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Deposition And Characterization Of Electroless Nickel-Phosphorus-Boron Coatings From Acidic Bath, Tai-Xiang Jiang, Hui-Huang Wu

Journal of Electrochemistry

Acknowledgments The authors gratefully acknowledge Professor B.W.Mao for use of AFM facilities at her laboratory. We would also like to thank J.Tang for assistance with AFM measurements.

The Study On Fabricating Thin Electrodes For Polymer Electrolyte Membrane Fuel Cells (Pemfc), Yong-Sheng Yang, Jing-Hua Liu, Chang-Peng Liu, Gong-Quan Sun, Chang-Zhi Li, Tian-Hong Lu

Journal of Electrochemistry

To lower platinum loading in electrodes for polymer electrolyte membrane fuel cell, a new thin electrode fabrication technique (TEFT) was developed in this work. A series of low Pt loading electrodes with smooth and uniformed surface were fabricated by the TEFT. As a result, the maximum power density of the cell with platinum loading of 1 mg/cm² and Nafion 117 membrane as electrolyte was up to 0.3 W.cm^-2. Moreover, the effects of PTFE and Nafion content in cathodes on the performance of PEMFC with low Pt loading electrodes (1 mg Pt/cm²) were examined systematically.

Microsystem And Electrochemistry, Zhong-Qun Tian, Jian-Jun Sun

Journal of Electrochemistry

Microsystem or micro electromechanical system (MEMS) is briefly introduced. The electrochemical applications in microsystem are reviewed and prospective applications of microsystem in electrochemistry are discussed. Along with the rapid development of micro_ analytical chemical systems or lab-on-chips in 21st century, electrochemistry may play an increasingly important role in microsystem technology.

Study On Oxygenation Of Histidion-Cobalt And Monoiodohistidine-Cobalt Complexes By Cyclic Voltammtry, Yi Zhang, Ji-De Wang, Fan Yue, Xiao-Gang Zhang, Qi-Jun Song

Journal of Electrochemistry

The oxygenation of Histidine-Co and Monoiodohistidine-Co complexes were studied by cyclic valtammtry under certain conditions. The possibility of studing the oxygenation processes by cyclic voltammetry method was proposed and discussed in comparison with the results of potentiometry and spectrophotometry.

Studies On Electrochemical Synthesis Of 4,5-Disubstituted-1,2- Benzoquinones And The Reaction Mechanism, Xian-Zhang Bu, Gui-Wu Xiao, Lin Ma, Xing-Chum He, Ling-Quan Gu

Journal of Electrochemistry

The oxidation peak potentials (E_p) of alinine derivates and catechol in 0.1 mol/L KCl+15% alcohol solution were measured by cyclic voltammograms technique. The electrochemical oxidation condition was set according to the E_p. Three derivates of 4,5-disubstituted -1,2-benzoquinones were prepared via electrochemical oxidation-Michael addition reaction. The possible mechanism of electrochemical oxidation-Michael addition reaction is presented.

Study On Preparation Of Coarse And Fine γ-Lialo2 Mixed Powder Used For Mcfc Matrix, Hua-Xin Lin, Bao-Lian Yi, Lian-Ying Kong, En-Jun Zhang, Li Zhou, Feng-Xia Wang

Journal of Electrochemistry

Coarse α-LiALO₂ powder was transferred completely to γ-LiAlO₂ at 900 ℃ for ten hours. Fine γ-LiALO₂ powder was prepared by “chloride” synthesis. MCFC matrix was fabricated by mixing the coarse and fine γ-LiALO₂ powder and by tape cast. The out'put voltage of the cell assembled with the matrix was 0.85 and 0.75 V respectively at 200 and 300 mA/cm ², and power density was about 250 mW/cm². The performance of the matrix fabricated with the mixed powder was obviously more advanced than that of the matrix fabricated with only coarse γ-LiALO₂ powder.

