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Measuring The Orientations Of Hidden Subvertical Joints In Highways Rock Cuts Using Ground Penetrating Radar In Combination With Lidar, Adnan Mohammed Aqeel

Doctoral Dissertations

"Mapping discontinuities in rock cuts and measuring their orientations is crucial in assessing the stability of rock masses. This can be done usually using manual methods such as scanline or advanced techniques such as LIDAR. However, these methods are used only to map exposed discontinuities which may cause underestimation for slope stability. Accordingly, ground penetrating radar (GPR) has been recently used to detect such hidden discontinuities.

The used 400 MHz monostatic GPR antenna was significantly able to detect and map hidden subvertical joints within 4 m depths in five sandstone highways rock cuts and within 3 m depths in two …

Complex Scaling Behavior In Animal Foraging Patterns, Prabhavi Kaushalya Premachandra

Doctoral Dissertations

This dissertation attempts to answer questions from two different areas of biology, ecology and neuroscience, using physics-based techniques. In Section 2, suitability of three competing random walk models is tested to describe the emergent movement patterns of two species of primates. The truncated power law (power law with exponential cut off) is the most suitable random walk model that characterizes the emergent movement patterns of these primates. In Section 3, an agent-based model is used to simulate search behavior in different environments (landscapes) to investigate the impact of the resource landscape on the optimal foraging movement patterns of deterministic foragers. …

Chelating Compounds As Potential Flash Rust Inhibitors And Melamine & Aziridine Cure Of Acrylic Colloidal Unimolecular Polymers (Cups), Jigar K. Mistry

Doctoral Dissertations

Waterborne coatings on ferrous substrates usually show flash rusting which decreases the adhesion of the coating and the corrosion products can form a stain. Chelating compounds were investigated as potential flash rust inhibitors. Compounds being evaluated include amine alcohols, diamines and sulfur containing amines. A new corrosion inhibitor 2,5-bis(thioaceticacid)-1,3,4-thiadiazole (H2ADTZ) was synthesized and its performance characteristics were evaluated. It was noted that the observed structure of 1,3,4-thiadiazolidine-2,5-dithione (also known as 2,5-dimercapto-1,3,4-thiadiazole (DMTD or DMcT)) has been previously reported in three different tautomeric forms including -dithiol and -dithione. The relative stability of each form as well as the synthesis and characterization …

Purification Of Metals Through Filtration And Electromagnetic Separation, Lucas Nana Wiredu Damoah

Doctoral Dissertations

"The applicability of a high frequency electromagnetic field to the removal of nonmetallic inclusions from silicon and aluminum, and the mechanism of depth mode filtration during aluminum purification were investigated. Electromagnetic separation experiments at frequencies of 63 - 120 kHz and aluminum filtration experiments using both conventional Al₂O₃ filters and AlF₃ coated Al₂O₃ filters were carried out by flowing molten aluminum through, and partly solidified in the filter bed followed by analysis of the metal and filter material. Materials were characterized with an optical microscope and macroscope, scanning electron microscope (SEM/EDX), x-ray diffraction (XRD), electron probe microanalysis (EPMA) and glow …

An Improved Dipole-Moment Model Based On Near-Field Scanning For Characterizing Near-Field Coupling And Far-Field Radiation From An Ic, Zhenwei Yu

Doctoral Dissertations

"Radio Frequency Interference (RFI) problems are critical issues in wireless platform design. The accurate noise model of integrated circuits (ICs) is needed to help designers to diagnose and predict RFI problems. In this dissertation, an improved IC radiated emission model based on near-field measurements is proposed. The regularization technique and the truncated SVD method are employed together with the least square method to calculate the dipole moments from the near-field data. This dipole model has clear physical meaning: the electric and magnetic dipoles represent the voltage and the current in the circuit, respectively. One application of this dipole model is …

Thermal Properties Of Spinel Based Solid Solutions, Kelley R. Wilkerson

Doctoral Dissertations

"Solid solution formation in spinel based systems proved to be a viable approach to decreasing thermal conductivity. Samples with systematically varied additions of MgGa₂O₄ to MgAl₂O₄ were prepared and thermal diffusivity was measured using the laser ash technique. Additionally, heat capacity was measured using differential scanning calorimetry and modeled for the MgAl₂O₄-MgGa₂O₄ system. At 200⁰C thermal conductivity decreased 24% with a 5 mol% addition of MgGa₂O₄ to the system. The solid solution continued to decrease the thermal conductivity by 13% up to 1000⁰C with 5 mol% addition. The decrease in thermal conductivity ultimately resulted in a decrease in heat flux …

