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Articles 27811 - 27840 of 29367
Full-Text Articles in Entire DC Network
My Journey From Physician To Psychologist: Relational Touch In Psychotherapy, Brita S. Reed
My Journey From Physician To Psychologist: Relational Touch In Psychotherapy, Brita S. Reed
Antioch University Dissertations & Theses
A physician's armamentarium includes the presence of the tool of touch which is used not only to diagnose and to heal, but also to reassure patients that they are safe and well cared for in the hands of the physician. The use of touch in the practice of psychology, however, is relatively proscribed. In this essay, I examine how we, as psychologists, can best "hold" our clients without the use of touch. In the first part of this essay, I explore some theoretical considerations on relational touch in psychotherapy. I define relational touch as touch that occurs between people and …
What Are The Key Competencies, Qualities, And Attributes Of The African American Municipal Police Chief?, Patrick Oliver
What Are The Key Competencies, Qualities, And Attributes Of The African American Municipal Police Chief?, Patrick Oliver
Antioch University Dissertations & Theses
The purpose of this dissertation was to identify and understand the dimensions of leadership of those African Americans, who are effective as the chief executive officer (CEO) of a municipal law enforcement agency, and thereby to educate and inform both those aspiring to be police chiefs and those presently serving as police chiefs, particularly African Americans. Four content areas were examined to gain a better understanding of the research question: (1) Police executive leadership literature; (2) African American leadership; (3) The trait theory of leadership; (4) emotional intelligence. Study participants were all African American police chiefs with the expertise and …
Melungeon Portraits: Lived Experience And Identity, Tamara L. Stachowicz
Melungeon Portraits: Lived Experience And Identity, Tamara L. Stachowicz
Antioch University Dissertations & Theses
The desire to claim an ethnicity may be in response to an institutional and systemic political movement towards multiculturalism where ethnic difference is something to be recognized and celebrated (Jimenez, 2010; Tatum, 1997). Those who were a member of a dominant or advantaged group took that element of their identity for granted (Tatum, 1997). Identity work has included reflections and congruence between how individuals see themselves and how they perceive others to see them, including Optimal Distinctiveness Theory where one determines the optimal amount of individual distinctiveness needed to feel a healthy group and personal identity (Brewer, 2012). When most …
Under Siege: The U.S. Live Cattle Industry, Bill Bullard
Under Siege: The U.S. Live Cattle Industry, Bill Bullard
South Dakota Law Review
No abstract provided.
[Introduction To] Couched In Death: Klinai And Identity In Anatolia And Beyond, Elizabeth P. Baughan
[Introduction To] Couched In Death: Klinai And Identity In Anatolia And Beyond, Elizabeth P. Baughan
Bookshelf
In Couched in Death, Elizabeth P. Baughan offers the first comprehensive look at the earliest funeral couches in the ancient Mediterranean world. These sixth- and fifth-century BCE klinai from Asia Minor were inspired by specialty luxury furnishings developed in Archaic Greece for reclining at elite symposia. It was in Anatolia, however—in the dynastic cultures of Lydia and Phrygia and their neighbors—that klinai first gained prominence not as banquet furniture but as burial receptacles. For tombs, wooden couches were replaced by more permanent media cut from bedrock, carved from marble or limestone, or even cast in bronze. The rich archaeological …
Weight Loss Methods And Eating Disorder Risk Factors In Collegiate Wrestlers, Jessica Rea
Weight Loss Methods And Eating Disorder Risk Factors In Collegiate Wrestlers, Jessica Rea
All-Inclusive List of Electronic Theses and Dissertations
Purpose: The purpose of the study is to investigate the weight loss of collegiate wrestlers and assess their risk for eating disorders (ED). Methods: Wrestlers were recruited by contacting the athletic trainer (AT) at the institution they wrestled. ATs who agreed to participate were sent an electronic link containing a survey, 143 wrestlers provided usable data. The survey was created from two surveys one allows the athlete to describe his eating behaviors and the ATHLETE questionnaire which measures risk for ED. We analyzed the data using descriptive statistics and frequencies. Results: 76.6% of wrestlers indicated binge eating; eating behaviors are …
2013 January, Office Of Communications & Marketing, Morehead State University.
2013 January, Office Of Communications & Marketing, Morehead State University.
Morehead State Press Release Archive, 1961 to the Present
Press releases for January of 2013.
