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Azeotrope Enabled Anionic Polymerization Of Ethylene Oxide Using Initiators With Different Functional Groups, Dronareddy Madugula

Master's Theses

Poly(ethylene oxide) (PEO) is a nonionic hydrophilic polymer having the same repeat unit as poly(ethylene glycol) (PEG). It is of interest in both biology and materials science. PEO surfaces demonstrate a unique lack of protein adhesion, and PEO block copolymers are widely used in applications such as drug delivery. Unfortunately, the synthesis of PEO homopolymers and block copolymers can be experimentally challenging, with a typical method involving air sensitive organometallics and the removal of compounds such as naphthalene from the final product. Here we report a synthetic route that avoids these difficulties by using azeotropic distillation to remove water from …

The Symbiotic Green Algae, Oophila (Chlamydomonadales, Chlorophyceae): A Heterotrophic Growth Study And Taxonomic History, Nikolaus Schultz

Master's Theses

The green alga Oophila ambystomatus (Chlamydomonadales, Chlorophyceae) is

well known as the symbiotic partner of Ambystoma maculatum, the yellow-spotted

salamander. Recent molecular work has revealed phylogenetic diversity within isolates of

Oophila from New England. Here I investigate physiological properties and genetic

diversity of the algal symbionts representing different evolutionary lineages. In other

well-studied symbiotic systems involving algae, e.g., Chlorella and Hydra, algae and

lichen, or Symbiodinium and Scleractinian corals, the algal symbiont is capable of

multiple trophic modes, thus influencing its capacity as a partner. In this study I

investigated whether genetically differentiated strains of Oophila are capable of

absorbing …

The Politics Of Contagion, Joseph M. Young

Master's Theses

Contagion events have occurred throughout history leaving death and destruction in their wake. Often sensationalized in movies and shows such as Contagion and The Walking Dead, contagion events are life-altering events filled with gory symptoms and elevated mortality rates. The dangers of contagion events prompted governments to develop agencies with the purpose of preventing and mitigating the risks contagions pose. The Centers for Disease Control and Prevention (CDC) and other agencies across the globe pour millions of dollars each year into eliminating the risk of contagions and making the world a safer place. However, while more resources are dedicated to …

Distorting The Life Of Maca (Lepidium Miyenii), Fabiola Tavui

Master's Theses

The supply and demand of maca (Lepidium Miyenii), a native Peruvian vegetable, increased over the past decade; however, it has recently reduced. There are many implications for this outcome. Maca, a product with several health benefits, caught the attention of not just foreign businesses and investors but also of Peruvians. As maca became highly commercialized and exported abroad, the actors involved in the maca “business” at all levels contributed to its market to prospered but also to crumble. Some of the reasons due to the exploitation of maca itself for economic gains; distorting maca’s ecological environment and relation …

Rape As A Weapon Of War In Darfur, Fardowsa Abdullahi

Master's Theses

In the Darfur conflict the Sudanese government forces and the Janjaweed have used rape as a weapon of war, in the ethnic cleansing of non-Arab tribes in the region. Rape as a weapon of war was also used to degrade, terrorize women and destroy families and communities. In Darfur women and girls were raped in front of their family members. Victims ranging as young as eight years were raped in Darfur. This research investigates rape as a weapon of war. I took a qualitative approach by examining how rape was used as a weapon of war in Darfur and by …

Phylogenetics, Biogeography, And Climate Niche Variation Of South Pacific And Hawaiian Psychotria, Elaine Zhang

Master's Theses

Why do some species have broad geographic distributions, while other species are confined to a narrow distribution? Species age, ecological niche, or dispersal traits may help explain why some insular species are abundant and found on many islands, while others are rare and restricted to one island. In this study, I inferred a robust, time-calibrated phylogeny of the Hawaiian Psychotria, using two nuclear and eight chloroplast loci, sampling 67 individuals. I coupled my phylogenetic hypothesis with climatic data, ecological niche modeling, and morphological dispersal characteristics to explain the variation in number of islands occupied by each species. My inferred phylogeny …

A Political Ecology Of Copper Production And Environmental Degradation In Zambia, Chalwe C. Mwansa