Addressing Control And Capacitor Voltage Regulation Challenges In Multilevel Power Electronic Converters, Hossein Sepahvand

Doctoral Dissertations

Multilevel power electronic converters are the current industry solutions for applications that demand medium voltage, reasonable efficiency, and high power quality. The proper operation of these types of power converters requires special control, modulation methods, and capacitor voltage regulation techniques. Both developing capacitor voltage regulation methods and addressing their associated issues with such fall within the primary focus of this dissertation. In this dissertation an investigation was conducted on the capacitor voltage regulation constraints in cascaded H-bridge multilevel converters with a staircase output voltage waveform. In the proposed method, the harmonic elimination technique is used to determine the switching angles. …

Compressive Sensing For 3d Microwave Imaging Systems, Hamed Kajbaf

Doctoral Dissertations

"Compressed sensing (CS) image reconstruction techniques are developed and experimentally implemented for wideband microwave synthetic aperture radar (SAR) imaging systems with applications to nondestructive testing and evaluation. These techniques significantly reduce the number of spatial measurement points and, consequently, the acquisition time by sampling at a level lower than the Nyquist-Shannon rate. Benefiting from a reduced number of samples, this work successfully implemented two scanning procedures: the nonuniform raster and the optimum path.

Three CS reconstruction approaches are also proposed for the wideband microwave SAR-based imaging systems. The first approach reconstructs a full-set of raw data from undersampled measurements via …

Densification And Thermal Properties Of Zirconium Diboride Based Ceramics, Matthew Joseph Thompson

Doctoral Dissertations

"The research presented in this dissertation focuses on the processing and thermomechanical properties of ZrB₂ based ceramics. The overall goal was to improve the understanding of thermal and mechanical properties based on processing conditions and additives to ZrB₂. To achieve this, the relationships between the thermal and mechanical properties were analyzed for ZrB₂ ceramics that were densified by different methods, varying amounts of carbon, B₄C, or TiB₂ additions. Four main areas were investigated in this dissertation. The first showed that decreased processing times, regardless of densification method, improved mechanical strength to >500 MPa. This study also revealed that lower oxygen …

Free-Radical Maleation Of Poly(Butylene Adipate-Co-Terephthalate) In Supercritical Carbon Dioxide And Its Effect On The Percolation And Deformation Mechanism Of Layered Silicate Nanocomposites, Alexandria Niemoeller

Doctoral Dissertations

The utilization of compostable polymers such as poly(butylene adipate-co-terephthalate) (PBAT) in single-use packaging applications can mitigate the water, solvents, and energy required for processing plastic waste. PBAT exhibits exceptional elongational properties, but its moderate water vapor permeability and low tensile modulus limit the applications in which PBAT can be employed. In this work, PBAT nanocomposites were produced at various loadings of organically-modified montmorillonite. The secondary structure of nanoparticles formed within the PBAT matrix was evident in the terminal region of the linear viscoelastic response under oscillatory shear, and a percolation threshold was determined to occur at 3.88% clay by weight. …

Investigation Of Wellbore Stability In A North Sea Field Development, Steven Austin Hilgedick

Doctoral Dissertations

"Planning drilling operations is key to the development of oil and natural gas fields. As part of well design, wellbore stability and pore pressure analysis are main factors in determining the safe operating window for selecting mud density. The motivation for this research was to conduct wellbore stability based on exploration wells as basis for planning new offshore field developments with deviated and horizontal wells. A second objective was to investigate the use of a probabilistic approach to wellbore stability, and compare it to the conventional deterministic methods, in order to evaluate the value of including a probabilistic approach to …

Lifetime Prediction And Confidence Bounds In Accelerated Degradation Testing For Lognormal Response Distributions With An Arrhenius Rate Relationship, Steven Michael Alferink

Doctoral Dissertations

"Determining the lifetime of a product is an important component of quality assurance. Traditional life testing methods are infeasible for products that have been designed to have a very long lifetime because they require a lengthy testing period. An alternative method is accelerated degradation testing, where a response variable determining the usability of the product is measured over time under multiple accelerating stress levels. The resulting data are then used to predict the life distribution of the product under the design stress level. In this dissertation, several methods are proposed and studied for obtaining prediction bounds for the lifetime of …

