Digital Commons Network^™

Paleoecological Successions From Shallow-Marine Depositional Environments In Upper Silurian Carbonate Rocks Of Blair County, Pennsylvania, Shadya El-Ashkar

Graduate Theses, Dissertations, and Problem Reports (ETD)

Studies of paleoenvironment and paleoecology are important for investigating relationships between the different environmental and biological variables that influenced biodiversification patterns during the Silurian Period. The mixed carbonate and siliciclastic rocks of the Bloomsburg and Mifflintown Formations in central Pennsylvania represent transitions between carbonate ramp and deltaic settings. The goal of this study was to assess changes in depositional environment and paleoecology of an undescribed Bloomsburg/Mifflintown locality in Bellwood, Pennsylvania. In central Pennsylvania, the interfingered relationship of mixed carbonate and siliciclastic mudstones of the Mifflintown Formation with red fine-grained sandstones and shales of the Bloomsburg Formation presented challenges for deciphering …

A Study On The Hydrodynamics Of A Bench-Scale Top-Fed Bubbling Fluidized Bed Gasifier Using Biomass And Coal As Feedstocks, Ali Can Sivri

Graduate Theses, Dissertations, and Problem Reports (ETD)

The production of synthetic gas (syngas) from renewable or carbon-neutral sources can significantly reduce greenhouse and other emissions associated with conventional fuels. One of the most promising technologies to efficiently convert carbonaceous feedstocks such as biomass, coal, or municipal waste into syngas for transportation, power, heat, electricity generation, and or production of added-value chemicals is the bubbling fluidized-bed gasifier (BFBG). However, the gasification process inside a BFBG is a very complex high-temperature multiphase flow phenomena still not well understood, particularly when binary mixtures are investigated. As a result, despite the numerous correlations in the literature developed to predict the hydrodynamics …

Individual Differences In Social Decision-Making Preferences, Kelly R. Smith

Graduate Theses, Dissertations, and Problem Reports (ETD)

Most research on decision making to date has focused primarily on the individual decision maker and has not looked at social aspects of decision making. A review of decision making in older adults indicated that older adults rate their own decision-making competence as worse than younger adults, even though not all facets of decision making decline with age (Strough, Bruine de Bruin, & Peters, 2015). Because of social roles that contribute to gender differences, women are theorized to be more interpersonally-oriented than men, suggesting that they may prefer to make decisions with others (Eagly, 1983). As population age continues to …

An Appraisal Of The Evolution Of Western Art Music In Nigeria, Agatha Onyinye Holland

Graduate Theses, Dissertations, and Problem Reports (ETD)

Nigeria has greatly evolved as an intercultural society given her history of colonization, the influence of foreign religion (Christianity and Islam, primarily) and the impact of globalization. Africa had her socio-cultural practices and art idioms before these foreign influences. For instance, music existed in everyday Africa as part of culture, religion, vocation, and drama. However, music never existed as an entity on its own. The culture of stage performers and audience never existed. This status quo changed with the introduction of Western art music through Christianity and education by the missionaries; since then, music assumed a bi-cultural status. This research …

Novel Roles Of Tobacco-Associated Genes Underlying Disparate Survival In Appalachian Head And Neck Squamous Cell Carcinoma, Brenen William Papenberg

Graduate Theses, Dissertations, and Problem Reports (ETD)

Head and neck squamous cell carcinoma (HNSCC) is an aggressive neoplasm primarily caused by tobacco consumption or human papillomavirus (HPV) infection. Incidence and mortality rates for HNSCC vary geographically. Appalachian residents consume tobacco products to a greater extent than national averages, a risk factor known to promote HPV-negative HNSCC through increased genomic instability. Male Appalachian patients display significantly worse relative survival than Appalachian females or non-Appalachian residents of either sex. Secondary analysis of available cancer registry outcome data from 2007-2013 indicates that white males with stage IV oral cavity/pharyngeal (OC/P) HNSCC are responsible for the decreased male survival observed within …

Solutions To Some Mine Subsidence Research Challenges, Jian Yang

Graduate Theses, Dissertations, and Problem Reports (ETD)

The objective of this work is to address three challenging topics, (1) effects of overburden key strata on subsurface subsidence; (2) effects of longwall subsidence on interstate highways and highway bridges; and (3) effects of dewatering mine water on surface subsidence over inactive room-and-pillar mines, in mine subsidence and to continue improvement of mine safety and health by reducing mine-subsidence related hazards.