Master's Theses

Zambia has been producing copper for more than a century. Over the past three decades, the country has attracted large scale investments within the mining sector making it one the formidable destination for investment in Africa. However, the relationship between copper production and environmental degradation is intrinsically linked and further hampered by socioeconomic, political and developmental factors.The case of Zambia is used to empirically validate and authenticate how environmental management resulting from copper production has adversely affected the country. The nation's copper production was initially under private ownership in the colonial era; Post Independence, nationalization of copper production was initiated …

Comprehensive Applications Of Rice Husk Biomass, Zichao Wei

Master's Theses

Rice husks (RHs) have recently attracted high attention due to their potential for many applications, including construction materials, composite materials, adsorption materials, chemical production, and power generation. RHs are an appealing alternative because of their low cost and high silica content. So far, most researchers mainly focus on the utilization of one component (such as silica) while ignoring others. Comprehensive utilization of RH biomass and diversified products are the key goals for this research field.

In this thesis, the two main components of RHs, silica and lignocellulose, were extracted from RH biomass. The high tempered calcination served as the extraction …

Addressing The Gender Workforce Gap In The Scientific Journal Editorial Hierarchy, Nishelli Ishti Ahmed

Master's Theses

No abstract provided.

Determining The Efficacy Of Antimicrobials For The Inhibition And Inactivation Of Listeria Monocytogenes In Broth, Whole Milk, And Fresh Cheese., Sarah Kozak

Master's Theses

Listeria monocytogenes is a bacterial pathogen that causes listeriosis, the third-leading cause of death related to foodborne illness. The anti-listerial efficacy of acidified calcium sulfate with lactic acid (ACSL), beta-resorcylic acid (BR), caprylic acid (CA), e-polylysine (EPL), hydrogen peroxide (HP), lauric arginate ethyl ester (LAE), and sodium caprylate (SC) was determined in Brain Heart Infusion broth, ultra-high-temperature pasteurized milk, and fresh cheese (Queso Fresco). Binary combinations of antimicrobials were tested to identify synergistic interactions, which can reduce usage rates. Overall, HP was the most efficacious treatment with concentrations of 40-50 ppm inhibiting L. monocytogenes in broth, 200 ppm resulting in …

Subphonemic Sensitivity In Low Literacy Adults, Monica Y.C. Li

Master's Theses

The link between phonological abilities and reading skills has been well-established in both typical and atypical language development. However, the nature of the phonological deficits in poor readers remains a debated topic. While poor readers have been mostly assumed to have underspecified or “fuzzy” phonological representations (Tallal et al., 1998), the opposite alternative, over-specified phonological representations, has also been hypothesized (Serniclaes, 2006). To examine the two phonological hypotheses, the current study used the eye-tracking paradigm in the study of Dahan et al. (2001) to investigate individuals’ sensitivity to subphonemic information in young adults with a wide range of reading abilities. …

Novel Integration Of Conductive-Ink Circuitry With A Paper-Based Microfluidic Battery As An All-Printed Sensing Platform, Rishi A. Kripalani

Master's Theses

The addition of powered components for active assays into paper-based analytical devices opens new opportunities for medical and environmental analysis in resource-limited applications. Current battery designs within such devices have yet to adopt a ubiquitous circuitry material, necessitating investigation into printed circuitry for scalable platforms. In this study, a microfluidic battery was mated with silver-nanoparticle conductive ink to prototype an all-printed sensing platform. A multi-layer, two-cell device was fabricated, generating 200 μA of direct electrical current at 2.5 V sustained for 16 minutes with a power loss of less than 0.1% through the printed circuitry. Printed circuitry traces exhibited resistivity …

Game Theory Analysis Of Intra-District Water Transfers; Case Study Of The Berrenda Mesa Water District, Harry Riordan Ferdon

Master's Theses

California state officials have continued to warn and encourage preparedness for the growing threats of water scarcity. This puts pressure on water suppliers to develop technological and managerial solutions to alleviate the problems associated with scarcity. A recent popular management strategy for distributing water is encouraging water transfers. While there has been analyses on water transfers between large districts and agencies, little analysis has been completed for smaller scale trades, i.e. between individuals in the same water district. This analysis models an agricultural water district, based on the Berrenda Mesa Water District (BMWD). In the model, the growers in the …

Three-Dimensional Analysis Of The Development Of Upper Arm Musculoskeletal Stress Markers In Late Adolescents And Young Adults Of Archaic And Mississippian Populations Of Tennessee, Heather Marie Guzik

