Digital Commons Network^™

Renewable Carbon From Lignin Biomass And Its Electrode And Catalyst Applications In Batteries, Supercapacitors, And Fuel Cells, Muslum Demir

Theses and Dissertations

Over the last century, almost all of the carbon materials developed for the energy industry are derived from fossil fuels. The growing global concerns about energy needs, fossil fuels consumption, and the related environmental issues have motived scientists to find new, green and sustainable energy resources such as the wind, solar and biomass energy. Essentially, biomass-derived materials can be utilized in energy storage and conversion devices such as Li-ion batteries, fuel cells, and supercapacitors. Among the biomass resources, lignin is a high volume byproduct from the pulp and paper industry and is currently burned to generate electricity and steam. The …

Photoelectrochemical Cell Constructed From Bby Membrane With Various Substrate Materials, Yang Liu

Theses and Dissertations

Photoelectrochemical cells have been intensively studied in recent years with regard to using thylakoid and photosynthesis system I/II. BBY membrane is another protein complex that has potential to be utilized to build photoelectrochemical cells. Within the BBY membrane lies the highly active photosynthesis system II complex, which upon light activation, generates electrons transported within the electron transport chain during photosynthesis in green plants. This study presents an approach of immobilizing thylakoid or BBY membrane onto gold nanoparticle modified gold plate or multi-walled carbon nanotube (MWCNT) modified indium tin oxide vi (ITO) coated glass substrate. The results show that BBY membrane …

Novel Therapeutic Delivery Via Cell-Nanoparticle Hybridization, Remy C. Cooper

Theses and Dissertations

The immobilization of surface-modified polyamidoamine (PAMAM) dendrimers on the cell surface introduces a novel approach for efficient and specific cellular uptake of therapeutic-carrying nanoparticles. This cell surface-nanoparticle hybridization event takes place via bioorthogonal copper-free click chemistry between a dibenzocyclooctyne (DBCO) group on the dendrimer surface and azide-capped glycans expressed on the cell membrane through metabolic incorporation of azido sugars. This particular cell-nanoparticle hybridization method can be exploited to deliver a variety of therapeutic, genetic or fluorescent payloads directly into cells. Here, this method was employed to deliver plasmid DNA, siRNA and the hydrophobic anticancer drug Camptothecin (CPT) to enhance transfection …

Synthesis, Characterization, And Enhanced Magnetic Properties Of Iron Carbide Nanomaterials, Brent M. Williams

Theses and Dissertations

Permanent magnets are classified as hard magnetic materials with the main purpose of generating flux for applications such as electric motors, turbines, and hard drives. High coercivity, magnetic remanence, and saturation values with high stability are some of the requirements for permanent magnets. Rare-earth magnets including neodymium and samarium based magnets are known to have superior magnetic properties due to their high magnetocrystalline anisotropy. However, due to the price of rare-earth materials development of alternate permanent magnets composed of inexpensive materials is an ongoing process. Previously cobalt carbide (Co_xC) have shown promise as a potential rare-earth free magnet …

A Study Of Sediment Accretion Dynamics In Mature And Restored Tidal Freshwater Forested Wetlands In The James River Watershed Using Surface Elevation Tables And Marker Horizons, Ronaldo Lopez

Theses and Dissertations

Sediment accretion and elevation change in tidal forests, and the corresponding ability of these wetlands to keep pace with sea-level rise (SLR), represent data gaps in our understanding of wetland sustainability. Surface Elevation Tables and marker horizons were installed in three mature tidal forests and a restored tidal marsh, allowing us to measure elevation change, accretion, and subsidence. Additionally, we measured predictor variables to test for their significance in explaining accretion and elevation change rates. Mean accretion at our sites was 11.67 +/- 3.01 mm yr^-1 and mean elevation change was -20.22 +/- 8.10 mm yr^-1, suggesting …

Quantifying Current Sediment Deposition, Legacy Sediments, And Pre-Impoundment Vertical Accretion And Carbon Dynamics Following Dam Removal In A Recently Restored Tidal Freshwater Wetland, Melissa J. Davis

Theses and Dissertations

Damming disrupts natural sediment flow to downstream resulting in legacy sediment accumulation. Legacy sediments have been well investigated in streams throughout the Piedmont region; however, there is no research of legacy sediments following dam removal in low-gradient Coastal Plain streams. Research objectives were to: characterize legacy sediments in a low-gradient stream restoration, quantify pre-impoundment accretion and carbon dynamics, and assess current sediment deposition rates via ¹⁴C analyses within sediment cores and sediment collection tiles. Carbon accumulation and accretion rates of modern tidal sediment have reached that of the tidal relic benchmark and current sediment deposition rates are similar between …

