Digital Commons Network^™

Toward Sustainable Environmental Quality: Priority Research Questions For Europe, Den Brink Pj Van, Aba Boxall, L Maltby, Bw Brooks, Ma Rudd, T Backhaus, D Spurgeon, V Verougstraete, C Ajao, Gt Ankley, Se Apitz, K Arnold, T Brodin, M Cañedo-Argüelles, J Chapman, J Corrales, M-A Coutellec, Tf Fernandes, J Fick, At Ford, Papiol G Giménez, Kj Groh, Th Hutchinson, H Kruger, Jvk Kukkonen, S Loutseti, S Marshall, D Muir, Me Ortiz-Santaliestra, Kb Paul, A Rico, I Rodea-Palomares, J Römbke, T Rydberg, H Segner, M Smit, Gestel Cam Van, M Vighi, I Werner, Ei Zimmer, Wensem J Van

School of Geography, Earth and Environmental Sciences

The United Nations' Sustainable Development Goals have been established to end poverty, protect the planet, and ensure prosperity for all. Delivery of the Sustainable Development Goals will require a healthy and productive environment. An understanding of the impacts of chemicals which can negatively impact environmental health is therefore essential to the delivery of the Sustainable Development Goals. However, current research on and regulation of chemicals in the environment tend to take a simplistic view and do not account for the complexity of the real world, which inhibits the way we manage chemicals. There is therefore an urgent need for a …

Hidden In Plain Sight: Species Richness And Habitat Characterisation Of Sublittoral Pebble Beds, Julian Evans, Martin J. Attrill, Joseph A. Borg, Peter A. Cotton, Patrick J. Schembri

School of Biological and Marine Sciences

No abstract provided.

Infragravity Waves: From Driving Mechanisms To Impacts, X Bertin, Ma Davidson

School of Biological and Marine Sciences

No abstract provided.

Block And Boulder Accumulations On The Southern Coast Of Crete (Greece): Evidence For The 365 Ce Tsunami In The Eastern Mediterranean, Sarah J. Boulton, Michael R.Z. Whitworth

School of Geography, Earth and Environmental Sciences

No abstract provided.

The Courtyard Pattern's Thermal Efficiency: Limits And Significance Of Impact, O Al-Hafith, Bk Satish, S Bradbury, P Dewilde

School of Art, Design and Architecture

No abstract provided.

Using Natural Analogues To Investigate The Effects Of Climate Change And Ocean Acidification On Northern Ecosystems, Samuel S.P. Rastrick, Helen Graham, Kumiko Azetsu-Scott, Piero Calosi, Melissa Chierici, Agneta Fransson, Haakon Hop, Jason Hall-Spencer, Marco Milazzo, Peter Thor, Tina Kutti

School of Biological and Marine Sciences

No abstract provided.

Intravenous Injection Of Unfunctionalized Carbon-Based Nanomaterials Confirms The Minimal Toxicity Observed In Aqueous And Dietary Exposures In Juvenile Rainbow Trout ( Oncorhynchus Mykiss ), David Boyle, Paul A. Sutton, Richard D. Handy, Theodore B. Henry

School of Geography, Earth and Environmental Sciences

No abstract provided.

Detecting Environmental Change: How Many Samples Are Required?, M. J. Gardner, S. D.W. Comber

School of Geography, Earth and Environmental Sciences

One of the most important functions of environmental monitoring is the detection of change. This can be the delineation of deteriorating circumstances or the identification of the success of remedial measures. The design of effective monitoring of change (and hence the optimisation of resources devoted to monitoring) relies on appropriate replication - knowing how many samples are required. Lack of information on the variance of the measured parameter is often a barrier to determining the optimum sampling strategy. An important new information resource on within-site variance of the concentrations of over 60 trace substances in wastewater treatment works effluents has …

Sterol Identification In Floating Arctic Sea Ice Algal Aggregates And The Antarctic Sea Ice Diatom Berkeleya Adeliensis, Simon T. Belt, Thomas A. Brown, Lukas Smik, Philipp Assmy, C. J. Mundy

School of Geography, Earth and Environmental Sciences

No abstract provided.

