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2012

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Wetland Hydrodynamics And Long-Term Use Of Spring Migration Areas By Lesser Scaup In Eastern South Dakota, Sharon N. Kahara, Steven R. Chipps Apr 2012

Wetland Hydrodynamics And Long-Term Use Of Spring Migration Areas By Lesser Scaup In Eastern South Dakota, Sharon N. Kahara, Steven R. Chipps

Great Plains Research: A Journal of Natural and Social Sciences (through 2013)

Lesser scaup (Aythya affinis [Eyton]) populations remain below their long-term average despite improved habitat conditions along spring migration routes and at breeding grounds. Scaup are typically associated with large, semipermanent wetlands and exhibit regional preferences along migration routes. Identifying consistently used habitats for conservation and restoration is complicated by irregular wetland availability due to the dynamic climate. We modeled long-term wetland use by lesser scaup in eastern South Dakota based on surveys conducted during below-average (1987-1989) and above-average (1993-2002) water condition years. Wetland permanence, longitude, and physiographic region were all significant determinants of use (P < 0.01). Long-term use was best described by a quadratic equation including wetland surface area variability, an index of wetland hydrodynamics that is linked to productivity, biodiversity, and value to waterfowl. Contrary to previous findings, our study shows that over the long term, lesser scaup are more than twice as likely to use permanent wetlands as they are semipermanent wetlands. The northern region of South Dakota's Prairie Coteau, which holds the highest density of hydrologically dynamic permanent wetlands, should be considered an area of conservation concern for lesser scaup. The criteria we identified may be used to identify important lesser scaup habitats in other regions of the Prairie Pothole Region.


Synthesis And Cellular Investigations Of The 131-Lysyl Derivative Of Chlorin E6, Stewart Wynn Humble Apr 2012

Synthesis And Cellular Investigations Of The 131-Lysyl Derivative Of Chlorin E6, Stewart Wynn Humble

Honors Capstones

No abstract provided.


Neural Basis Of Egalitarian Behavior, Christopher T. Dawes, Peter John Loewen, Darren Schreiber, Alan N. Simmons, Taru Flagan, Richard Mcelreath, Scott E. Bokemper, James H. Fowler, Martin P. Paulus Apr 2012

Neural Basis Of Egalitarian Behavior, Christopher T. Dawes, Peter John Loewen, Darren Schreiber, Alan N. Simmons, Taru Flagan, Richard Mcelreath, Scott E. Bokemper, James H. Fowler, Martin P. Paulus

Department of Political Science: Dissertations, Theses, and Student Research

Individuals are willing to sacrifice their own resources to promote equality in groups. These costly choices promote equality and are associated with behavior that supports cooperation in humans, but little is known about the brain processes involved. We use functional MRI to study egalitarian preferences based on behavior observed in the “random income game.” In this game, subjects decide whether to pay a cost to alter group members’ randomly allocated incomes.Wespecifically examinewhether egalitarian behavior is associated with neural activity in the ventromedial prefrontal cortex and the insular cortex, two regions that have been shown to be related to social preferences. …


Synergistic Effect Of Subnanosecond Pulsed Electric Fields And Temperature On The Viability Of Biological Cells, James Thomas Camp Apr 2012

Synergistic Effect Of Subnanosecond Pulsed Electric Fields And Temperature On The Viability Of Biological Cells, James Thomas Camp

Electrical & Computer Engineering Theses & Dissertations

Pulsed electric fields have been used to induce a biological response in cells, and at sufficient energy, can cause cell death. By reducing the pulse duration from presently used nanosecond to subnanosecond ranges, the electric field can be delivered to biological tissue non-invasively by the use of an antenna instead of electrodes, such as needles. Studies have previously been completed in which the aim was to determine the energy density (electric field strength, number of pulses) required to induce cell death with 800 ps pulses. Based on this data, it was concluded that for pulse durations of 200 ps, with …


The Advocate (Spring 2012), Lewis & Clark Law School Apr 2012

The Advocate (Spring 2012), Lewis & Clark Law School

The Advocate

No abstract provided.