Effects Of Silencing Cyc2-Like Genes On Floral Development In Solanum Lycopersicum L. And Nicotiana Obtusifolia M. Martens & Galeotti (Solanaceae), Joonseog Kim

Theses and Dissertations

CYCLOIDEA (CYC) and DICHOTOMA (DICH) of the CYC2 clade of the TCP gene family have been shown to play a significant role in regulating the identity of the dorsal petals and abortion of the single dorsal stamen in Antirrhinum majus. It is believed that CYC2-like genes are responsible for the convergent evolution of floral zygomorphy, but their role in the development of actinomorphic flowers is still unknown. In Solanaceae, previous analysis has identified two paralogs of CYC2-like genes, CYC2A and CYC2B, resulting from a gene duplication that predates the origin the family. …

The Characterization Of Chimeric Chaperone Flagrp170 As A Novel Radioprotectant, Tyler L. Nguyen

Theses and Dissertations

Abstract

THE CHARACTERIZATION OF CHIMERIC CHAPERONE FLAGRP170 AS A NOVEL RADIOPROTECTANT

By Tyler Nguyen, M.S.

A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science at Virginia Commonwealth University.

Virginia Commonwealth University, 2017

Major Director: Dr. Xiang-Yang (Shawn) Wang, Ph.D., Professor, Department of Human and Molecular Genetics

Radiation therapy (RT) is restricted by toxic effects on adjacent normal tissue, which limits RT efficacy in cancer treatment. Damage to normal tissue, such as radiosensitive intestine and bone marrow compartments, results in acute radiation damage. To reduce normal tissue injury in the setting of RT, we …

Recognizing Her Characteristics As A Leader: An Examination Of The Self-Assessment Of Women Leaders As Shaped By Social Identity Theory And The Concept Of Double Consciousness, John C. Gregory

Theses and Dissertations

Women leaders are grossly underrepresented in police and Army organizations and relevant research suggests that women face the most significant challenges in reaching leadership positions in male dominant organizations. Although there have been recent policy changes to increase opportunities for women in police and Army organizations, women are still barely represented in senior command and primary staff positions in police and Army organizations. When women are underrepresented, particularly at the most senior ranks, there are implications regarding cultural, structural, and attitudinal challenges that simply should not still exist in these organizations. Using qualitative methods, this study examined the experiences of …

Comparative Studies Of Diffusion Models And Artificial Neural Intelligence On Electrochemical Process Of U And Zr Dissolutions In Licl-Kcl Eutectic Salts, Samaneh Rakhshan Pouri

Theses and Dissertations

The electrorefiner (ER) is the heart of pyroprocessing technology operating at a high-temperature (723 K – 773 K) to separate uranium from Experimental Breeder Reactor-II (EBR-II) used metallic fuel. One of the most common electroanalytical methods for determining the thermodynamic and electrochemical behavior of elemental species in the eutectic molten salt LiCl-KCl inside ER is cyclic voltammetry (CV). Information from CV can possibly be used to estimate diffusion coefficients, apparent standard potentials, transfer coefficients, and numbers of electron transferred. Therefore, predicting the trace of each species from the CV method in an absence of experimental data is important for safeguarding …

Decomposition Algorithms In Stochastic Integer Programming: Applications And Computations., Babak Saleck Pay

Theses and Dissertations

In this dissertation we focus on two main topics. Under the first topic, we develop a new framework for stochastic network interdiction problem to address ambiguity in the defender risk preferences. The second topic is dedicated to computational studies of two-stage stochastic integer programs. More specifically, we consider two cases. First, we develop some solution methods for two-stage stochastic integer programs with continuous recourse; second, we study some computational strategies for two-stage stochastic integer programs with integer recourse. We study a class of stochastic network interdiction problems where the defender has incomplete (ambiguous) preferences. Specifically, we focus on the shortest …

Tuning Optimization Software Parameters For Mixed Integer Programming Problems, Toni P. Sorrell

Theses and Dissertations

The tuning of optimization software is of key interest to researchers solving mixed integer programming (MIP) problems. The efficiency of the optimization software can be greatly impacted by the solver’s parameter settings and the structure of the MIP. A designed experiment approach is used to fit a statistical model that would suggest settings of the parameters that provided the largest reduction in the primal integral metric. Tuning exemplars of six and 59 factors (parameters) of optimization software, experimentation takes place on three classes of MIPs: survivable fixed telecommunication network design, a formulation of the support vector machine with the ramp …