An Eis Study On The Synergetic Filming Between Cathodic Protection And The Corrosion Inhibitor, Yong-Tao Zhao, Jian-Hua Wu, Jian-Hua Qian, Hui Yu

Journal of Electrochemistry

The electrochemical impedance spectroscope (EIS) of 907A steel in seawater was investigated to study the film formation and destruction. The corrosion protection mechanism of the synergy interaction between cathodic protection and YKI-5 corrosion inhibitor (a mixture of polyhydric alcohol phosphate ester, phosphate and polyphosphate) is discused. Typical EIS spectral changes were clearly observed during the film formation and destruction processes. EIS results indicated that the film seemed to formed a multi-layered structure which consist of an inner layer (this may be an inhibitor-metal complex layer) and many outer layers of calcareous deposits. The film possesses of good persistency under the …

Electro-Oxidation Of Glyoxal To Glyoxalic Acid, Yin-Sheng Chen, Xin-Sheng Zhang, Jun Hu, Ying-Chun Dai

Journal of Electrochemistry

An investigation has been made to obtain the glyoxalic acid by the electrochemical oxidation of glyoxal solution with hydrochloric acid under various experimental conditions.The cell used consists of a lead cathode, a DSA anode and a cation-exchange membrane of model CM001. The current efficiency and yield for glyoxalic acid generation were 80.0% and 91.1% respectively, under optimal operating conditions: velocity of electrolyte flow 1.4 m·s^-1 ,current density 450 A·m^-2, temperature 30～40 ℃, initial concentration of glyoxal and hydrochloric acid 9.1%～16.0%, 4%～6%, respectively.

Studies Of The Preparation Of Electrodes From Lead Carbonate For Lead-Acid Battery Ⅱ. The Preparation Of Paste Electrodes, Zhong-Xu Dai, Di-Hua Wang, Hao-Hao Ke, Jin-Yun Zou, Yun-Hong Zhou

Journal of Electrochemistry

The positive and negative pastes were prepared by mixing PbCO₃ and H₂SO₄ solution as well as relative additives, respectively. The effects of the various formation methods and the charge/discharge conditions on discharge capacity and active material utilization of both electrodes were examined. The results indicate that the performance of the positive electrode formed at 2.0 mA/cm² is better than that formed at higher current density under the same charge/discharge condition, the PAM utilization reaches 74.4 % under discharging at 2.0 mA/cm²; and the property of the negative electrode formed by unsymmetrical square wave …

Inhibition Of N,N'-O-Phenylen-Bis(3-Methoxysalicylidenimine) On Copper In Halide Solutions, Hou-Yi Ma, Shen-Hao Chen, Zhen-Lan Quan, Lin Niu, Shu-Lan Li

Journal of Electrochemistry

Inhibition of N,N'-o-phenylen-bis(3-methoxysalicylidenimine) (V-o-Ph-V) on corrosion and anodic disslution of copper in neutral NaCl and NaBr solutions was investigated in terms of potentiostatic steady-state polarization and A.C. impedance techniques. The inhibition mechanism of V-o-Ph-V to copper corrosion was interpreted in detail by comparing the electrochemical behaviors of copper in halide solutions with or without V-o-Ph-V. Besides, the inhibition effect of self-assembled V-o-Ph-V film on copper corrosion in NaCl was also studied.

Uncertainity Principles On Some Lie Groups., Swagato Kumar Ray Dr.

Doctoral Theses

The uncertainty principles of Harmonic Analysis say that: a nonzero func- tion and its Fourier transform cannot both be sharply concen- trated. After the initial work on this phenomenon in 1920s, the last two decades witnessed a spurt of activity in this direction (we refer the reader to a very readable survey [FS]). One may notice two broad phases in this activity, the first concentrating on R where the notion of concentration is given different formulations to see whether the phenomenon still holds. In the later phase R is replaced by other commutative or noncommutative groups, or more generally by …

Sprayed And Thermally Evaporated Carbon Films As Anodes For Lithium Ion Batteries, Shu-Gao Zhang, M.Schleich Donald

Journal of Electrochemistry

Carbon films were made using spray-thermal evaporation from a kind of pyrolytic carbon powder. The films obtained with graphite structure were both potentio-statically and galvanostaically tested. Cycling patterns indicated a reduction peak on the first cycle corresponding to the formation of solid electrolyte interface, and the capacity values and x values were quite acceptable compared to theoretical ones when charging-discharging current density was suitable. Based on the experimental results, the obtained carbon films could be used as anode materials for relatively determining the electrochemical performances of cathode materials.