Nonosecond Pulsed Electric Field Induced Changes In Dielectric Properties Of Biological Cells, Jie Zhuang Apr 2012

Nonosecond Pulsed Electric Field Induced Changes In Dielectric Properties Of Biological Cells, Jie Zhuang

Electrical & Computer Engineering Theses & Dissertations

Nanosecond pulsed electric field induced biological effects have been a focus of research interests since the new millennium. Promising biomedical applications, e.g. tumor treatment and wound healing, are emerging based on this principle. Although the exact mechanisms behind the nanosecond pulse-cell interactions are not completely understood yet, it is generally believed that charging along the cell membranes (including intracellular membranes) and formation of membrane pores trigger subsequent biological responses, and the number and quality of pores are responsible for the cell fate. The immediate charging response of a biological cell to a nanosecond pulsed electric field exposure relies on the …


Probabilistic Model For Laser Damage To The Human Retina, David A. Wooddell Jr. Mar 2012

Probabilistic Model For Laser Damage To The Human Retina, David A. Wooddell Jr.

Theses and Dissertations

Understanding how lasers interact with media during propagation is a premiere field of physics. The subject area known as laser bioeffects explores laser interactions with biological cells, tissues, organs, and bodies. This research includes laser applications used in medicine, establishes safe exposure limits for industry and academia, and generally studies the many effects of laser light on living creatures. The bioeffects community relies heavily on deterministic modeling and simulation tools to support experimental research into damage thresholds and laser effects. However, recent laser applications require a probabilistic approach to support risk management and analyses methodologies. Some probabilistic models exist, but …


Session 1c, Kentucky Water Resources Research Institute, University Of Kentucky Mar 2012

Session 1c, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

  • The Effects of Prescribed Fire on Amphibian and Reptile Diversity in an Oak-Grassland Restoration Area, Robert Knopp and Howard Whiteman, Dept Biological Sciences and Watershed Studies, Murray State University
  • Results of a Data Evaluation to Establish Priority Remediation Areas for Dry Weather Fecal Contamination in a Karst Influenced Watershed, Steve Evans and others, Third Rock Consultants, Lexington, KY
  • Development of In-House Methods for High-Throughput DNA Extraction, Kimberly L. Cook and LorraBelle Hill, USDA-ARS, Bowling Green, KY
  • Validation of the Sanitary Category Value Model (SCV) for the Identification of Leaking Sewer Lines: A Study of the West Hickman …


Proceedings Of 2012 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky Mar 2012

Proceedings Of 2012 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

This symposium was planned and conducted as a part of the state water resources research institute annual program that is supported by Grant/Cooperative Agreement Number G11AP20081 from the United States Geological Survey. The contents of this proceedings document and the views and conclusions presented at the symposium are solely the responsibility of the individual authors and presenters and do not necessarily represent the official views of the USGS or of the symposium organizers and sponsors. This publication is produced with the understanding that the United States Government is authorized to reproduce and distribute reprints for government purposes.


March 2012 Academic Affairs Minutes, University Of Nebraska At Kearney Academic Affairs Committee Mar 2012

March 2012 Academic Affairs Minutes, University Of Nebraska At Kearney Academic Affairs Committee

Academic Affairs Committee Minutes

No abstract provided.


Daily Eastern News: March 09, 2012, Eastern Illinois University Mar 2012

Daily Eastern News: March 09, 2012, Eastern Illinois University

March

No abstract provided.


Multiscale Feature Analysis Of Salivary Gland Branching Morphogenesis, Melinda Larsen, William P. Daley, Shayoni Ray, Cemal Cagatay Bilgin, Banu Baydil, Bulent Yener Mar 2012

Multiscale Feature Analysis Of Salivary Gland Branching Morphogenesis, Melinda Larsen, William P. Daley, Shayoni Ray, Cemal Cagatay Bilgin, Banu Baydil, Bulent Yener

Biological Sciences Faculty Scholarship

Pattern formation in developing tissues involves dynamic spatio-temporal changes in cellular organization and subsequent evolution of functional adult structures. Branching morphogenesis is a developmental mechanism by which patterns are generated in many developing organs, which is controlled by underlying molecular pathways. Understanding the relationship between molecular signaling, cellular behavior and resulting morphological change requires quantification and categorization of the cellular behavior. In this study, tissue-level and cellular changes in developing salivary gland in response to disruption of ROCK-mediated signaling by are modeled by building cell-graphs to compute mathematical features capturing structural properties at multiple scales. These features were used to …


Proceedings Of The 39th Annual Meeting, Southern Soybean Disease Workers (March 7-8, 2012, Pensacola Beach, Florida), Tom Allen, Boyd Padgett, Danise Beadle, Stephen R. Koenning Mar 2012

