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Computational And Experimental Studies Of Non-Covalent Interactions: Characterization Of Ch...Π Interactions And Structure Of 1,1-Difluoroethylene...Carbon Dioxide, Ashley M. Anderton

Masters Theses

Weakly bound CH/π interactions, due to the abundance of C-H bonds and π systems that exist in larger organic molecules, are an important driving force in the construction of biomacromolecules, supramolecular assemblies and crystal packing of organic compounds. To assist in the characterization of CH/π interactions, a density functional theory (DFT) study has been conducted to determine a quick and cheap method for accurate determination of the binding energy and rotational constants for CH/π interactions. Seven complexes were used in this study: five benzene-HY complexes (where Y= C≡CH, Cl, F, Br and C≡N) and two fluorobenzene-HY complexes (where Y= C≡CH …

The Risks And Rewards Of Personal Writing In The High School Classroom, Dannette L. Williamson

Masters Theses

In light of the Common Core State Standards, more research is needed on the importance and transfer value of personal writing high school classrooms. These standards have brought a more rigorous focus to student learning. With a stronger emphasis on argument and source-based writing, high school educators need to reexamine if or how personal writing should fit into curricula. For this study, approximately thirty students from each grade at Effingham High School were surveyed. The entire English department, as well as staff members from other disciplines at Effingham High School, were also surveyed. Prominent findings of the data show that …

Synthesis And Characterization Of Molecular Components For The Preparation Of Poly-Rotaxanes, Austin P. Welti

Masters Theses

The self-sorting ability of certain crown ethers make them important players in the field of supramolecular chemistry, especially those studying mechanically interlocked molecules (MIMs). Of these MIMs, rotaxanes and catenanes are the most common. Our approach in the synthesis of poly-rotaxane systems involves the preparation of axles containing multiple recognition motifs to determine the self-sorting principles that each motif shows. These principles include narcissistic self-sorting, and also type I and type II social self-sorting principles. Using these techniques, poly-rotaxane formation can be made readily available.

A hetero-poly-rotaxane equipped with a naphthalene diimide (NDI) site and two ammonium salt sites has …

Floodplain Mapping In Response To Surface Mine Reclamation, Erin E. O'Leary

Graduate Theses, Dissertations, and Problem Reports (ETD)

Surface mining and the associated reclamation cause changes in land use and land cover. This change can affect the hydrologic balance. In some cases, an increase in number and magnitude of flood events is observed both on site and in surrounding areas. This research analyzed the hydrologic effects downstream of a reclaimed surface mine, considering the impact of an alternative reclamation technique. Geomorphic landform design (GLD) is a reclamation method that considers the development mature landform shapes to help create a long-term hydrologic balance. Flood maps were created for the pre-mined condition and compared to maps created for three reclamation …

Finding The Right Fit: Multiculturalism And Low-Income Urban Schools, Grace Shin Won Kim Canada

Theses and Dissertations

This study addressed the difficulty of recruiting and retaining qualified teachers by examining the qualities and characteristics of teacher fit in a group of Southern California charter schools that serve low-income Black and Hispanic students. Given the significance and importance of culturally relevant and responsive education in schools that serve primarily Black and Hispanic students (Castagno, 2009; Gay, 2000; Howard, 2003; Ladson-Billings, 1994; 1995; 2006; Lindsey, Karns, & Myatt 2010; Nieto, 2005a; Poveda & Martin, 2004), three survey instruments; a demographic questionnaire, the Teachers Multicultural Attitudes Survey (TMAS), and the Multicultural Teaching Competency Scale (MTCS); were used to assess teacher …

Developing A Model For Understanding Mindfulness As A Potential Intervention For Obsessive-Compulsive Disorder, Steven I. Rudoy

Theses and Dissertations

The paucity of effective alternative or augmentative treatments available for OCD coupled with the emerging potential of mindfulness-based treatments indicate that exploring the potential utility of such interventions for the OCD population is a useful area of inquiry. In addition, although more general examinations of the mechanisms by which mindfulness contributes to positive change have been conducted, those mechanisms of action have never been theoretically linked with the mechanisms of action believed to underlie the mental processes in OCD. The current study will include a critical analysis of the existing literature covering the cognitive and biological bases for understanding the …

A Guide For Mental Health Practitioners Working With Collective Trauma Victims From Latin America: An Experiential Approach, Melissa Cordero