Archaeal And Bacterial Glycerol Dialkyl Glycerol Tetraether (Gdgt) Lipids In Environmental Samples By High Temperature-Gas Chromatography With Flame Ionisation And Time-Of-Flight Mass Spectrometry Detection, Sabine K. Lengger, Paul A. Sutton, Steven J. Rowland, Sarah J. Hurley, Ann Pearson, B. David A. Naafs, Xinyue Dang, Gordon N. Inglis, Richard D. Pancost

School of Geography, Earth and Environmental Sciences

Archaeal isoprenoidal glycerol dibiphytanyl glycerol tetraether lipids (iGDGTs) and their non-isoprenoidal branched bacterial analogues (brGDGTs) have widespread applications in biogeochemistry and paleothermometry. Analysis of GDGTs usually involves separation using high performance liquid chromatography, typically coupled via atmospheric pressure chemical ionisation to mass spectrometric detection in selected ion-monitoring mode (HPLC–APCI-MS). However, reliable determination of ratios and, in particular, quantification by this technique, can be challenging due to differences in ionisation efficiencies of the various compounds. Quantification of GDGTs also relies on external calibration of the relative response to an internal standard with authenticated GDGTs, which are often not readily accessible. Here, …

Improving The Quality Of Cognitive Screening Assessments: Acemobile, An Ipad‐Based Version Of The Addenbrooke's Cognitive Examination‐Iii, Cgj Newman, Ad Bevins, Jp Zajicek, Jr Hodges, Et Al

Peninsula Medical School

Introduction Ensuring reliable administration and reporting of cognitive screening tests are fundamental in establishing good clinical practice and research. This study captured the rate and type of errors in clinical practice, using the Addenbrooke's Cognitive Examination-III (ACE-III), and then the reduction in error rate using a computerized alternative, the ACEmobile app. Methods In study 1, we evaluated ACE-III assessments completed in National Health Service (NHS) clinics (n = 87) for administrator error. In study 2, ACEmobile and ACE-III were then evaluated for their ability to capture accurate measurement. Results In study 1, 78% of clinically administered ACE-IIIs were either scored …

Including Topographical Effects In Slant-Range Modeling, Kari C. Ward, Kyle J. Demarsy

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Spacecraft descent-to-landing navigation often includes the use of a slant-range measurement, the distance from the spacecraft to a surface along the off-nadir pointing direction of the sensor. Modeling a slant range sensor requires a reference surface, approximations of which include spherical and ellipsoidal surfaces, spherical harmonic models, and topographical maps based on prior reconnaissance data. For the spherical and ellipsoidal reference surfaces, a closed-form solution of the slant-range measurement exists. However, these approaches are inaccurate with respect to the true surface. This paper develops a method to implement digital elevation maps of a given surface to create a topography-based model …

Electric Solid Propellant Ablation In A Pulsed Electric Thruster, Matthew S. Glascock, Joshua L. Rovey

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Electric solid propellants are advanced solid chemical rocket propellant that can be controlled (ignited, throttled and extinguished) with electric current. Work reported here focuses on application of electric solid propellant in a pulsed electric thruster similar to a pulsed plasma thruster. In the future it may be possible to develop a dual-mode electric solid propellant thruster that is switchable between steady applied electric current chemical mode and pulsed alternating electric current electric mode. Results presented here use a laboratory test thruster to create an arc discharge of 5-20 J per pulse in a cylindrical cavity of propellant. Results for Teflon …

Square-Root Consider Filters With Hyperbolic Householder Reflections, James S. Mccabe, Kyle J. De Mars

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Maintaining positive definiteness of a filter's error covariance estimate is of paramount importance to any stable and reliable estimation scheme. Two widely used methods for protecting a filter from loss of positive-definiteness are that of consider filtering and square-root filtering. Despite their widespread use in estimation applications, a filtering methodology that combines the two techniques has yet to be presented in a unified, streamlined architecture. This paper develops a new approach to square-root filtering using hyperbolic Householder reflections. A specialization of the method is considered to permit computationally efficient applications, and a numerical example pertaining to a ballistic reentry is …

Set-Theoretic Model Reference Adaptive Control Of A Generic Transport Model, Ehsan Arabi, Tansel Yucelen, Nhan T. Nguyen

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper illustrates an application of a recently developed set-theoretic model reference adaptive control architecture on a generic transport model developed by NASA. The set- theoretic model reference adaptive control allows the system error bound between the state of an uncertain dynamical system and the state of a given reference model to be less than a-priori, user-defined worst-case performance bound. Thus, it has the capability to enforce strict performance guarantees to the adaptively controlled uncertain dynamical systems. specifically, after designing set-theoretic adaptive controllers for both longitudinal and lateral-directional dynamics here, the efficacy of this architecture is illustrated on the NASA …

Linear Burn Rate Of Monopropellant For Multi-Mode Micropropulsion, Alex J. Mundahl, Steven P. Berg, Joshua L. Rovey

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Multi-mode micro propulsion is a technology that can enable rapidly composable small satellites with unprecedented mission flexibility. To maximize mission flexibility a multi-mode micro propulsion monopropellant must be shared between the chemical and electric propulsion modes. Previous research has identified a promising monopropellant that is both readily catalytically exothermically decomposed (chemical mode) and electro sprayable (electric mode). In this work the linear burn rate of this monopropellant is determined and used to aid the design of a microtube catalytic chemical thruster. Experiments with a pressurized fixed volume reactor are used to determine the linear burn rate. Benchmark experiments use a …