A Hierarchical Architectural Framework For Securing Unmanned Aerial Systems, Matthew Leccadito

Theses and Dissertations

Unmanned Aerial Systems (UAS) are becoming more widely used in the new era of evolving technology; increasing performance while decreasing size, weight, and cost. A UAS equipped with a Flight Control System (FCS) that can be used to fly semi- or fully-autonomous is a prime example of a Cyber Physical and Safety Critical system. Current Cyber-Physical defenses against malicious attacks are structured around security standards for best practices involving the development of protocols and the digital software implementation. Thus far, few attempts have been made to embed security into the architecture of the system considering security as a holistic problem. …

Omni-Directional Infrared 3d Reconstruction And Tracking Of Human Targets, Emrah Benli

Theses and Dissertations

Omni-directional (O-D) infrared (IR) vision is an effective capability for mobile systems in robotics, due to its advantages: illumination invariance, wide field-of-view, ease of identifying heat-emitting objects, and long term tracking without interruption. Unfortunately, O-D IR sensors have low resolution, low frame rates, high cost, sensor noise, and an increase in tracking time. In order to overcome these disadvantages, we propose an autonomous system application in indoor scenarios including 1) Dynamic 3D Reconstruction (D3DR) of the target view in real time images, 2) Human Behavior-based Target Tracking from O-D thermal images, 3) Thermal Multisensor Fusion (TMF), and 4) Visual Perception …

Eye Movement Control: An Index For Athleticism, Brittany L. Oshea

Theses and Dissertations

Athletic potential is one of the most complex human traits. An elite athlete is produced from a complex interaction of an innumerable number of traits exhibited by the athlete. However, it’s not clear whether these traits are innate, allowing the athlete to excel, or, alternatively, are a consequence of practice. To be successful, athletes rely heavily on sensory information from the visual and vestibular systems. This study investigated the relationship eye movement control has with innate athleticism by comparing the saccadic and Vestibulo-Ocular Reflex (VOR) responses of former, no longer practicing, elite athletes against their age and gender matched counterparts …

The Identity Formation Of South Asians: A Phenomenological Study, Shabana Shaheen

Theses and Dissertations

This research explores the lived experiences of South Asians college students. This research, through a qualitative study that is rooted in the philosophy of phenomenology, explores the essence South Asians’ identity formation. Qualitative data was collected through semi-structured interviews with South Asian college students. The data analysis was under a phenomenological lens that centered the lived experiences and the essence of these experiences in the results. Seven themes emerged from this phenomenological study: negotiating bicultural identity, model minority expectations, meaningful impact of religious spaces, understandings of intra-community tensions, racialization of Islamophobia, understandings of South Asian identity and efficacy of Asian …

Preparation And Evaluation Techniques Of Porous Materials And Mixed Matrix Membranes For Targeted Co2 Separation Applications, Tsemre Tessema

Theses and Dissertations

The use of porous sorbents for physisorptive capture of CO₂ from gas mixtures has been deemed attractive due to the low energy penalty associated with recycling of such materials. Porous organic polymers (POPs) have emerged as promising candidates with potential in the treatment of pre- and post- fuel combustion processes to separate CO₂ from gas mixtures. Concurrently, significant advances have been made in establishing calculation methods that evaluate the practicality of porous sorbents for targeted gas separation applications. However, these methods rely on single gas adsorption isotherms without accounting for the dynamic gas mixtures encountered in real-life applications. …

Respiratory Prediction And Image Quality Improvement Of 4d Cone Beam Ct And Mri For Lung Tumor Treatments, Seonyeong Park

Theses and Dissertations

Identification of accurate tumor location and shape is highly important in lung cancer radiotherapy, to improve the treatment quality by reducing dose delivery errors. Because a lung tumor moves with the patient's respiration, breathing motion should be correctly analyzed and predicted during the treatment for prevention of tumor miss or undesirable treatment toxicity. Besides, in Image-Guided Radiation Therapy (IGRT), the tumor motion causes difficulties not only in delivering accurate dose, but also in assuring superior quality of imaging techniques such as four-dimensional (4D) Cone Beam Computed Tomography (CBCT) and 4D Magnetic Resonance Imaging (MRI). Specifically, 4D CBCT used in CBCT …

Accurate Acoustic Ranging System Using Android Smartphones, Mohammadbagher Fotouhi

Theses and Dissertations

ACCURATE ACOUSTIC RANGING SYSTEM USING ANDROID SMARTPHONES

By Mohammadbagher Fotouhi, Master of Science

A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science at Virginia Commonwealth University

Virginia Commonwealth University 2017

Major Director: Dr. Ruixin Niu, Associate Professor of Department of Electrical and Computer Engineering

In this thesis, we present the design, implementation, and evaluation of an android ranging system, a high-accuracy acoustic-based ranging system which allows two android mobile phones to learn their physical distance from each other.

