. In order to understand the adaptive significance of fruit morphology we must first understand the genetic structure of A. lentiginosus. Varieties of A. lentiginosus vary considerably in their range size …


Policing Queer Sexuality, Ari Ezra Waldman Jan 2023

Policing Queer Sexuality, Ari Ezra Waldman

Michigan Law Review

A Review of Vice Patrol: Cops, Courts, and the Struggle over Urban Gay Life Before Stonewall. By Anna Lvovsky.


The Indian Child Welfare Act In The Multiverse, M. Alexander Pearl Jan 2023

The Indian Child Welfare Act In The Multiverse, M. Alexander Pearl

Michigan Law Review

A Review of Adoptive Couple v. Baby Girl By Matthew L.M. Fletcher and Kathryn E. Fort, in Critical Race Judgments: Rewritten U.S. Court Opinions on Race and the Law 452, 471. Edited by Bennett Capers, Devon W. Carbado, R.A. Lenhardt and Angela Onwuachi-Willig.


Nepantla/Coatlicue/Conocimiento, Gerald Torres Jan 2023

Nepantla/Coatlicue/Conocimiento, Gerald Torres

Michigan Law Review

A Review of Borderlands/La Frontera: The New Mestiza. By Gloria Anzaldúa.


Equity, Equality, And Justice: Defined, Jerry “Jay” Thomas Jan 2023

Equity, Equality, And Justice: Defined, Jerry “Jay” Thomas

Seattle Journal for Social Justice

No abstract provided.


Assessing Pandemic Preparedness, Response, And Lessons Learned From The Covid-19 Pandemic In Four South American Countries: Agenda For The Future, Andrea Ramírez Varela, Michael Touchton, J Jaime Miranda, Juliana Mejía Grueso, Rachid Laajaj, Gabriel Carrasquilla, Martha Vives Florez, Ana María Vesga Gaviria, Ana María Ortiz Hoyos, Esteban Orlando Vanegas Duarte, Alejandra Velásquez Morales, Nubia Velasco, Silvia Restrepo Restrepo Jan 2023

Assessing Pandemic Preparedness, Response, And Lessons Learned From The Covid-19 Pandemic In Four South American Countries: Agenda For The Future, Andrea Ramírez Varela, Michael Touchton, J Jaime Miranda, Juliana Mejía Grueso, Rachid Laajaj, Gabriel Carrasquilla, Martha Vives Florez, Ana María Vesga Gaviria, Ana María Ortiz Hoyos, Esteban Orlando Vanegas Duarte, Alejandra Velásquez Morales, Nubia Velasco, Silvia Restrepo Restrepo

Faculty, Staff and Student Publications

INTRODUCTION: The COVID-19 pandemic emerged in a context that lacked adequate prevention, preparedness, and response (PPR) activities, and global, regional, and national leadership. South American countries were among world's hardest hit by the pandemic, accounting for 10.1% of total cases and 20.1% of global deaths.

METHODS: This study explores how pandemic PPR were affected by political, socioeconomic, and health system contexts as well as how PPR may have shaped pandemic outcomes in Argentina, Brazil, Colombia, and Peru. We then identify lessons learned and advance an agenda for improving PPR capacity at regional and national levels. We do this through a …


Editorial: The Impact Of Inflammation On The Oral Microbiome, Chun-Teh Lee, Loreto Abusleme, Thomas E Van Dyke Jan 2023

Editorial: The Impact Of Inflammation On The Oral Microbiome, Chun-Teh Lee, Loreto Abusleme, Thomas E Van Dyke

Faculty, Staff and Student Publications

No abstract provided.


