Digital Commons Network^™

Computer Solutions To Depletion Drive Hydrocarbon Systems, Tu Kao Chen

Masters Theses

"Three computer analyses of oil production by depletion drive have been developed. These analyses, Tarner's method of depletion drive oil production prediction, depletion drive performance productions of Schilthuis, and depletion drive calculations by a finite difference material balance, have been programmed for computers having Fortran IV compilers and a minimum of 40 K bytes of core storage capacity. Modifications have been incorporated in the last two techniques for (a) constant volume injection of produced gas, (b) the presence of a gas cap, (c) gas-cap injection of produced gas volumes, (d) varying water encroachment and production, and/or, (e) varying sweep efficiencies …

The Recovery And Characterization Of Organic Micropollutants From Missouri Subsurface Waters, John Warren Smith

Masters Theses

"The main objectives of this investigation were the recovery and partial characterization of organic micropollutants from Missouri subsurface waters and the evaluation of the number of filters in series required for effective removal of organic materials from water using the Carbon Adsorption Method.

The organics were recovered from a spring and two deep wells using three large capacity (1. 5 cu. ft.) activated carbon filters in series. Chloroform and ethanol were employed as primary elutants, but acetone and benzene were also investigated. Characterization was by organoleptic, chemical, and biological determinations, toxicity measurements, and solubility partitioning.

Organic materials were found in …

Stresses In A Thick Spherical Shell, David Wayne Moore

Masters Theses

"This thesis reports a method to evaluate the stresses in a segment of a thick spherical shell. In the numerical examples loads due to thermal expansion as the shell is constrained at the free edge and a dead load acting vertically downward were considered for a shell assumed pinned but free to rotate and for a shell assumed completely fixed at the edge. A concrete shell was specifically studied but the method would also apply to a shell of any homogeneous, isotropic material"--Abstract, page i.

Convective Heat Transfer In Small Cylindrical Enclosures Heated From Below, Donald Wayne Land

Masters Theses

"Free convection in enclosed air spaces is often of prime importance in the design and analysis of panels utilizing the insulating properties of air and other gases. Previous investigations were performed on very thin air layers.

This thesis presents the results of an experimental investigation to determine the heat transfer by convection and conduction through air layers with relative sizes in terms of length/diameter ratios of one-fourth to one.

Eight cylindrical samples were tested. Four had inside diameters of 2.0 inches, and the others were 2.75 inches in diameter. Heat was transferred across the air layers by both conduction and …

Some Aspects Of Transient Flow Behavior In Artesian Aquifers And In Hydrocarbon Reservoirs Surrounded By Artesian Aquifers, Alton John Nute

Masters Theses

"An analysis of the principal theories concerning the transient movement of water in artesian aquifers and from artesian aquifers into hydrocarbon reservoirs is presented. Various analytical methods which can be applied to depict the behavior of these two types of aquifer systems are compared.

Most aquifer studies to date have been based upon the Thesis Non-Equilibrium Formula. This equation has been used to calculate the coefficients of storage and transmissibility for aquifers; to evaluate well performance; and to investigate problems concerning recharge, movement, and discharge of aquifer water. However, one problem which still remains is that of accurately predicting the …

The Separation Of Optical Isomers By Gas Chromatography, Donald Ellis Carpenter

Masters Theses

"The purpose of this investigation was to study the separation of optical isomers by gas chromatography. An optically inactive solid support was coated with an optically active substrate. Racemic compounds were used as samples. The optically active packing materials tried were d-tartaric acid, d-diethyl tartrate, sucrose, d-camphoric acid, d-camphor-10-sulfonic acid, α -methyl-D-glucoside and L-(α)-glutamic acid.

Racemic compounds that were tried included 2-butanol, 3-methyl- 2-butanol, 2-methyl-1-butanol, 2-octanol, 2-bromooctane, 2-methoxy-octane, methyl-2-bromobutyrate, and 3-methylhexane.