Surface and subsurface subsidence events induced by underground mining activities are often capable of causing significant disturbances not only to surface structures, but also to subsurface structures. In this work, models and techniques to study three challenging topics …

Synthesis And Characterization Of Pyridine Dipyrrolide Iron Complexes Relevant To Nitrene And Carbene Group Transfer, Brett M. Hakey

Graduate Theses, Dissertations, and Problem Reports (ETD)

The synthesis and electronic structures of the square-planar high-spin Fe^II complexes (^MesPDP^Ph)Fe(OEt₂) and (^MesPDP^Ph)Fe(thf) were investigated. Analysis of these compounds using a combination of ¹H NMR and ⁵⁷Fe Mössbauer spectroscopies, in conjunction with computational analysis, has resulted in a rationalization for their unusual electronic structures, which arise from the unique coordination environment enforced by the pyridine dipyrrolide chelate ligand.

The reactivity of (^MesPDP^Ph)Fe(thf) with organic azides has been probed and resulted in the isolation of an array of products that are consistent with …

Recovery Of Benthic Macroinvertebrate Communities After Restoration In Two Intensively Mined Watersheds, Brian R. Gordon

Graduate Theses, Dissertations, and Problem Reports (ETD)

As the body of literature supporting watershed-scale restoration projects continues to grow, there is need for a greater understanding of the underlying mechanisms that drive it. With data spanning ten years capturing pre- and post-restoration benthic macroinvertebrate communities in two distinct watersheds of West Virginia, we seek to contribute to the developing pool of knowledge regarding these dynamics. Sites were laid out prior to remediation in such a manner as to capture the spectrum of water quality conditions present, these are divided into three treatment types: reference, treated, and abandoned mine drainage (AMD). Our objectives were to: 1) determine if …

Haemonchus Contortus Antigen Identification And Use Of Tropomyosin In Ovine Vaccine Development, Brynnan P. Russ

Graduate Theses, Dissertations, and Problem Reports (ETD)

Globally, the small ruminant industry loses hundreds of millions of dollars due to parasitism by the gastrointestinal nematode Haemonchus contortus. This parasite feeds on blood in the host’s abomasum leading to disease including anemia, hypoproteinemia, lethargy, and death. There have been exhaustive efforts to manage this parasite including different management applications, anthelmintic treatment, and now integration of resistance genetics into a flock. Like antibiotics, overuse of anthelmintics has led to resistance of H. contortus to these drugs. Therefore, other methods of control are the main focuses of many research initiatives. St. Croix are a resistant breed of sheep that mount …

Evaluating The Use Of The M-Vac® Wet Vacuum System To Recover Dna From Cotton Fabric, Phillip Reilly Irion

Graduate Theses, Dissertations, and Problem Reports (ETD)

With the current state of the field of forensic biology, collecting DNA from evidence samples may pose some difficulty. Traditional methods for collection of DNA from biological fluids and touch samples include cuttings, scrapings, and the double swab method. While all of these methods have benefits, they also have their drawbacks. In order to more efficiently collect DNA from an evidence sample, novel approaches need to be explored. This novel approach is the microbial vacuum (M-Vac®) Wet Vacuum System.

This system utilizes a sterile collection solution and a vacuum to collect DNA material from evidence samples. While it is similar …

"Treading On The Footprints Of History": American Catholic Pilgrimage As Public History, Charlotte Vester

Graduate Theses, Dissertations, and Problem Reports (ETD)

In this thesis, I demonstrate how Catholic pilgrimage is a public history phenomenon. I define public history as public engagement, understanding, and use of the past. While I assert that pilgrimage is a public history phenomenon both in the past and in the present, my thesis will focus on American Catholic pilgrimage at the turn of the twentieth century. Each individual chapter will demonstrate that through pilgrimage, the faithful are engaged in public history in its various forms. Catholics actively took part in past-making and identity-construction in their roles as pilgrims. Through pilgrimage, Catholics were involved in the preservation and …

Avian And Salamander Response To Young Forest Management In West Virginia, Eric L. Margenau

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation focuses on the effects of various young forest habitat management techniques on the avian and salamander community in West Virginia. Wildlife species associated with the nascent stage of forest succession are experiencing precipitous population declines throughout much of the eastern United States due to decreases in the amount of young forest area which have been brought on by changes in disturbance regimes over the past century. As a result, the need to find novel approaches for creating young forest habitats to sustain young forest wildlife populations is necessary. However, young forest habitat creation often negatively affects species that …

Silver-Mediated Decarboxylation Reactions: Expanding Reaction Scope Through Kinetic Analysis, Robert Anthony Crovak

Graduate Theses, Dissertations, and Problem Reports (ETD)

Transition metal-catalyzed decarboxylative coupling reactions have received considerable attention in recent years as a method to obtain biaryl compounds. However, the oxidative version of this reaction class is still in its infancy, limited to specific substitution patterns on the benzoic acids – ortho-substitution - used in these transformations. This thesis describes our attempts to understand the key decarboxylation step of this important class of reactions. The first chapter of this thesis discusses an introduction into cross-coupling reactions, decarboxylative cross-coupling reactions, and outlines relevant physical organic parameters. The following chapter details the synthesis of a series of (1,10-phenanthroline)silver(benzoate) complexes. This chapter …