The Origins Of Dance: Characterizing The Development Of Infants' Earliest Dance Behavior, Minju Kim, Adena Schachner Jan 2023

The Origins Of Dance: Characterizing The Development Of Infants' Earliest Dance Behavior, Minju Kim, Adena Schachner

Psychology Faculty Articles and Research

Dance is a universal human behavior and a crucial component of human musicality. When and how does the motivation and tendency to move to music develop? How does this behavior change as a process of maturation and learning? We characterize infants’ earliest dance behavior, leveraging parents’ extensive at-home observations of their children. Parents of infants aged 0–24 months (N = 278, 82.7% White, 84.5% in the United States, 46.0% of household incomes ≥ $100,000) were surveyed regarding their child’s current and earliest dance behavior (movement by the child, during music, that the parent considered dance), motor development, and their …


Wastewater Pandemic Preparedness: Toward An End-To-End Pathogen Monitoring Program, Justin R Clark, Austen Terwilliger, Vasanthi Avadhanula, Michael Tisza, Juwan Cormier, Sara Javornik-Cregeen, Matthew Clayton Ross, Kristi Louise Hoffman, Catherine Troisi, Blake Hanson, Joseph Petrosino, John Balliew, Pedro A Piedra, Janelle Rios, Jennifer Deegan, Cici Bauer, Fuqing Wu, Kristina D Mena, Eric Boerwinkle, Anthony W Maresso Jan 2023

Wastewater Pandemic Preparedness: Toward An End-To-End Pathogen Monitoring Program, Justin R Clark, Austen Terwilliger, Vasanthi Avadhanula, Michael Tisza, Juwan Cormier, Sara Javornik-Cregeen, Matthew Clayton Ross, Kristi Louise Hoffman, Catherine Troisi, Blake Hanson, Joseph Petrosino, John Balliew, Pedro A Piedra, Janelle Rios, Jennifer Deegan, Cici Bauer, Fuqing Wu, Kristina D Mena, Eric Boerwinkle, Anthony W Maresso

Faculty, Staff and Student Publications

Molecular analysis of public wastewater has great potential as a harbinger for community health and health threats. Long-used to monitor the presence of enteric viruses, in particular polio, recent successes of wastewater as a reliable lead indicator for trends in SARS-CoV-2 levels and hospital admissions has generated optimism and emerging evidence that similar science can be applied to other pathogens of pandemic potential (PPPs), especially respiratory viruses and their variants of concern (VOC). However, there are substantial challenges associated with implementation of this ideal, namely that multiple and distinct fields of inquiry must be bridged and coordinated. These include engineering, …


Genetic Sex Estimation From Aztatlán Sites In West Mexico, Ava Carolyn Godhardt Jan 2023

Genetic Sex Estimation From Aztatlán Sites In West Mexico, Ava Carolyn Godhardt

Graduate Student Theses, Dissertations, & Professional Papers

No abstract provided.


Journeys To Destinations: Applying Big Data And Qualitative Gis To Understand Recreational Ecosystem Services And Visitor Decision-Making In Park And Protected Area Networks In Missoula, Mt, Peter J. Whitney Jan 2023

Journeys To Destinations: Applying Big Data And Qualitative Gis To Understand Recreational Ecosystem Services And Visitor Decision-Making In Park And Protected Area Networks In Missoula, Mt, Peter J. Whitney

Graduate Student Theses, Dissertations, & Professional Papers

No abstract provided.


Causes Of Low Leaf-Shredding Insect Diversity In Neotropical Streams, Pavel Ernesto Garcia Soto Jan 2023

Causes Of Low Leaf-Shredding Insect Diversity In Neotropical Streams, Pavel Ernesto Garcia Soto

Graduate Student Theses, Dissertations, & Professional Papers

Biological diversity peaks in tropical regions followed by a steady decline towards the poles. It is a pattern in γ-diversity that sometimes explains latitudinal patterns in local assemblages (α) and their species turnover (β), which suggests that similar ecological mechanisms might be operating at different latitudes. However, not all taxa have more species towards the equator. Aquatic shredder insect richness peaks in temperate streams relative to tropical streams, where local aquatic shredder insect assemblages have low α-diversity. Three mechanisms have been proposed as factors structuring aquatic shredder insect assemblages in tropical streams, leading to shredder assemblages with low α-diversity, 1) …


Supervised Cancer Rehabilitation: Applications For Utilizing Existing Cardiopulmonary Rehabilitation Facilities For Cancer Patients And Survivors, Nancy A. Condit Jan 2023

Supervised Cancer Rehabilitation: Applications For Utilizing Existing Cardiopulmonary Rehabilitation Facilities For Cancer Patients And Survivors, Nancy A. Condit