Theses and Dissertations

A resource guide for mental health practitioners working with Latino victims of collective trauma was developed based on a review of the literature. The development of the resource was also informed by two structured interviews with experts in the field of collective trauma within the Latino population. Review of the literature and structured interviews were used to develop culturally sensitive treatment approaches for victims of collective trauma from Latin America. The resource guide offers clinicians culturally adapted interventions, including PTSD measures, a table to identify culture bound syndromes, PTSD psychoeducation handouts (provided in Spanish and English), relaxation skills (e.g. breathing …

A Phenomenological Study: Personal Criteria For Emancipated Foster Youth Entering College, Christina Acoff

Theses and Dissertations

This qualitative study examined 4 emancipated foster youth who are attending college in California. The purpose of this phenomenological study was to explore the personal criteria of 2 male and 2 female emancipated foster youths entering college and determine what factors they perceived helped them to attend college. The researcher recruited a total of 4 participants, 1 male from El Camino College Compton Center, 1 female from El Camino College, and 1 male 1 one female from CSU Dominguez Hills. The research question for this study was, What motivates emancipated foster youths to attend college? The phenomenon of being a …

Trainee Therapist Responses To The Discussion Of Trauma In Therapy, Courtney Bancroft

Theses and Dissertations

Responses to disclosures/discussions of trauma can have lasting impacts on survivors who choose to share their experiences and historically have been categorized as positive, negative, and/or neutral responses with corresponding effects on the survivor. Literature recommends the use of tenets and techniques reminiscent of therapeutic common factors (e.g., listening skills, empathy, support, validation, creating a safe environment and strong therapeutic alliance) when responding to trauma. However, existing research focuses on reactions to survivors' disclosures outside of therapy and there is little research focusing on therapists' responses. Specifically, there are no studies that investigate how therapists or trainees are actually responding …

Emotional Intelligence And Racial Identity's Impact On Academic Achievement In American Multiracial High School Students, Mary Ann Freeman

Theses and Dissertations

Minorities reached 50.4% of the American population, representing a majority for the first time, and those self-reporting as multiracial grew by a larger percentage than those reporting a single race (U.S. Census Bureau, 2011). Millennials born after 1980 are the most racially diverse generation (Pew Research Center, 2014). This study investigated how racial identity and emotional intelligence might impact academic achievement among U.S. Millennial multiracial adolescents of African descent. Research suggests a student's racial identification has a significant impact on academic performance (Herman, 2009) and minority youth struggle academically (Annie E. Casey Foundation, 2014). The theoretical framework included the construct …

Leading Under Pressure, Coping Practices Of Executives: A Mixed Methods Study, Darlene Thomas

Theses and Dissertations

Work-related stress continues is the largest contributor to the rise in insurance cost for most organizations (Dewe, O'Driscoll, & Cooper, 2010). The biopharmaceutical industry is no exception. Today's leaders must focus on efficiencies, cost reduction, and organization performance while restructuring the organization to do more with less, which can create tremendous stress. This research explored coping strategies practiced by executive leaders in the biopharmaceutical industry. The overarching research question was: How do senior leaders confronted by work pressure attempt to cope, and are the coping strategies practiced effective at reducing and deflecting stress in a way that doesn't adversely affect …

Can I Be Sued For That? Liability Risk And The Disclosure Of Clinically Significant Genetic Research Findings, Ellen Wright Clayton, Amy L. Mcguire, Et Al.

Vanderbilt Law School Faculty Publications

Genomic researchers increasingly are faced with difficult decisions about whether, under what circumstances, and how to return research results and significant incidental findings to study participants. Many have argued that there is an ethical—maybe even a legal—obligation to disclose significant findings under some circumstances. At the international level, over the last decade there has begun to emerge a clear legal obligation to return significant findings discovered during the course of research. However, there is no explicit legal duty to disclose in the United States. This creates legal uncertainty that may lead to unmanaged variation in practice and poor quality care. …

Neuroscientists In Court, Owen D. Jones, Anthony D. Wagner, David L. Faigman, Marcus E. Raichle

Vanderbilt Law School Faculty Publications

Neuroscientific evidence is increasingly being offered in court cases. Consequently, the legal system needs neuroscientists to act as expert witnesses who can explain the limitations and interpretations of neuroscientific findings so that judges and jurors can make informed and appropriate inferences. The growing role of neuroscientists in court means that neuroscientists should be aware of important differences between the scientific and legal fields, and, especially, how scientific facts can be easily misunderstood by non-scientists,including judges and jurors.