2013 Web Features, Office Of Communications & Marketing, Morehead State University.
2013 Web Features, Office Of Communications & Marketing, Morehead State University.
Morehead State Press Release Archive, 1961 to the Present
Web features for 2013.
Weight Loss Methods And Eating Disorder Risk Factors In Collegiate Wrestlers, Jessica Rea
Weight Loss Methods And Eating Disorder Risk Factors In Collegiate Wrestlers, Jessica Rea
All-Inclusive List of Electronic Theses and Dissertations
Purpose: The purpose of the study is to investigate the weight loss of collegiate wrestlers and assess their risk for eating disorders (ED). Methods: Wrestlers were recruited by contacting the athletic trainer (AT) at the institution they wrestled. ATs who agreed to participate were sent an electronic link containing a survey, 143 wrestlers provided usable data. The survey was created from two surveys one allows the athlete to describe his eating behaviors and the ATHLETE questionnaire which measures risk for ED. We analyzed the data using descriptive statistics and frequencies. Results: 76.6% of wrestlers indicated binge eating; eating behaviors are …
Intercalibraton In Chemical Oceanography-- Getting The Right Number, Gregory A. Cutter
Intercalibraton In Chemical Oceanography-- Getting The Right Number, Gregory A. Cutter
OES Faculty Publications
Intercalibration has a strict metrological definition, but in brief, it's an open sharing of methods and results between laboratories to achieve the most accurate data with the fewest random and systematic errors. In the field of chemical oceanography where concentrations of many constituents can be in the nano- to picomolar range, the salt water matrix can be difficult to analyze, and knowing the exact concentrations, or even chemical forms, of biologically required elements is essential, intercalibration is a very relevant and needed tool. Implementing it is not simple because errors can occur at any step in the process of taking …
A Two-Component Protocol For Synthesis Of 3-(2-(Substituted Phenylamino)Thiazol-4-Yl)-2h-Chromen-2-Ones, Aamer Saeed, Mubeen Arif, Madiha Irfan, Michael Bolte
A Two-Component Protocol For Synthesis Of 3-(2-(Substituted Phenylamino)Thiazol-4-Yl)-2h-Chromen-2-Ones, Aamer Saeed, Mubeen Arif, Madiha Irfan, Michael Bolte
Turkish Journal of Chemistry
An efficient 2-component synthesis of a series of 3-(2-(substituted phenylamino)thiazol-4-yl)-2H-chromen-2-ones (3a--j) was achieved by the reaction of 3-(2-thiocyanatoacetyl)-2H-chromen-2-one (1) with a variety of suitably substituted anilines in 1:1 molar ratio in ethanol. The structures of the products were established by elemental analyses, and UV-vis, FTIR, ^1H and ^{13}C NMR, and mass spectroscopy. 3-(2-(4-Methylphenylamino)thiazol-4-yl)-2H-chromen-2-one (3j) was further characterized by single crystal X-ray diffraction study. This compound, C_{19}H_{14}N_2OS, crystallizes in the orthorhombic space group Pna21, with Z = 4, and unit cell parameters a = 13.0785(11), b = 25.746(2), c = 4.7235(3) Å, \alpha = \beta = \gamma = 90°.
Calixarene-Based Receptors For Molecular Recognition, Mustafa Yilmaz, Serkan Erdemi̇r
Calixarene-Based Receptors For Molecular Recognition, Mustafa Yilmaz, Serkan Erdemi̇r
Turkish Journal of Chemistry
Calixarene-based molecular receptors have been a widely developing area in material science and technology for the last few decades. Due to their bowl-shaped geometry, calixarene macrocycles are used as hosts allowing organic and inorganic guests to coordinate/sorb onto their cavity. This work briefly reviews the recent development of calixarenes.