Proceedings Of The 39th Annual Meeting, Southern Soybean Disease Workers (March 7-8, 2012, Pensacola Beach, Florida), Tom Allen, Boyd Padgett, Danise Beadle, Stephen R. Koenning

Southern Soybean Disease Workers: Conference Proceedings

Contents

Symposium: Soybean Nematodes: Their Status, Impact and Management

The Current Status of Nematodes of Soybean in Louisiana and Arkansas. Charles Overstreet, Edward C McGawley, Melea Martin, and Terry Kirkpatrick

A Molecular Analysis of Resistance of Soybean to the Soybean Cyst Nematode. Vincent Klink

Racism in Nematology. Terry Niblack

SCN-resistant Soybeans, HG types, Yield, and SCN Reproduction: How It All Comes Together in the Field in Iowa. Gregory Tylka

Soybean Lines Evaluated for Resistance to Reniform Nematode. Sally Stetina

Graduate student presentations (Boyd Padgett, moderator)

Fungicide Resistance in Cercospora kikuchii, a Major Pathogen of Louisiana Soybean. Trey Price

Variation …


Inactivation Of Androgen-Induced Regulator Ard1 Inhibits Androgen Receptor Acetylation And Prostate Tumorigenesis, Zehua Wang, Zemin Wang, Jianhui Guo, Yingchun Li, Jasmin H. Bavarva, Chiping Qian, M. Christiane Brahimi-Horn, Deyong Tan, Wanguo Liu Feb 2012

Inactivation Of Androgen-Induced Regulator Ard1 Inhibits Androgen Receptor Acetylation And Prostate Tumorigenesis, Zehua Wang, Zemin Wang, Jianhui Guo, Yingchun Li, Jasmin H. Bavarva, Chiping Qian, M. Christiane Brahimi-Horn, Deyong Tan, Wanguo Liu

Faculty Publications

Androgen signaling through androgen receptor (AR) is critical for prostate tumorigenesis. Given that AR-mediated gene regulation is enhanced by AR coregulators, inactivation of those coregulators is emerging as a promising therapy for prostate cancer (PCa). Here, weshowthat the N-acetyltransferase arrest-defect 1 protein (ARD1) functions as a unique AR regulator in PCa cells. ARD1 is up-regulated in human PCa cell lines and primary tumor biopsies. The expression of ARD1 was augmented by treatment with synthetic androgen (R1881) unless AR is deficient or is inhibited by AR-specific siRNA or androgen inhibitor bicalutamide (Casodex). Depletion of ARD1 by shRNA suppressed PCa cell proliferation, …


Daily Eastern News: February 16, 2012, Eastern Illinois University Feb 2012

Daily Eastern News: February 16, 2012, Eastern Illinois University

February

No abstract provided.


Slow Amyloid Nucleation Via Α-Helix-Rich Oligomeric Intermediates In Short Polyglutamine-Containing Huntingtin Fragments, Murali Jayaraman, Ravindra Kodali, Bankanidhi Sahoo, Ashwani K. Thakur, Anand Mayasundari, Rakesh Mishra, Cynthia B. Peterson, Ronald Wetzel Feb 2012

Slow Amyloid Nucleation Via Α-Helix-Rich Oligomeric Intermediates In Short Polyglutamine-Containing Huntingtin Fragments, Murali Jayaraman, Ravindra Kodali, Bankanidhi Sahoo, Ashwani K. Thakur, Anand Mayasundari, Rakesh Mishra, Cynthia B. Peterson, Ronald Wetzel

Faculty Publications

The 17-amino-acid N-terminal segment (httNT) that leads into the polyglutamine (polyQ) segment in the Huntington's disease protein huntingtin (htt) dramatically increases aggregation rates and changes the aggregation mechanism, compared to a simple polyQ peptide of similar length. With polyQ segments near or above the pathological repeat length threshold of about 37, aggregation of htt N-terminal fragments is so rapid that it is difficult to tease out mechanistic details. We describe here the use of very short polyQ repeat lengths in htt N-terminal fragments to slow this disease-associated aggregation. Although all of these peptides, in addition to httNT itself, form α-helix-rich …


Dobzhansky's Dictum: An Object Lesson For Critical Thinking, William D. Stansfield Feb 2012

Dobzhansky's Dictum: An Object Lesson For Critical Thinking, William D. Stansfield

Biological Sciences

A creationist has called Dobzhansky's dictum a myth. Discussion of this debate could be used as an object lesson for critical thinking.