This article describes similarities, as well as key differences, of legal and scientific cultures. And it explains six key principles about neuroscience that …

The Classical Constitution And The Historical Constitution: Separated At Birth, Suzanna Sherry

Vanderbilt Law School Faculty Publications

No abstract provided.

Designing Administrative Law For Adaptive Management, J.B. Ruhl, Robin Craig

Vanderbilt Law School Faculty Publications

Administrative law needs to adapt to adaptive management. Adaptive management is a structured decision-making method the core of which is a multi-step iterative process for adjusting management measures to changing circumstances or new information about the effectiveness of prior measures or the system being managed. It has been identified as a necessary or best practices component of regulation in a broad range of fields, including drug and medical device warnings, financial system regulation, social welfare programs, and natural resources management. Nevertheless, many of the agency decisions advancing these policies remain subject to the requirements of either the federal Administrative Procedure …

Teachers' Utilization Of Field Trips: A Comparative Study, Joshua Kenna

Electronic Theses and Dissertations

Field trips are visits to an out-of-school setting designed for educational and academic purposes whereby as a result students gain firsthand knowledge and experiences. Historically, it was the potential for student learning that motivated teachers to utilize field trips. However, there is reasonable suspicion among scholars today that teachers are utilizing field trips less since the start of the new millennia; the common reasons being cited among others include a slumping economy, an increase in accountability due to high-stakes testing, and rising fuel costs. Unfortunately, there is no empirical evidence that can confirm or deny this suspicion. Therefore, the purpose …

Novel Developments On The Extraction And Analysis Of Polycyclic Aromatic Hydrocarbons In Environmental Samples, Walter Wilson

Electronic Theses and Dissertations

This dissertation focuses on the development of analytical methodology for the analysis of polycyclic aromatic hydrocarbons (PAHs) in water samples. Chemical analysis of PAHs is of great environmental and toxicological importance. Many of them are highly suspect as etiological agents in human cancer. Among the hundreds of PAHs present in the environment, the U.S. Environmental Protection Agency (EPA) lists sixteen as "Consent Decree" priority pollutants. Their routine monitoring in environmental samples is recommended to prevent human contamination risks. A primary route of human exposure to PAHs is the ingestion of contaminated water. The rather low PAH concentrations in water samples …

The Modern Gender Gap In Partisanship And Ideology: A Cross-National Analysis, Tiffany Quick

Electronic Theses and Dissertations

This thesis updates and expands upon the developmental theory of the gender gap in party and ideological identification originally posited by Norris and Inglehart (2000) to explain why women in advanced industrial nations are more likely to hold more leftist ideological identification than men. A comparative cross-national analysis using data from the World Values Survey (2004-2008) extends Norris and Inglehart's study, with an examination of the gender gap in advanced industrial, post-communist and developing nations. To further explore the nature of the gender gap in the United States, data from the American National Election Study (Cumulative File and 2012 cross-section) …

Movements, Fishery Interactions, And Unusual Mortalities Of Bottlenose Dolphins, Steven Shippee

Electronic Theses and Dissertations

Bottlenose dolphins inhabiting coastlines and estuaries in Florida have been impacted in the past decade by development, algal blooms, catastrophic pollution, and fishery interactions (FI). Dolphins react to disturbance and environmental stressors by modifying their movements and habitat use, which may put them in jeopardy of conflict with humans. FI plays an increasing role in contributing to dolphin mortalities. I investigated dolphin movements, habitat use, residency patterns, and frequency of FI with sport fishing. Tagging studies with short-term data tags and bolt on radio-transmitters were done in several locations in Florida and the east coast providing fine-scale measurements of swimming, …

The Role Of Invitational Theory On Minority Student Enrollment In Advanced Placement Courses, Jason Mcdonald

Electronic Theses and Dissertations

The number of students enrolling in Advanced Placement (AP) classes has been increasing in Florida and across the nation over the last decade. However, this trend is not happening for traditionally underserved groups of students such as African Americans, Hispanics, and students from low socioeconomic backgrounds. These minority groups are underrepresented in AP classes, while Asian and White students are overrepresented. This trend is alarming because there are qualified minority students who have a great chance of being successful in AP classes according to AP Potential data. For some reason though, these qualified minority and low income students are nevertheless …

