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Articles 101761 - 101790 of 103581
Full-Text Articles in Entire DC Network
A Shortened Synthesis Of Optically Pure Tricarbonyl[Methyl (2e,4e)-6-Oxo-2,4-Hexadienoate]Iron Leading To Improved Yield, Rajesh K. Pandey, Sergey V. Lindeman, William A. Donaldson
A Shortened Synthesis Of Optically Pure Tricarbonyl[Methyl (2e,4e)-6-Oxo-2,4-Hexadienoate]Iron Leading To Improved Yield, Rajesh K. Pandey, Sergey V. Lindeman, William A. Donaldson
Chemistry Faculty Research and Publications
The (+)- and (–)-enantiomers of tricarbonyl[methyl (2E,4E)-6-oxo-2,4-hexadienoate]iron are prepared in 4 steps from commercially available hexadienal (26% and 25% yields, respectively).
Anion Exchange Kinetics Of Nanodimensional Layered Metal Hydroxides: Use Of Isoconversional Analysis, Stephen Majoni, Jeanne Hossenlopp
Anion Exchange Kinetics Of Nanodimensional Layered Metal Hydroxides: Use Of Isoconversional Analysis, Stephen Majoni, Jeanne Hossenlopp
Chemistry Faculty Research and Publications
Anion exchange reactions of nanodimensional layered metal hydroxide compounds are utilized to create materials with targeted physical and chemical properties and also as a means for controlled release of intercalated anions. The kinetics of this important class of reaction are generally characterized by model-based approaches. In this work, a different approach based on isothermal, isoconversional analysis was utilized to determine effective activation energies with respect to extent of reaction. Two different layered metal hydroxide materials were chosen for reaction with chloride anions, using a temperature range of 30−60 °C. The concentrations of anions released into solution and the changes in …
Immobilization Of The Aminopeptidase From Aeromonas Proteolytica On Mg2+/Al3+ Layered Double Hydroxide Particles, Steven T. Frey, Stephanie L. Guilmet, Richard G. Egan Iii, Alyssa Bennett, Sarah R. Soltau, Richard C. Holz
Immobilization Of The Aminopeptidase From Aeromonas Proteolytica On Mg2+/Al3+ Layered Double Hydroxide Particles, Steven T. Frey, Stephanie L. Guilmet, Richard G. Egan Iii, Alyssa Bennett, Sarah R. Soltau, Richard C. Holz
Chemistry Faculty Research and Publications
A novel biomaterial formed by the immobilization of the Aminopeptidase from Aeromonas proteolytica (AAP) on synthetic Mg2+ and Al3+ ion-containing layered double hydroxide (LDH) particles was prepared. Immobilization of AAP on the LDH particles in a buffered, aqueous mixture is rapid such that the maximum loading capacity, 1 × 10−9 moles of AAP/mg LDH, is achieved in a few minutes. X-ray powder diffraction of LDH samples before and after treatment with AAP indicates that the enzyme does not intercalate between the layers of LDH, but instead binds to the surface. Treatment of AAP/LDH with various amounts of …
Immobilization Of Motile Bacterial Cells Via Dip-Pen Nanolithography, Dorjderem Nyamjav, Sergey Rozhok, Richard C. Holz
Immobilization Of Motile Bacterial Cells Via Dip-Pen Nanolithography, Dorjderem Nyamjav, Sergey Rozhok, Richard C. Holz
Chemistry Faculty Research and Publications
A strategy to bind bacterial cells to surfaces in a directed fashion via dip-pen nanolithography (DPN) is presented. Cellular attachment to pre-designed DPN generated microarrays was found to be dependent on the shape and size of the surface feature. While this observation is likely due in part to a dense, well formed mercaptohexadecanoic acid (MHA) monolayer generated via DPN, it may also simply be due to the physical shape of the surface structure. Motile Pseudomonas aeruginosa bacterial cells were observed to bind to DPN generated mercaptohexadecanoic acid/poly-L-lysine (MHA/PLL) line patterns, 'blocks' made up of eight lines with 100 nm spacings, …
Affinity Capillary Electrophoretic Study Of K+/Na+ Selectivity Of Hexaarylbenzene-Based Polyaromatic Receptor, Sille Ehala, Rajendra Rathore, Emanuel Makrlik, Petr Toman, Václav Kašička
Affinity Capillary Electrophoretic Study Of K+/Na+ Selectivity Of Hexaarylbenzene-Based Polyaromatic Receptor, Sille Ehala, Rajendra Rathore, Emanuel Makrlik, Petr Toman, Václav Kašička
Chemistry Faculty Research and Publications
Affinity capillary electrophoretic (ACE) study has proved the selectivity of hexaarylbenzene-based polyaromatic receptor (R) for K+ ion over Na+ ion. The apparent binding constants of the R complexes with K+ and Na+ ions were determined from the dependence of effective electrophoretic mobility of R on the concentration of the above alkali metal ions in the background electrolyte using a non-linear regression analysis. The apparent binding constants (Kb) of the K-R+ and Na–R+ complexes in methanolic medium were evaluated as log Kb = 3.20 ± 0.22 for the K–R+ complex, and log Kb≅−0.7 for the Na–R+ complex.