Synthesis And Biological Activities Of Methylenebis-4h-1,2,4-Triazole Derivatives, Yildiz Uygun, Hacer Bayrak, Havva Özkan
Synthesis And Biological Activities Of Methylenebis-4h-1,2,4-Triazole Derivatives, Yildiz Uygun, Hacer Bayrak, Havva Özkan
Turkish Journal of Chemistry
5,5'-Methylenebis(4--phenyl-4H-1,2,4-triazole-3-thiol) (2) was synthesized starting from hydrazinecarbothioamide compound (1). Treatment of compound 2 with ethyl bromoacetate produced diethyl 5,5'-{methylenebis[(4-phenyl-4H-1,2,4-triazole-5,3-diyl)thio]}diacetate (3), which was converted to the corresponding diacetohydrazide derivative (4) by treatment with hydrazine hydrate. The reaction of compound 4 with several aldehydes produced the corresponding arylidene hydrazides, 5a--d. Syntheses of Mannich bases 6a--c were carried out by the treatment of compound 2 with several amines in the presence of formaldehyde. (4{[5-({5-[(4-Amino-2-chlorophenyl)thio]-4-phenyl-4H-1,2,4-triazol-3-ylmethyl)-4-phenyl-4H-1,2,4-triazol-3-yl]thio}-3-chlorophenyl)amine (8) was prepared by reduction of 2 nitro groups of 3,3' -methylenebis{5-[(2-chloro-4-nitrophenyl)thio]-4-phenyl-4H-1,2,4-triazole} (7) that were obtained from the condensation of 2} with 3,4-dichloronitrobenzene. The newly synthesized compounds were screened …
Synthesis, Spectroscopic Characterization, And Biological Screening Of Binuclear Transition Metal Complexes Of Bicompartmental Schiff Bases Containing Indole And Resorcinol Moieties, Mahendra Raj Karekal, Mruthyunjayaswamy Bennikallu Hire Mathada
Synthesis, Spectroscopic Characterization, And Biological Screening Of Binuclear Transition Metal Complexes Of Bicompartmental Schiff Bases Containing Indole And Resorcinol Moieties, Mahendra Raj Karekal, Mruthyunjayaswamy Bennikallu Hire Mathada
Turkish Journal of Chemistry
A series of binucleating Cu(II), Ni(II), and Zn(II) complexes of bicompartmental ligands with ONO donors were prepared. The ligands were synthesized by the condensation of 5-substituted-3-phenyl-1H-indole-2-carboxyhydrazides and 4,6-diacetylresorcinol. The newly synthesized ligands and their complexes were characterized by elemental analysis and various spectral studies like IR, ^1H NMR, ESI-mass, UV-Vis, ESR, thermal studies, magnetic susceptibility, molar conductance, and powder-XRD data. All the complexes were binuclear and monomeric in nature. Cu(II) complexes have octahedral geometry, whereas Ni(II) and Zn(II) complexes have square planar and tetrahedral geometry, respectively. The redox property of the Cu(II) complex was investigated by electrochemical method using cyclic …
A Kinetic Study Of Atom Transfer Radical Polymerization Of Styrene With Bis(2-Pyridyl)Ethylenedimethanimine Derivative Ligands, Hülya Arslan, Yasemi̇n Küçük, Ayfer Menteş, Meti̇n Hayri̇ Acar
A Kinetic Study Of Atom Transfer Radical Polymerization Of Styrene With Bis(2-Pyridyl)Ethylenedimethanimine Derivative Ligands, Hülya Arslan, Yasemi̇n Küçük, Ayfer Menteş, Meti̇n Hayri̇ Acar
Turkish Journal of Chemistry
Atom transfer radical polymerization (ATRP) of styrene was carried out with multidentate nitrogen-based ligands, namely N,N'-bis[phenyl(pyrid-2-yl)methylene] ethane-1,2-diamine (BPDA) and N,N'-bis[methyl(pyrid-2-yl)methylene] ethane-1,2-diamine (BMDA), and catalyst systems at catalyst/ligand molar ratios of 1/0.33, 1/0.5, 1/1, and 1/1.5 by using 2 different initiators, (1-bromoethyl)benzene (BEB) and ethyl-2-bromopropionate (EBP). Linear first-order kinetic plots were observed for ATRP of styrene upon using BPDA as a ligand with both initiators. Even though the linear slopes indicate that radical concentration remains constant during reactions, high molecular weights were obtained at low conversion and showed a linear relation thereafter. To investigate the molecular weight effect, reactions were also …