In this system we propose a practical solution for accurate ranging based on acoustic communication …

Communication, Empathy, And Trust: Exploring Teachers' Partnerships With The Families Of Their Most Challenging Students, Kimberly W. Mcknight

Theses and Dissertations

The purpose of this embedded mixed methods collective case study was to explore eight kindergarten, first, and second grade teachers’ experiences partnering with families of their students who are at risk for emotional or behavioral disorders (EBDs). The teachers worked in two high-poverty, non-accredited Title-1 schools in an urban city. The study was part of a federally funded intervention called Behavioral, Emotional, and Social Training: Competent Learners Achieving School Success (BEST in CLASS- Elementary; BiC-E; Sutherland et al., 2017), which is targeted for students at risk for the development of EBDs. It uses evidence- based instructional practices to decrease students’ …

Cooperative Wideband Spectrum Sensing Based On Joint Sparsity, Ghazaleh Jowkar

Theses and Dissertations

COOPERATIVE WIDEBAND SPECTRUM SENSING BASED ON JOINT SPARSITY

By Ghazaleh Jowkar, Master of Science

A thesis submitted in partial fulfillment of the requirements for the degree of Master of Science at Virginia Commonwealth University

Virginia Commonwealth University 2017

Major Director: Dr. Ruixin Niu, Associate Professor of Department of Electrical and Computer Engineering

In this thesis, the problem of wideband spectrum sensing in cognitive radio (CR) networks using sub-Nyquist sampling and sparse signal processing techniques is investigated. To mitigate multi-path fading, it is assumed that a group of spatially dispersed SUs collaborate for wideband spectrum sensing, to determine whether or not …

Modified Pamam Dendrimers In Tunable Drug-Delivery Systems: A Sustained-Release Dendrimer Hydrogel For Anti-Glaucoma Drugs And Surface-Engineered Macrophages As Nanoparticle Carriers For Targeted Anti-Cancer Therapy, Christopher A. Holden

Theses and Dissertations

Two specific drug-delivery applications were sought in this work using polyamidoamine (PAMAM) dendrimers. One drug-delivery system used a novel dendrimer hydrogel (DH) for sustained delivery of anti-glaucoma drugs. In this work, PAMAM G3.0 dendrimers were covalently bonded with poly(ethylene glycol) (PEG­₁₂₀₀₀) molecules which were subsequently acrylated, resulting in photocurable DH conjugates. For pharmacological studies, DH were loaded with a solution of intraocular pressure lowering drugs, brimonidine and timolol maleate, and were characterized for in vitro release and ex vivo transport and uptake. DH formulations were shown to increase the loading of drug molecules, increase transcorneal drug delivery, and …

Validation Study Of The Science Literacy Assessment: A Measure To Assess Middle School Students' Attitudes Toward Science And Ability To Think Scientifically, Tammy Mckeown

Theses and Dissertations

This study investigated validity evidence for the Science Literacy Assessment, an instrument designed to assess middle school students’ ability to think scientifically as well as their motivation and beliefs about science (Fives, Huebner, Birnbaum, & Nicolich, 2014). Specifically, three sources of evidence were considered; internal structure, concurrent criterion-related, and predictive criterion-related. Exploratory factor analysis was utilized to examine the underlying factor structure of each of the instrument’s two components, motivation and beliefs related to science and demonstrated scientific literacy. Pearson product-moment correlations were calculated to determine the relationship between scores on the motivation and belief component of the Science Literacy …

Coherent/Incoherent Magnetization Dynamics Of Nanomagnetic Devices For Ultra-Low Energy Computing, Md Mamun Al-Rashid

Theses and Dissertations

Nanomagnetic computing devices are inherently nonvolatile and show unique transfer characteristics while their switching energy requirements are on par, if not better than state of the art CMOS based devices. These characteristics make them very attractive for both Boolean and non-Boolean computing applications. Among different strategies employed to switch nanomagnetic computing devices e.g. magnetic field, spin transfer torque, spin orbit torque etc., strain induced switching has been shown to be among the most energy efficient. Strain switched nanomagnetic devices are also amenable for non-Boolean computing applications. Such strain mediated magnetization switching, termed here as “Straintronics”, is implemented by switching the …