It was found that racemic compounds could be separated by using an optically active material for packing in the gas chromatographic columns. Racemic 2-butanol, 3-methyl-2-butanol, and 2-methyl-1- butanol were …

Quality Of Surface And Subsurface Water In A Missouri Carbonate Karst Terrain (Dry Fork, Norman, And Benton Creek Watersheds), James Chi Huang

Masters Theses

"Little is known about the effect of carbonate karst terrain on water quality in the United States. Karst topography occurs over a large portion of Missouri and over a significant part of other midwestern states. The objectives of this study were the determination of the quality of surface and subsurface water in carbonate karst terrain and the investigation and evaluation of the effect of rainfall and runoff on water quality in the Meramec Spring area, east of Rolla, Missouri, during both the dry and wet seasons over the period of one year. Water samples were collected at a large number …

A New Performance Index For Sensitivity And Energy Optimization., Mohamed Zafer Dajani

Masters Theses

"The principal aim of this thesis is to present a new index of performance which when minimized will simultaneously optimize the system energy and sensitivity function of a multivariable linear control system. With this performance index it is usually desirable to discriminate between the sensitivity factor and the energy term by weighting them differently. Two types of weighting factors are presented. Since it is not easy to minimize that performance index for all types of problems, further research is suggested to find methods of solution for such problems. Illustrative examples demonstrate the optimization process and the type of assumptions needed …

Estimation Of Regional Trends In Gravity Using Gram Orthogonal Polynomials, Stanley Dean Thompson

Masters Theses

"A computer program is presented which estimates the trend in a rectangular array of gravity measurements. It is assumed that the regional trend of gravity may be estimated by a low-order polynomial. The method of least-squares is applied to solve for the low-order polynomial which best approximates this trend. Gram orthogonal polynomials are used in the solution of this least-squares surface fit. The program is tested on a known polynomial and on some hypothetical Bouguer gravity data and found to approximate the ʺregional trend of gravity in these cases. The importance of eliminating any significant noise in the observations before …

Some Effects Of Nickel On The Microbial Population Of Activated Sludge, Virgil Eugene Carr

Masters Theses

"The purpose of this investigation was to study the effects of nickel on the microbial population of activated sludge, to establish a relationship between effluent quality and changes in microbial population, and to determine the fate of nickel applied. Five one liter fill and draw activated sludge units were fed settled domestic sewage and received constant daily nickel doses of 1-10 mg/l, and a 50 mg/l slug dose applied after 27-30 days of operation. The parameters used were the chemical oxygen demand (COD) of the effluent and membrane filtered effluent, mixed liquor and effluent total suspended solids, mixed liquor volatile …

A Study Of The Afterglow Of An R-F Excited Mercury Discharge, James A. Aubrecht

Masters Theses

"The short duration afterglow of an r-f discharge in mercury has been examined versus ground state mercury atom density and r-f power. The intensity of the 5771, 5462, 4360, 4079, 4047, 3907, 3651/56, 3342, and 3127/32Å atomic mercury lines were observed to decay as a function of time after the shut off of the active discharge. At temperatures below 333⁰K, all atomic lines decayed exponentially, and no molecular emission was observed. From 333⁰K to 423⁰K, the atomic lines were observed to decay rapidly initially, then exhibit an enhancement effect in intensity which was produced by metastable atom collisions, and finally, …

Small-Signal Impedance Of A Junction Diode At High Injection Levels, John E. Lundy

Masters Theses

"A mathematical expression for the driving point impedance of a junction diode at high injection levels is developed. To evaluate the impedance versus frequency characteristic of a diode, it is necessary to know the minority carrier lifetime as a function of injection level and doping density in the base (lightly doped) region, the junction area, and the base width. The interesting characteristic of the diode impedance at high injection levels is the inductive reactance displayed by the diode.

The expression is developed by solving the differential equation for charge flow in the base region of a diode assuming space-charge neutrality …

Analysis Of Trace Elements In River And Spring Waters, Faridoon Andeshire Namdarian

Masters Theses

"Methods for the analysis of trace elements in natural fresh waters were investigated.