Master's Theses

This study compares three methods for the evaluation of morphology of musculoskeletal attachment sites. Two methods were macroscopic and the third was microscopic, utilizing three-dimensional laser scanning and fractal analysis The morphology of 19 upper limb attachment sites was observed in 33 males aged 15 and 30+ years, dating to the Archaic and Mississippian periods from the southeastern U.S. It was hypothesized that 1) the microscopic method would identify subtler differences than the macroscopic methods; 2) enthesis development would be greater in the Mississippian population due to the increased subsistence workload, even among younger individuals; and 3) late adolescents would …

The Elasmobranch-Microbe Relationship: Trimethylamine N-Oxide Synthesis, Urea Hydrolysis, And Microbe-Osmolyte Interactions In The Atlantic Stingray, Dasyatis Sabina, Kaitlin Kelly Doucette

Master's Theses

The elasmobranch osmoregulatory strategy is predicated on the accumulation of nitrogenous compounds, primarily urea and trimethylamine n¬-oxide (TMAO). Despite the abundance of these plasma osmolytes, it is notable that elasmobranchs appear to lack urease and TMA oxidase (Tmase), enzymes that scavenge urea-nitrogen and synthesize TMAO, respectively. However, urease and Tmase are found in many species of bacteria. Therefore, I hypothesized that intestinal bacteria are responsible for urease and Tmase activity in elasmobranchs. Absent dietary nitrogen sources, I evaluated the effects of reduced intestinal microbiota on osmoregulation in Atlantic stingray (Dasyatis sabina) in vivo. D. sabina were given …

Circadian And Circatidal Rhythms Of Protein Abundance In The Intertidal Mussel Mytilus Californianus, Cory Elowe

Master's Theses

The intertidal zone is a dynamic environment that fluctuates with the 12.4-h tidal and 24-h light/dark cycle to predictably alter food availability, temperature, air exposure, wave action, oxygen partial pressure, and osmotic conditions. Intertidal sessile bivalves exhibit behavioral or physiological changes to minimize the persistent challenges of fluctuating environmental conditions, such as adjusting gaping behavior and heart rate. At the cellular level, transcriptomic studies on mussels’ baseline circadian and circatidal rhythms have determined that the circadian rhythm is the dominant transcriptional rhythm. However, as proteins reflect the basic molecular phenotype of an organism and their abundance may differ greatly from …

Fecal Bacterial Communities As An Indicator Of Trophic Interactions Among Anuran Larvae, Steven Jacob Everman

Master's Theses

Anurans are mass spawners, often with multiple females spawning together, resulting in thousands of tadpoles sharing a habitat. Such large numbers of tadpoles with limited dispersal can lead to intense competition for resources. Inter and intra-specific competition for food could have negative impacts on the growth and survival of smaller tadpoles. Fecal bacterial communities have the potential to be used as indicators of changes in diet making it possible to determine if tadpoles in the wild are eating the same food or not. After feeding on two prepared diets that differed in the percentage of complex carbohydrates, the fecal bacterial …

Effect Of Fragmentation And Habitat Type On Coastal Nekton In Mississippi, Thomas Bennett Sevick

Master's Theses

Coastal wetlands are extremely productive ecosystems that support an abundance of organisms at higher tropic levels. Coastal wetlands also act as important buffers from storms and help protect major cornerstones of coastal economies, such as tourism and fisheries. Despite the clear need for the protection of these habitats, anthropogenic use of coastal wetlands has increased in frequency and intensity, resulting in the fragmentation of once continuous habitats. A central challenge to assessing the impact of marsh fragmentation is the lack of quantitative distribution and abundance data from specific habitat types. This is especially true for species that are not commercially …

Gulf Sturgeon (Acipenser Oxyrinchus Desotoi) Pre-Restoration Occupancy Patterns On Ship Island, Mississippi Sound With An Evaluation Of Designated Critical Habitat Use By Eastern And Western Population Segments, Page Elizabeth Vick