Mantle Flow And Lithosphere-Asthenosphere Coupling Beneath The Southwestern Edge Of The North American Craton: Constraints From Shear-Wave Splitting Measurements, Hesham A. Refayee

Doctoral Dissertations

"High-quality broadband seismic data recorded by the USArray and other stations in the southwestern United States provide a unique opportunity to test different models of anisotropy-forming mechanisms in the vicinity of a cratonic edge. Systematic spatial variations of anisotropic characteristics are revealed by 3027 pairs of splitting parameters measured at 547 broadband seismic stations. The western and southern edges of the North American craton show edge-parallel fast directions with larger-than-normal splitting times, and the continental interior is characterized by smaller splitting times spatially consistent fast directions that are mostly parallel to the absolute plate motion direction of North America. Except …

Meso-Scale Fluidic Devices With Chemical Sensors For Biological Applications, Satya Gowthami Achanta

Doctoral Dissertations

"Molecular oxygen and humidity are some of the major environmental quantities being measured for various industrial and commercial applications. This dissertation focuses on the design, fabrication and characterization of optofluidic biosensor systems for oxygen and humidity quantification using color charge-coupled device (CCD) camera as a photodetector and LED panel as an excitation source. Meso-scale fluidic devices with integrated oxygen and humidity sensors for potential applications to hydrotropic and oxytropic studies of small plant roots have been investigated in this study. Meso-scale sensor platform was fabricated using porphyrine complex as the sensitive dye embedded within Ethyl Cellulose (EC) polymer matrix. Green …

Nitrification Performance Of Activated Sludge Under Low Dissolved Oxygen Conditions, Guoqiang Liu

Doctoral Dissertations

"The combined effects of solids retention time (SRT) and dissolved oxygen (DO) concentration on nitrification, nitrifying bacterial communities, and aeration needs in the activated sludge process were studied. Nitrification was almost completed in the 10, 20, and 40-day SRT reactors with a minimum DO of 0.37, 0.25, and 0.16 mg/L, respectively. Under long-term low DO conditions, the endogenous decay of nitrifiers was slowed down and then nitirfier biomass concentration increased, thereby reducing the adverse effect of low DO on nitrification. Under long-term low DO conditions, the oxygen affinity of nitrite-oxidizing bacteria (NOB) increased significantly and as a result, NOB became …

Plate Kinematics Of The Afro-Arabian Rift System With An Emphasis On The Afar Depression, Helen Carrie Bottenberg

Doctoral Dissertations

This work utilizes the Four-Dimensional Plates (4DPlates) software, and Differential Interferometric Synthetic Aperture Radar (DInSAR) to examine plate-scale, regional-scale and local-scale kinematics of the Afro-Arabian Rift System with emphasis on the Afar Depression in Ethiopia. First, the 4DPlates is used to restore the Red Sea, the Gulf of Aden, the Afar Depression and the Main Ethiopian Rift to development of a new model that adopts two poles of rotation for Arabia. Second, the 4DPlates is used to model regional-scale and local-scale kinematics within the Afar Depression. Most plate reconstruction models of the Afro-Arabian Rift System relies on considering the Afar …

Quantitative Analysis Of Co-Enzyme A In A Plant Tissues And Cancer Biomarkers In Urine Samples By Using Capillary Electrophoresis And Liquid Chromatography-Mass Spectrometry, Yongqing Jiang

Doctoral Dissertations

"Despite continuous effort and progress in cancer detection and therapy, cancer remains one of our greatest health concerns because of its low survival rate and rapid incidence increase. One reason for this is the late detection and therefore pre-cancer diagnosis is crucial. In pre-cancer studies, cancer biomarkers become significant because of the useful information it contains such as possible cancer type and stage. Separation and detection technique plays an important role in cancer biomarker identification.

