Digital Commons Network^™

Mechanism Of Solvolysis Of 3-Methyl-2-Butyl Brosylates., Luu Le Nghi

Masters Theses

"The brosylates of 3-methyl-2-butanol and it's a-d₁-, ß-d₁-, B-d₃-, and S-d₄- analogs have been synthesized. The solvolytic rate data for these compounds were determined. The solvolytic products in 70% (vol.) ethanol-water have been identified by flame ionization gas chromatography using a Carbowax 20M column. The amount of each product was measured by integrating the peak areas from the chromatograms. By analyzing the isotope effect data, the rate determining step is shown to be the formation of the hydrogen bridged ion pair intermediate. By evaluating the GC-mass spectral analysis of the isopentenes, a …

The Investigation Of Video Sensitivity And Data Processing Errors Encountered In An Airborne Receiver, James Lee Hamilton

Masters Theses

"The investigation of video sensitivity and both biphase demodulation and Doppler shift processing errors is performed. The effect of pass band ripple on the noise bandwidth of two pole filters is developed. The effect of feedback on the effective noise figure of a high gain IF (Intermediate Frequency) amplifier is investigated and discussed. An analysis of a limiting amplifier-biphase demodulator circuit is attempted. A computer simulation of this same circuit is also performed and the results are compared to measurements taken in the laboratory. With respect to multipath corrupted input signals, a differential phase shift keyed biphase demodulator is shown …

The Control Of Noise In Urban Areas., Edwin Eugene Frye Jr.

Masters Theses

"Noise has recently been labeled the 'fourth pollutant' and defined by some as the 'unwanted sound' that pervades our work environments and the privacy of our homes. This concern for noise and its effects has resulted from our nation's increasing population density, the increasing use of mechanized conveniences, the influx and growing use of mass transportation systems, and the public's awareness that noise not only 'annoys' and can increase everyday tensions and anxieties, but at certain levels can cause permanent hearing loss.

In order to curb the 'noise problem' legislators and municipal representatives began applying legal controls to noisy activities …

Amine Flotation Of Feldspar From Magnetite Concentrate., Gary William Hudiburgh Jr.

Masters Theses

"The gangue in some magnetite ore bodies contains feldspar; the alkali content of the feldspar reduces the usefulness of these iron ores. One method of decreasing the feldspar content in magnetite concentrate is froth flotation.

The amine flotation of feldspar from magnetite concentrate was investigated using zeta potential measurements, Hallimond tube flotation tests and laboratory-scale flotation tests. The zeta potential of various feldspars (microcline, albite, anorthite, oligoclase and anorthoclase) were determined as a function of pH; the point of zero charge ranged from pH 1.4 to 2.5. Hallimond tube flotation tests using two amine reagents were conducted on the feldspars. …

Effect Of Nodule Count And Cooling Rate On The Matrix Of Nodular Iron., Subrata Sen Gupta

Masters Theses

"The objective of this investigation was to establish the relationship between the nodule count, the matrix structure, and the cooling rate through the eutectoid in nodular iron. The chemical composition of the nodular iron was held constant while various inoculation methods, inoculants, and mold designs, including chills, were used to vary the solidification time and cooling rate through the eutectoid range. This produced variations in both the matrix structure and the nodule count.

The nodule count has a power relationship with the percent pearlite in the matrix at fixed cooling rates: Percent pearlite = K (Nodule count)^-n where the …

High Density Serial Encoded Tape Systems., Billy J. Romine

Masters Theses

"A digital approach to phase lock loop design is presented. Two separate circuits are developed and analyzed. The circuits developed have certain characteristics which can be applied to serial data encoded tape systems. One of the circuits can be expanded into a multiple track configuration with a minimum amount of hardware. The second circuit features a fast initial synchronization method over a wide input frequency range.

The application 0£ the phase lock loops to the retrieval 0£ serial encoded data is investigated. Three representative data encoding methods are considered. The approximate bit density obtainable with each encoding method is calculated …

Application Of An Inverse Heat Conduction Technique To A Simulated Injection Mold., Noel Joy Rytter

Masters Theses

"An analytical model was constructed to investigate the heat transfer in an injection mold for which the temperature was controlled by a special mold heating-cooling process. Several techniques were used to test the validity and accuracy of the analytical model of the mold and to explain some singularities that occurred. It was determined that the thickness of the plastic part being molded is the primary factor affecting the minimum cycle time for the molding operation. Also, abrupt changes in temperature on the molding surfaces are very difficult to obtain because this requires drastic temperature changes for the working fluid that …

A Study Of Digital Computer Control Of A Continuous Pulp Digester., Charles Edward Barker