Graduate Student Theses, Dissertations, & Professional Papers

Currently, the NIH reports there are approximately 18 million Americans with a history of cancer. Cancer statistics are projected to rise to 22.1 million by 2030. In addition to cancer, cardiovascular diseases are globally the leading causes of mortality and morbidity. The body of research in this area clearly demonstrates that greater amounts of physical activity correspond with a lower risk of cancer recurrence and all-cause mortality, including cardiovascular disease (CVD). Exercise rehabilitation success in cancer patients, both during and after treatment, is limited by several barriers, including the lack of facilities, trained personnel and financial resources. In response to …


Perspectives Of Foster Parents And Former Foster Children Surrounding Emancipation And College Supports And Barriers, Ashlyn Maize Kincaid Jan 2023

Perspectives Of Foster Parents And Former Foster Children Surrounding Emancipation And College Supports And Barriers, Ashlyn Maize Kincaid

Graduate Student Theses, Dissertations, & Professional Papers

The current study had two aims. The first aim was to explore and compare the perspectives of former foster youth and foster parents surrounding the emancipation process. The current study aimed to uncover what information is being shared with foster children when approaching the age of emancipation about life choices such as college, careers, housing, finances, and social support, as well as who is sharing this information and how accurate and helpful it is for the foster youth. Foster parents were asked questions pertaining to their level of training, knowledge of available resources, and experiences with transitioning foster children out …


“Frozen”: Tonic Immobility And Posttraumatic Outcomes Among Survivors Of Sexual Assault, Nora Grace Halverson Jan 2023

“Frozen”: Tonic Immobility And Posttraumatic Outcomes Among Survivors Of Sexual Assault, Nora Grace Halverson

Graduate Student Theses, Dissertations, & Professional Papers

Tonic immobility (TI), a temporary, involuntary state of paralysis marked by motor inhibition and vocal suppression, has been a well-documented occurrence among animals. Humans also experience TI, which has previously been referred to as trauma- or rape-induced paralysis and freezing. TI among survivors of sexual assault has been associated with greater PTSD and increased risk of depression. Existing studies have not adequately explored additional posttraumatic outcomes of TI beyond PTSD diagnostic criteria, nor has prior research sufficiently tested the mechanistic relationship between TI and PTSD. The objective of the current study was to integrate and expand upon prior research regarding …


Suppress Not: Examining The Relationship Between Prospection And Emotional Suppression In A Depressed Population, Chelsey M. Maxson Jan 2023

Suppress Not: Examining The Relationship Between Prospection And Emotional Suppression In A Depressed Population, Chelsey M. Maxson

Graduate Student Theses, Dissertations, & Professional Papers

The aim of the present study was to elucidate the relationship between two transdiagnostic mechanisms of psychopathology: prospection (i.e., one’s ability to imagine the future), and emotional suppression, a maladaptive emotion regulation (ER) strategy. Specifically, we proposed that when individuals engage in emotional suppression, it interferes with prospection, which might then contribute to the development of depressive symptoms.

To assess the relationship between emotional suppression and prospection in individuals with depression we used an online experimental paradigm with an MTurk sample of 128 participants (64 depressed; 64 non-depressed) randomly assigned to one of two conditions: the depressed suppression induction condition …


Structural Properties Of The Interactions Between Cytochrome C And Cardiolipin, Ariel Kristine Frederick Jan 2023

Structural Properties Of The Interactions Between Cytochrome C And Cardiolipin, Ariel Kristine Frederick

Graduate Student Theses, Dissertations, & Professional Papers

The interaction between cytochrome c and cardiolipin is known to be essential for the onset of apoptosis: cytochrome c becomes competent for peroxidase activity due to the presence of reactive oxygen species and oxidizes cardiolipin, ultimately resulting in mitochondrial membrane pores that allow cytochrome c to escape into the cytosol and form the apoptosome complex. As such, understanding this reaction is critical to understanding the mechanisms of programmed cell death. Despite this, many components of this interaction are still under debate. Examples of this include which components of cytochrome c structure are responsible for the large differences in peroxidase activity …


