Digital Commons Network^™

Tunable Electronic And Optical Properties Of Low-Dimensional Materials, Shiyuan Gao

Arts & Sciences Graduate Student Theses and Dissertations

Two-dimensional (2D) materials with single or a few atomic layers, such as graphene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMDCs), and the heterostructures or one-dimensional (1D) nanostructures they form, have attracted much attention recently as unique platforms for studying many condensed-matter phenomena and holds great potentials for nanoelectronics and optoelectronic applications. Apart from their unique intrinsic properties which has been intensively studied for over a decade by now, they also allow external control of many degrees of freedom, such as electrical gating, doping and layer stacking. In this thesis, I present a theoretical study of the electronic and …

Radiolabeled Nanohydroxyapatite As A Platform For The Development Of New Pet Imaging Agents, Stacy Lee Queern

Arts & Sciences Graduate Student Theses and Dissertations

Positron emission tomography (PET) imaging utilizes drugs labeled with positron emitters to target and evaluate different biological processes occurring in the body. Tailoring medicine to the individual allows for higher quality of care with better diagnosis and treatment and is a key purpose for advancing research into developing new platforms for PET imaging agents. A PET nuclide of high interest for the development of these agents is 89Zr. This can be attributed to the long half-life of 3.27 days and low positron energy of 89Zr.In this work, we developed a production method for 89Zr using Y sputtered coins that is …

Modeling The Bioactivation And Subsequent Reactivity Of Drugs, Tyler Brian Hughes

Arts & Sciences Graduate Student Theses and Dissertations

Metabolism can convert drugs to harmful reactive metabolites that conjugate to DNA and off-target proteins. Reactive metabolites are a significant driver of both drug candidate attrition and withdrawal from the market of already approved drugs. Unfortunately, reactive metabolites are difficult to study in vivo, because they are transitory and generally do not circulate. Instead, this work computationally models both metabolism and reactivity. Using deep learning, predictive models were developed for the metabolic formation of quinones and epoxides, which together account for about half of known reactive metabolites. Additionally, an accurate model of DNA and protein reactivity was constructed, which predicts …

Anodic Cyclization Reaction: Manipulation Of Reaction Pathway And Efforts To Radical Cation And Radical Intermediate, Ruozhu Feng

Arts & Sciences Graduate Student Theses and Dissertations

In recent years, synthetic chemists have been expressing significant interest in electro-organic synthetic methods. This interest is being fueled by the existence of an increasing number of successful methods in the literature and the availability of new electrochemical equipment that removes the barrier to attempting an electrolysis reaction for the first time. Yet while these developments have fueled growth in some areas of electro-organic synthesis (the recycling of chemical catalysts for example), other areas remain underdeveloped. One such area is the exploration of reactions that can be triggered directly as an electrode surface without the use of any chemical reagent. …

Linking Structure And Dynamics In Metallic Liquids: A Combined Experimental And Molecular Dynamics Approach, Robert Ashcraft

Arts & Sciences Graduate Student Theses and Dissertations

A major outstanding problem in condensed matter physics is the nature of the glass transition, in which a rapidly cooled liquid can bypass the transition into a crystalline state and the liquid structure is "frozen-in" due to kinetic arrest. To characterize the fundamental features behind this transition the liquid, both in the high temperature (equilibrium) and supercooled state, needs to be better understood. By examining the relationship between structure and dynamics a better characterization of the liquid state and a determination of the mechanisms that are ultimately important for the formation of the glass can be gained. In this dissertation, …

Neural And Behavioral Associations Of Drinking And Empathic Processing, Charles Samuel Henry Robinson

Psychology ETDs

Alcohol Use Disorder (AUD) is a major health problem, yet most individuals with AUD do not perceive a need for formal treatment and do not receive treatment. The lack of treatment seeking among individuals with AUD may suggest a lack of self-awareness and insight into the seriousness of AUD related problems. Moreover, individuals who have lost or are at risk of losing major relationships are especially likely to perceive the need for help. Thus, it may be the case that awareness of the influence of one’s drinking on social relationships and the feelings of others (i.e., empathy) could improve treatment …

Making Space For Makerspace: How Adding A Makerspace Can Benefit Art Museum Education Programming, Kaeleigh Thorp