Balancing Of Markets, Litigation And Regulation, Keith N. Hylton, Larry E. Ribstein, Paul H. Rubin, Todd J. Zywicki
Balancing Of Markets, Litigation And Regulation, Keith N. Hylton, Larry E. Ribstein, Paul H. Rubin, Todd J. Zywicki
Faculty Scholarship
In addition to judicial education programs that the Law and Economics Center conducts, we also have a division that focuses on public policy research, known as the Searle Civil Justice Institute. In November, we held a public policy roundtable where we commissioned a variety of research and brought together a group of experts, both academic and practitioner experts, to discuss the issue of balancing the appropriate roles of markets, litigation, and regulation. And the notion there is that each one - markets, litigation, and regulation - can and probably should play a role in addressing various consumer harms.
Breaking The Cycle: Impact Of Sterically-Tailored Tetra(Pyrazolyl)Lutidines On The Self-Assembly Of Silver(I) Complexes, Tyler James Morin, Andrew Merkel, Sergey V. Lindeman, James R. Gardinier
Breaking The Cycle: Impact Of Sterically-Tailored Tetra(Pyrazolyl)Lutidines On The Self-Assembly Of Silver(I) Complexes, Tyler James Morin, Andrew Merkel, Sergey V. Lindeman, James R. Gardinier
Chemistry Faculty Research and Publications
A improved preparation of the pentadentate ligand α,α,α′,α′-tetra(pyrazolyl)lutidine, pz4lut, and the syntheses of three new alkyl-substituted pyrazolyl derivatives pz4′4lut (pz4′ = 4-methylpyrazolyl), pz*4lut (pz* = 3,5-dimethylpyrazolyl), and pzDIP4lut (pzDIP = 3,5-diisopropylpyrazolyl) are described. The silver(I) complexes of these ligands were studied to ascertain the impact of pyrazolyl substitution, if any, on their binding modes and on solubility issues. In the solid state, [Ag(pz4lut)](BF4) (1), [Ag(pz4′4lut)](BF4) (2), and [Ag(pz*4lut)](BF4) (3 …
Revolution In Pragmatist Clothing: Nationalizing Workplace Law, Jeffrey M. Hirsch
Revolution In Pragmatist Clothing: Nationalizing Workplace Law, Jeffrey M. Hirsch
Faculty Publications
No abstract provided.
Managing Medical Bills On The Brink Of Bankruptcy, Melissa B. Jacoby, Mirya Holman
Managing Medical Bills On The Brink Of Bankruptcy, Melissa B. Jacoby, Mirya Holman
Faculty Publications
No abstract provided.
Procedures For Public Law Remediation In School-To-Prison Pipeline Litigation: Lessons Learned From Antoine V. Winner School District, Catherine Y. Kim
Procedures For Public Law Remediation In School-To-Prison Pipeline Litigation: Lessons Learned From Antoine V. Winner School District, Catherine Y. Kim
Faculty Publications
No abstract provided.
Twenty-Five Years Of Health Law Through The Lens Of The Civil False Claims Act, Joan H. Krause
Twenty-Five Years Of Health Law Through The Lens Of The Civil False Claims Act, Joan H. Krause
Faculty Publications
No abstract provided.
Protecting The Innocent: Part Of The Solution For Inadequate Funding For Defenders, Not A Panacea For Targeting Justice, Robert P. Mosteller
Protecting The Innocent: Part Of The Solution For Inadequate Funding For Defenders, Not A Panacea For Targeting Justice, Robert P. Mosteller
Faculty Publications
No abstract provided.
Why Defense Attorneys Cannot, But Do, Care About Innocence, Robert P. Mosteller
Why Defense Attorneys Cannot, But Do, Care About Innocence, Robert P. Mosteller
Faculty Publications
No abstract provided.
Toward A Theory Of Precedent In Arbitration, W. Mark C. Weidemaier
Toward A Theory Of Precedent In Arbitration, W. Mark C. Weidemaier
Faculty Publications
No abstract provided.
Judicial Abdication And Equal Access To The Civil Justice System, Gene R. Nichol Jr.