Coenzyme A (CoA) facilitates more than 100 chemical reactions in cells. Because of its low abundance accumulated in cells, it is critical to develop a …

Role Of Alloy Additions On Strengthening In 17-4 Ph Stainless Steel, Arpana S. Murthy

Doctoral Dissertations

"Alloy modifications by addition of niobium (Nb ), vanadium (V), nitrogen (N) and cobalt (Co) to cast 17-4 PH steel were investigated to determine the effect on mechanical properties. Additions of Nb, V, and N increased the yield strength from 1120 MPa to 1310 MPa while decreased the room temperature charpy V notch (CVN) toughness from 20 J to four Joules. The addition of Co to cast 17-4 PH steel enhanced the yield strength and CVN toughness from 1140 MPa to 1290 MPa and from 3.7 J to 5.5 J, respectively. In the base 17-4 PH steel, an increase in …

Spatial-Temporal Reasoning Applications Of Computational Intelligence In The Game Of Go And Computer Networks, Tae-Hyung Kim

Doctoral Dissertations

"Spatial-temporal reasoning is the ability to reason with spatial images or information about space over time. In this dissertation, computational intelligence techniques are applied to computer Go and computer network applications. Among four experiments, the first three are related to the game of Go, and the last one concerns the routing problem in computer networks.

The first experiment represents the first training of a modified cellular simultaneous recurrent network (CSRN) trained with cellular particle swarm optimization (PSO). Another contribution is the development of a comprehensive theoretical study of a 2x2 Go research platform with a certified 5 dan Go expert. …

Stability Challenges And Solutions In Current-Mode Controlled Power Electronic Converters, Seyed Mostafa Khazraei

Doctoral Dissertations

"This dissertation focuses on stability issues in single-staged and multi-staged current controlled power electronic converters. Most current-mode control (CMC) approaches suffer from sub-harmonic oscillations. An external ramp is usually added to solve this problem. However, to guarantee stability this ramp has to be designed for the worst possible case which consequently over damps the response. Adaptive slope compensation (ASC) methods are the solution for this problem. In paper 1 of this dissertation, first three ASC methods will be investigated and analyzed through their small signal models. Then, through simulation analyses and experimental test of a variable-input voltage converter the results …

Strategic Management And Entrepreneurship As Economic Development Tools, Norbert Ziemer

Doctoral Dissertations

This research develops a framework of Biobased Entrepreneurial Ventures for Rural Economic Development. Rural economic development poses unique challenges and opportunities, based on available production assets, workforce trends like "brain drain," and access to industry clusters. However, certain entrepreneurial venture opportunities are preferable for rural economic development. Since supply chains are vital to business success, initial emphasis is placed on the biomass resource base to be transformed through entrepreneurial activity into higher economic value outputs. The literature contains research on specific opportunities in rural economic development (e.g. ethanol, wind power). Many of these are limited in scope and depend on …

Stochastic Optimal Adaptive Controller And Communication Protocol Design For Networked Control Systems, Hao Xu

Doctoral Dissertations

"Networked Control System (NCS) is a recent topic of research wherein the feedback control loops are closed through a real-time communication network. Many design challenges surface in such systems due to network imperfections such as random delays, packet losses, quantization effects and so on. Since existing control techniques are unsuitable for such systems, in this dissertation, a suite of novel stochastic optimal adaptive design methodologies is undertaken for both linear and nonlinear NCS in presence of uncertain system dynamics and unknown network imperfections such as network-induced delays and packet losses. The design is introduced in five papers.

In Paper 1, …

Sustainable Engineering Practices In Transportation Projects, Kiran Rangarajan

Doctoral Dissertations

"Sustainability has become an important issue in transportation and infrastructure development projects. While several agencies are trying to incorporate a range of sustainability measures in their goals and missions, only a few planning agencies have been able to implement these policies and they are far from perfect. The low rate of success in implementing sustainable policies is primarily due to incomplete understanding of the system and the interaction between various elements of the system. The conventional planning efforts focuses mainly on performance measures pertaining to the system and its impact on the environment but seldom on the social and economic …

The Effect Of Supercritical Water On Crude Glycerin Solution, Jared Bouquet

Doctoral Dissertations

"Crude glycerin solution, a principal byproduct of the conventional biodiesel process, was reacted in supercritical water using a specially designed Haynesʼ Alloy 282 reactor system for the production of hydrogen rich syngas. The effects of temperature, pressure, water-to-carbon molar ratio, reactor residence time, and glycerin-to-methanol weight ratio on the extent of carbon gasification and gas composition were explored. Based on the results, the extent and selectivity of reactions that concurrently occur when methanol and glycerin are in the presence of supercritical water were analyzed. A decomposition reaction pathway for glycerin conversion to syngas was hypothesized, and then utilizing the results …