In-Situ Simultaneous Esr And Conductivity Measurements For Polyaniline, Lin Zhuang, Qing Zhou, Jun-Tao Lu

Journal of Electrochemistry

With a new cell design, simultaneous electrochemical ESR and conductance measurements were realized for the first time. The in-situ cell consisted of a dual working electrode, a counter electrode and a reference electrode accommodated in a capillary of 1mm diameter. The dual working electrode was composed of two closely spaced Pt electrodes: a Pt disk electrode (0.5 mm diameter) sealed in a thin glass tube and a Pt layer deposited on the outside wall of the glass tube. The two working electrodes were separated by the glass gap about 20 μm thick. Two potentiostats were used to control electrode potential …

Electrochemical Characterization Of Ir-Ta-Ti Metal Oxide Coated Titanium Anodes, Ting-Yong Wang, Li-Kun Xu, Guang-Zhang Chen

Journal of Electrochemistry

Ir-Ta-Ti metal oxide coated titanium anodes of variable composition were prepared by thermal decomposition. Their micro morphorogies and electrochemical properties were characterized by scanning electron microscope, open circuit potential, cyclic voltammetry, consumption rate measurements and accelerated life test. The SEM results indicated that all coatings were of a porous and cracked-mud microstructure influenced greatly by the composition of coatings. The electrochemical measurements showed that the Ir-Ta-Ti ternary oxide-coated anodes exhibited excellent electrochemical activity and electrochemical stability in both acidic media and seawater which were affected by the composition and microstructure of the coatings. Owing to good corrosion resistance and low …

Fabrication And Examination Of Reduced Temperatrue Solid Oxide Fuel Cell Using A Supported Thin Ysz Electrolyte Substrate, Yi-Huang Zhang, Yong-Lei Dong, Yi Jiang, Zhi-Gui Lu, Jing-Wang Yan

Journal of Electrochemistry

By using a cost-effective wet process,dense yttria stabilized zirconia (YSZ) films on Ni-YSZ anode substrates have been prepared successfully. The YSZ film was characterized to be around 10 μm in thickness, sufficiently dense, uniform and crack free. A single solid oxide fuel cell fabricated from the supported YSZ film electrolyte on the anode substrate and a LSM cathode prepared on the YSZ film was tested. The power density reached to 0.1 W/cm² at 800 ℃, showing a reasonable performance. Further analysis on both electrodes shows that the anodic overpotential was much larger than IR drop (including YSZ resistance and …

Investigations Of Lithium Ion Battery Electrolyte Solution, Jing-Li Han, Qing-Guo Liu

Journal of Electrochemistry

Synthesis and electrochemical investigations of {LiB[(SO₃)C₆H₃(O)(COO)]OC₆H₅} in EC/DMC or DMSO/PC mixtures are presented.

Winter Habitat Use And Survival Of Female Ring-Necked Pheasants (Phasianus Colchicus) In Southeastern North Dakota, H. Jeffrey Homan, George M. Linz, William J. Bleier

United States Department of Agriculture Wildlife Services: Staff Publications

From 1992 to 1995 we used radiotelemetry to monitor winter habitat selection and survival of female ring-necked pheasants (Phasianus colchicus) in southeastern North Dakota. We captured 100 birds at nine sites in six study blocks centered on cattail-dominated (Typha spp.) semi-permanent wetlands. Pheasants showed nonrandom habitat use at two hierarchical scales. At the second-order scale (23-km² blocks) semi-permanent wetlands were preferred during two winters in which habitat selection could be assessed (1992–1993 and 1994–1995). An additional second-order preference for grass-covered uplands was shown during the mild 1994–1995 winter. At the third-order scale (home-range) pheasants preferred the …

Modeling Conifer Tree Crown Radius And Estimating Canopy Cover, Samantha J. Gill, Gregory S. Biging, Edward C. Murphy

Natural Resources Management and Environmental Sciences

Models of tree crown radius were developed for several conifer species of California. Typical forest inventory variables (DBH, height, height-to-crown base, crown class, basal area per hectare, and trees per hectare) were considered as independent variables in model development. Models were fitted using both ordinary and weighted least squares methods. It was found that for the species studied, an ordinary least squares linear regression with DBH as the only independent variable was appropriate. For some species studied, the addition of other independent variables provided minor improvements over the model with only DBH. These models of crown radius could be summed …

February 25th 2000, Csusb

Coyote Chronicle (1984-)

No abstract provided.

We Are…Marshall, February 25, 2000, Office Of Marshall University Communications

We Are ... Marshall: the Newsletter for Marshall University 1999-2023

No abstract provided.

Funding Private Investigation Of Santa Barbara County Court Case Files Of Insanity Actions.