Master's Theses

Critical spawning and feeding habitat was designated for federally threatened, anadromous Gulf Sturgeon (GS) to aid in population recovery. This study examined GS occupancy, habitat use, and movement through critical habitat monitored by the Ship Island (SI) acoustic array during overwintering periods from 2011 to 2015 prior to MsCIP SI restoration. An occupancy index analyzed patterns of spatial and temporal habitat use of both western and eastern population segments (WPS and EPS, respectively) of GS on the SI array. The ends of SI along with the passes and cuts of the island, especially Dog Keys Pass (DKP), were occupied by …

The Effects Of Tootling Combined With Public Posting In High School Classrooms, Sarah Joan Wright

Master's Theses

A traditional tootling procedure was implemented along with a public posting component to determine the effects on academically engaged, disruptive, and passive off task behaviors in four general education high school classrooms. The study employed an A/B/B+C multiple baseline design across classrooms. The primary focus of the study was to assess potential increases in academically engaged behavior across intervention conditions. Students in the traditional tootling phase (B) were instructed to report on their peers’ positive, prosocial behaviors. At the end of the class period, the teacher silently read through the tootles and added the total toward the group goal. When …

Correspondence Between Haptic And Visual Perception Of Stand-On-Ability: Do Hills Look As Steep As They Feel?, Jonathan Kenealy Doyon

Master's Theses

Vision and haptics play a central role in perceiving environmental layout to guide action. Hajnal, Wagman, Doyon, and Clark (2016) demonstrated that visual perception of stand-on-ability is accurate compared to action capabilities, whereas haptic perception of stand-on-ability reliably underestimates action capabilities. This finding contradicts Gibson’s (1979) theory of equivalence in perceptual systems, which suggests that perception should be equivalent regardless of modality. Previous comparisons of visual and haptic perception tested the modalities in isolation. The current experiment directly compares visual to haptic perception of stand-on-ability by using one perceptual system to estimate the other. Observers viewed a surface set to …

Modern Fair-Weather And Storm Sediment Transport Around Ship Island, Mississippi: Implications For Coastal Habitats And Restoration Efforts, Eve Rettew Eisemann

Master's Theses

The Mississippi – Alabama barrier island chain is experiencing accelerated sea level rise, decreased sediment supply, and frequent hurricane impacts. These three factors drive unprecedented rates of morphology change and ecosystem reduction. All islands in the chain have experienced land loss on the order of hectares per year since records began in the 1840s. In 1969, Hurricane Camille impacted as a Category 5, breaching Ship Island, and significantly reduced viable seagrass habitat. Hurricane Katrina impacted as a Category 3 in 2005, further widening Camille Cut. To better understand the sustainability of these important islands and the ecosystems they support, sediment …

Bloom Or Bust: Retrospective Analysis Of The Giant Jellyfish, Nemopilema Nomurai (Scyphozoa: Rhizostomeae), Ecology In The East Asian Marginal Seas, Naomi Yoder

Master's Theses

The Giant Jellyfish, Nemopilema nomurai, is a large-bodied bloom-forming jellyfish that occurs in the semi-enclosed basins of the East Asian Marginal Seas. N. nomurai has bloomed more frequently in the past 20 years than in any period previously recorded. In Japan, recent N. nomurai blooms were responsible for millions of dollars in lost revenue and equipment damage to commercial fisheries alone. This study statistically analyzed 21 environmental factors in connection with N. nomurai occurrence (using occurrence as a proxy for blooms). Eight factors resulted in a statistically significant or marginally significant (p ≤ 0.10), linear or non-linear relationship with …

Functional 3-D Cellulose And Nitrocellulose Paper-Based, Microfluidic Device Utilizing Elisa Technology For The Detection/Distinction Between Hemorrhagic And Ischemic Strokes, Alicia Leanne Holler

Master's Theses

The purpose of this thesis project is to demonstrate and evaluate an enzyme-linked immunosorbent assay (ELISA) on a paper microfluidic device platform. The integration of ELISA technology onto paper microfluidic chips allows for a quantitative detection of stroke biomarkers, such as glial fibrillary acidic protein (GFAP). Dye experiments were performed to confirm fluid connectivity throughout the 3D chips. Several chip and housing designs were fabricated to determine an optimal design for the microfluidic device. Once this design was finalized, development time testing was performed. The results confirmed that the paper microfluidic device could successfully route fluid throughout its channels at …

Compounding Fire Disturbance History Encourages Coast Redwood (Sequoia Sempervirens) Regeneration And Community Dominance, Matthew R. Brousil