Masters Theses

"Detailed analysis of six basic control loops for a Kamyr continuous digester is described using z- and s- transform methods. An example of a digital computer control system for a continuous digester is also presented"-- Abstract, p. ii

Development Of A Four Channel Cloud Nucleus Spectrometer., Larry Allan Brunner

Masters Theses

"A four-channel vertical flow thermal diffusion chamber for use as a cloud nucleus counter is described. The droplets in each channel are photographically counted. The instrument provides about 20 seconds of available growth time, which enables better distinction of active droplets than does ii the conventional horizontal chamber. Droplet growth calculations show that the uncertainty in droplet count due to limited available growth time is negligible for supersaturations above 0.3% but increases rapidly as the supersaturation is lowered below 0.3%. For example, at 0.1% supersaturation, the uncertainty is -27% to +38% in the drop count. The possible error in supersaturation …

Graph Model Analysis Of Computer Structures, Ömür Taşar

Masters Theses

"Graph theory is applicable to the solving of problems in nearly every field of scientific study. The purpose of this thesis is to consider its applications in representing and analyzing digital computers. Fundamental graph theory definitions, the types and the properties of the directed graphs, the matrix representation, and several reduction techniques are discussed. The blocking gate method for diagnosing computer systems is described and applied to the Scientific Control Corporation (SCC) 650 for its fault-diagnosis.

Microprogramming has been a significant trend in hardware and software designs of computers. Microprogrammed computers are discussed in comparison to conventional computers. A general …

A Computational Method For Determining The Growth Rates Of Saline Water Drops., Robert Alexander Fletcher

Masters Theses

"A phenomenologica1 theory is presented which describes the growth or evaporation of cloud droplets containing dissolved NaCl. The main interest is in the early stages of growth. The Maxwell-Fuchs equation is employed with refinements to account for the high sa1t concentration in small droplets. A computer program is presented that ca1culates the growth time as a function of radius for cloud droplets nucleated with NaCl.

The growth times obtainable from the Maxwe11-Fuchs equation differ significantly from the growth times ca1culated using the refined Maxwell-Fuche equation for ambient relative humidities less than or equal to 100%. Growth times for droplets nucleated …

A Digital Simulation Of The Statistical Properties Of Ionospheric Scintillation, William Frederick Deckelman

Masters Theses

"This thesis shows that a bandlimited bivariate-normal time series is a useful model for the envelope of scintillating radio signals traversing the ionosphere. A software computer model is designed and its parameters varied to obtain good fits of the fade duration distribution of the time series generated by the model with that of an actual block of ionospheric scintillation data. The power spectrum of the actual time series corresponding to the in-phase and phase quadrature components of ionospheric scintillation is shown to lie between that of a first- and second-order Butterworth filter through comparison with model generated data"--Abstract, page ii.

On The Extension Of The Output Capabilities Of Flowware, A Graphical Interactive Digital System Simulator., R. Dean Delker

Masters Theses

"A research effort which addresses the problem of providing output from a register transfer level digital simulator which allows the user to better understand how his simulated system functions are described. A review of the output capabilities of existing register transfer level systems indicates that a strictly textual output leaves much to be desired, and for that reason, this work concentrates on developing forms of meaningful graphical output displays. This criterion of "meaningfulness" can be considered as a twofold objective to be reached in that the output must both reflect the functioning of the system and be presented in a …

Feasibility Study Of An Electromagnetic Trap Fusion Reactor., Dennis Gilbert Blondin

Masters Theses

"Through the use of detailed particle and energy balances, electromagnetic traps with magnetic cusps are found to be unsatisfactory for continuous operation when using only neutral particle beams to sustain a thermonuclear plasma. Low power multiplication characteristics inherent in this CTR design probably preclude supplemental plasma heating methods. However, by using an alternate Yin-Yang magnetic system, continuous CTR operating regimes are found at an ion temperature of 20 keV while assuming only neutral particle beam heating. Although these regimes require applied electrostatic potentials approaching a half-million volts, this device demonstrates a capability for efficient power production"-- Abstract, p. ii

Combined Forced And Free Convection On A Vertical Cylinder And Flat Plate, Aleksandros Mucoglu

Masters Theses

"In the study of fluid flow over heated surfaces, it is customary to neglect the effects of buoyancy force when the flow is horizontal. However, such a practice is not justified when the forced flow is along an inclined or a vertical surface, because under these conditions the buoyancy force modifies considerably the flow field and hence the heat transfer rate from the surface. Such a flow is termed combined forced and free convective flow.