Master's Projects and Capstones

In this capstone project, I advocate for adding makerspaces to art museum education programming. I review the foundational educational concepts of a makerspace which help explain why it is a modern strategy to increasing visitor learning. This includes John Dewey’s theories of experience and education, Howard Gardner’s multiple intelligences theory, George Hein’s studies of museum visitor behavior, and the physiological science of learning. I then propose four key terms essential for visitor learning, and explain how makerspaces successfully incorporate them. The four key terms are: 1. multiple intelligences, 2. direct experience, 3. inquiry based and open ended learning, and 4. …

Examining The Training Transfer Practice Of A Financial Institution: An Action Research Study, Maria Lourdes Lourdes Gutierrez

UNLV Theses, Dissertations, Professional Papers, and Capstones

Many organizations rely on training to improve the skills and knowledge of its human resources. The underlying assumption is that employees will use what they learned when they return to the workplace. Although there is evidence that learning occurred it does not always result in transfer (Mosel, 1957). Transfer is an issue of concern for training practitioners. If despite the significant investment no return is realized, then the training is not effective and the investment is wasted. This action research study was conducted in a financial institution in the Southwestern United States. The purpose of this study was to (1) …

Uas-Based Object Tracking Via Deep Learning, Marc Dinh

UNLV Theses, Dissertations, Professional Papers, and Capstones

Tracking is the task of identifying an object of interest and detect its position over time, and has numerous applications like surveillance, security and traffic control. In present times, unmanned aerial vehicles (UAV) have been more and more common which provides us with a new and less explored domain, with an ideal vantage point for surveillance and monitoring applications.. Aerial tracking is a particularly challenging task as it introduces new environmental variables such as rapid motion in 3D space. We propose a new deep learned tracker architecture catered to aerial tracking.

First, a study of six state-of-the-art deep learned trackers …

Human Thermal Comfort In Transition Space, Asawari Anil Pawar

UNLV Theses, Dissertations, Professional Papers, and Capstones

ABSTRACT

HUMAN THERMAL COMFORT IN TRANSITION SPACES

Objective: To evaluate and identify the relationship between personal factors and the climatic conditions that influence the human thermal comfort in transition spaces and suggest solutions for adaptation of the built environment, that would encourage active and healthy living in the tourist as well as local community.

Background:

By 2050, there is a prediction that two-thirds of the world population will be living in urban areas, which would add more than 2.5 billion people living in cities (Melnikov et al., 2017). Since Las Vegas is one of the fastest growing cities in Nevada, …

The Effectiveness Of State Ethics Commissions On Curbing Corruption And The Effect Of Corruption On State Economic Performance, Anthony J. Prato

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation investigates the effectiveness of anti-corruption policies implemented across the United States that significantly reduce public sector corruption. In addition to the normative desire to combat corruption, it documents, the economic impact that corruption has on each state's per capita gross domestic product. To investigate public sector corruption articles between the years 2010 – 2015were reviewed for news stories that report on public sector corruption at the state level and below. The practical implications of this dissertation, if incorporated into a state level anti-corruption policy, could be used to reduce public sector corruption and increase that states' economic health. …

Petrogenesis Of Enriched And Intermediate Poikilitic Shergottites: From Magmatic Source To Emplacement, Rachel Rahib

UNLV Theses, Dissertations, Professional Papers, and Capstones

Poikilitic shergottites, making up >20% of martian meteorites, likely represent a significant composition of the martian crust, as intrusive gabbroic rocks. To further constrain petrogenetic relationships amongst enriched and intermediate poikilitic shergottites, we utilize bulk rock trace element compositions, mineral major element compositions, phosphorus maps of olivine grains, oxygen fugacity (ƒO2) values, subsolidus equilibration temperatures, and quantitative textural analyses, of the most comprehensive suite of poikilitic shergottites yet (11 samples), including three newly recovered samples (Northwest Africa [NWA] 11065, NWA 11043, NWA 10961). Although petrographically light rare earth element (LREE) enriched and intermediate poikilitic shergottites are similar, distinct LREE abundances …

The Use Of Chemical Element Fingerprints To Investigate The Transformation Of Lake Sediments To Land Soils In Drying Lakes: A Case Study At Lake Mead, Nevada, Ji Hye Park

UNLV Theses, Dissertations, Professional Papers, and Capstones

Drying lakes are a worldwide catastrophe. The goals of this dissertation research were (1) to investigate whether chemical fingerprints of lake sediments, and nearby land soils, could be established by the analysis of 44 chemical elements, moisture content, Eh, pH, and leachable anions and if so, (2) whether the fingerprints could help explain the process of physical and chemical changes in the lake sediments as they became soils when the lake's water level fell and the anoxic sediments were exposed to the air and weather.

