Digital Commons Network^™

Synthesis And Optical Properties Of Silver Nanostructures, John Heckel

All Dissertations

Silver nanoparticles interact with light via the excitation of plasmon resonances that are the collective oscillations of the free electron density. This excitation represents the most efficient mechanism for the interaction of light with matter and therefore the nanoparticles are of great interest for both fundamental and practical points of view. In the following dissertation, silver nanoparticles, core-shell nanoparticles, and silver nanoparticle clusters were synthesized and there optical properties were investigated.
Chapter 1 contains general background information about the optical properties of bulk and silver nanoparticles. It also contains a concise description of two of my collaborative projects that did …

Characterization Of Anti-Proteolytic And Anti-Proliferative Activities Of Pentagalloylglucose; Its Potential Application As A Therapeutic Agent In Vascular Diseases, Chaitra Cheluvaraju

All Dissertations

Cardiovascular diseases are the leading causes of mortality in the United States and will cost around $500 billion this year alone. Elevated proteolytic activity, increased proliferation and migration of vascular smooth muscle cells are hallmarks of atherosclerosis, stenosis and aortic aneurysms. These diseases often manifest the transdifferentiation of vascular smooth muscle cells into osteoblast-like cells followed by deposition of hydroxyapatite–like mineral in the arterial walls.
Currently, there are no standard treatments available for vascular calcification or aneurysms. Atherosclerosis treatment options are limited to statins while balloon angioplasty and stenting – surgical procedures for stenosis, often end in restenosis. Therefore, we …

Two Endangered Species In The Adirondacks In The Context Of Constitutional “Wilderness”, Michael A. Dibrizzi

Elisabeth Haub School of Law Student Publications

Our society has developed with a distinct homocentric view toward the natural world and all of its inhabitants. Wildlife has mostly been regarded as the exclusive chattel of man to dispense with at his discretion. This attitude has led to the extinction of some species and near extinction of many others. Through legislation, lawmakers have attempted to regulate management and exploitation of different species, with varying success. The goal of good environmental regulations is to break from traditional views; regulations in recognizing man’s superiority and control over the natural world will impose a responsibility on man to protect and preserve …

Article Xiv, Agriculture, And Keeping New York’S Wilderness Wild, Hilary Atkin

Elisabeth Haub School of Law Student Publications

When the constitutional convention question is put on the ballot in 2017 as required by Article XIX, Section two of the New York State Constitution, the voters of New York will again choose whether to have a convention to revise or replace their Constitution. There are many issues related to the Forest Preserves of New York State that may lead delegates to consider whether Article XIV, Section one’s “forever wild” provision should be amended or eliminated. With the increasing popularity of the local farming movement in and around the Adirondack and Catskill Parks, delegates could consider amendments that clarify the …

Labile Soil Carbon Inputs Mediate The Soil Microbial Community Composition And Plant Residue Decomposition Rates, Marie-Anne De Graaff, Aimee T. Classen, Hector F. Castro, Christopher W. Schadt

Biology Faculty Publications and Presentations

• Root carbon (C) inputs may regulate decomposition rates in soil, and in this study we ask: how do labile C inputs regulate decomposition of plant residues, and soil microbial communities?

• In a 14 d laboratory incubation, we added C compounds often found in root exudates in seven different concentrations (0, 0.7, 1.4, 3.6, 7.2, 14.4 and 21.7 mg C g soil) to soils amended with and without ¹³C-labeled plant residue. We measured CO₂ respiration and shifts in relative fungal and bacterial rRNA gene copy numbers using quantitative polymerase chain reaction (qPCR).