Preconcentration of the water samples by reducing the volume and by using cation adsorption resins was studied. It was concluded that cation absorption was the more promising procedure.

The methods used for analysis were absorption spectrophotometry, neutron activation analysis, and atomic absorption spectrophotometry. Atomic absorption spectrophotometry was considered the most suitable method for the analysis of trace elements in waters.

Calcium, copper, lead, zinc, and cadmium were determined in a number of Missouri springs and stream water samples"--Abstract, page ii.

A Study Of The Genesis Of The Pyritic Gneiss In The Grenville Series, St. Lawrence And Jefferson Counties, New York, Dennis O'Leary

Masters Theses

"The pyrite-pyrrhotite belt is a northeast-southwest trending area about 35 miles long and three to four miles wide located in Jefferson and western St. Lawrence counties, New York, within the metamorphosed Grenville Lowland just northwest of the Adirondack massif.

Outcropping within this belt are a number of thin discontinuous quartz-biotite-oligoclase gneisses with an unusually high graphite, chlorite, and pyrite content, known as "rusty gneisses." Sulfides are concentrated in these gneisses into zones of up to 50% or more pyrite. The pyrite is granular or crystalline and is invariably accompanied by large amounts of chlorite and graphite and local minor segregations …

A Study Of The Complexes Of Diketocyclobutenediol, Stewart Michael Condren

Masters Theses

"In this study of the complexes of diketocyclobutenediol, squaric acid, the following original compounds were prepared: zirconyl squarate, indium (III) squarate; titanium (III) squarate, ruthenium (III) squarate, tungsten (VI) squarate, vanadium (III) squarate, and niobium (V) squarate, where squarate refers to the dianion of diketocyclobutenediol. Metal analyses were made on all of these except the ruthenium. However, only three of these metal analyses, namely those for titanium (III) squarate, indium (III) squarate, and zirconyl squarate, warrented [sic] further investigation. Carbon and hydrogen analyses were then made for these three compounds. From the percentage compositions, possible structures were proposed.

The tungsten, …

Characteristic Impedance Of Open Microstrip Transmission Lines Having Finite Thickness And Multiple Dielectric, Philip Julian Carter

Masters Theses

"A computer program is provided for determining the characteristic impedance of microstrip transmission lines having finite thickness. Infinite and finite ground planes are incorporated into the program. The programmer need only supply information in the form of a data card. This procedure is clearly outlined.

Graphical solutions of characteristic impedance for multiple dielectric microstrip transmission line problems are obtained using a discrete resistive analogue. Computer network analysis programs are viewed as having several advantages not possessed by the physical resistive analogue"--Abstract, page 2.

Collision And Pursuit Course Terminal Closures For Spacecraft To Satellite Rendezvous, John Anthony Campbell

Masters Theses

"Collision and pursuit course closure maneuvers were studied for correcting position and velocity errors in the terminal phase of spacecraft to satellite rendezvous.

Minimum values of the ratio of initial range to velocity necessary to achieve rendezvous were determined for collision closures as a function of the initial line of sight. The time and velocity increment required for rendezvous were computed as a function of initial conditions.

Pursuit closure maneuvers were analyzed and time and velocity increments defined as a function of initial range, closing velocity, line of sight angle and angular velocity.

The velocity increments required were significantly higher …

Preparation And Spectra Of Some New Alkyl Ammonium Salts Of The Tetrachlorocuprate (Ii) Ion., Paul Douglas Griffin

Masters Theses

"Several compounds containing the complex tetrachlorocuprate(II) anion, CuCl₄⁼, and various alkyl or aryl cations were prepared. These include bis(methylammonium)tetrachlorocuprate(II), bis(isopropylammoniumtetrachlorocuprate(II), 1,3-propanediammoniumtetrachlorocuprate(II), bis(furfuryl-ammonium)tetrachlorocuprate(II), and a series of ethylene ammonium salts. Some unsuccessful and difficult preparations are described. Spectra were taken in acetone, 4-butyrolactone, and methanoleaf An explanation of the effects of various solvents on the absorption spectrum and structure of the complex ion is given"--Abstract, page ii.