Cave Research Foundation Quarterly, Volume 40, No. 1, February 2012, Laura Lexander Feb 2012

Cave Research Foundation Quarterly, Volume 40, No. 1, February 2012, Laura Lexander

KIP Articles

Contents: Donkey-Mammoth Cave Connection: Eleventh Cave Joins the Longest Cave, May 28, 2011 / Roger W. Burcker -- Ave Atque Vale / Scott House -- From the President: / Charles Fox -- Regional Expedition Reports -- 2012 Expedition Calendar


Synthesis, Characterisation, And Preliminary In Vitro Studies Of Vanadium(Iv) Complexes With A Schiff Base And Thiosemicarbazones As Mixed Ligands, Nerissa A. Lewis, Fange Liu, Luke Seymour, Anthony Magnusen, Travis R. Erves, Jessa Faye Arca, Floyd A. Beckford, Ramaiyer Venkatraman, Antonio González-Sarrías, Frank R. Fronczek, Don G. Vanderveer, Navindra P. Seeram, Aimin Liu, William L. Jarrett, Alvin A. Holder Feb 2012

Synthesis, Characterisation, And Preliminary In Vitro Studies Of Vanadium(Iv) Complexes With A Schiff Base And Thiosemicarbazones As Mixed Ligands, Nerissa A. Lewis, Fange Liu, Luke Seymour, Anthony Magnusen, Travis R. Erves, Jessa Faye Arca, Floyd A. Beckford, Ramaiyer Venkatraman, Antonio González-Sarrías, Frank R. Fronczek, Don G. Vanderveer, Navindra P. Seeram, Aimin Liu, William L. Jarrett, Alvin A. Holder

Faculty Publications

[VO(sal‐L‐tryp)(H2O)] (1, sal‐L‐tryp = N‐salicylidene‐L‐tryptophanate) was used as a precursor to produce the new complexes [VO(sal‐L‐tryp)(MeATSC)]·1.5C2H5OH [2, MeATSC = 9‐Anthraldehyde‐N(4)‐methylthiosemicarbazone], [VO(sal‐L‐tryp)(N‐ethhymethohcarbthio)]·H2O [3, N‐ethhymethohcarbthio = (E)‐N‐ethyl‐2‐(4‐hydroxy‐3‐methoxybenzylidene)hydrazinecarbothioamide] and [VO(sal‐L‐tryp)(acetylethTSC)]·C2H5OH {4, acetylethTSC = (E)‐N‐ethyl‐2‐[1‐(thiazol‐2‐yl)ethylidene]hydrazinecarbothioamide} by reaction with the respective thiosemicarbazone. The chemical and structural properties of these ligands and complexes were characterised by elemental analysis, ESI‐MS, FTIR, UV/Vis, ESR and 1H and …


The Evaluation Of Erk1 Dimerization Models Using Fluorescence Correlation Spectroscopy And The Development Of Analysis Algorithms For Single-Molecule Super Resolution, Fang Huang Feb 2012

The Evaluation Of Erk1 Dimerization Models Using Fluorescence Correlation Spectroscopy And The Development Of Analysis Algorithms For Single-Molecule Super Resolution, Fang Huang

Physics & Astronomy ETDs

In this dissertation, we describe three advancements in the area of fluorescence spectroscopy and microscopy. First, we have implemented Fluorescence Correlation Spectroscopy on a home-built confocal microscope. We proposed F/N analysis which stands for the ratio between average intensity and average number of moving objects in FCS as a method to detect dimerization of fluorescently tagged proteins diffusing in three dimensions. We used the technique to evaluate the dimerization hypothesis of ERK1 protein during nucleus translocation and it shows that ERK1 nucleus translocation is dimerization independent. Second, we have developed a multi-emitter analysis algorithm for single-molecule super resolution techniques that …


Biomechanics, Brooke A. Slavens, Gerald F. Harris Feb 2012

Biomechanics, Brooke A. Slavens, Gerald F. Harris

Biomedical Engineering Faculty Research and Publications

Biomechanics is a vast discipline within the field of Biomedical Engineering. It explores the underlying mechanics of how biological and physiological systems move. It encompasses important clinical applications to address questions related to medicine using engineering mechanics principles. Biomechanics includes interdisciplinary concepts from engineers, physicians, therapists, biologists, physicists, and mathematicians. Through their collaborative efforts, biomechanics research is ever changing and expanding, explaining new mechanisms and principles for dynamic human systems. Biomechanics is used to describe how the human body moves, walks, and breathes, in addition to how it responds to injury and rehabilitation. Advanced biomechanical modeling methods, such as inverse …