Photo-Induced Protonation Of Polyaniline Composites And Mechanistic Study Of The Degradation Of Polychlorinated Biphenyls With Zero-Valent Magnesium, Candace Kirkland

Electronic Theses and Dissertations

As technology advances, a need for non-metal, conductive materials has arisen for several types of applications. Lithographic techniques are helpful to develop some of these applications. Such techniques require materials that are insulating and become conductive after irradiated. Composites of polyaniline in its emeraldine base form (PANI-EB) doped with photo-acid generators (PAG) become conductive upon photo-irradiation. This increase in conductivity is due to the protonation of PANI-EB. Such materials may be utilized to fabricate conducting patterns by photo-irradiation; however, the conductivity obtained by direct irradiation of PANI-EB/PAG composites is normally quite low (<10-3 S/cm) due to aggregation of highly loaded PAG. In this work, poly(ethylene glycol) (PEG), a proton transfer polymer, was added to PANI-EB/PAG. Results showed the addition of low molecular weight (MW) (550) PEG significantly enhanced the photo-induced conductivity to a level comparable to that of PANI-salt synthesized by oxidizing aniline in the presence of an acid. High MW (8000) PEG is less effective than PEG 550, and composites of PANI-EB and N-PEG-PANI showed conductivity as high as 102 S/cm after treatment with HCl vapor. The photo-induced conductivity of the N-PEG-PANI/PANI-EB/PAG composite reached 10-2-10-1 S/cm. Polychlorinated biphenyls (PCBs) are a class of chemicals with 209 different congeners, some of which are known carcinogens, and are persistent organic pollutants in the environment. After its synthesis, it was seen as a phenomenal additive in a multitude of different applications leading to the wide spread use of PCBs and a need for a safe, effective, and inexpensive remediation technique. While it is known that magnesium can degrade PCBs, the mechanism of this reaction was not well-understood. In order for magnesium to be broadly used as a remediation tool, it is necessary to fully understand how the reaction is taking place and if the PCBs are able to be fully dechlorinated into biphenyl. This research focuses on the hydrodechlorination of PCBs with zero-valent magnesium in acidified ethanol. The degradation pathways of 2, 2', 3, 5, 5', 6- hexachlorobiphenyl were investigated to determine the identity of the daughter PCBs produced, how and if they continue to be dechlorinated into biphenyl. The proton source for this hydrodehalogenation reaction was also studied using both deuterated solvent and acid to give more detail to the mechanism of this reaction.

Mothers' Temperament And Personality: Their Roles In Parenting Behaviors, Parent Locus Of Control, And The Outcomes Of Young Children, Jayme Puff

Electronic Theses and Dissertations

Many researchers have used the terms 'temperament' and 'personality' interchangeably when describing parents' behavioral styles. Although individual relationships among parents' temperament and personality, parenting behaviors, other parent characteristics, and young children's outcomes have been documented in the literature, parents' temperament and personality have not been examined collectively in conjunction with parenting and child outcome variables. As part of this study, 214 culturally diverse mothers with young children who ranged in age from 2- to 6-years rated their own temperament and personality, their parenting characteristics, and their young child's functioning (i.e., temperament and emotional and behavioral functioning). When examining mothers' temperament …

Physiological Constraints On Warm-Water Habitat Site Selection And Utilization By The Florida Manatee (Trichechus Manatus Latirostris) In East Central Florida, Ann Spellman

Electronic Theses and Dissertations

Living at the northern limits of its geographic range, the Florida manatee is particularly susceptible to cold stress-related mortality during the winter months, with most deaths occurring in the lower two-thirds of the state. Contributing to this cold stress susceptibility is the manatee's limited physiological and behavioral responses available when thermally stressed. While capable of migrating south in response to falling water temperatures, manatees must still find warm water when ambient river temperature drops below 20°C for more than a few days. This is in part due to the species low metabolic rate, limited capacity for thermogenesis, and limited ability …

Role Of Cardiac Catecholamines In Embryos And Adults Under Stress, Candice Baker

Electronic Theses and Dissertations

Cardiovascular disease is responsible for the loss of one life every 38 seconds and accounts for 26.6 percent of all infants that die of congenital birth defects. Adrenergic hormones are critically important regulators of cardiovascular physiology in embryos and adults. They are key mediators of stress responses and have profound stimulatory effects on cardiovascular function, and dysregulation of adrenergic function has been associated with many adverse cardiac conditions, including congenital malformations, arrhythmias, ischemic heart disease, heart failure, and sudden cardiac death. Despite intensive study, the specific roles these hormones play in the developing heart is not well-understood. Further, there is …