The Effects Of Personal Protective Respirators On Human Motor, Visual, And Cognitive Skills, Anas Ahmed Alghamri

Doctoral Dissertations

"In oxygen-deficient or toxic environments in which controlling the hazard is not feasible, workers wear personal protective respirators. Hazard controls include but are not limited to engineering controls, such as ventilation, and substituting less hazardous materials. However, respirator selection and the design of tasks that require respirators are critical issues. Understanding the effects of respirators on human abilities is critical to respirator selection and therefore to the safety and efficiency of workers. This research investigated the effect of respirators on human abilities. A review of the relevant literature was conducted, revealing that respirators can affect physiological, psychological, motor, and visual …

Hollow Hydroxyapatite Microspheres As Devices For Controlled Delivery Of Proteins And As Scaffolds For Tissue Engineering, Hailuo Fu

Doctoral Dissertations

"Hollow HA microspheres were prepared by converting Li₂O-CaO-B₂O₃ glass microspheres in a K₂HPO₄ solution. Process parameters, such as reaction temperature (25°C-60°C) and concentration of the phosphate solution (0.02-0.25 M) significantly influenced the microstructure of the hollow HA microspheres. Microspheres with the largest hollow core size were obtained at lower temperature or with low K₂HPO₄ concentration. In comparison, microspheres with high surface area (~140 m²/g) were obtained at higher K₂HPO₄ concentration (0.25 M). Upon heat treatment (up to 900°C), the surface area of the hollow HA microspheres decreased (from ~100 m²/g to ~2 m²/g), and the rupture strength increased (from ~11 …

Investigation Of Biomarkers For Noninvasive Early Diagnosis Of Cancer, Sanjeewa Bandara Gamagedara

Doctoral Dissertations

"Cancer is the second leading cause of death worldwide, and deaths from cancer worldwide are projected to continue rising, with an estimated 12 million deaths in 2030. Cancer occurs when cells in a part of the body begin to grow out of control. It develops very rapidly, and early diagnosis offers a greater chance of successful treatment and a higher survival rate. Biomarkers are good potential tools for early diagnosis. The main hypothesis of this study is that the levels of certain metabolites present in human urine can indicate the current or future behavior of cancer. Therefore, these studies focused …

Manufacturing And Characterization Of Soy-Based Polyurethane Composites, Rama Bhadra Raju Vuppalapati

Doctoral Dissertations

"The major cost drivers for composites are raw materials and manufacturing process. Automated manufacturing processes like pultrusion and low cost bio-based raw materials can significantly lower the cost of composites. Polyurethane (PU) resin systems are being introduced in the pultrusion industry as they have higher performance characteristics and manufacturing feasibility when compared to conventional resin systems such as polyester and vinyl ester. PU resin systems are generally characterized as aromatic and aliphatic. Aliphatic PU has lower mechanical properties than the aromatic resin system due to its chemical structure. Nano materials can be used to increase the mechanical properties of aliphatic …

Numerical Simulations Of Fracture Propagation And Sealing: Implications For Wellbore Strengthening, Saeed Salehi

Doctoral Dissertations

"To mitigate the small tolerance between pore pressure and fracture gradients an engineering practice referred to as "wellbore strengthening" is conducted to increase the fracture gradient. The method relies on propping and/or sealing the fractures with specially designed materials. Different competing theories exist for physical wellbore strengthening mechanisms which can be categorized into two groups. The first group explains that strengthening happens as a result of increasing wellbore hoop stress when fractures are sealed while the second group emphasis is on fracture tip isolation with suitable materials and enhancing fracture propagation pressure. The numerical models and lab experiments …

Real-Time Supply Chain Predictive Metrics, William Scott Hunter

Doctoral Dissertations

"Supply chains drive the production world. Virtually all products use a supply chain to produce them and they can determine the success of companies using them. The ability to manage supply chains is currently a mix of relationship management and science, combining personal and company relationships with data analysis.

The increased dependency on supply chains has increased the need to develop and use predictive real-time metrics to manage supply chain risk, measure suppliers and drive performance. Current metrics used are reactive and stagnant in nature. Real-time metrics will allow supply chain professionals to better manage risk. Current management techniques include …