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The Kinetics Of The Reaction Of M-Nitrobenzyl Bromide With Hydroxide Ion In Aqueous-Aprotic Solvent Mixtures, Ramesh Nagindas Sheth

Masters Theses

"The reaction between m-nitrobenzyl bromide and sodium hydroxide in homogeneous aqueous dioxane and aqueous tetrahydrofuran media was studied.

The product of the reaction was identified by infrared, gas chromatography and chemical tests as m-nitrobenzyl alcohol.
The kinetics of the reaction are second order with practically no variation in the rate constants as the % of the organic solvent was changed in the medium. This seems to imply hydrolysis of the organic halide by a process involving both bond-breaking and bond-formation in the transition state.
The activation energy, measured in 50% aqueous dioxane, between 20⁰ and 69.5⁰C at 5 different temperatures, …

An Investigation Of Consolidation On Compacted Partially Saturated Clarksville Soil, Ma-Tai Matthew Chen

Masters Theses

"The Terzaghi theory of consolidation and the assumption of his theory, pore pressure and effective stress, secondary compression and rheology were all reviewed and discussed. Eight compacted unsaturated samples made from Clarksville silty clay (CL) under different compaction efforts and moisture contents were subjected to consolidation load increments. Each load increment was maintained for 24 hours. An extra compacted sample was loaded for one month to investigate secondary compression.

From e-p curves, five settlement vs. compacted embankment height curves were derived for different compaction effort and moisture contents. These curves may be of practical use, when checked by field measurements …

Ecology And Distribution Of Foraminifers Of A Traverse In The Northwestern Gulf Of Mexico, Faiz Nassir Thomas

Masters Theses

"Foraminiferal populations have been analyzed from five bottom samples along a traverse in the northwestern Gulf of Mexico, approximately 27⁰20' to 97⁰15' north latitude and 97⁰20' to 97⁰05' west longitude. Eighty-eight species and twenty-nine genera, belonging to eighteen families, were recorded. Species were identified and described.

Statistical studies indicate that probably five benthonic foraminiferal depth facies could be recognized in the area at the following approximate depths: 4 fathoms, 4-8 fathoms, 8-12 fathoms, 12-16 fathoms, and 16-20 fathoms. Determination of facies is based largely on the range of species. The frequency distribution of species of foraminifers was plotted against change …

A Numerical Method For The Solution Of Cylindrical Shell Structures, Chen-Jow Hsiao

Masters Theses

"Many studies and analyses of shell structures to date have been either so complex and laborious as to preclude their application in practical design problems or so approximate, because of basic assumptions, as to limit their scope of application. Hence, a method of shell analysis which is convenient to use, reasonable in its results and general in its application is really needed. It is the purpose of this study to supply such a method of analysis.

In this investigation it is proposed to replace the shell structure which has an infinite number of degrees of indeterminancy with an analogous framework …

A Mathematical Study Of Voigt Viscoelastic Love Wave Propagation, David Nuse Peacock

Masters Theses

"This research is a mathematical investigation of the propagation of a Love wave in a Voigt viscoelastic medium. A solution to the partial differential equation of motion is assumed and is shown to satisfy the three necessary boundary conditions. Velocity restrictions on the wave and the media are developed and are shown to be of the same form as those governing the elastic Love wave"--Abstract, page ii.

The Anodic Oxidation Of Crotonic Acid In Basic Solutions, Richard C. Porter

Masters Theses

"The purpose of this study was to investigate the anodic oxidation of crotonic acid in basic solutions. Potassium hydroxide solutions of pH 12.3 and KOH-K₂CO₃ solutions of pH 11.5 and 10.5 were used. The investigation was carried out on platinized-platinum anodes at 80°C.

Experimental studies were conducted to determine the effects of crotonic acid concentration, pH, and temperature on the current. Faradaic efficiency was determined by analysis of CO₂ produced and was approximately 100 per cent.

The results were interpreted in terms of a mechanism having the following characteristics:

1. The first electron transfer is the rate …

Two-Dimensional Seismic Model Studies, Joong Hee Chun

Masters Theses

"The purpose of this research was to design and construct apparatus suitable for two-dimensional seismic model studies.

A new technique for two-dimensional seismic model testing was devised which allows wide application of the equipment. This enabled the author to place the source and receiver in any desired position on the model, thereby permitting the recording of seismic events as function of distance and depth at any position

Two simple geometric models were tested to demonstrate the experimental range of the apparatus designed. The recorded data were compared with theoretical predictions and were found to be in good agreement"--Abstract, page ii.