The present study is concerned with the effects of buoyancy force on forced convection along an isothermal vertical cylinder and a flat plate. This type …

Magnetostrictive Aftereffects In A Dilute 50fe-50ni-C Alloy, Raj N. Master

Masters Theses

"Crystallographically equivalent interstitial sites are energetically equivalent when the host crystal is free of any fields. This situation is shown in Fig. Pl from which it may be appreciated that the difference of the free energy of the "crystal" with an interstitial "I" located in "x" and "y" sites, respectively, is equal to zero. This energy equivalence of the various interstitial sites is destroyed when the host crystal is subjected to fields such as strain fields, magnetization fields or a combination of both as may be appreciated from Figs. P2 through P4. In this case, the interstitials will preferentially occupy …

Transformer Connection Study For 138 Kv To 12.47 Kv Substations Of The Union Electric Company St. Louis, Missouri, John Glenn Walsh

Masters Theses

"This thesis examines the transformer connections that can be used in the new 138-12.47 kV substations on the Union Electric power system. The object is to determine if a zero phase shift transformer without a delta connected tertiary winding can be used and economically justified. Traditionally a delta winding has been automatically included for this application without taking engineering time and effort to study all ramifications including possible dollar savings available with other connections. Three transformer manufacturers supplied technical and cost data which are analyzed, based on Union Electric system conditions. Consideration of relaying, harmonics and unbalanced loading shows that …

Determination Of Oxygen Chemical Diffusion Coefficients In Single Crystal Strontium Titanate By Capacitance Manometry, Douglas Bugh Schwarz

Masters Theses

"The use of the tensi-volumetric apparatus to study the non-stoichiometric behavior of strontium titanate was discussed. Oxidation kinetics of reduced single crystal strontium titanate were measured with an ultrasensitive capacitance manometer as the sample absorbed oxygen in response to a changing oxygen activity.

The oxidation kinetics were found to fit a solution to Fick's second law for rectangularly shaped samples....

The procedure selected for measurement of the oxidation kinetics, and the method of obtaining diffusion coefficients from the oxidation data was discussed along with potential sources of error of the system"--Abstract, page ii.

Detection Of Impurities In Zinc Sulfate Electrolytes By Cyclic Voltammetry Techniques., Bruce Alan Lamping

Masters Theses

"A cyclic voltammetric technique has been developed for quantitatively detecting the presence of active chemical species present in zinc sulfate electrolytes. The experimental apparatus consisted of a pyrex "H" cell, an Al cathode encased in a Teflon holder, a carbon anode and a mercurous sulfate reference electrode. Voltammograms were obtained from industrial, purified neutral leach solution (Cominco Ltd., Trail, B.C.) acidified to give a final concentration of 0.77 M Zn⁺⁺, 1 M H₂SO₄. The polarization curves were then evaluated and used as a reference standard to compare with results obtained when various organic and …

Characterization And Pollutional Contribution Of Stormwater Runoff From A Small Urban Area., John Lamb Wendleton

Masters Theses

"Stormwater runoff from urban areas has long been recognized as a pollutional source, however, only in the last decade has there been an extensive eff ort to measure its effect on receiving lakes and streams. Because runoff from small urban communities has received limited attention, this investigation was undertaken to determine the quality and pollutional contribution of stormwater runoff from a small urban area. The specific objectives of the study were: to characterize and correlate runoff quality with land use activity and to qualitatively and quantitatively measure the pollutants discharged with respect to time.

Runoff from 3 test watersheds in …

The Geology And Hydrogeology Of The New Lead Belt, Missouri, Charles Scott Fletcher

Masters Theses

"In order to analyze the effects of pumping groundwater from underground lead mines upon present groundwater resources of the New Lead Belt area, the geology and hydrogeology of that area must first be determined. The primary method of investigation of this analysis was interpretation of ecologic and hydrogeologic data taken from water well logs and mineral exploration well logs, with supplemental information supplied by published and unpublished literature sources. From all these sources of data, structural contour maps of the Precambrian erosional surface; the tops of the Lamotte, Bonneterre, and Davis Formations; isopachous maps of the Davis and the Lamotte/Bonneterre …

An Economical-Digital Interface For Multiplex Recording Of Analog Signals, Samuel Knoles George

Masters Theses

"In measuring and evaluating performance of an automobile and driver combination it is necessary to record data from the vehicle and driver while both are in the field.

The University of Missouri - Rolla Transportation Research Program performs this type of evaluation. The present method of recording data in the field is with a large, bulky, and somewhat fragile strip chart recorder.