Minocycline As A Treatment For Traumatic Brain Injury-Induced Impulsive And Attentional Deficits, Kristen M. Pechacek

Graduate Theses, Dissertations, and Problem Reports (ETD)

Traumatic brain injury (TBI) impacts millions worldwide and can cause lasting psychiatric symptoms. Chronic neuroinflammation is a characteristic of post-injury pathology and is positively associated with psychiatric conditions such as ADHD and bipolar disorder. Therefore, the current study sought to treat TBI-induced impulsivity and inattention using minocycline, an antibiotic with anti-inflammatory properties. Rats were trained on the five-choice serial reaction time task (5CSRT), a measure of motor impulsivity and attention. After behavior was stable on the 5CSRT, rats received either a bilateral frontal TBI or sham procedure. Minocycline was given at either 1 h post-injury or beginning at 8 weeks …

Examining The Career Pathways For Women Administrators At A Land-Grant University, Meridith A. Balas

Graduate Theses, Dissertations, and Problem Reports (ETD)

This feminist-centered, narrative study focuses on the troubling gender gaps in higher education leadership by exploring the career paths and lived experiences of current women administrators at a large, public land-grant institution. This research identifies specific supports and barriers women face throughout their careers that might enable or prevent them from attaining or accessing high-level leadership roles in academic and non-academic administration. The study leans on feminist theory to position perceptions of women in leadership roles across many disciplines in the university setting while observing it as a critical lens to analyze gender inequality in the career pipeline for women …

The Fight Is Still On: An Ethical Analysis Of The American Civil Liberties Union’S Partisan Rhetoric In The Trump Era, Emily Charlotte Gerber

Graduate Theses, Dissertations, and Problem Reports (ETD)

The 2016 U.S. presidential election of Donald Trump generated a newfound surge in political advocacy that greatly benefitted certain nonprofits and grassroots organizations. One of these organizations was the American Civil Liberties Union, a nonpartisan nonprofit dedicated to protecting and defending civil liberties and rights in the U.S. The ACLU received an unprecedented number of donations following Election Day and has since pursued an aggressive campaign against President Donald Trump.

In order to explore this phenomenon, this thesis analyzed the ACLU’s rhetoric between Presidents George W. Bush and Donald Trump (both Republicans) and between Presidents Barack Obama (Democrat) and Donald …

The Societal Influence On Individual Identity And The Relationship Of Costume Design In Caryl Churchill’S Cloud 9, Laura Kay Plikerd

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cloud 9 is a play written by Caryl Churchill in 1978. Act one of the play takes place in 1870, British Occupied Africa and act two takes place in contemporary London. In our production, contemporary London was set in 2018. The dramatic shift in time during the two acts brings attention to the changing societal ideals and practices of each era. The costumes for this production of Cloud 9, illuminated the differences between the times by highlighting the stark differences in societally accepted fashion in the chosen time periods and regions.

In Cloud 9, the costumes create a …

Fundamental Studies On The Recovery Of Rare Earth Elements From Acid Mine Drainage, Xue Huang

Graduate Theses, Dissertations, and Problem Reports (ETD)

The Rare Earth Elements (REEs) are a group of 17 chemically similar elements that are essential raw materials for modern society. Given their increasing importance in civil and defense applications, many national governments, including the US, have denoted the REEs as critical materials and emphasized the need to identify and develop both conventional and unconventional resources to meet the growing demand. To address this challenge, the US Department of Energy has recently spearheaded efforts to evaluate the technical and economic feasibility of recovering REEs from coal and coal byproducts, which have been shown to contain REEs at an elevated concentration …

Teacher As “Team Player”: An Early Career Teacher’S Refinement Of Critical Pedagogical Discourses, Keisha-Moraé Hopkins Kibler

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study centers on one early-career English language arts (ELA) teacher’s development of his critical pedagogical discourses (CPD) within the contextual discourses of collaboration and data informed instruction. These contextual discourses circulated assumptions of teaching and learning that are privileged by the political ideologies of the neo-liberal agenda, which can erode the democratic purposes of education. Data is drawn from an eight-month interpretive qualitative case study that included classroom observations and semi-structured interviews. The two research objectives for this study included: to come to understand the range of ways an early-career ELA teacher navigated the tensions between his belief and …

Cobalt-Catalyzed Aerobic Oxidative Cyclization Reactions Of Bisnucleophiles: New Methodologies And The Role Of Bisnucleophiles In O2 Activation, Jiaqi Liu

Graduate Theses, Dissertations, and Problem Reports (ETD)