Lake Mead was chosen to model drying lakes because its water level has fallen over …

Prokaryotic Diversity And Aqueous Geochemistry Of Subsurface Environments Of The Death Valley Regional Flow System, Joshua David Sackett

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation summarizes over four years of effort towards the completion of a Ph.D. in Biological Sciences. The work presented in this document covers a broad range of topics, but a central unifying theme is prokaryotic life in the continental subsurface. The work presented in each chapter relied heavily on cultivation-independent methods for assessing prokaryotic communities, including prokaryotic community structure reconstruction from high-throughput sequencing of 16S rRNA gene libraries and single-cell genome analysis of novel uncultivated bacteria.

Chapter 2 examines the aqueous geochemistry and prokaryotic diversity of Devils Hole, a cavernous limnocrene and sole natural habitat for the critically endangered …

Calculation Of Access Charge For High Speed Rail Xpresswest Of Nevada, Sameeksha Sapkota

UNLV Theses, Dissertations, Professional Papers, and Capstones

XpressWest is a High Speed Rail (HSR) system that plans to connect Las Vegas with California at Palmdale. It will utilize the railway network of the California High Speed Rail (CAHSR) to connect Las Vegas with California destinations that include Los Angeles and San Francisco. For sharing the railway network of CAHSR, XpressWest will pay certain charge known as an access charge. The access charge is the fee paid by the train operator to the infrastructure owner for the addition of trains in a track. There are several access charge systems in the world. However, there is no study that …

Studies Of Inner-Shell Chemistry Of Mercury Based Compounds At Extreme Conditions, Sarah Schyck

UNLV Theses, Dissertations, Professional Papers, and Capstones

It has been theoretically predicted that when mercury difluoride (HgF2) is pressurized to above 50 GPa in the presence of molecular fluorine, it will most likely transform into mercury tetrafluoride (HgF4), thus mercury will behave as a transition element at high pressure. However, there is no experimental evidence verifying this prediction yet. To begin with, the crystalline properties of pure HgF2 at high pressure were not experimentally established. In this thesis, the high pressure structural properties of HgF2 are investigated by means of synchrotron X-ray powder diffraction. Our results reveal that the predicted, ambient cubic structure of HgF2 with the …

Application Of Machine Learning Techniques In Credit Card Fraud Detection, Ronish Shakya

UNLV Theses, Dissertations, Professional Papers, and Capstones

Credit card fraud is an ever-growing problem in today’s financial market. There has been a rapid increase in the rate of fraudulent activities in recent years causing a substantial financial loss to many organizations, companies, and government agencies. The numbers are expected to increase in the future, because of which, many researchers in this field have focused on detecting fraudulent behaviors early using advanced machine learning techniques. However, the credit card fraud detection is not a straightforward task mainly because of two reasons: (i) the fraudulent behaviors usually differ for each attempt and (ii) the dataset is highly imbalanced, i.e., …

Estimation Of The Parameters In A Spatial Regressive-Autoregressive Model Using Ord's Eigenvalue Method, Sajib Mahmud Mahmud Tonmoy

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this thesis, we study one of Ord's (1975) global spatial regression models.

Ord considered spatial regressive-autoregressive models to describe the interaction

between location and a response variable in the presence of several covariates. He also

developed a practical estimation method for the parameters of this regression model

using the eigenvalues of a weight matrix that captures the contiguity of locations.

We review the theoretical aspects of his estimation method and implement it in the

statistical package R.