A Petrofabric Study Of The Iron Ore Of Benson Mines, Star Lake, New York, Remo Antonio Masiello

Masters Theses

"The petrofabrics of the host gneiss silicates and Ovate ore grains were studied in thin sections of oriented specimens collected from widely scattered positions in the iron ore deposit at Benson Mines, New York.

Ten oriented specimens selected for petrofabrics study were comprised primarily of feldspar, quartz, garnet and ores, with lesser quantities of biotite and sillimanite. Petrofabric diagrams were prepared for the orientation fabrics of magnetite and biotite in eight of the ten specimens, but sillimanite and quartz were sufficiently abundant for fabric determination in only three specimens. Duplicate thin section and perpendicular sections were utilized to check the …

A Comparison Of Friction And Drum Hoisting Systems On An Energy-Input Basis, Hemendra Nath Kalia

Masters Theses

"The purpose of this thesis is to provide a suitable basis for comparing the relative advantages of the friction and drum hoists under various conditions of operation.

Such comparisons are mainly and necessarily based upon physical characteristics of the mechanisms for lack of appropriate economic data. It is believed, however, that this inadequacy may be alleviated to some extent by substituting comparative theoretical energy requirements of' the two hoisting systems under identical duty conditions over a practical range of mining situations involving various depths and daily productions.

This has been accomplished by adapting a computer to standard mine-hoist design techniques …

A Determination Of The Rate Of Evaporation Of Zinc At Atmospheric Pressure., Yu Ming Su

Masters Theses

"Measurements of evaporation rates of zinc in three different residual gases, e.g., argon, carbon monoxide, and hydrogen at one atmosphere pressure, were made. It was found that the rate of evaporation of zinc in one atmosphere of argon was almost the same as that in carbon monoxide, while the rate in hydrogen was almost twice the rate in argon or carbon monoxide. Measurements of evaporation rate of zinc in one atmosphere of argon-oxygen mixtures were also made. The evaporation rate was considerably reduced because the formation of the oxide film retards the zinc vapor escaping from the evaporating surface"--Abstract, page …

Film Boiling From Horizontal Plates With Low Thermal Capacity, K. M. Ragsdell

Masters Theses

"The object of this investigation was to obtain data for saturated film pool boiling from a low thermal capacity flat plate at atmospheric pressure. A test plate, constructed from resistance strip, was placed horizontally in a pool of liquid, and was heated electrically. Refrigerant-11 and nitrogen were used as the boiling liquids. Heat transfer results were obtained in both fluids over a temperature range of approximately 1200F⁰ (400-1600⁰F). Surface size, roughness and orientation effects were observed for flat horizontal heated surfaces with one dimension near the most dangerous wavelength. No surface material effect was observed. Excellent correlation of the data …

Studies In Coprecipitation Of Trace Amounts Of Elements, Gerald Delano Schucker

Masters Theses

"A new approach to preconcentration of trace amounts of elements has been demonstrated whereby traces of metals tied up as chelates are coprecipitated on a column of solid organic material. Complete coprecipitation was found to occur within very narrow pH ranges, thereby allowing separation as well as concentration of the elements by careful adjustment of acidity and concentration of chelating agent. The separation is based on the difference in stability constants of the metal chelates. Preliminary studies with different physical forms of the carrier precipitate, indicate adsorptive processes could play a significant role in the mechanism of the column-coprecipitation process. …

Shutdown Reactivity Worth Of Reactor Control Rods By A Subcritical Multiplication Method, Leslie Roger Conner

Masters Theses

"Two modified subcritical multiplication methods for measuring the reactivity worth of control elements were developed and investigated. The first involved the calibration of a subcritical count interval by the asymptotic period method. The second involved the calibration of a subcritical count interval by a rod interchange with the reactor regulating rod which had previously been calibrated by the asymptotic period method. The accuracy of these methods is relatively poor. this inaccuracy is due to shadowing effects and to the spatial harmonics which exist in the core. An investigation of the spatial harmonics to determine the best location for the neutron …