The Role Of Mitochondrial Dysfunction In Neurodegenerative Proteinopathies And Aging., Alejandro Ocampo Jan 2012

The Role Of Mitochondrial Dysfunction In Neurodegenerative Proteinopathies And Aging., Alejandro Ocampo

Open Access Dissertations

Age-related neurodegenerative proteinophaties, including polyglutamine (polyQ) diseases such as Huntington’s disease, are a group of disorders in which a single protein or a set of proteins misfold and aggregate resulting in a progressive and selective loss of anatomically or physiologically related neuronal systems. Despite evidence showing a clear relationship between mitochondrial dysfunction, aging and neurodegenerative proteinophaties, the extent of the mitochondrial respiratory chain deficits, the involvement of mitochondrial dysfunction and the mechanisms responsible for these processes are largely unknown. Using yeast models of cellular aging and polyQ disorders we show that mitochondrial dysfunction is an important contributor to the process …


Transcriptome-Based Differentiation Of Closely-Related Miscanthus Lines, Philippe Chouvarine, Shane C. Burgess, Daniel G. Peterson Jan 2012

Transcriptome-Based Differentiation Of Closely-Related Miscanthus Lines, Philippe Chouvarine, Shane C. Burgess, Daniel G. Peterson

CVM Publications

No abstract provided.


Design, Synthesis, And In Vitro And In Vivo Biological Studies Of A 3′-Deoxythymidine Conjugate That Potentially Kills Cancer Cells Selectively, Qiong Wei, Dejun Zhang, Anna Yao, Liyi Mai, Zhiwei Zhang, Qibing Zhou Jan 2012

Design, Synthesis, And In Vitro And In Vivo Biological Studies Of A 3′-Deoxythymidine Conjugate That Potentially Kills Cancer Cells Selectively, Qiong Wei, Dejun Zhang, Anna Yao, Liyi Mai, Zhiwei Zhang, Qibing Zhou

Medicinal Chemistry Publications

Thymidine kinases (TKs) have been considered one of the potential targets for anticancer therapeutic because of their elevated expressions in cancer cells. However, nucleobase analogs targeting TKs have shown poor selective cytotoxicity in cancer cells despite effective antiviral activity. 3′-Deoxythymidine phenylquinoxaline conjugate (dT-QX) was designed as a novel nucleobase analog to target TKs in cancer cells and block cell replication via conjugated DNA intercalating quinoxaline moiety. In vitro cell screening showed that dT-QX selectively kills a variety of cancer cells including liver carcinoma, breast adenocarcinoma and brain glioma cells; whereas it had a low cytotoxicity in normal cells such as …


Augmenter Of Liver Regeneration (Alr) Promotes Liver Outgrowth During Zebrafish Hepatogenesis, Yan Li, Muhammad Farooq, Donglai Sheng, Chanchal Chandramouli, Tian Lan, Nilesh K. Mahajan, R. Manjunatha Kini, Yunhan Hong, Thomas Lisowsky, Ruowen Ge Jan 2012

Augmenter Of Liver Regeneration (Alr) Promotes Liver Outgrowth During Zebrafish Hepatogenesis, Yan Li, Muhammad Farooq, Donglai Sheng, Chanchal Chandramouli, Tian Lan, Nilesh K. Mahajan, R. Manjunatha Kini, Yunhan Hong, Thomas Lisowsky, Ruowen Ge

Biochemistry and Molecular Biology Publications

Augmenter of Liver Regeneration (ALR) is a sulfhydryl oxidase carrying out fundamental functions facilitating protein disulfide bond formation. In mammals, it also functions as a hepatotrophic growth factor that specifically stimulates hepatocyte proliferation and promotes liver regeneration after liver damage or partial hepatectomy. Whether ALR also plays a role during vertebrate hepatogenesis is unknown. In this work, we investigated the function of alr in liver organogenesis in zebrafish model. We showed that alr is expressed in liver throughout hepatogenesis. Knockdown of alr through morpholino antisense oligonucleotide (MO) leads to suppression of liver outgrowth while overexpression of alr promotes liver growth. …


Epigenetics And Obesity: A Multi-Disciplinary Approach To Research And Treatment, Constance A. Ohlinger Jan 2012