• Increased labile C input …

A New Species Of Cyclobulura (Nematoda: Subuluridae) From Zaedyus Pichiy And Chaetophractus Vellerosus (Xenarthra: Dasypodidae) In Argentina, Graciela T Navone, María C Ezquiaga, Juliana Notarnicola, F Agustín Jiménez-Ruiz

Publications

Cyclobulura superinae n. sp. collected from Zaedyus pichiy and Chaetophractus vellerosus is herein described as the second species in Cyclobulura Quentin, 1977, and the first subulurid in armadillos. The species is unique in the spur-like structures present at the tip of both spicules, yet they conform to the description of Cyclobulura in the structure of the buccal parts. Specimens of the new species show longer chordal lobes and more conspicuous radial lobes and are smaller than specimens of C. lainsoni. In addition, males of C. superinae exhibit a spur-like process in the distal end of the spicules and a shorter …

Regulation Of Cyclin E Stability In Xenopus Laevis Embryos, Yekaterina Brandt-(Webb)

Biomedical Sciences ETDs

Cyclin-Cdk complexes positively regulate cell cycle progression. Cyclins are regulatory subunits that bind to and activate cyclin-dependent kinases or Cdks. Cyclin E associates with Cdk2 to mediate G1/S phase transition of the cell cycle. Cyclin E is overexpressed in breast, lung, skin, gastrointestinal, cervical, and ovarian cancers. Its overexpression correlates with poor patient prognosis and is involved in the etiology of breast cancer. We have been studying how this protein is downregulated during development in order to determine if these mechanisms are disrupted during tumorigenesis, leading to its overexpression. Using Xenopus laevis embryos as a model, we have shown previously …

An Impaired 20s Proteasome Contributes To The Accumulation Of Oxidized Proteins In Multiple Sclerosis And Its Animal Model, Jianzheng Zheng

Biomedical Sciences ETDs

Carbonylated (oxidized) proteins are known to accumulate in the brain of patients with multiple sclerosis (MS) and in the spinal cord of rats with acute experimental autoimmune encephalomyelitis (EAE). Yet, our knowledge regarding mechanism(s) underlying the build-up of protein carbonyls in these inflammatory demyelinating disorders is quite limited. The objectives of this dissertation were (1) to measure the changes in protein carbonylation during disease progression, and to identify the target cells and modified proteins in the cerebellum of EAE animals, prepared by active immunization of C57/BL6 mice with MOG35-55 peptide, (2) to determine if the accumulation of carbonylated proteins in …

Characterization Of Acetogenic And Methanogenic Leachates Generated From A Sanitary Landfill Site, Aik Heng Lee, Hamid Nikraz, Yung Tse Hung

Civil and Environmental Engineering Faculty Publications

Decomposition processes take place in landfill generate leachates that can be categorized mainly of acetogenic and methanogenic in nature. BOD:COD ratio computed in this study for a landfill site over a 3 years duration revealed as a good indicator to identify acetogenic leachate from methanogenic leachate. Correlation relationships to predict pollutant level taking into consideration of climatic condition are derived.

The Effectiveness Of Silica Sand In Semi-Aerobic Stabilized Landfill Leachate Treatment, Ezlina Othman, Mohd Suffian Yusoff, Hamidi Abdul Aziz, Mohd Nordin Adlan, Mohammed J.K. Bashir, Yung Tse Hung

Civil and Environmental Engineering Faculty Publications

© 2010 by the authors. This study examines the suitability of natural silica sand as a low-cost adsorbent for the removal of ammoniacal nitrogen and heavy metals, particularly iron and zinc, from semi-aerobic stabilized landfill leachate. Leachate samples were collected from the Pulau Burung landfill site (PBLS) in Penang, Malaysia. The above-mentioned contaminants are highlighted in this study because of their unsafe concentrations at PBLS. The effects of shaking time, settling time, and silica sand dosage on the study parameter removal efficiencies were investigated to predict the performance of the process. The adsorptions of ammoniacal nitrogen, iron, and zinc were …

Singular Value Decomposition Metrics Show Limitations Of Detector Design In Diffuse Fluorescence Tomography, Frederic Leblond, Kenneth M. Tichauer, Brian W. Pogue