An Economic Base Study Of Paris, Illinois, Charles E. Womack

Masters Theses

No abstract provided.

Nucleate-Boiling Heat Transfer To Water At Atmospheric Pressure, H. D. Chevali

Masters Theses

"The purpose of this investigation was to study the hysteresis effect, the effect of micro-roughness and orientation of the heat-transfer surface, and the effect of infra-red-radiation-treated heat-transfer surfaces on the nucleate-boiling curve.

It has been observed that there exists no hysteresis effect for water boiling from a cylindrical copper surface in the nucleate-boiling region over the range studied. The nucleate-boiling curve has been found to be independent of micro-roughness and orientation of the heat-transfer surface. There was no detectable change in the nucleate-boiling characteristics of the heat-transfer surface when the surface was treated with infra-red radiation"--Abstract, page ii.

Absolute Soft X-Ray Dosimetry For Radiation Chemistry Studies, Howard Sajon Joyner

Masters Theses

"A homogeneous, variable plate separation ion chamber consisting of a polyethylene body and employing flowing ethylene as the cavity gas has been designed and tested for the specification soft x-ray (<75kV) energy deposition in typical hydrocarbons. The variable plate separation feature provided primary data on the differential specific ionization originating within the cavity gas occupying the effective collector volume which is independent of inherent chamber inhomogeneities associated with the electrically conducting films comprizing the chamber electrodes. These data demonstrated that charged particle equilibrium is established within the first few ten thousandths of an inch in typical solid hydrocarbons irradiated with this class of sources. Comparison of this type of chamber with a fixed plate separation, static cavity gas mode of operation showed that the latter may predict dose rates with inherent errors exceeding 100%. With the quality of electronic readout accessories presently available, the variable plate separation chamber yielded dose rate data exhibiting a probable error of 3.8 percent (plus the unknown uncertainty in the literature data on the energy required to form an ion pair), and an ultimate limiting error of less than 2 percent appears feasible"--Abstract, page ii.

Anodic Dissolution Of Lead In Aqueous Solutions, Christopher Kuo-Chieh Wu

Masters Theses

"The apparent valence of lead was determined in one normal solutions of potassium nitrate, ammonium acetate, lead nitrate, and lead acetate at temperatures of 25 and 50°C. The current density was varied from 0.001 to 1.00 amp•cm ^-2. The apparent valence of lead ranged between 1.90 and 2.00 in all solutions. The lower valences were reached at higher current densities. The amount of disintegration was very small, and was dependent upon film formation on the surface of the anode.

Potential-current density relationships for the anodic dissolution of lead were obtained in the electrolytes mentioned above. In potassium nitrate and …

An Investigation Of Failure Patterns Of Layered Specimens Loaded In Uniaxial Compression, Narendra Y. B. Choudary

Masters Theses

"Uniaxial compressive strength for two and three-layered specimens was obtained with different thicknesses of layers and also for different length to diameter ratios. The fracture and failure pattern was studied. Shear and extension fractures were observed in the layers. Geometry and end conditions of the specimen had a great influence in the failure and fracture pattern.

The uniaxial compressive strength of a layered specimen was found to be lower than the weighted average strength and either low or high when compared to the arithmetic average strength, depending on the ratio of the heights of the layers. The compressive strength of …

Measurement Of The Velocity And Temperature Profiles Of Air Swirling Through A Conical Shaped Nozzle, Stephen Abner Thompson

Masters Theses

"A study was conducted to determine the velocity and temperature distributions in swirling flow of air through a converging nozzle. Radial traverses were taken at three axial positions with a specially designed pitot tube constructed of hypodermic needles. The most significant finding was the large magnitude of the radial velocity component. A combination of reversed axial flow along the nozzle axis, and an outward flow near the nozzle surface was also experienced. An increase of temperature with increasing radial position may be attributed to the Ranque-Hilsch effect"--Abstract, page ii.

Empirical Evaluation Of The Eccentric Orifice In Small Diameter Pipes, Gary A. Hinz

Masters Theses

"This investigation has taken different orifice sizes (0.3005", 0.4000", 0.5045", 0.6015") and tested their flow characteristics when used in a 1" diameter pipe. Each orifice was initially placed in a fully eccentric position, that is the circumference of the orifice was placed tangent to the inside circumference of the pipe. Data was taken with the orifice eccentric to concentric in increments of 0.050".

Plots of flow coefficient versus Reynold's number were made for each position of the four orifices tested.

Empirical equations were developed for determining the flow coefficient of the various orifice sizes placed in any eccentric position.