Structural And Functional Studies Of Glycine Riboswitches And Development Of Fab Chaperone Assisted Rna Crystallography, Eileen Sherman

Electronic Theses and Dissertations

The glycine riboswitch is a structured RNA found upstream of genes in mRNA transcripts in many bacteria, functioning as a biofeedback gene regulator. Upon binding glycine, a complete RNA transcript including gene sequences is transcribed, effectively turning on gene expression. In an effort to understand the intricacies of its functioning, many mutants of the riboswitch were made and characterized during Ph. D. work, resulting in discovery of a P0 duplex/kink-turn motif involving a few nucleotides upstream of the established glycine riboswitch sequence which changed its ligand binding characteristics (Chapter 1). Previously, the two aptamers of the riboswitch were thought to …

Eurocentrism, Modernity And Chinese Sociality : An Ethnographic Study Of Everyday Socio-Cultural Life In New-Millennium China, Tung Yi Kho

Lingnan Theses

This dissertation seeks to contribute to our understanding of Eurocentrism, Modernity,and their impacts on traditional Chinese cultural formations. It is based on ethnographic research conducted in Shenzhen, South China and Qinghai, West China, and explores the impacts of Chinese modernization on everyday forms of sociality.

I conceive of Eurocentrism foremost as an Ontology, a mode-of-being grounded in a cosmology about the nature of reality and human being-and-becoming in the world. I argue that because Eurocentrism is an ontology predicated on materialism and individualism - “matter” being the basis of reality and the “individual”, the fundamental unit of society, respectively - …

Catholic Healing Masses: Intersections Of Health And Healing In Yucatan, Suzanne Draper

Electronic Theses and Dissertations

The conception of illness and healing in contemporary Mexican Catholic discourse highlights both particular and ubiquitous instances of a health experience perceived locally and widespread. Catholic healing masses are utilized as supplemental methods of individual health restoration coupled with Western medicinal techniques in Catholic dramas. Aside from the spiritual and religious significance of this practice, the use of healing masses as an additional means to achieving an optimal health status implies that something is lacking in current biomedical models. The purpose of my research is to explore the humanistic terms under which healing masses operate and translate these terms into …

Ar Physics: Transforming Physics Diagrammatic Representations On Paper Into Interactive Simulations., Yao Zhou

Electronic Theses and Dissertations

A problem representation is a cognitive structure created by the solver in correspondence to the problem. Sketching representative diagrams in the domain of physics encourages a problem solving strategy that starts from 'envisionment' by which one internally simulates the physical events and predicts outcomes. Research studies also show that sketching representative diagrams improves learner's performance in solving physics problems. The pedagogic benefits of sketching representations on paper make this traditional learning strategy remain pivotal and worthwhile to be preserved and integrated into the current digital learning landscape. In this paper, I describe AR Physics, an Augmented Reality based application that …

A Thomistic Critique Of The Ethics Of Alasdair Macintyre, Marcus Otte

Electronic Theses and Dissertations

Alasdair MacIntyre argues in favor of a historicist Thomism in ethics and political philosophy. In his theory, sociological categories take up much of the space traditionally occupied by metaphysics. This peculiar feature of MacIntyre's Thomism, and its merits and demerits, is already a subject that has been taken up by many critics. In this thesis, these criticisms are supplemented and unified by identifying what is perhaps the most fundamental difficulty with MacIntyre's ethics: his version of Thomism is problematic because it treats epistemology as first philosophy. This misstep compromises MacIntyre's ability to provide a defense of moral objectivity, while also …

Evaluation Of A Digitally-Automated Alcohol Curriculum Designed To Alter Expectancies And Alcohol Use In First Year College Students, Amy Schreiner

Electronic Theses and Dissertations

High-risk alcohol consumption remains a primary public health concern for students on college campuses. In response to this concern the National Advisory Council of the National Institute on Alcohol Abuse and Alcoholism created a task force to identify and recommend strategies to aid college administrators in implementing effective alcohol programming at their institutions. While most administrators report being aware of these recommendations, many have not successfully implemented empirically supported interventions on their campuses. One significant barrier is the cost and difficulty of training and hiring skilled staff to implement these interventions. Of the strategies identified as effective, challenging alcohol expectancies …