Sesquiterpene Hydrocarbons Of The Essential Oil Of Actinolema Macrolema Boiss, Betül Demi̇rci̇, Gülden Koltuksuz Yasdikcioğlu, Kemal Hüsnü Can Başer
Sesquiterpene Hydrocarbons Of The Essential Oil Of Actinolema Macrolema Boiss, Betül Demi̇rci̇, Gülden Koltuksuz Yasdikcioğlu, Kemal Hüsnü Can Başer
Turkish Journal of Chemistry
The essential oils of Actinolema macrolema Boiss. (Apiaceae) were obtained by hydrodistillation in the first 3 (sample A) and the following 3 h (sample B) from crushed fruits and dried leaves (sample C), which were subsequently analyzed by GC and GC-MS. Overall, 64 components were characterized, representing 93% of the leaf oil. Thirty components were characterized from the fruit oil representing 95% of the first fraction and 90% of the second fraction consecutively. Guaia-5,7(11)-diene, selina-3,7(11)-diene, and juniper camphor were isolated from the oils by column chromatography and their structures were elucidated by GC-MS, ^1H NMR, and ^{13}C NMR. The occurrence …
Fabrication Of Layer-By-Layer Deposited Films Containing Carbon Nanotubes And Poly(Malachite Green) As A Sensor For Simultaneous Determination Of Ascorbic Acid, Epinephrine, And Uric Acid, Jahan Bakhsh Raoof, Reza Ojani, Mehdi Baghayeri
Fabrication Of Layer-By-Layer Deposited Films Containing Carbon Nanotubes And Poly(Malachite Green) As A Sensor For Simultaneous Determination Of Ascorbic Acid, Epinephrine, And Uric Acid, Jahan Bakhsh Raoof, Reza Ojani, Mehdi Baghayeri
Turkish Journal of Chemistry
A simple approach to constructing a double-layer voltammetric sensor is described. The poly(malachite green) (PMG) and multiwalled carbon nanotubes (MWCNTs) were coimmobilized at the surface of the glassy carbon electrode (GCE) for fabrication of PMG/MWCNT/GCE. The modified electrode was characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), differential pulse voltammetry (DPV), and chronoamperometric techniques. Using DPV, the obtained catalytic peak current was linearly dependent on the ascorbic acid (AA), epinephrine (EP), and uric acid (UA) concentrations in the ranges of 0.4-100.0, 0.1-100.0, and 0.3-90.0 \muM, respectively. The resultant detection limits for AA, EP, and UA were 0.23, 0.0820, and …
Disposable Carbon Electrodes As An Alternative For The Direct Voltammetric Determination Of Alkyl Phenols From Water Samples, Iulia Gabriela David, Irinel Adriana Badea, Gabriel Lucian Radu
Disposable Carbon Electrodes As An Alternative For The Direct Voltammetric Determination Of Alkyl Phenols From Water Samples, Iulia Gabriela David, Irinel Adriana Badea, Gabriel Lucian Radu
Turkish Journal of Chemistry
Disposable sensors based on a pencil graphite electrode were described for detection of alkyl phenols. The performances of the disposable bare pencil graphite electrode (PGE) and PGE modified with carbon nanotubes, regarding the cyclic and differential pulse voltammetric determination of 4-nonylphenol, 4-octylphenol, and 4-tert-octylphenol, were compared. Some experimental variables of the electrode surface pretreatment and measurement parameters were optimized. Using a phosphate buffer solution (pH 7.40) as the supporting electrolyte, alkyl phenols gave a well-defined oxidation peak at about 700 mV vs. Ag/AgCl. The detection limits established for each alkyl phenol were: 0.25 \muM for 4-octylphenol, 0.42 \muM for 4-nonylphenol, …