The digital recording interface described in this paper is designed to permit replacement of the strip chart recorder with an audio tape recorder. The interface will allow simultaneous recording of two analog channels which may be reproduced as …

A Comparative Analysis Of The Capabilities Of Three Stereo Radar Techniques When Operating In The Presence Of System Errors, George L. Bair

Masters Theses

"Three stereo radar techniques for producing stereo images from which topographic data and maps may be obtained are described and their performance in the presence of system errors is determined. The techniques are: an improved single flight technique which uses a combination of two antenna beam characteristics which permits terrain illumination from nearly the same aircraft position, a previously proposed single flight technique which uses two horizontal linear arrays generating vertical fan beams at different azimuth angles, and an existing two flight technique which uses a horizontal array generating a side-looking fan beam.

Error analyses are performed to determine the …

A Discrete Approach To Surface Interpolation, Jerry Lee Albert Sandvos

Masters Theses

"An equidistant spacing of two dimensional data points is a requirement of most automated analysis routines. In this thesis, a method of generating such equispaced data from randomly spaced data is developed and implemented by a set of computer routines. The method represents the study area as a two dimensional spatial array, in which each array cell represents the data value of a subarea of the study area. A routine sorts and places the data in the array. Missing values in the array are interpolated from nearest neighbors. Filtering is used to smooth errors and a contouring routine is used …

A Computerized Simulation Of A Personal Rapid Transit System., James Richard Cromer

Masters Theses

"The movement of people from an origin to a destination has become a complex and sometimes severe problem, The present modes of transportation available, which include the rapid rail systems, bus transit service, and the personal automobile, have proven quite ineffective in dealing with the situation, A new concept in the transportation area is that of Personal Rapid Transit (PRT). This concept offers a promising solution to many of our people and goods movement difficulties. Before this new system can be implemented it is necessary that various design, construction, and operational criteria be evaluated to determine the optimal system to …

A Study Of Some Heuristic Models For Predicting The Reflection From Spherical Surfaces., Bruce Wayne Rau

Masters Theses

"Four heuristic models' available for predicting the behavior or radiation Non regularly reflected from spherical surfaces have been studied. The four models include: the classical Lambert, the s-factor as deduced by Look, the Lommel-Seeliger, and the Euler's approach. Because each of these analyses was deduced for flat plate geometry, it was first necessary to integrate these flat plate expressions over the surface of a sphere to develop appropriate expressions for the power rejected from the surface of a sphere based upon e ach of the above theories. As an integral part of this investigation, various basic quantities were listed (i. …

A Solid Waste Plan For The Ozark Foothills Region Of Missouri., Don Raymond Swyers

Masters Theses

"This paper has been developed as a result of the concern over prevailing solid waste practices in the Ozark Foothills Region of Missouri. An attempt has been made to assess the present solid waste collection and disposal practices found in the Ozark Foothills Region. The analysis of the existing solid waste practices indicates that to accomplish the collection and disposal of solid waste in an efficient and sanitary manner with an acceptable level of public expenditure requires the establishment of solid waste management systems based upon cooperative programs of intermunicipal and intercounty action.

Seven alternative management systems for solid waste …

Data Acquisition And Analysis System For Computer Modal Analysis Of Automotive Exhaust Emissions., Edward Leroy Mabie Jr.

Masters Theses

"A data acquisition and reduction method for modal analysis of undiluted automotive exhaust emissions is presented. 'The procedure on which this method is based ·wa.s developed and presented in a. paper by Donald L. Stivender, in 1971, entitled, "Development of a Fuel-Based Emission Measurement Procedure." This method is presented as a. viable a.1ternative to the diluted constant volume sample by bag collection technique specified in the federal test procedure for emissions from light duty vehicles.

The instrumentation used for the acquisition of data was the type normally used for automotive emission studies. The four instruments used for exhaust gas analysis …

Regional Geological Engineering Mapping By Erts-1 Imagery A Case Study On Taiwan., Shih-Tsu Chen

Masters Theses

"Three types of maps of Taiwan were made by using color composites of ERTS-1 images. The three types of maps, consisting of a regional land use map, an offshore sediment distribution map, and a tectonic map, were made from a color composite imagery utilizing Diazo chrome and Esco chrome films with a planimetrically accuracy sufficient for a 1:1,000,000 scale map.

Color enhanced imagery was found to increase the accuracy level of the land use interpretation. Three color enhancement techniques were used to increase the color contrast between the scenes of different land use. Particular land use scenes required a special …

Study Of Techniques For Designing Large Digital Systems Interactively., Harold Dale Puls

Masters Theses

"FLOWWARE [1-4] is an interactive register transfer language based upon the concept of flowcharting. The graphic nature of the language, however, generates a few disadvantages when it is used on a large design. Changes have been made to the basic FLOWWARE package to aid the user in specifying and displaying his design. In addition, responsibility for the design has been shifted to the remote large computer to lessen the size requirement on the local minicomputer"--Abstract, p. ii