It …

Calibration Of An Instrument To Calibrate Accelerometers, Nader Khorzad

Masters Theses

"The purpose of this research was to calibrate an instrument with which an accelerometer could be calibrated accurately. The instruments used were a piezoelectric shaker and a modified Michelson interferometer together with necessary electronic equipment. This equipment was used to calibrate a Kistler Model 808A accelerometer.

Weight was added to the shaker in the second part of this experiment in order to determine its effect on the amplitude and frequency of oscillation of the shaker.

Results show that this instrument may be used to calibrate an accelerometer quite accurately. The weight added to the shaker will effect only the amplitude …

Fluid Flow In Pipes Of Rectangular Cross Sections, Bruce Harold Bradford

Masters Theses

"Head loss due to fluid friction was measured in smooth conduits of rectangular cross section. The data covers the laminar and turbulent range. Results were compared with previous theoretical and empirical data.

The customary practice of calculating head loss in non-circular conduits by use of the friction factor obtained on an “equivalent” circular pipe was discussed. It was found that this practice is successful in square cross sections undergoing turbulent flow. In laminar flow, however, this method is not accurate"--Abstract, page ii.

Geology Of The Acari Iron Mining District Arequipa, Peru, Raul Alejandro Zevallos

Masters Theses

"The Acari Iron Mining District, part of a tilted uplifted fault block, comprises an area about 300 square kilometers, in the southern part of the coastal belt of Peru. It is in the foothills of the western range of the Andes and it is dominantly formed by granodioritic and granitic intrusive rocks which belong to the Andean batholith of Cretaceous-Tertiary age. The intrusive rocks are overlain by a central, elongated, northwest trending band, of metasedimentary and volcanic rocks

The magnetite deposits of Acari district are long, dike-shaped bodies, which fill two systems of fractures in the granodiorite intrusive, located in …

An Ac Method Of Measuring The Conductivity Of Dielectric Liquids., Henry E. Fischer

Masters Theses

"The problem undertaken in this thesis is the presentation of a method of measuring the conductivity of dielectric liquids in which the liquid is used as the parallel tank circuit of a modified Wien-bridge oscillator. The main advantage of this method is that the frequency of the voltage applied to the liquid can be varied by simply varying the oscillator frequency. This allows the selection of a frequency which is best suited to the liquid in regard to polarization and relaxation time.

An oscillator was designed, built and used in the laboratory to measure the conductivity of the dielectric liquids …

Analysis Of Time-Varying Linear Multipole Filters With Sampled Nonstationary Random Inputs, Ming-Chwan Chow

Masters Theses

"In this thesis an analytical method is developed to determine an optimum time-varying linear filter in order to satisfy the following specifications. The filters are of sampled data multipole form with n inputs and m outputs. The signal of each input is a member of a nonstationary random process, and the signal is corrupted by stationary noise.

The statistical optimization theory developed by Wiener is extended to a linear time- varying filter with nonstationary input. Correlation functions are defined for nonstationary ensembles. The mean- square error is calculated in terms of these correlation functions. By minimization of the mean-square error, …

Heat Flow In The Boss Deposit Of Missouri, Don Stainbrook

Masters Theses

"Values of heat flow through a Precambrian mineral deposit were determined in the Boss area of Missouri, where 350 meters of Paleozoic sedimentary rocks overlie a complex series of rhyolite flows which have been altered and contain a copper bearing magnetite deposit. Geothermal data were obtained from a closely spaced grid of 17 diamond drill holes penetrating to depths of 1000 meters below ground surface. Temperature measurements were made at 5 meter intervals in the Precambrian section of all holes. These and thermal conductivity measurements made on representative core samples from 300 to 400 meters below the top of the …

A Periodic Dielectric Rod Antenna, Robert C. Peirson

Masters Theses

"The periodic dielectric rod antenna structure under consideration consists of identical dielectric rod sections of radius a meters situated on a common axis. These sections are of length 1₁ meters and are separated in free space by distance 1₂ meters.

Field analysis employing Floquet's theorem, in terms of the exemplary TM₀₁ circular mode, gives expressions for the various field components and an eigenvalue equation. Digital solution of this eigenvalue equation establishes the location of propagation bands as a function of frequency. Such bands are characteristic of any periodic wave guiding structure."--Abstract, page ii.

