Digital Commons Network^™

Effect Of Elevated Temperature On Efficiency Of Corrosion Inhibitors, Walter Dzingala

Theses

An experimental program was set up to investigate the effect of temperature on the protection efficiency of various inhibitors of metal corrosion. Contrary to most studies, an appreciable amount of the work was done with the corrosive effect being determined on the metal specimens that were exposed first to the inhibitor, then to air at different temperature, and finally to the corrosive medium with no inhibitor present. The purpose being to determine whether the inhibitor treatment would provide a permanent protection for a metal surface or would it be necessary to furnish a continuous supply of the inhibitor to the …

Fugacity Coefficients Of Gases In Binary Mixtures, Louis David Mazzeii

Theses

A method of Pitzer for predicting component fugacity coefficients of gases in binary mixtures is evaluated by calculating 2100 fugacity coefficients and comparing the results to experimental data.

Pitzer employed the technique of Gamson and Watson in deriving an expression for fugacity coefficients. The expression is based on a three parameter corresponding states theory set of equations, and a definition of pseudo critical properties of mixtures, both previously proposed by Pitzer.

A further comparison with values calculated by similar methods of Edmister and Ruby, and Redlich et al (which previously were established as the most accurate general methods) indicates Pitzer's …

Thermodynamic Properties Of Hydrazine, Michael Perlswieg

Theses

The thermodynamic properties of hydrazine have been evaluated for the saturated region and for the superheated vapor. The superheated vapor properties were determined for temperatures up to 2200°F and pressures to 3000 psia. Enthalpy, entropy, and specific volume are reported for the saturated vapor and liquid and the superheated vapor. Results are reported in the form of tables.

Enthalpy values are relative to the saturated liquid at 32°F. Entropy values are absolute. The thermodynamic properties have been based on experimental data where possible. Due to the lack of experimental pressure-volume-temperature data, however, the generalized correlations of Lydersen, Greenkorn, and Hougen …

Viscosity Correlations Of Saturated Fatty Acids And Their Esters, Thomas Joseph Redling

Theses

Several correlations have been developed which permit calculation of the viscosities of the n-paraffin fatty acids and esters, beginning with formic and including stearic acid.

The correlations were obtained by interrelating the Log u and the Log P_v at the same temperature, where u is the viscosity in centipoise and P_v is the vapor pressure in millimeters Hg. A single line relationship represents all the fatty acids from propionic acid to and including stearic acid, while formic acid and acetic acid each have their own line. Methyl, ethyl, propyl and butyl formate can be represented by a single …

The Electrolytic Oxidation Of Para-Nitrotoluene, Mustafa Darwish Shamy

Theses

The factors affecting the electrolytic oxidation of p-nitrotoluene to p-nitrobenzoic acid have been studied, and optimum conditions determined for obtaining the best overall yield of 65.7 per cent. These Anode:lead sheetCathode:lead sheetAnolyte:250 cc of 50 per cent sulfuric acid
10 grams of p-nitrotoluene
5 grams of chromic trioxideCatholyte:250 cc of 50 per cent sulfuric acidVoltage:4.5 ± .5 voltsCurrent density:3.0 amperes per square decimeter.Temperatures65 ± 3°CReaction time:fifty per cent of the theoretical time required

It was observed that high potentials and prolonged reaction periods are detrimental to the yield.

A mechanism for the electrolytic oxidation process is suggested, based on experimental …

The Kinetics Of Hydrogen Reduction Of Chromic Oxide, Kurt Strater

Theses

The hydrogen reduction of Cr₂O₃ to chromium metal was found to be feasible at very low water vapor concentrations, approximately -38° to -24°C, over a temperature range of 1130° to 1490°C. Hydrogen reduction under these conditions was predicted by the calculated equilibrium curves which also indicated that Cr₂O₃ is reduced directly to chromium without forming the intermediate oxide, CrO. This reduction path was confirmed by X-ray diffraction analysis.

The percent reduction of Cr₂O₃ at each reaction temperature was constant with time suggesting an inhibiting effect of the gaseous reaction product, water …

Attrition In A Fluidized Bed, Andrew Joseph Welter

Theses

The object of this thesis is to study attrition in a fluidized bed in an attempt to find a reliable method for predicting attrition rate when fluid flow rates and particle sizes are varied.