We also implement Ord's methods on the Columbus, Ohio, crime data set from the

year 1980, which involves the crime rate of …

Cfd Modeling Of Smoke Movement In An Atrium, Robin Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this paper is to better understand the behavior of smoke movement in an atrium. Thus gives first responders and civilians in and out of building a better understanding

With the advancements of modern technology, computers and softwares make simulation models possible such as fire models to simulate fire and smoke movements. In this paper, a computational fluid dynamic (CFD) software Fire Dynamic Simulator (FDS) is used to conduct a series of atrium tests to investigate the effectiveness of smoke exhaust systems. FDS solves the Navier-Stokes equations appropriate for low speed flows (Ma < 0.3) with an emphasis on smoke, heat transport and CO2 concentrations from fires. The default turbulence model used in FDS simulation is the Large Eddy Simulation (LES), which is the solution of Navier-Stokes equations at low speed.

The compartment tested was 9 …

Novice Versus Expert Algebraic Problem-Solving Strategies: An Eye Tracking Approach, Krystal Kamekona-Mendoza

UNLV Theses, Dissertations, Professional Papers, and Capstones

Algebra continues to be an important point along the educational spectrum. It is often the point at which we see a deviation of educational trajectories for those who are interested in pursuing additional math and science courses and those who are not. Understanding how college algebra students perform is a crucial step in further understanding the difficulties that students often encounter, as well as understanding other potential factors that may contribute to their performance. The novice/expert paradigm is one way to examine performance differences. While existing literature indicates that novices and experts perceive, sort, and solve problems differently across a …

Using Design Science Research To Develop A Conceptual Solution For Improving Knowledge Sharing In A Virtual Workspace, Lata Koneru

UNLV Theses, Dissertations, Professional Papers, and Capstones

Enhancements in technology have resulted in significant changes to day-to-day operations of organizations in the present day. One especially noteworthy change is the alteration in the nature of teams from being co-located, with face-to-face interaction, to virtual, with the involvement of information and communication technologies (ICT) to facilitate communication. This change in team character has had a downstream impact on a key element of an organization’s competitive edge, namely knowledge.

Overall, there is consensus that knowledge is a crucial facet of the competitive edge of an organization. Consequently, knowledge management, knowledge sharing, and organizational learning are essential components of an …

How Instruction, Math Anxiety, And Math Achievement Affect Learning A Novel Math Task: Evidence For Better Instruction, Amy Jane Mcauley

UNLV Theses, Dissertations, Professional Papers, and Capstones

The primary goal of this paper is to test how math anxiety, achievement, and instruction affect learning a novel math task. Currently, most research measures achievement and math anxiety on previously learned tasks. A two-part study was proposed to measure the effects of math anxiety on learning modular arithmetic (MA), a novel math task that involves subtraction and division. Participants of varying degrees of anxiety and achievement were randomly assigned to either a specific or vague instruction condition. Participants were either taught how to solve the task or given minimal information about how to solve the task. Before moving on, …

High Speed Fast Transient Digitizer Design And Simulation, Eric Clark Monahan

UNLV Theses, Dissertations, Professional Papers, and Capstones

In microelectronics, analog-to-digital converters (ADCs) are used as interfaces to convert analog inputs into discrete time or digital values that can be read via microcontrollers. As speed requirements and processing times in electronics continue to increase, high speed ADCs are increasingly critical components in the design of application-specific integrated circuits (ASICs). However, high speed ADCs introduce quantization error and are inefficient relative to size, cost, and power dissipation when compared to a High Speed Fast Transient Digitizer (HSFTD).

This thesis presents the design, layout, and simulation of a HSFTD designed to sample, in time at a fast rate, a high-speed …

Scheduling Two Machines With Dissimilar Costs, Madhurupa Moitra

UNLV Theses, Dissertations, Professional Papers, and Capstones

We consider two devices, which has states ON and OFF. In the ON state, the devices use their full power whereas in the OFF state the devices consume no energy but a constant cost is associated with switching back to ON. Such two devices are configured with different run and power-up costs on which a sequence of jobs must be processed. The object is to minimize the cost. Such systems are widely used to conserve energy, for example, to speed scale CPUs, to control data centers, or to manage renewable energy.