Verbal Response Modes In Action:Microrelationships As The Building Blocks Of Relationship Role Dimensions, Ayesha Shaikh, Lynne M. Knobloch-Fedders, William B. Stiles
Verbal Response Modes In Action:Microrelationships As The Building Blocks Of Relationship Role Dimensions, Ayesha Shaikh, Lynne M. Knobloch-Fedders, William B. Stiles
Psychology Faculty Research and Publications
Dimensions of interpersonal relationships, such as attentiveness, directiveness, and presumptuousness, have typically been assessed through impressionistic ratings or by aggregate scores derived from coding of specific (e.g., verbal) behaviors. However, the meanings of these dimensions rest on the interpersonal microrelationships that are actually observed by the raters or coders. In this qualitative study, the way these global relationship qualities were built from microrelationships at the utterance level was examined in passages from one medical interaction. Applications of microrelationships to future communications research are suggested.
Reflector Magazine, Georgia Southern University, Student Media
Reflector Magazine, Georgia Southern University, Student Media
Reflector Magazine
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Collection Development In The Digital Age [Book Review], Robert P. Holley
Collection Development In The Digital Age [Book Review], Robert P. Holley
School of Information Sciences Faculty Research Publications
No abstract provided.
Examining The Hidden Ideologies Within Cultural Competence Discourses Among Library And Information Science (Lis) Students: Implications For School Library Pedagogy, Kafi D. Kumasi, Renee F. Hill
Examining The Hidden Ideologies Within Cultural Competence Discourses Among Library And Information Science (Lis) Students: Implications For School Library Pedagogy, Kafi D. Kumasi, Renee F. Hill
School of Information Sciences Faculty Research Publications
In order to provide culturally responsive instruction to all students, school library professionals need to recognize the various discourses around cultural competence that exist in the field of library and information science (LIS) and understand the broader meanings that are attached to these discourses. This study presents an evaluation of the underlying ideologies that are embedded in the textual responses of a group of LIS students reporting on their perceived levels of cultural competence preparation. The results reveal that there are dominant and competing discourses around cultural competence in the LIS field, which are important to make visible. The paper …
“Reinventing” Higher Education: Symbolism, Sloganeering, And Subjectivity In The Lone Star State, Staci M. Zavattaro, Terence Garrett
“Reinventing” Higher Education: Symbolism, Sloganeering, And Subjectivity In The Lone Star State, Staci M. Zavattaro, Terence Garrett
Political Science Faculty Publications
Higher education is part and parcel of a market spectacle (Debord 1967/1994; Garrett and Sementelli 2012) that follows some prescriptions of reinventing government (Osborne and Gaebler 1993), essentially charging these institutions with inefficient operations and minimal customer service standards. Following the “reinventing government” qua business model, any semblance of public service (Denhardt and Denhardt 2007) – now including public colleges and universities – that ignores “customers” is under attack. While governance values shifted with these business-based movements (Box, et al 2001), higher education values, too, have moved universities from producing academic capital to economic capital (Naidoo and Jamieson 2005).