The system studied consisted of air as the fluidizing median with bauxite and fuller's earth as the solids in suspension. Fluid flow rates were changed while all other variables were held constant. Systems with both large and small particles were studied for each material.

It was found that the attrition rate of the material when the bed is maintained at a constant mass flow rate is …

Investigation Of The Stability And Response Of A Reboiler Under Condensate Control, Francis Arthur Winter

Theses

Control of heat flux by condensate throttling was investigated theoretically by frequency response analysis and experimentally on a simulated reboiler control system.

Transfer functions were derived for each component and ware used to describe the response of the experi- mental system. Experimental controller settings were in reasonable agreement with the calculated results. However, general overall control was poor because of dead time and cyclic disturbances. Experiments showed that the process contained dead time in the order of three to seven times the ultimate period (0.5 - 1.0 minutes). Several sources of disturbances prevented an accurate evaluation of stability at low …

Limitations On Expression Involved In The Materials And Certain Techniques Of Ceramic Sculpture, Peter B. Riley

Theses

None provided.

Thermodynamic Properties Of Formaldehyde, Raymond H. Koo

Theses

The thermodynamic properties of saturated and superheated formaldehyde were evaluated at ten degree temperature intervals from -19°C. to 400°C. and at various pressures up to 150 atmospheres.

Lydersen's correlations were used to estimate the critical constants.

Vapor pressure data were calculated using Riedel's method.

The generalized thermodynamic correlations of Hougen, Lydersen,'and Greenkorn were employed to obtain values of the thermodynamic properties in the saturated and superheated regions.

The values for temperature, pressure, specific volume, enthalpy, and entropy for saturated and super-heated formaldehyde are presented in the form of tables and graphs.

Structure, Wood, And The Form Of Furniture, William Keyser

Theses

None provided.

An Investigation Into Halftone Density Variation With Pre-Screened Graphic Emulsions, Robert Chaffee

Theses

Information relating to the variation that can be expected in utilizing Graphic Arts emulsions has been of some interest in the past several years. A test was formulated utilizing a Pre-screened graphic emulsion and was conducted each day for a period of two weeks. Test results indicate that the density level is of definate significance. The variability that can be expected at higher levels of density is outside the relm of desired conformance.

Ceramic Murals, Candeger Furtun

Theses

In my Thesis I propose to study the Ceramic Murals at its beginning and at the present Age. Since it is a very wide and long topic to be handled by one person within a limited time, I shall confine myself to the first attempts of Mankind in the making of Murals in clay in Prehistoric times, in Mesopotamia and murals that are done very recently , mainly in the United States.

A Study Of The Possibilities Of Developing Practical Ceramic Ware For Charcoal Cooking, John J. Masson

Theses

Not provided.

Hiding Power Of White Pigments : Theory And Measurement, Parker Bovaird Mitton, Lawrence Vejnoska

Theses

Optical properties of pigmented films such as hiding power, scattering coefficient, and absorption coefficient were measured at three bands of wavelength of light (blue, green, red) for ten white pigments at seven pigment concentrations in a paint. These pigments range from the highest index of refraction (rutile) to the very low index of an extender pigment (CaC031); they range from a fine particle size (average 0.2 microns) to a relatively coarse size (average 2.2 microns).

Among the findings presented below the first two confirm the general observations of pigment behavior found by others; the rest of the findings are new. …

Prediction Of Binary-Liquid System Viscosity From Vapor-Liquid Equilibria Data, Eugene Henry Okrent

Theses

This paper reviews the proposed methods for prediction of binary mixture viscosity. A calculation method is developed which predicts the binary liquid mixture viscosity of non-ideal systems of organic materials. The calculation method is an extension of the statistical mechanically derived equation:

η_m = Nh/V exp[χ₁Δ_G1⁺⁺ + χ₂ΔG₂⁺⁺ -ΔG^?/κ vap]/RT

A method has been developed for establishing the value of (ΔG^E/RT)vap from the constants of the Margules equation, which is an improvement over previous methods. The proposed equation is:

Log η_m = χ₁ log η …

Vapor-Liquid Equilibria System : Carbon Tetrachloride, Benzene, Methyl Cellosolve, Frederick Ormande Fisher

Theses

An Othmer still was used to determine the vapor-liquid equilibria for the ternary system: carbon tetrachloride (CCl₄), benzene (C₆H₆), and methyl cellosolve (C₃H₈O₂). The solutions were assayed by refractive index and density measurements. The data were correlated to theoretical considerations by the use of the Margules 3-suffix ternary equationso

In the course of the investigation of the ternary system, vapor-liquid equilibria were determined for each of the three binary systems. The CCl₄-C₆H₆ system is well known and data are presented in the International …

Correlation Of Pressure Drop And Holdup In A Packed Distillation Column, Nello Del Gobbo

Theses

Reed and Fenske have proposed a relationship that correlates the variables of packing dimensions, operating conditions, and fluid properties involved in countercurrent flow through packed distillation columns. Pressure drop and holdup data, obtained by atmosphere is distillation in columns packed with wire helices, was applied to the correlation by Reed and Fenske with good results. At reduced pressures limited data indicated the possibility of variations in the correlation as a function of the molecular weight of the material distilled.

Cummins investigated the effect of reduced pressure and holdup in distillation for several liquids using protruded packing. An attempt to correlate …

Particle-Liquid Flow In Vertical Tubes, Frederick John Rowe

Theses

It was the purpose of this investigation to develop an experimental Procedure which would allow the prediction of the variation of fraction void with varying liquid and solid rates from a minimum number of experiments carried out in simple apparatus. This procedure should allow prediction for both smooth and rough particles, and should be valid for several different shapes. The data collected can be plotted on a single chart showing the relation between fraction void, solids throughput, and liquid throughput for all vertical particle fluid systems. Such a method was suggested by Mertes and Rhodes1 in their work developing a …

Heat Transfer Coefficients In Nucleate Boiling, Gerald Burt Fefferman

Theses

The purpose of this study was to investigate some new approaches to the problem of correlating heat transfer coefficients in nucleate boiling, A survey of previous work done in this field reveals much inconsistency in recorded data relating the heat transfer coefficient to other properties of the observed system, but general agreement has been reached, however, concerning the important influence of the temperature difference between the heating element surface and the boiling liquid. As this temperature difference is increased, the surface coefficient of heat transfer rises until a critical point is reached, marking the end of nucleate boiling and the …

Equilibrium And Reaction Rate Constants Of Esterification Of Nitrobenzoic Acids, John Nicholas Korzun

Theses

A determination of equilibrium constants and reaction kinetics for the esterification of ortho, meta, and para-nitrobenzoic acids with methanol and ethanol was performed. A search of past literature showed that the equilibrium constants for the above acids and alcohols had not been measured previously.

The equilibrium constants (Ke) obtained for ortho, meta, and para-nitrobenzoic acids using p-toluene sulfonic acid as catalyst and ethanol as the alcohol were 3.59, 4.56, and 2.91: respectively. Using methanol as the alcohol, the corresponding constants were 2.61: 2.65, and 1.92.

Hydrochloric acid was also studied as a reaction catalyst, but, a side reaction between catalyst …

The Electrochemical Product Of Sodium Meta Periodate, John Joseph Mooney

Theses

An investigation of an electrolytic cell utilizing a nickel anode in alkaline solution for the production of sodium meta periodate from sodium iodate was conducted. The problem was to find an improved method of producing the salts of periodic acid.

The test conditions of cell operation were varied, i. e., temperature, concentration, hydrogen ion concentration, current density and the physical dimensions of the electrolytic cell. The optimum conditions cell operation were found to be a temperature of 21°C, a concentration of 0.10 grams per milliliter of sodium iodate, a pH of 13, current density of between 32 and 42 milliamperes …

Fugacity Coefficients Of Gases In Binary Mixtures, David W. H. Roth

Theses

Fugacity coefficients of components in gaseous mixtures have been calculated by a method proposed by Joffe which is based on the use of generalized thermodynamic functions, and on Kay's rule for definition of the pseudocritical points of a gaseous mixture. The method should be applicable to compounds which can be correlated by the theory of corresponding states.