Dartmouth Scholarship

The spatial resolution and recovered contrast of images reconstructed from diffuse fluorescence tomography data are limited by the high scattering properties of light propagation in biological tissue. As a result, the image reconstruction process can be exceedingly vulnerable to inaccurate prior knowledge of tissue optical properties and stochastic noise. In light of these limitations, the optimal source-detector geometry for a fluorescence tomography system is non-trivial, requiring analytical methods to guide design. Analysis of the singular value decomposition of the matrix to be inverted for image reconstruction is one potential approach, providing key quantitative metrics, such as singular image mode spatial …

Kearifan Tradisional Suku Maybrat Dalam Perburuan Satwa Sebagai Penunjang Pelestarian Satwa, Freddy Pattiselanno, George Mentansan

Makara Human Behavior Studies in Asia

Widlife management as food resources in the tropical areas is very rarely done. Traditional wisdom as an aspect that plays an important role in wildlife sustainability still put into practice by certain tribals. Study on traditional wisdom of Maybrat ethnic group was done to observe the practice of traditional wisdom create important impact to the effort of wildlife sustainability in Sorong Selatan Regency. The results indicate that traditional wisdom practice such as the use of hunting tools, places for hunting and wildlife hunted that indirectly give positive impact in order to support wildlife sustainability in Sorong Selatan.

Does Pyrogenicity Protect Burning Plants?, Paul R. Gagnon, Heather A. Passmore, William J. Platt, Jonathan A. Myers, C. E.Timothy Paine, Kyle E. Harms

Faculty Publications

Pyrogenic plants dominate many fire-prone ecosystems. Their prevalence suggests some advantage to their enhanced flammability, but researchers have had difficulty tying pyrogenicity to individual-level advantages. Based on our review, we propose that enhanced flammability in fire-prone ecosystems should protect the belowground organs and nearby propagules of certain individual plants during fires. We base this hypothesis on five points: (1) organs and propagules by which many fire-adapted plants survive fires are vulnerable to elevated soil temperatures during fires; (2) the degree to which burning plant fuels heat the soil depends mainly on residence times of fires and on fuel location relative …

Functional Traits And The Growth-Mortality Trade-Off In Tropical Trees, S. Joseph Wright, Kaoru Kitajima, Nathan J.B. Kraft, Peter B. Reich, Ian J. Wright, Daniel E. Bunker, Richard Condit, James W. Dalling, Stuart J. Davies, Sandra Díaz, Bettina M.J. Engelbrecht, Kyle E. Harms, Stephen P. Hubbell, Christian O. Marks, Maria C. Ruiz-Jaen, Cristina M. Salvador, Amy E. Zanne

Faculty Publications

A trade-off between growth and mortality rates characterizes tree species in closed canopy forests. This trade-off is maintained by inherent differences among species and spatial variation in light availability caused by canopy-opening disturbances. We evaluated conditions under which the trade-off is expressed and relationships with four key functional traits for 103 tree species from Barro Colorado Island, Panama. The trade-off is strongest for saplings for growth rates of the fastest growing individuals and mortality rates of the slowest growing individuals (r2 = 0.69), intermediate for saplings for average growth rates and overall mortality rates (r 2=0.46), and much weaker for …

Molecular Mechanisms Of Ligand-Mediated Attenuation Of Dna Binding By Marr Family Transcriptional Regulators, Inoka C. Perera, Anne Grove

Faculty Publications

Bacteria and archaea encode members of the large multiple antibiotic resistance regulator (MarR) family of transcriptional regulators. Generally, MarR homologs regulate activity of genes involved in antibiotic resistance, stress responses, virulence or catabolism of aromatic compounds. They constitute a diverse group of transcriptional regulators that includes both repressors and activators, and the conventional mode of regulation entails a genetic locus in which the MarR homolog and a gene under its regulation are encoded divergently; binding of the MarR homolog to the intergenic region typically represses transcription of both genes, while binding of a specific ligand to the transcription factor results …