Judicial Abdication And Equal Access To The Civil Justice System, Gene R. Nichol Jr.
Faculty Publications
No abstract provided.
The Golden Metwand': The Measure Of Justice In Shakespeare's Measure For Measure, John V. Orth
The Golden Metwand': The Measure Of Justice In Shakespeare's Measure For Measure, John V. Orth
Faculty Publications
No abstract provided.
Dog Wags Tail: The Continuing Viability Of Minority-Targeted Aid In Higher Education, Osamudia James
Dog Wags Tail: The Continuing Viability Of Minority-Targeted Aid In Higher Education, Osamudia James
Faculty Publications
No abstract provided.
Government Speech And Online Forums: First Amendment Limitations On Facilitating And Moderating Public Discourse On Government Websites,, David S. Ardia
Government Speech And Online Forums: First Amendment Limitations On Facilitating And Moderating Public Discourse On Government Websites,, David S. Ardia
Faculty Publications
No abstract provided.
The Consequence Of Human Differences, Jospeh Vining
The Consequence Of Human Differences, Jospeh Vining
Articles
This essay explores the ways in which the recognition of individual and person in the legal form of thought distinguishes it from forms of thought in evolutionary biology and mathematics that are put forward as means to a complete picture of the world. The essay observes that the legal form of thought is in fact deeply involved in our modern understanding of Nature itself.
Red Algae Lose Key Mitochondrial Genes In Response To Becoming Parasitic, Lillian Hancock, Lynda Goff, Christopher E. Lane
Red Algae Lose Key Mitochondrial Genes In Response To Becoming Parasitic, Lillian Hancock, Lynda Goff, Christopher E. Lane
Biological Sciences Faculty Publications
Red algal parasites are unusual because the vast majority of them parasitize species with which they share a recent common ancestor. This strategy has earned them the name “adelphoparasites,” from the Greek, adelpho, meaning “kin.” Intracellular adelphoparasites are very rare in nature, yet have independently evolved hundreds of times among the floridiophyte red algae. Much is known about the life history and infection cycle of these parasites but nearly nothing in known about their genomes. We sequenced the mitochondrial genomes of the free-living Gracilariopsis andersonii and its closely related parasite Gracilariophila oryzoides to determine what effect a parasitic lifestyle has …
Shark Scavenging Behavior In The Presence Of Competition, Shannon P. Gerry, Andrea J. Scott
Shark Scavenging Behavior In The Presence Of Competition, Shannon P. Gerry, Andrea J. Scott
Biological Sciences Faculty Publications
The distribution of organisms within a community can often be determined by the degree of plasticity or degree of specialization of resource acquisition. Resource acquisition is often based on the morphology of an organism, behavior, or a combination of both. Performance tests of feeding can identify the possible interactions that allow one species to better exploit a prey item. Scavenging behaviors in the presence or absence of a competitor were investigated by quantifying prey selection in a trophic generalist, spiny dogfish Squalus acanthias, and a trophic specialist, smooth-hounds Mustelus canis, in order to determine if each shark scavenged …
2010 A Spotlight On San Diego's Third Sector, Melanie Hitchcock, Laura Deitrick
2010 A Spotlight On San Diego's Third Sector, Melanie Hitchcock, Laura Deitrick
State of Nonprofits and Philanthropy in San Diego
What is the economic impact of San Diego's nonprofit sector and what role does it play in the region's larger economy? How is San Diego's nonprofit sector unique? How confident are people in San Diego's nonprofit organizations? Read our latest report on the state of San Diego's nonprofit sector.
Operating In Uncertain Times: How Economic Conditions Have Affected San Diego County's Nonprofit And Philanthropic Sectors, Laura Deitrick, Lindsey Mcdougle, Taylor Peyton Roberts
Operating In Uncertain Times: How Economic Conditions Have Affected San Diego County's Nonprofit And Philanthropic Sectors, Laura Deitrick, Lindsey Mcdougle, Taylor Peyton Roberts
State of Nonprofits and Philanthropy in San Diego
How have San Diego County's nonprofit and philanthropic organizations been managing during the economic downturn? This report: Operating in Uncertain Times, highlights the strategies and approaches taken by some of the County's largest nonprofit and philanthropic providers.