Master's Theses

Disturbance is fundamental to forest ecosystem function and overall health, but climate change is likely to increase both disturbance frequency and intensity in the future. Forests subject to increasingly frequent and intense disturbances are more likely to experience compounding disturbance effects. Compounding disturbances may exert unpredicted, non-additive stresses on ecosystems, leading to novel conditions that may exceed the capacity for local species to survive and regenerate. I further hypothesize that compounding disturbances could create conditions misaligned with species’ adaptations by altering physical and chemical growing conditions in forest soils, affecting forest composition, structure, and, subsequently, function for many years following …

The Impacts Of Arterial Occlusion, Sex, And Exercise On Arteriogenesis And Functional Vasodilation, Megan Tze-Mei Chu

Master's Theses

The most frequent clinical presentation of peripheral arterial occlusive disease (PAOD) is intermittent claudication, which may be caused by impaired vasodilation. Patients demonstrate both local and systemic impairments in vasodilation, but as the collateral circulation is the primary site of resistance to the ischemic zone, impaired collateral vasodilation would have the greatest potential to induce claudication. Collateral function following arterial occlusion is not well defined, but immature collaterals may demonstrate impaired vasodilation in animal models, although this is potentially improved with exercise training. Furthermore, as females exhibit poorer physical function with ischemia and less improvement with therapeutic exercise, there appears …

The Response Of A Predatory Fish, Ophiodon Elongatus, To A Marine Protected Area: Variation In Diet, Catch Rates, And Size Composition, Eric S. Anderson

Master's Theses

Marine Protected Areas (MPAs) are a management tool used to protect and sustain many ecologically and economically important fish species from overexploitation by recreational and commercial fishing. Lingcod (Ophiodon elongatus) and some of its prey species, such as rockfish (Sebastes spp.), are species that are protected from fishing in some California MPAs. Lingcod is an apex predator that consumes a variety of fish and invertebrate species. In this study, I sought to assess the effect of an MPA on the abundance, size and diet of Lingcod. I hypothesized that Lingcod in a no-take MPA would be more …

Evaluation Of Efficiency Of Various Materials To Shield From Radiation In Space Using The Monte Carlo Transport Code Called Fluka, Roman Savinov

Master's Theses

The purpose of this study is to improve spacecraft shielding from radiation in space. It focuses on the evaluation of shielding efficiency of different materials. The efficiency of a shield is evaluated by the dose profile within the shield and the amount of dose absorbed by a target using the Monte Carlo transport code called FLUKA. The output of this code is validated by recreating the experiments from published papers and comparing the results. Once the FLUKA’s output is validated, the efficiency of sixteen materials, subject to SPE and GCR sources, are evaluated. The efficiency comparison is made by fixing …

Metabolic Regulation And Cryotolerance Of In Vitro-Produced Holstein Embryos, Melissa Ann Roberts

Master's Theses

In vitro production and transfer of embryos has become a common practice within the dairy industry to efficiently breed superior animals and meet the consumption demand of the growing population. Cyropreservation is necessary for the application of commercialized embryo transfer, however, in vitro-produced embryos show morphological and physiological defects which negatively impact their ability to withstand cryopreservation in comparison to their in vivo counterparts. These artifacts result from culture conditions that cause stress to the embryo during development, leading to an accumulation of intracellular lipids, mitochondrial dysfunction, and ultimately poor ability to withstand freezing and thawing. The objective of …

Field Emissions Of (Hydro)Chlorofluorocarbons And Methane From A California Landfill, Alexander H. Sohn

Master's Theses

A comprehensive field investigation was conducted at Potrero Hills Landfill (PHL) located in Suisun City, California to quantify emissions of twelve (hydro)chlorofluorocarbons (i.e. F-gases). The specific target constituents for this study included CFC-11, CFC-12, CFC-113, CFC-114, HCFC-21, HCFC-22, HCFC-141b, HCFC-142b, HCFC-151a, HFC-134a, HFC-152a, and HFC-245fa. The majority of the F-gas emission studies have been conducted outside of the United States and very limited field landfill emission data are available in the United States. Because of historical usage of blowing agents in insulation foams including CFC-11, HCFC-142b, HFC-134a, and HFC-245fa, models reported in literature predicted high F-gas emissions from a landfill …