Accurate Quantification Of Seasonal Rainfall And Associated Climate-Wildfire Relationships, Matthew G. Slocum, William J. Platt, Brian Beckage, Steve L. Orzell, Wayne Taylor

Faculty Publications

Wildfires are often governed by rapid changes in seasonal rainfall. Therefore, measuring seasonal rainfall on a temporally finescale should facilitate the prediction of wildfire regimes. To explore this hypothesis, daily rainfall data over a 58-yr period (1950-2007) in south-central Florida were transformed into cumulative rainfall anomalies (CRAs). This transformation allowed precise estimation of onset dates and durations of the dry and wet seasons, as well as a number of other variables characterizing seasonal rainfall. These variables were compared with parameters that describe ENSO and a wildfire regimeinthe region (at the Avon Park Air Force Range). Onset dates and durations were …

Colony Breeding System Influences Cuticular Bacterial Load Of Formosan Subterranean Termite (Isoptera: Rhinotermitidae) Workers, Claudia Husseneder, Dawn M. Simms, Gabriel K. Aluko, Jennifer Delatte

Faculty Publications

The goal of this study was to test whether the breeding system and/or the degree of inbreeding of field colonies of the Formosan subterranean termite, Coptotermes formosanus, Shiraki (Isoptera: Rhinotermitidae) influences bacterial load on the cuticle of foraging workers. We enumerated bacterial load on the cuticle of groups of workers foraging in 20 inground monitoring stations surrounding the French Market in New Orleans, LA, and identified bacteria species using 16S rRNA gene sequencing. We used microsatellite genotyping to assign the 20 worker groups to seven simple family colonies (headed by a single pair of reproductives) and four extended family colonies …

2-(2-Chloropyridin-3-Yl)-N-Ethyl-4-Methyl-1,3-Oxazole-5-Carboxamide, Guiqiu Yang, Jiakuang Liang, Haibo Yu, Bin Li

Faculty Publications

In the title compound, C12H12ClN3O 2, the dihedral angle between the aromatic rings is 8.42 (10)°. In the crystal, molecules are linked by N - H⋯O hydrogen bonds, generating C(4) chains propagating in [001].

Variation In The Checkpoint Kinase 2 Gene Is Associated With Type 2 Diabetes In Multiple Populations, Kari E. North, Nora Franceschini, Christy L. Avery, Lisa Baird, Mariaelisa Graff, Mark Leppert, Jay H. Chung, Jinghui Zhang, Craig Hanis, Eric Boerwinkle, Kelly A. Volcik, Megan L. Grove, Thomas H. Mosley, Charles Gu, Gerardo Heiss, James S. Pankow, David J. Couper, Christie M. Ballantyne, W. H. Linda Kao, Alan B. Weder, Richard S. Cooper, Georg B. Ehret, Ashley A. O'Connor, Aravinda Chakravarti, Steven C. Hunt

Faculty Publications

Identification and characterization of the genetic variants underlying type 2 diabetes susceptibility can provide important understanding of the etiology and pathogenesis of type 2 diabetes. We previously identified strong evidence of linkage for type 2 diabetes on chromosome 22 among 3,383 Hypertension Genetic Epidemiology Network (HyperGEN) participants from 1,124 families. The checkpoint 2 (CHEK2) gene, an important mediator of cellular responses to DNA damage, is located 0.22 Mb from this linkage peak. In this study, we tested the hypothesis that the CHEK2 gene contains one or more polymorphic variants that are associated with type 2 diabetes in HyperGEN individuals. In …

Interrogating Local Population Structure For Fine Mapping In Genome-Wide Association Studies, Huaizhen Qin, Nathan Morris, Sun J. Kang, Mingyao Li, Bamidele Tayo, Helen Lyon, Joel Hirschhorn, Richard S. Cooper, Xiaofeng Zhu