Electrospray Mass Spectroscopy Of A Han-Based Monopropellant, Mitchell J. Wainwright, Joshua L. Rovey, Shawn W. Miller, Benjamin D. Prince, Steven P. Berg

Mechanical and Aerospace Engineering Faculty Research & Creative Works

A mixture of [Emim][EtSO4]-HAN is a potential propellant suitable in a multi-mode chemical-electric microtube-electrospray micro propulsion system. This paper reports experimental mass spectrum results for this liquid when electro sprayed in a 50 μm capillary emitter. Mass spectra from 0-600 amu were obtained over a variety of angles and flow rates from 2 pL/sec to 3 nL/sec in both cation and anion extraction mode. Effects of flow rate and angular orientation on the spectra agree well with literature. Results show at least three of the four monomer species are emitted, along with numerous other species, some of which have been …

Review Of Metal Am Simulation Validation Techniques, Aaron Flood, Frank W. Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Due to the complexity of metal AM (additive manufacturing), it can require many trial runs to obtain processing parameters which produce a quality build. Because of this trial and error process, the drive for simulations of AM has grown significantly. A simulation only becomes useful to researchers if it can be shown that it is a true representation of the physical process being simulated. Each process being simulated has a different method of validation to show it is an accurate representation of the process. This paper explores the various methodologies for validation of laser-based metal AM simulations, focusing mainly on …

Industrial Robot Trajectory Accuracy Evaluation Maps For Hybrid Manufacturing Process Based On Joint Angle Error Analysis, Zhiyuan Wang, Renwei Liu, Todd E. Sparks, Xueyang Chen, Frank W. Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Industrial robots have been widely used in various fields. The joint angle error is the main factor that affects the accuracy performance of the robot. It is important to notice that these kinematic parameters error cannot be eliminated from the robot system completely. Even after calibration, these errors still exist and will be fluctuated during the robot system running. This paper proposed a new method of finding the best position and orientation to perform a specific working path based on the current accuracy capacity of the robot system. By analyzing the robot forward/inverse kinematic and the angle error sensitivity of …

A Two-Dimensional Simulation Of Grain Structure Growth Within Substrate And Fusion Zone During Direct Metal Deposition, Jingwei Zhang, Lei Yan, Wei Li, Frank W. Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

In this chapter, a predictive multiscale model based on a cellular automaton (CA)-finite element (FE) method has been developed to simulate thermal history and microstructure evolution during metal solidification for direct metal deposition (DMD) process. The macroscopic FE calculation that is validated by the thermocouple experiment is developed to simulate the transient temperature field and cooling rate of single layer and multiple layers. In order to integrate the different scales, a CA-FE coupled model is developed to combine with thermal history and simulate grain growth. In the mesoscopic CA model, heterogeneous nucleation sites, grain growth orientation and rate, epitaxial growth, …

Efficient Inverse Design Of Transonic Airfoils Using Variable-Resolution Models And Manifold Mapping, Xiaosong Du, Leifur Leifsson, Slawomir Koziel

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This paper presents an efficient approach for simulation-based inverse design of airfoil shapes using variable-fidelity computational fluid dynamics models and manifold mapping (MM). Inverse design involves determining an airfoil shape fulfilling a given target performance characteristic. In particular, the pressure coefficient distribution is typically used in aerodynamic inverse design. Such a task can be challenging when using computationally expensive simulations. In the context of local optimization, the MM technique searches for a new design in the vicinity of the current design by constructing a fast multi-fidelity model, which is setup by the available evaluations of each of the high- and …

Monobore Completion Design: Classification, Applications, Benefits And Limitations, Anwar Khaled Al-Fadhli

Masters Theses

"A monobore completion is a simple completion design that uses the same internal diameter from the bottom of the well to surface. This may be accomplished by cementing a string of casing in a well, or by having tubing stabbed into a polished bore receptacle on a casing liner the same size as the tubing. Monobore completions have been applied extensively in oil and gas fields around the world, both onshore and offshore, from very low reservoir flow to extremely high production rates, since the late 1980s. They have proven beneficial due to their simplicity and cost savings. This study …

Data Analysis Of Low-Salinity Waterflooding To Enhance The Oil Recovery In Sandstone Reservoirs, Nadia Ariani

Masters Theses

"The lack of a single reasonable general mechanism to describe how low-salinity waterflooding can improve oil recovery in both laboratory and field pilot projects has increased the interests of many researchers and stakeholders. There has not been observed the relationship of formation brine salinity and injected brine salinity to see how much salinity is reduced to produce the maximum enhanced oil recovery by LSWF. There is no guidance in what EOR stage the LSWF is best implemented. This work collects data from various published literature to develop a comprehensive data set regarding low-salinity waterflooding in sandstone reservoirs. The LSWF mechanisms …