The Importance Of Digitization In Teaching-Oriented University And College Libraries, Craighton Hippenhammer
The Importance Of Digitization In Teaching-Oriented University And College Libraries, Craighton Hippenhammer
The Christian Librarian
An increasing number of university and college libraries have started digitization programs, and there are good reasons why they are doing so. First, we are in the middle of revolutionary change as to how ideas get published and distributed. Over 50 percent of scholarly publishing has gone digital, and over 20 percent has gone open access. Governments worldwide are beginning to require that tax-supported research be published in open access venues. Secondly, it is imperative that academic institutions increase their archives’ digital presence. Traditional approaches to preserving institutional histories are being lost because many archives continue to preserve only paper …
Resource Reviews, Phyllis Fox
Resource Reviews, Phyllis Fox
The Christian Librarian
Reviews of
Dead Sea Scrolls and the Bible, by James Vanderkam. Grand Rapids: William B. Eerdmans, 2012. 188 pp. $17.00; ISBN 0-8028-6679-0. Reviewed by Robert Burgess, Head, Acquisitions, Midwestern Baptist Theological Seminary, Kansas City, Missouri.
Jerusalem Testament Palestinian Christians Speak, 1988-2008, by Melanie A. May. Grand Rapids: William B. Eerdmans, 2010. 180 pp. $16.00; ISBN 0-8028-6485-7. Reviewed by Robert Burgess, Head, Acquisitions, Midwestern Baptist Theological Seminary, Kansas City, Missouri.
Jesus Christ and the Life of the Mind, by Mark A. Noll. Grand Rapids: William B. Eerdmans, 2011. 180 pp. $16.99. ISBN 978-0-8028-6637-0. Reviewed by Jane Scott, Public Services Librarian, George …
Osgoode Syllabus Of Courses And Seminars: 2013 - 2014, Office Of Student Services
Osgoode Syllabus Of Courses And Seminars: 2013 - 2014, Office Of Student Services
Syllabi
No abstract provided.
Ionic Liquid Mediated Synthesis, Reactions, And Insecticidal Activity Of 1-[(1h-Benzoimidazol-2-Yl)Amino]Spiro[Azetidine-4,4'-[4'H]Chroman]-2-Ones, Dr Kanti Sharma, Renuka Jain
Ionic Liquid Mediated Synthesis, Reactions, And Insecticidal Activity Of 1-[(1h-Benzoimidazol-2-Yl)Amino]Spiro[Azetidine-4,4'-[4'H]Chroman]-2-Ones, Dr Kanti Sharma, Renuka Jain
Turkish Journal of Chemistry
Ionic liquid mediated synthesis of novel heterocyclic compounds 1-[(1H-benzoimidazol-2-yl)amino]-2'-phenylspiro[azetidine- 4,4'-[4'H]chroman]-2-ones (3) and 1-[(1H-benzoimidazol-2-yl)amino]- 3-chloro-2'-phenylspiro[aze tidine-4,4'-[4'H] chroman]-2-ones (4) was accomplished by condensing substituted 2-hydrazino benzimidazole (1), flavanone (2), and acetyl chloride/chloroacetyl chloride in ionic liquid, [bmim]PF_6 with or without using catalyst in excellent yield (90%--95%). Further, compounds 3 and 4 were acylated with trifluoroacetic anhydride to give N-acylated products (5 and 10); 3 when treated with HCHO and (C_2H_5)_2NH gave Mannich bases (6) and with aldehydes afforded 3-arylidene-2-azetidinone (7). Compounds 4 underwent nucleophilic substitution with (i) KI (Finkelstein reaction) and (ii) phenols to give the corresponding iodo and phenoxy derivatives (8 …
Synthesis And Antimicrobial Investigation Of Some 5h-Pyridazino[4,5-B]Indoles, İlker Avan, Alaetti̇n Güven, Kiymet Güven