If I Had A Hammer: Can Shepardizing, Synthesis, And Other Tools Of Legal Writing Help Build Hope For Law Students?, Edward R. Becker
If I Had A Hammer: Can Shepardizing, Synthesis, And Other Tools Of Legal Writing Help Build Hope For Law Students?, Edward R. Becker
Articles
Are lawyers mechanics? In 1920, photographer Lewis Hines took a striking photo of a powerhouse mechanic sure-handedly wielding a large wrench to tighten bolts on a steam pump. This picture may bring to mind many things, but I suspect that many legal writing professors in our (past or present) incarnations as practicing attorneys would not look at this image and think, "My job is a lot like that." Similarly, I assume that many of our students do not think of a lawyer's role in this way. Indeed, many of our students might have chosen to pursue a career in law …
Presentation: Operating In Uncertain Times: How Economic Conditions Have Affected San Diego County's Nonprofit And Philanthropic Sectors, Laura Deitrick, Lindsey Mcdougle, Taylor Peyton Roberts
Presentation: Operating In Uncertain Times: How Economic Conditions Have Affected San Diego County's Nonprofit And Philanthropic Sectors, Laura Deitrick, Lindsey Mcdougle, Taylor Peyton Roberts
State of Nonprofits and Philanthropy in San Diego
How have San Diego County's nonprofit and philanthropic organizations been managing during the economic downturn? This report presentation: Operating in Uncertain Times, highlights the strategies and approaches taken by some of the County's largest nonprofit and philanthropic providers.
The Copyright Principles Project: Directions For Reform, Jessica D. Litman, Pamela Samuelson, The Copyright Principles Project
The Copyright Principles Project: Directions For Reform, Jessica D. Litman, Pamela Samuelson, The Copyright Principles Project
Articles
Copyright law performs a number of important functions. It facilitates public access to knowledge and a wide range of uses of creative works of authorship, and, in so doing, it helps educate our populace, enrich our culture, and promote free speech, free expression, and democratic values. It provides opportunities for rights holders to recoup investments in creating and disseminating their works and to enjoy the fruits of whatever success arises from the public's uses of their works. In the process, copyright also plays a role in regulating new technologies and services through which creative works may be accessed. A well-functioning …
The Last Best Hope For Progressivity In Tax, E. J. Mccaffery, James R. Hines Jr.
The Last Best Hope For Progressivity In Tax, E. J. Mccaffery, James R. Hines Jr.
Articles
We argue that a spending tax, as opposed to an income or wage tax, is the “last best hope” for a return to significantly more progressive marginal tax rates than obtain today. The simple explanation for this central claim looks to incentive effects, especially for “rich people,” as both economists and commentators are inclined to focus. High marginal tax rates under an income tax fall on and hence deter the socially productive activities of work and savings. High marginal rates under a wage tax fall on and hence deter the socially productive activity of work alone. But high marginal rates …
Attorneys As Arbitrators, Adam C. Pritchard, Stephen J. Choi, Jill E. Fisch
Attorneys As Arbitrators, Adam C. Pritchard, Stephen J. Choi, Jill E. Fisch
Articles
We study the role of attorneys as arbitrators in securities arbitration. We find that arbitrators who also represent brokerage firms or brokers in other arbitrations award significantly less compensation to investor-claimants than do other arbitrators. We find no significant effect for attorney-arbitrators who represent investors or both investors and brokerage firms. The relation between representing brokerage firms and arbitration awards remains significant even when we control for political outlook. Arbitrators who donate money to Democratic political candidates award greater compensation than do arbitrators who donate to Republican can-didates. We also study the dynamics of panel interaction. We find that the …
Redesigning The St. Louis Journalism Review: A New Media Task In Web And Critique, Diana K. Soliwon
Redesigning The St. Louis Journalism Review: A New Media Task In Web And Critique, Diana K. Soliwon
Research Papers
The present project took root when the St. Louis Journalism Review (SJR) agreed to give its rights and publication to the School of Journalism at Southern Illinois University Carbondale. The work began before the July 1, 2010 transfer date and as homage to the collaborative nature of web development and journalism, will continue after this degree. At hand was a new media task: with creative freedom, redesign the SJR’s website to fit the parameters of the new management, with considerations for the challenged journalism industry, its principles, workflow, the guidelines of web development and visual communication, and a budget. The …
Reply To Richard A. Leo And Jon B. Gould, Samuel R. Gross, Barbara O'Brien
Reply To Richard A. Leo And Jon B. Gould, Samuel R. Gross, Barbara O'Brien
Articles
The following is a letter to the Ohio State Journal of Criminal Law received from Professors Samuel Gross and Barbara O'Brien, responding to an article published in the Journal in Fall 2009 by Professors Richard Leo and Jon Gould. This letter is followed by a reply from Professors Leo and Gould. Professors Gross and O'Brien did not see the reply prior to the Journal going to press. As we have indicated before, we welcome letters to the Journal from readers on any topic covered in a prior issue. - Editors