Faculty Publications

Motivation: Adjustment for population structure is necessary to avoid bias in genetic association studies of susceptibility variants for complex diseases. Population structure may differ from one genomic region to another due to the variability of individual ancestry associated with migration, random genetic drift or natural selection. Current association methods for correcting population stratification usually involve adjustment of global ancestry between study subjects.Results: We suggest interrogating local population structure for fine mapping to more accurately locate true casual genes by better adjusting the confounding effect due to local ancestry. By extensive simulations on genome-wide datasets, we show that adjusting global ancestry …

Special Report, Celebrating The Tenth Anniversary Of State Wildlife Grants In Tennessee, Tennessee. Wildlife Resources Agency.

Strategic and Management Plans

No abstract provided.

An Analysis Of Psycho-Educational Profiles Of Elementary Students Referred For Special Education Consideration Due To Literacy Difficulties, Amy M. Bowers

Masters Theses and Doctoral Dissertations

This study examined the results of a uniquely constructed literacy assessment technique, combining Dehn’s (2006) interpretation of psychological processing assessment and the Reading Rockets (Greater Washington Educational Telecommunications Association, Inc., 2005) interpretation of academic achievement. The study employed a quantitative descriptive research design using ex post facto data. The population was selected from one northwest Georgia school district and consisted of 54 elementary school students (first through fifth grades). Participants in the population met the following criteria: 1) received three tiers of reading intervention in the RTI process, 2) were referred for initial special education consideration, 3) were from either …

Clinical Evidence Of Ozone Interaction With Pain Mediators, Lamberto Re, Gregorio M. Sanchez, Nabil Mawsouf

Saudi Medical Journal

OBJECTIVE: To address the clinical evidence that may support the fact that subcutaneous administration of ozone has anti-hyperalgesic effects probably acting by modifying specific pain targets. METHODS: Fifty-two patients attending the Medinat Clinic, Camerano, Ancona, Italy between October 2004 to October 2009 were eligible to participate in the study. Panoramic photos of painful and not painful areas submitted to oxygen /ozone treatment injection were analyzed to detect the intensity of erythema. RESULTS: The erythematic areas after ozone subcutaneous puncture showed significant (p<0.05) increment (83±5%) in the painful area versus 7±6% in the contralateral area. CONCLUSION: The surrounding erythema observed during ozone intervention should explain at least in part, its interaction with some pain mediators. This may involve algesic mediators or receptors. The analgesic mechanism induced by oxygen/ozone may involve 2 independent steps: a short-term mechanism that may correspond with the direct oxidation on biomolecules, and a long-term mechanism that may involve the activation of antioxidant pathways. Further studies are needed to support the biochemical analgesic mechanism of ozone therapy.

Doug Ruthven And Jorg Karger: Their Individual And Collective Contributions To The Field Of Zeolite Science And Engineering, Dhananjai B. Shah

Chemical & Biomedical Engineering Faculty Publications

Prof. Doug Ruthven and Prof. Jörg Kärger are two giants in the field of zeolite science and engineering. Over their academic careers encompassing almost forty years each, they have contributed significantly to the advancement of fundamental understanding of adsorption and diffusion in zeolites as well as their industrial applications. The author, in the beginning of his academic career, had an opportunity to spend two years as a post-doctoral fellow in Prof. Ruthven’s laboratory at the University of New Brunswick (1975–1977). This experience actually motivated me to spend my academic career in working in the field of zeolite adsorption and …

Optimizing In Vitro Propagation Of Rosa Persica, Maryam Jafarkhani-Kermani, Pegah Khosravi, Somayeh Kavand

Publications and Research

Rosa persica with a distinctive red eye is a good candidate for addition to the breeding pool of roses. In order to optimize micropropagation of R. persica, three culture media (MS, QL and VS) were compared. The maximum growth rate was observed in the VS medium. Addition of FeEDTA (Fe: 65.4 mg/l), calcium gluconate (Cg: 2.7 g/l) and Gamborg vitamins (B5) instead of VS vitamins, alone or in combinationwith VS medium were compared. The maximum growth rate was obtained in the medium containing VS + Cg + B5 (VSCgB5). Various concentrations of BAP (0, 2, 4 and 8 μM ) …