Epigenetics And Obesity: A Multi-Disciplinary Approach To Research And Treatment, Constance A. Ohlinger

Honors Thesis Collection

Epigenetics is an up and coming field that investigates heritable changes in gene expression that are a result of our environment and, in many cases, our lifestyle and culture. In an effort to look at the current obesity epidemic from multiple disciplines, this thesis encompassed both a biological and an anthropological study. The biological aim was to investigate a possible correlation between lifestyle and the expression of genes related to obesity. The anthropological aim was to investigate mechanisms of lifestyle change and social understandings of epigenetic phenomena. The project resulted in a refined protocol for future multi-disciplinary research into obesity …


Pseudo-Diel Vertical Migration In Zooplankton: A Whole-Lake 15N Tracer Experiment, Xavier Armengol, Wayne A. Wurtsbaugh, Antonio Camacho, Maria R. Miracle Jan 2012

Pseudo-Diel Vertical Migration In Zooplankton: A Whole-Lake 15N Tracer Experiment, Xavier Armengol, Wayne A. Wurtsbaugh, Antonio Camacho, Maria R. Miracle

Watershed Sciences Faculty Publications

Diel vertical migration (DVM) of zooplankton is commonly considered an adaptation for feeding in food-rich and warm surface waters at night and avoiding visual predators during the day. However, the critical assessment of migration patterns frequently suggests that: (i) zooplankton may leave deeper waters with rich, deep-chlorophyll layers and move into the epilimnion where food resources are lower and/or (ii) the night-time increase in epilimnetic plankton abundance is not matched by a density decrease in deeper strata. To study these discrepancies, we measured DVM of zooplankton in a 1.3-ha Spanish karst lake (Laguna del Tejo) where the phytoplankton in the …


7th Susquehanna River Symposium Program, Bucknell Center For Sustainability And The Environment Jan 2012

7th Susquehanna River Symposium Program, Bucknell Center For Sustainability And The Environment

Susquehanna River Symposium -- Conference materials

No abstract provided.


Cellular Analysis Of Hepg2 Cells On Gastrin Releasing Peptide (Grp) Nanostructure, Karshak Kosaraju Jan 2012

Cellular Analysis Of Hepg2 Cells On Gastrin Releasing Peptide (Grp) Nanostructure, Karshak Kosaraju

Theses

Artificial juxtacrine stimulation arises from the covalent attachment of growth factors onto biomaterials. Incorporation of growth factors onto cell culture substrates has been found to enhance the functionality of cells in vitro. In this study, we describe how the immobilization of Gastrin Releasing Peptide (GRP) enhances the viability of hepatocarcinoma cell line, HepG2 up to 4 days. The biomaterial for immobilization of GRP was prepared using indium tin oxide (ITO) sputtered on polyethylene terephthalate (PET). A self-assembled monolayer (SAM) of 3-aminopropyl triethoxysilane (3-APTES) on ITO was covalently attached to GRP. Characterization of the substrates before and after immobilization of GRP …


Coordination Studies Of Copper(Ii), Cobalt(Ii) And Iron(Ii) With Isomeric Pyridyl-Tetrazole Ligands, Fintan Kelleher, Andrew Bond, Adrienne Fleming, Jackie Gaire, John Mcginley, Vickie Mckee, Ursula Sheridan Jan 2012

Coordination Studies Of Copper(Ii), Cobalt(Ii) And Iron(Ii) With Isomeric Pyridyl-Tetrazole Ligands, Fintan Kelleher, Andrew Bond, Adrienne Fleming, Jackie Gaire, John Mcginley, Vickie Mckee, Ursula Sheridan

Articles

The reaction of 2-(2H-tetrazol-5-yl)pyridine (L1) with 1,6-dibromohexane results in formation of the isomers 2-(6′′-bromohexyl-(1-tetrazol-5-yl)pyridine (L2) and 2-(6′′-bromohexyl-(2-tetrazol-5-yl)pyridine (L3). Coordination reactions of L2 and L3 with CuCl2·2H2O, Co(SCN)2 and Fe(ClO4)2·H2O yielded the strongly coloured solids [Cu(II)(L2)Cl2]2 (1), [Cu(II)(L3)Cl2]2 (2), [Co(II)(L2)2(NCS)2] (3), [Co(II)(L3)2(NCS)2] (4), [Fe(II)(L2)2(H2O)2](ClO4) …