A Method For Approximating A Specified Impulsive Response, Charles A. Gross

Masters Theses

"Given a system's time response, y(t), to a unit impulse, a method is presented by which an approximating function y*(t) may be determined. It is inherent in the method that the transform function Y*(s) is rational. The poles of the approximating function are found from the coefficients of a difference equation, which is made to fit the given data in a least mean square error sense. The zeros are determined by a procedure based on the fact that at a given time the given function and its approximate derivatives are known. Accuracy and implementation of the method are investigated primarily …

The Effect Of Non-Linearity On A Frequency-Modulated Wave, Tzu-Tien Hung

Masters Theses

"A method is presented for finding the effect of a nonlinear characteristic of a device on a wave which is frequency modulated by only one sinusoidal modulating wave. The distortion in the output has been found by passing a frequency-modulated wave (which is represented by a summation expression for the spectrum components) through a non-linear circuit having a Fourier series represention of its Characteristic. Two cases have been considered: (1) a nonlinear output-input characteristic, and (2) a non-linear amplitude-frequency characteristic"--Abstract, page ii.

Some Effects Of A Non-Uniform Specific Charge Upon Space Vehicle Parameters, Geary L. Leger

Masters Theses

"An equation is derived for the space-charge-limited current of an ion beam when there exist n different species of ions in the beam. The combined effects of non-uniform specific charge and space-charge-limited conditions upon thrust, propellant flow rate, and payload ratio are studied, and a graphical investigation and interpretation is made.

This thesis will show that: (1) The existence of multiply ionized species in an ion beam will increase the space-charge-limited current over that expected in a beam composed of purely singly ionized ions, (2) the thrust produced by the ion beam is independent of the non-uniform specific charge distribution, …

An Investigation Of The Maturation Of Articulation Of Elementary School Children, Thomas D. Marshall

Masters Theses

The Background and Purpose of the Study

Introduction

Developmental studies of speech (12, 13, 24) have indicated that the growth of articulation skills in children follows a definite pattern, with the vowels being first mastered, then the consonants, and finally, the consonant blends. Studies generally agree that the normal child acquires essentially adult articulation by eight years of age. It may be expected, then, that in the early elementary grades, immature articulation skills are not unusual in normal children, and that at higher grade levels, immature articulation skills are relatively less common. Mills and Streit (11), in a survey of …

Interests, Attitudes And Personality Patterns Of Undergraduate Students In Speech Pathology And Audiology, Sandra Mary Henderson

Masters Theses

Chapter I

The Problem and Its Background

Introduction

Over the past several decades there has been increasing interest in the occupational choices of men and women, and the interests and attitudes associated with various professional groups. Since occupations are becoming increasingly more specialized, employers and educators have found that those people who perform best in the position of their choice are those who exhibit certain interests and attitudes with regard to their occupation. Colleges emphasize the necessity of counseling in order to enable students to effectively choose general areas of concentration. The fields of study chosen by students are a …

Negligence In The Operation Of Business Aircraft, Daniel J. Garber

Masters Theses

Introduction

Basis for Business Aircraft

The use of airplanes as a production tool for executives and supervisory personnel by business firms in practically all fields of endeavor is ever increasing. This is true even though the airlines have largely substituted pure jet aircraft for piston powered airplanes and turbo-propelled ships on the trunk routes. This makes it more difficult for the business aircraft to save the executives of a company time and money by cutting down transportation waste in obtaining more hours of usefulness from those persons using business aircraft transportation and less expense for employee's hotel, meals and other …

The Utilization Of Artillery And Mortars As Infantry Support Weapons In The Chaco War, Charles John Goodall

Masters Theses

I. The Background of the Conflict

In the summer of 1932, while the world's attention was focused upon Japanese aggression in Manchuria, a border skirmish in the upper reaches of the Plata valley ignited a conflict which could not be extinguished by the good offices of the Pan-American Union or the peace-making machinery of the League of Nations. The prize in question, nearly one hundred and fifty thousand square miles of savanna and swamp, would be minuscule in comparison with the territorial acquisitions of the dictators of that era, but to the two politically unstable and highly nationalistic nations contesting …

United States Dollar Diplomacy In China During The Taft Administration, In Suk Ro

Masters Theses

I. Introduction

The fundamental aims of a nation's foreign policies are national security and the achievement of national objectives through diplomacy. At different periods in American history, the foreign policy of the United States has been designed to advance a variety of aims. It is possible, for example, to speak of missionary diplomacy, moral diplomacy, military diplomacy and dollar diplomacy. The latter characterizes one phase of economic foreign policy in which the administration of President William Howard Taft represents a dramatic turning point. The foreign aid programs of the period after World War II, such as the Marshall plan and …

The Resource Base For Water-Oriented Recreational Areas In Coles And Cumberland Counties, Roger J. Barry

Masters Theses

No abstract provided.