The method was tested by application to 255 experimental points comprised of four gaseous systems, and included Argon-Ethylene, Hydrogen - Nitrogen, Methane - Ethane, and Methane n Butane. Thermodynamic functions from two recent generalized correlations, that of Pitzer et al., and that of …

Power Requirements For Agitation In Fully Baffled Vertical Cylinders, Leo Francis Ryan

Theses

The decrease in power number with increasing Reynolds number sought in this thesis was observed. However, the majority of the data is not an indication of this phenomenon. Only with a relatively high ratio of turbine diameter to vessel diameter could a power number fall-off be obtained. The power number fall-off thus appears to be dependent upon this ratio of turbine diameter to vessel diameter. When the power number fall-off was evidenced, a deep vortex existed despite the presence of full baffling, and large quantities of air were entrained by the liquid.

Even after applying pseudo corrections for both entrained …

Thermodynamic Properties Of Methyl Isobutyl Ketone, Lionel James Sirois

Theses

The thermodynamic properties of methyl isobutyl ketone (4-methy1-2-pentanone, hexone) have been determined for the saturated region from 32°F to the critical temperature, 569°F. Properties in the superheated region were determined for temperatures from 200°F to 2000°F and over a pressure range from 5 psia to 1000 psia. Enthalpies, entropies, and specific volumes are reported for both phases where applicable. The datum point for all calculations was zero enthalpy and entropy for a unit mass of saturated liquid at 32°F and 0.083 psia.

Pressure-volume-temperature relations were predicted using the equation of state of Martin and Hou.⁽⁶⁾ This equation of state …

Absolute Viscosity Of The N-Paraffin Liquids, Gerald Permutt

Theses

The absolute viscosity of the normal paraffins C₅H₁₂ to C₂₀H₄₂ was studied to determine a relationship more useful in predicting liquid viscosities than existing correlations such as the methods of Andrade, Souders, Thomas, and Doolittle.

It was found that a function of corresponding liquid states could be designed which related viscosity to the number of carbon atoms. This function, here called liquidity, is defined as the extent to which a substance exists as a liquid with respect to temperature. This function can be expressed mathematically as:

L_c = (t - t_m)/(t …

Correlation Of Maximum Air Velocity With Angle Of Installation For Wire Mesh Mist Eliminators, John Lawrence Reid

Theses

Wire mesh entrainment separators were installed in a vertical cylindrical column at varying angles from the horizontal. With a fixed liquid loading, air flow rates were varied in order to determine the maximum capacity of the mist eliminator for any given angle of installation. Mist eliminators studied were 4" thick and constructed of 0. 011" diameter Type 304 stainless steel wire with a density of 12 lbs. per cubic foot and 5 lbs. per cubic foot.

For normal installations of mist eliminators in the horizontal plane, the following equation is used to determine maximum allowable design capacity:

V = K …

Single Particle Crushing Of Glass, John Boyd Painter

Theses

An investigation was made to determine the relationship between new surface formed and energy input in the slow compression crushing of single glass particles at levels of high energy input.

Particle geometry, as represented by various sized hollow and solid cylinders, showed no effect on the energy-area relationship obtained.

Using an average particle size relationship as a measure of surface area, a definite relationship was found to exist between the new surface formed and the energy input for the slow compression crushing of glass.

Surface area measurements were attempted by employing gas adsorption techniques using a continuous flow method. This …

Behavior Change Through Training, Robert Walter Messerschmidt

Theses

This thesis represents an investigation of attitude and behavior change as a result of human relations training, The elements of heredity and environment are proffered as a basis for attitude and behavior formation. It is denoted that these elements are also instrumental in subsequent development of adult behavior.

As noted in the literature, the term "individual differences" embodies the effect of virtually unique heredity and environmental conditions to which each person is exposed. These differences are also partly determined by the growth in developmental trends, which varies from individual to individual and from time to time.

The existence of individual …

A Course Of Study In Woodworking For The Art Education Student, John Stolz

Theses

Not Included