Synthesis And Antimicrobial Investigation Of Some 5h-Pyridazino[4,5-B]Indoles, İlker Avan, Alaetti̇n Güven, Kiymet Güven
Turkish Journal of Chemistry
Synthesis and in vitro antimicrobial activities are reported for a series of 1,3,5-substituted 4-oxo-3,4-dihydro-5H-pyridazino[4,5-b]indole derivatives. Corresponding pyridazino[4,5-b]indoles were prepared from ethyl 3-formyl-1H-indole-2-carboxylate precursors and the functional group in question was installed with hydrazine and its derivatives. The purity and primary structures of pyridazino[4,5-b]indole were confirmed by IR, ^1 H NMR, and ^{13}C NMR spectroscopy and elemental analyses. All of the indoles were tested for in vitro antimicrobial activity against 8 isolates of bacteria and a fungus including Staphylococcus aureus NRRL B-767, Escherichia coli ATCC 25922, Pseudomonas aeruginosa ATCC 27853, Proteus vulgaris NRRL-B123, Salmonella typhimurium NRRL B-4420, Bacillus subtilis NRRL 744, …
Potentiometric Study Of Equilibrium Constants Of A Novel Triazine--Thione Derivative And Its Stability Constants With Hg^{2+}, Cu^{2+}, Ni^{2+}, Pb^{2+}, And Zn^{2+} Metal Ions In Ethanol And Water Mixed, Fati̇h Polat, Hasan Atabey, Hayati̇ Sari, Alaaddi̇n Çukurovali
Potentiometric Study Of Equilibrium Constants Of A Novel Triazine--Thione Derivative And Its Stability Constants With Hg^{2+}, Cu^{2+}, Ni^{2+}, Pb^{2+}, And Zn^{2+} Metal Ions In Ethanol And Water Mixed, Fati̇h Polat, Hasan Atabey, Hayati̇ Sari, Alaaddi̇n Çukurovali
Turkish Journal of Chemistry
The deprotonation constants of 5-hydroxy-5,6-di-pyridin-2-yl-4,5-dihydro-2H-[1,2,4] triazine-3-thione (HPT) and the stability constants of its Hg^{2+}, Ni^{2+}, Cu^{2+}, Pb^{2+}, and Zn^{2+} ion complexes were studied in 20% ethanol and water mixed at 25 \pm 0.1 °C and ionic strength (I) of 0.1 M supported by NaCl. Four pK_a values of HPT were determined: 3.58, 6.30, 9.23, and 9.69. In various pH conditions, the different complex forms were formulated as ML, MHL, MH_2L, MH_3L, MH_4L, and MH_{-2}L between Hg^{2+}, Ni^{2+}, Cu^{2+}, Pb^{2+}, and Zn^{2+} ions and HPT. According to the potentiometric and spectrophotometric results, the HPT and Hg^{2+} combination formed a selective and …
(Nhc)-Pd(Ii) Complexes With Hydrophilic Nitrogen Ligands: Catalytic Properties In Neat Water, Hayati̇ Türkmen, Lütfi̇ye Gök, İbrahi̇m Kani̇, Beki̇r Çeti̇nkaya
(Nhc)-Pd(Ii) Complexes With Hydrophilic Nitrogen Ligands: Catalytic Properties In Neat Water, Hayati̇ Türkmen, Lütfi̇ye Gök, İbrahi̇m Kani̇, Beki̇r Çeti̇nkaya
Turkish Journal of Chemistry
The cleavage reactions of the dimers [(NHC)PdX_2]_2 with hydrophilic N-donors, L, afforded the mixed-ligand complexes of the type trans-[(NHC)LPdX_2] (X = Cl or Br; NHC = 1,3-dialkylbenzimidazol-2-ylidene (BIm) or bis(imino)acenaphthene-annulated bis(2,6-diisopropylphenyl)imidazol-2-ylidene (BIAN-IPr); L = diethanolamine (DEA), morpholine (MOR), and 3-pyridinecarboxylic acid (3-PCA)). The new complexes (1--3) were characterized by elemental analysis and spectroscopic methods and the molecular structure of 1a was determined by X-ray diffraction studies. These complexes were applied in the Suzuki--Miyaura cross-coupling reaction of phenylboronic acid with aryl halides in neat water. The activities of catalysts were monitored by gas chromatography--flame ionization detector and nuclear magnetic resonance. Whereas …