Facile Synthesis Of Nanostructured Metal Borides And Composites For Applications In Sustainable Energy, Maalavan Arivu

Masters Theses

"Electrocatalytic water splitting is a promising solution for sustainable energy generation since one of the half reactions lead to the formation of H₂ which is a clean fuel. The other half of the reaction leading to O₂ evolution is an energy intensive process necessitating the need for an electrocatalyst to break the activation barrier for the commencement of the reaction. In this work we will focus on expanding the family of non-oxidic OER electro-catalysts, especially borides, whereby, apart from facilitating delocalization of electron cloud on the catalytically active transition metal site, low anion electronegativity and increased covalency in …

Thermal Analysis And Control Of Small Satellites In Low Earth Orbit, Katelyn Elizabeth Boushon

Masters Theses

"Small satellites are becoming more popular in the space sector, primarily due to their lower cost and shorter development time. Much of the information available about satellite thermal analysis and control refers to larger spacecraft. Sorting through this information to find the practices specifically applicable for small satellites can be a daunting task, particularly for inexperienced engineers. This thesis study is intended to inform the reader about basic thermal control and analysis methods that relate specifically to small satellites in low Earth orbit. A case study involving a satellite designed by the Missouri University of Science and Technology Satellite Research …

Development And Monte Carlo Validation Of A Finite Element Reactor Analysis Framework, Wayne J. Brewster

Masters Theses

"This study presents the development and Monte Carlo validation of a continuous Galerkin finite element reactor analysis framework. In its current state, the framework acts as an interface between the mesh preparation software GMSH and the sparse linear solvers in MATLAB, for the discretization and approximation of 1-D, 2-D, and 3-D linear partial differential equations. Validity of the framework is assessed from the following two benchmarking activities: the 2-D IAEA PWR benchmark; and the 2-D Missouri Science and Technology Reactor benchmark proposed within this study. The 2-D IAEA PWR multi-group diffusion benchmark is conducted with the following discretization schemes: linear, …

Bioaccessibility Of Lead From Contaminated Soil Using Phosphate Treatment -- Physiologically Based Extraction Test And In Vitro Gastrointestinal Method Test, Austin Charles Doss

Masters Theses

"Phosphate treatments are used to immobilize lead in soil by forming pyromorphite. Soil from Bonne Terre, Mo was collected to study whether such treatment decreases the bioaccessibility of lead. The soil was treated using 0.5 soil wt% of phosphate. Treatments were: none, phosphoric acid, triple super phosphate, and organic bone meal. Each sample was studied after one, four, sixteen, and twenty weeks; during this time span, water was added approximating the average rainfall rate. Percolated water was collected to test the leached phosphate concentrations. Phosphate was below the detection limit in that leachate. Remediated soil samples were used in Physiologically …

An Integrated Method For Understanding The Fluid Flow Behavior And Forecasting Well Deliverability In Gas Condensate Reservoirs With Water Aquifer Drive, Abdulaziz Mustafa Em. Ellafi

Masters Theses

"Gas condensate reservoirs constitute a significant portion of global hydrocarbon reserves. In these reservoirs, as bottomhole pressure falls below the dew point, liquid develops in the pore space. This results in the formation of a liquid bank near the wellbore region that decreases gas mobility, which then reduces gas inflow. Some gas condensate reservoirs have bottom aquifer drive, which also negatively impacts gas production. This research used a field case study to demonstrate an integrated workflow for forecasting well deliverability in a gas condensate field in Libya. The workflow began with the interpretation of open-hole log data to identify the …

Computational Intelligence Methods For Predicting Fetal Outcomes From Heart Rate Patterns, Vinayaka Nagendra Harikishan Gude Divya Sampath

Masters Theses

"In this thesis, methods for evaluating the fetal state are compared to make predictions based on Cardiotocography (CTG) data. The first part of this research is the development of an algorithm to extract features from the CTG data. A feature extraction algorithm is presented that is capable of extracting most of the features in the SISPORTO software package as well as late and variable decelerations. The resulting features are used for classification based on both U.S. National Institutes of Health (NIH) categories and umbilical cord pH data. The first experiment uses the features to classify the results into three different …

Effect Of Variation Of Parameters On Biogas Production Using Aspen Plus & Dynamic Simulation Using Mimic, Shruti Shrikant Karambelkar

Masters Theses

"Design and management for Biogas production have gained significance in growing dependency on Renewable energy resources. This would need a detailed information on steady state and dynamic behavior of systems. In order to make this process environmentally ecofriendly, its needs a lot of improvisation on process simulation. Anaerobic digestion helps treat this inefficient water to be converted into water fit for effluent purposes.

Byproducts contain consists of organic, inorganic and wastes which lead to a high COD content and thus, cannot be discarded into the outlets. The anaerobic digestion process. A study of these effects with simulation need to be …