Initiatives

FUNDING PRIVATE INVESTIGATION OF SANTA BARBARA COUNTY COURT CASE FILES OF INSANITY ACTIONS. INITIATIVE STATUTE. Requires state to fund investigation of court files of insanity actions in Santa Barbara County. Funds to be available to voter approved investigator. Investigator is provided a superior court judge and courtroom equipped with video and sound recording equipment to take testimony on early court case files of insanity actions. Requires state to broadcast, on county government television, video documentation of investigation at minimum once each week for six months and, thereafter, once each month for ten years. Summary of estimate by Legislative Analyst and …

Alumni Association Newsletter, February 25, 2000, Volume 1, Number 3, California State University, Monterey Bay

Alumni Association Newsletters

Landing a Dream "Green" Job -- Win a CSUMB Fleece Pullover! -- What Do You Miss Most About CSUMB? -- New Science Academic Center Planned by CSUMB -- CSUMB Hires New CTO -- A Thirst for Knowledge -- Educational Tidbits! -- Commencement -- Commencement Volunteers -- A Warm Welcome From the Director of Alumni Relations & Annual Fund -- News Briefs -- CSUMB Opens New Student Center

Volume 37, Number 25: February 25, 2000, University Of North Dakota

University Letter Archive

No abstract provided.

The New Hampshire, Vol. 89 [90], No. 38 (Feb. 25, 2000), The New Hampshire

The New Hampshire Print Edition

An independent student produced newspaper from the University of New Hampshire. This volume was printed as 89, but it is the 90th volume in the series. This was corrected in pencil.

The Murray State News, February 25, 2000, The Murray State News

Murray State University Collection

No abstract provided.

High-Performance Liquid Chromatographic Separation Of The Enantiomers Of Unusual Α-Amino Acid Analogues, Antal Péter, Edit Olajos, Richard Casimir, Dirk Tourwé, Quirinus B. Broxterman, Bernard Kaptein, Daniel W. Armstrong

Chemistry Faculty Research & Creative Works

The direct and indirect stereochemical resolution of the enantiomers of ring- and α-methyl-substituted phenylalanines and phenylalanine amides was attempted by high-performance liquid chromatographic methods. The direct separation was carried out on two chiral stationary phases, the crown-ether- based Crownpak CR (+), and the teicoplanin-based Chirobiotic T, while the indirect resolution was performed by applying pre-column derivatization with 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate (GITC) and Nα- (2,4-dinitro-5-fluorophenyl)-L-alanine amide (Marfey's reagent, FDAA). The Chirobiotic T column was efficient in the separation of ring- and α-methyl- substituted phenylalanine analogues but was ineffective for the amides of these analogues. The Crownpak CR (+) column separated the ring-substituted …

Changes In Alfalfa Breeding — Where Is Alfalfa Headed?, Becky Greenwald

Kentucky Alfalfa and Stored Forage Conference

Alfalfa didn't earn the title "Queen of the Forages" just because of its good looks on rolling hills or sweet smell at harvest. Alfalfa was first described nearly 2,500 years ago, in 490 B.C in the desert regions of what is now Iran. From the Middle East, alfalfa was taken into Europe and South America by invading armies, explorers, and missionaries.

Little Known Facts About Alfalfa, Don Ball

Kentucky Alfalfa and Stored Forage Conference

During the previous nineteen Kentucky Alfalfa Conferences, many topics pertaining to alfalfa have undoubtedly been addressed. In fact, some topics such as establishment techniques, varieties, and factors affecting yield are important enough that they have probably been discussed in one form or another during most of these conferences.

However, a twentieth-year state commodity conference is a milestone that deserves some special consideration, and which should justify inclusion of one or more unique topics on the program. This line of thinking led to idea that for this presentation it might be interesting to discuss some facts about alfalfa that are not …

Reducing Alfalfa Harvesting Losses, Michael Collins

Kentucky Alfalfa and Stored Forage Conference

In some areas of the country, producers store a substantial portion of their forage for winter feeding as silage or haylage. However, hay remains the most popular storage method for forage. Hay stores well for long periods and is better suited to cash sale and transportation than silage. Mechanical conditioning, which gained acceptance during the 1950's is probably still the greatest single change in hay harvesting and storage technology during this century. However, a number of other noteworthy changes and innovations have occurred in recent years which have helped to reduce the extent of losses during hay harvesting and storage.

Opportunities For Alfalfa As A Grazing Crop In Kentucky, Ken Johnson

Kentucky Alfalfa and Stored Forage Conference

Why do we continue to hear people talk about Alfalfa as a grazing crop? In my opinion there are two words that come to mind when I think of grazing Alfalfa, quality and yield. Alfalfa is without a doubt the highest quality forage we can graze. Alfalfa is also one of the highest yielding forages we can graze and maybe the highest yielding widely known and widely grown forage available to Kentucky farmers.