The Role Of Afrocentric Features In Mental Healthcare Utilization And Counselor Preferences In Black College Students, Randl B. Dent

Theses and Dissertations

Though mental health issues are prevalent in Black young adults, they underutilize mental healthcare services. This research examined the role of feature-based discrimination in mental healthcare (under)utilization. Study 1, a secondary analysis of the National Longitudinal Study of Adolescent to Adult Health, provided no evidence supporting a link between skin tone and mental healthcare utilization, when controlling for depression diagnosis. However, when controlling for depression symptoms, there was a trend such that Black young adults with darker, as opposed to lighter, skin tone utilized healthcare less. Study 2, an experimental study with 33 Black college students, showed 73% of the …

One In Eight: Deciding To Pursue A College-Going Possible Self In A High-Poverty High School, David B. Naff

Theses and Dissertations

There is considerable research evidence suggesting that low-income, racial minority students value education and aspire for postsecondary educational attainment (Bloom, 2007; Destin & Oyserman, 2009; Wigfield & Eccles, 2002). However, their performance in school often does not align with those values and ambitions, as these students tend to underachieve in comparison with their higher-income, non-minority peers (Reardon, 2011), with particular gaps found in those attending schools of concentrated poverty (Rowan, 2011). This gap between educational ambition and attainment suggests that the experience of living and going to school in a high-poverty context could be related to the motivational processes driving …

An Investigation Of How Black Stem Faculty At Historically Black Colleges And Universities Approach The National Science Foundation Merit Review Process, Falcon Rankins

Theses and Dissertations

This qualitative inquiry explored the ways in which US-born, Black faculty member participants in science, technology, engineering, and mathematics (STEM) disciplines at Historically Black Colleges and Universities (HBCUs) interact with the National Science Foundation (NSF). Eight Black HBCU STEM faculty members with a range of involvement in NSF-related activities were individually interviewed. Topics of discussion with participants included their prior experiences with NSF, their understanding of the merit review process, and their understanding of their personal and institutional relationships with NSF and the STEM community. Two broad findings emerged from the conversations. The first was that issues of communities and …

Development Of High Efficiency Dry Powder Inhalers For Use With Spray Dried Formulations, Dale Farkas

Theses and Dissertations

Dry powder inhalers (DPIs) are advantageous for delivering medication to the lungs for the treatment of respiratory diseases because of the stability of the powders, relative low cost, synchronization of inhalation and dose delivery, and many design options that can be used for optimization. However, currently marketed DPIs are very inefficient in delivering medications to the lungs. This study has developed multiple new high efficiency DPIs for use with spray dried excipient enhanced growth (EEG) powder formulations based on the following platforms: capsule-based for oral inhalation, high-dose for oral inhalation, inline with 3D rod array dispersion, and inline with capillary …

The Effect Of Chronic Nutrient Addition From Wastewater On Forest Ecosystems At The Rice Rivers Center, Michael Beck

Theses and Dissertations

Wastewater application to land can be a useful tool for mitigating impacts of nutrient enrichment on aquatic systems. A land application treatment system at VCU’s Rice Rivers Center in Charles City County, VA provided an opportunity to study the impact of wastewater addition on the biogeochemistry of forests representative of the Mid-Atlantic Coastal Plain. Nutrient concentrations in throughfall and leachate were measured at Treatment and Control sites to assess differences in nutrient deposition and retention. Wastewater amended plots from the Walter L. Rice education building received 20-fold (N) and 6-fold (P) higher inputs relative to Control plots and plots located …

Electrospraying Extracellular Matrix To Form Nanoparticles, Patrick Link

Theses and Dissertations

Chronic Obstructive Pulmonary Disease (COPD) is a leading cause of death worldwide. Alveolar wall destruction is a significant contributor to COPD. Inflammatory macrophages are a major source of the Extracellular Matrix (ECM) proteolysis. ECM breakdown causes air to get trapped in the alveoli, obstructing airflow. One step in curing COPD may be to convert inflammatory to pro-regenerative macrophages. Recently, decellularized ECM scaffolds have shown the ability to induce a pro-regenerative phenotype.

Yet these scaffolds are incapable for reaching the alveolar region of the lungs. To reach the alveolar region particles need a diameter of 1-5 μm or smaller than 300 …