Compressive Creep Of High Alumina Refractories, Vernon Lee Burdick

Masters Theses

"The deformation of refractory materials consisting of 90% sintered or fused alumina plus 10% silica was measured at temperatures from 1450 to 1515⁰C and a compressive stress of 100 psi. Creep rates and activation energies were determined from the steady state portion of deformation vs. time data and correlated with the mineralogical composition. Supplemental measurements included x-ray diffraction, electron probe microanalysis, apparent porosity and tensile strength. conditions having an important effect upon the mineralolgical composition were: (1) duration of heat treatment, (2) amount of sodium oxide impurity, and (3) reactivity of the alumina grain. Prolonged heat treatment and sodium oxide …

A Study Of The Molecular Emission And Of The Life Times Of The Metastable States In The Afterglow Spectrum Of A Mercury Discharge, Bruce M. Whitcomb

Masters Theses

"Two methods of studying the spectrum in the early afterglow of a pure mercury sample are discussed. Using a time-sampling technique, information about the intensity of the spectrum as a function of time in the afterglow can be obtained. The intensities of two molecular bands, centered at 3350A and 4850A, are studied. The method of formation of the diatomic mercury molecule and the emission of radiation in the two bands are shown to be density dependent. Mechanisms are presented which explain both the molecular formation and the radiation in the two bands. In an absorption study, the half-lives of the …

A Class Of Pattern Recognition Machines, Shaw Yih Chung

Masters Theses

"The classification of signals through the use of pattern recognition techniques may be viewed as a statistical classification problem since at least some pattern classes are analog signals which have been contaminated by additive noise. In order to represent these signals at the input of a pattern classifier they are sampled and a vector and an m-dimensional vector space used to describe the pattern. Consequently, these pattern samples are processed to determine the parameters of the statistics. In this study the additive noise was assumed to be Gaussian in nature. This study was based on a priori knowledge of the …

Synthesis Of Filters Using Distributed Rc Networks, Mario Nader Nader

Masters Theses

"This paper deals with the problem of realizing filter and delay functions by means of distributed RC devices. The method is made possible through the use of a distributed RC network which possesses rational admittance parameters. The technique of approximating transfer functions using polynomial factors that are ration in e[superscript (a square root of s] is explained. These factors are used to approximate the magnitude and phase characteristics for a low-pass filter. This filter is then realized using the admittance functions studied by Wyndrum, the "s->W" transformation, and Richard's theorem. Those factors are then used to approximate high-pass and …

A Study Of Film Boiling Of Liquid Nitrogen And Liquid Argon Over A Wide Pressure Range With Cylindrical Heaters, V. J. Flanigan

Masters Theses

""A film boiling heat transfer study was conducted with three different diameter cylindrical copper heaters over a wide range of pressures for nitrogen and argon with the heat transfer surface in the horizontal position. The data were compared to the commonly used film boiling heat transfer relations. The common relations were found to be considerably in error for the range of variables covered in this investigation. A semi-empirical equation for corresponding states fluids which correlates the available data as a function of the reduced temperature and reduced pressure was derived and discussed"--Abstract, page iii.

Hydrologic Characteristics Of Shallow Bedrock Aquifers In The Vicinity Of Norman Creek, Central Phelps County, Missouri, Michael A. Nawrocki

Masters Theses

"Groundwater is becoming increasingly important as a source of water supply in the United States. Consequently, the prediction of well yields is a vital concern. In order to predict the quantity of water which can be reduced from a given aquifer it is necessary to know the aquifer's hydrologic characteristics. Many theoretical formulae have been derived for determining the aquifer characteristics. To date, these formulae have been tested mainly on unconsolidated and clastic rock aquifers. It has never been shown that these formulae can also be consistently applied to carbonate aquifers which underlie regions of karst terrain. This paper summarizes …