A Fiber Bragg Grating-Based All-Fiber Sensing Systems For Telerobotic Cutting Applications, Ginu Rajan, Dean Callaghan, Yuliya Semenova, Mark Mcgrath, Eugene Coyle, Gerald Farrell

Articles

A fiber Bragg grating (FBG)-based strain sensing system for minimally invasive telerobotic cutting applications is presented in this paper. Investigations assume that a scissor blade can be approximated as a uniformly tapered cantilever beam. A replica of the scissor blade is produced and strain characterization has been carried out using an FBG sensor system. Results are validated against measurements obtained using conventional electrical resistance strain gauges. The scissor blade experiences both direct and lateral forces during cutting, hence the system is characterized for a direct load range of 0-30 N and a lateral load range of 0-10 N. The results …

Generalized Ellipsometry On Sculptured Thin Films Made By Glancing Angle Deposition, Daniel Schmidt

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

In this thesis, physical properties of highly optically and magnetically anisotropic metal sculptured thin films made by glancing angle deposition are presented. Predominantly, the determination of optical and magneto-optical properties with spectroscopic generalized Mueller matrix ellipsometry and homogenization approaches is discussed. Nomenclatures are proposed to unambiguously identify the sculptured thin film geometry.

Generalized ellipsometry, a non-destructive optical characterization technique, is employed to determine geometrical structure and anisotropic dielectric properties of highly spatially coherent three-dimensionally nanostructured thin films in the spectral range from 400 to 1700 nm. The analysis of metal slanted columnar thin films (F1-STFs) deposited at glancing angle ( …

Perceptions Of Male Versus Female Students Enrolled In Science, Technology, Engineering And Mathematics Courses Regarding Peer Tutoring, A Component For Student Retention, Cheryl D. Kingsbury

Theses and Dissertations

Academic departments in the areas of science, technology, engineering, and mathematics, strive to develop in students the ability to problem solve, analyze, and to critically think about solutions to problems. Academic departments are committed to success, yet retention rates are lower than would be expected for females in science, technology, engineering, and mathematics fields of study, where female students are underrepresented.

The purpose of the study was to explore the perceptions of male and female traditional and nontraditional students who participated in a science, technology, engineering or mathematics STEM course during the spring 2010 semester regarding peer tutoring, and to …

Finding Myself: The Maturation Of Spirituality And Its Influence On Behavior During Late Adolescence, Deanna M. Mason

Theses and Dissertations

The purpose of this grounded theory study was to develop a theoretical model describing the influence of spirituality and/or religiosity on late adolescent behavior. Multiple quantitative research studies have linked spirituality and/or religiosity with both decreased health-risk behaviors and increased health-promotion behaviors during adolescence. However, as reductionist methods have not revealed underlying reasons for these relationships, the ability to apply this knowledge to practice is limited. Additionally, there is a lack of clear definitions for spirituality and/or religiosity firm enough to bridge disciplinary boundaries. A qualitative research perspective, which takes into account the embodied experience and development of individuals during …

Effects Of Fatigue And Self-Reported Countermeasures Used By Regional Airline Pilots Conducting Continuous Duty Overnight, Andrew Laventure

Theses and Dissertations

Fatigue poses a significant risk to commercial aviation. When pilots become fatigued they are more likely to make errors and in some instances those errors have been causal factors in accidents. Research not only tells us how the human body is affected by fatigue but also what can be done to temporarily reduce its negative impact on performance. However, relatively little data is available pertaining to one specific type of flight operation, the Continuous Duty Overnight (CDO). They are frequently conducted by regional airlines within the United States and typically resemble schedules for workers on a 3rd shift, otherwise known …