Queering Adolescent Ecology: A Minority Stress-Informed Exploration Of Risk And Protective Factors Related To Anxiety Symptoms In Gender And Sexual Minority Adolescents, Kinsie Jean Dunham Jan 2023

Queering Adolescent Ecology: A Minority Stress-Informed Exploration Of Risk And Protective Factors Related To Anxiety Symptoms In Gender And Sexual Minority Adolescents, Kinsie Jean Dunham

Graduate Student Theses, Dissertations, & Professional Papers

Substantial epidemiological research (Talley et al., 2016; Burton et al., 2013; Institute of Medicine [IOM], 2011) indicates that gender and sexual minorities (GSM; non-cisgender and non-heterosexual, respectively) disproportionately experience health disparities, including anxiety disorders (e.g., panic disorder, generalized anxiety disorder, social anxiety disorder; Cochran et al., 2003; Gillman et al., 2001). Disparities in anxiety symptoms and disorders for GSM adults may begin to emerge in adolescence (Fish & Pasley, 2015; Needham, 2012; Ueno, 2010). In particular, GSM adolescents report higher rates of anxiety symptoms and anxiety disorders (Kosciw et al., 2014; Mutanski & Liu, 2013) than heterosexual, cisgender adolescents. Minority …


Evaluating The Relative Influence Of Soil Water Potential, Soil Moisture, And Vapor Pressure Deficit On Semi-Arid Vegetation Dynamics, Kayla R. Jamerson Jan 2023

Evaluating The Relative Influence Of Soil Water Potential, Soil Moisture, And Vapor Pressure Deficit On Semi-Arid Vegetation Dynamics, Kayla R. Jamerson

Graduate Student Theses, Dissertations, & Professional Papers

Knowledge of vegetation’s response to soil water availability and atmospheric demand is critical to understanding the impact of climate change on semi-arid ecosystems. However, limited field-based research has been conducted to assess the relative importance of these drivers and previous research has simplified the assessment of soil water availability by relying on soil volumetric water content (VWC) as a primary control on plant growth, which, as opposed to soil water potential (Ψsoil), does not account for the effects of soil texture on plant available water. To address these gaps, we compared remotely sensed indicators of vegetation response to field based …


Investigating Changes In Er-To-Golgi Protein Transport Following A Short Calcium Pulse: Roles Of Alg-2 And Peflin, Alaa Mohammed Yosri Shaheen Jan 2023

Investigating Changes In Er-To-Golgi Protein Transport Following A Short Calcium Pulse: Roles Of Alg-2 And Peflin, Alaa Mohammed Yosri Shaheen

Graduate Student Theses, Dissertations, & Professional Papers

The ER-Golgi interface is a very dynamic environment that involves the movement of protein-loaded vesicles forward and backward. The movement of COPII-coated vesicles from the ER to the Golgi is the initial step in the movement of secreted, organellar, and cell surface proteins toward their final destinations. Many factors can regulate this step, including cytosolic calcium increases. In this study, we examined the effect of a transient calcium pulse on recruitment to ER exit sites of cargo proteins for ER export, the calcium-sensitive regulatory proteins apoptosis-linked gene 2 (ALG-2) and peflin, and the COPII outer coat subunits Sec31A and Sec13. …


Fundamental Investigation On Anion Binding Employing The Hydrogen Bond Enhanced Halogen Bond, Jiyu Sun Jan 2023

Fundamental Investigation On Anion Binding Employing The Hydrogen Bond Enhanced Halogen Bond, Jiyu Sun

Graduate Student Theses, Dissertations, & Professional Papers

Noncovalent interactions play a critical role in chemistry and biochemistry. Understanding how to modulate closely situated noncovalent interactions is of utmost importance in the design of functional materials, supramolecular assemblies, pharmaceuticals, and catalysts. Over the past two decades, there has been a significant surge in research and applications on halogen bonds, driven by their exceptional properties such as high directionality and unique tunability when compared to hydrogen bonds. Taking inspiration from nature and other synthetic anion-binding receptors that effectively employ multiple noncovalent interactions in a concerted manner, we have developed an innovative preorganization strategy termed the "Hydrogen Bond Enhanced Halogen …