The problems are studied in the framework of online …

Efficient And Practical Composition Of Lock-Free Data Structures, Neha Bajracharya

UNLV Theses, Dissertations, Professional Papers, and Capstones

A concurrent data object is lock-free if it guarantees that at least one, among all concurrent operations, finishes after a finite number of steps. In other words, a lock free technique guarantees that some thread always makes progress. Lock-free data objects offer several advantages over their blocking counterparts, such as being immune to deadlocks and priority inversion, and typically provide high scalability and performance, especially in shared memory multiprocessor architectures.

Composition of data structures is a powerful approach to combine simple data structures to create more complex ones. It works as a building block for many advanced useful data structures. …

Conversational Movement Dynamics And Nonverbal Indicators Of Second Language Development: A Microgenetic Approach, Kristine Marie Bragg

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation study extends on current understandings of gesture and embodied interaction with the eco-social environment in second language development (SLD) while introducing new aspects of movement analysis through dynamical modeling. To understand the role of embodiment during learning activities, a second language learning task has been selected. Dyads consisting of a non-native English-speaking student and a native English-speaking tutor were video recorded during writing consultations centered on class assignments provided by the student. Cross-recurrence quantification analysis was used to measure interactional movement synchrony between the members of each dyad. Results indicate that students with varied English proficiency levels synchronize …

A Framework To Capture Dynamic Traffic Trends From Historical Sensor Data, Carlos Gaviria

UNLV Theses, Dissertations, Professional Papers, and Capstones

The typical approach of increasing infrastructure to alleviate traffic issues such as congestion is becoming unviable due to limited space, high cost, and associated externalities. Control and management strategies using Intelligent Transportation Systems (ITS) seek to maximize the use of existent infrastructure. Many ITS strategies, such as the deployment of information, require or benefit from knowledge about traffic patterns and trends. This study proposes a mathematical programming formulation and solution algorithm that considers multiple time intervals for the estimation of network-wide traffic states and calculation of the corresponding transition probabilities. The proposed solution enables the determination of sections of the …

Mechanisms For The Incorporation And Distribution Of Radionuclides In Near-Surface Fallout, Marc Alan Fitzgerald

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fallout is the radioactive glass formed from a mixture of vaporized anthropogenic materials with proximate environmental material. These glassy byproducts constitute a compositional record of environmental materials such as soil and vapor precursors that are responsible for chemical heterogeneity in the glasses. The work of this dissertation is to untangle these different sources of compositional heterogeneity, distinguishing low-abundance vaporized anthropogenic-rich material from natural compositions, in order examine soil behavior and chemical evolution during fallout formation. Unfortunately, mixing convolutes the multivariate elemental relationships in these melts due to overlapping element abundances that might distinguish different source materials and chemical behaviors, making …

Influencing Hawai‘I Hotel Patrons To Use Reef-Safe Sunscreens, Rochelle Good

UNLV Theses, Dissertations, Professional Papers, and Capstones

The health of Hawaiian coral reefs is threatened by pollution from common sunscreen ingredients such as oxybenzone. Hawai‘i hotel patrons using sunscreens with harmful ingredients contaminate coral reefs when these products wash off while swimming or bathing. Reef-safe sunscreens are alternative sunscreens that provide effective sun protection while averting damage to coral reefs. The purpose of this research was to determine the dominant factors leading to the pro-environmental behavior of using reef-safe sunscreen and identify practices that Hawai‘i hotel operators could implement to influence patrons to engage in this behavior. This research applied an integrative conceptual framework to model pro-environmental …

Optimization Of Useful Hard X-Ray Photochemistry, David Lewis Goldberger

UNLV Theses, Dissertations, Professional Papers, and Capstones

X-ray induced damage is generally considered a nuisance, but in the field of Useful Hard X-ray Photochemistry we harness the highly ionizing and penetrating properties of hard X-rays (> 7 keV) to initiate novel photochemical decomposition and synthesis at ambient and extreme conditions. Preliminary experiments suggest that the energy of irradiating photons and the sample pressure play roles in determining the nature of X-ray induced damage. Here, we present the X-ray energy dependence of damage induced in strontium oxalate, strontium nitrate, and barium nitrate, as well as the pressure dependence of X-ray induced damage of strontium oxalate. Our results indicate …