Over the past few decades, transition metals have found wide applications in the development of selective oxidative transformations mediated by molecular oxygen. Due to the benign nature of molecular oxygen as an oxidant and an increasing awareness of green chemistry practice, tremendous progress has been made towards the development of Cu-and Pd-catalyzed aerobic oxidation reactions. As a first-row transition metal alternative to copper, cobalt has been employed in aerobic catalytic transformations for its cost-efficiency and earth abundance; however, redox-active mediators such as benzoquinone (BQ), N-hydroxyphthalimide (NHPI) or salen-type ligands are usually required. To date, reactions mediated by Co/O₂ catalytic …

Development Of New Synthetic Methods For Carbon Nanohoops, Merfat Aljhdli

Graduate Theses, Dissertations, and Problem Reports (ETD)

Carbon nanotubes have received much attention from the material chemists after the synthesis and structure analysis by Iijima in 1991. It was envisioned that cycloparaphenylenes (CPPs), which comprise a sequence of benzene units connected at para position to make a cyclic ring structure, are possible templates for growing carbon nanotubes of a single chirality and single diameter for nanotechnology application. Recently, chemists turned their attention to synthesizing aromatic carbon nanobelts proposed as a general term for carbon molecules composed of fused benzene rings in cylindrical structure shape. Cyclophenacenes (CPAs) as carbon nanobelts are expected to be more suitable candidates for …

Comparison Of The Batch And Individual Log Study Methods For Use In Determining Log Breakeven Pricing, Levi Eric Sisler

Graduate Theses, Dissertations, and Problem Reports (ETD)

Understanding log yields and overrun is critical to a profitable sawmill operation. Lumber yield and overrun data can be gathered through one of two types of sawmill studies: batch studies or individual log studies. Little to no research has previously been conducted to determine if one method provides more reliable results than the other method. For this effort, 16 batch studies were conducted. Individual log studies were also conducted on the same logs, allowing a direct comparison of the results from both study types. A breakeven analysis was conducted for each study type, which determined the amount of variability in …

Green Completion As A Mitigation For Btex Exposure In Gas Flaring: Nigeria Case Study (Exposure Assessment And Cost Model), Akintunde S. Akinyemi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Gas flaring is an essential part of the oil and gas industry safety and waste management procedures; however, it presents a potential exposure to BTEX compounds, a group of Non-Methane Volatile Organic Compounds (NMVOC), within up to a 10-mile radius of the flare point. The physical and the psychological cost of the journey to work, make employees live close to the workplace. This study examined the perceived exposure of oil and gas industry workers to possible carcinogenic emissions outside the workplace. It looked at the outcomes of the exposure to BTEX through gas flaring drawing on archival data and using …

International Students’ Adjustment Challenges In The United States: A Case Study Of West Virginia University, Lawrencia Baaba Okai

Graduate Theses, Dissertations, and Problem Reports (ETD)

International students face challenges as they endeavor to study abroad ranging from host government policies to the host country’s attitudes vis-à-vis foreign students and immigration. In some instances, they also face obstacles leaving their country of origin. The United States is the largest destination country with 24% of all international students worldwide, followed by the United Kingdom, Australia, France, and Germany. In the United States, international students make up about 6% of all college students. They make significant contributions to the United States economy and bring several benefits, particularly to federal and state governments. They contribute to the federal government’s …

Rail-To-Rail Operational In Low-Power Reconfigurable Analog Circuitry, Jared Dale Baker

Graduate Theses, Dissertations, and Problem Reports (ETD)

Analog signal processing (ASP) can be used to decrease energy consumption by several orders of magnitude over completely digital applications. Low-power field programmable analog arrays (FPAA) have been previously used by analog designers to decrease energy consumption. Combining ASP with an FPAA, energy consumption of these systems can be further reduced. For ASP to be most functional, it must achieve rail-to-rail operation to maintain a high dynamic range. This work strives to further reduce power consumption in reconfigurable analog circuitry by presenting a novel data converter that utilizes ASP and rail-to-rail operation. Rail-to-Rail operation is achieved in the data converter …

The Effects Of Membrane Physicochemical Properties On Huntingtin Membrane Association And Downstream Aggregation, Maryssa Beasley

Graduate Theses, Dissertations, and Problem Reports (ETD)

Huntington’s Disease (HD) is a fatal neurodegenerative disorder caused by an expanded glutamine repeat region (polyQ) within the huntingtin protein (htt). As a result of the expanded polyQ domain, htt associates into a variety of toxic aggregate species. The polyQ domain of htt is flanked at the N-terminal end by 17 amino acids (Nt17) that adopt an amphipathic α-helical structure in the presence of binding partners such as lipid membranes. In addition to comprising a lipid binding domain, the Nt17 amphipathic α -helix has been directly implicated in htt aggregation initiation via self-association with other Nt17 α -helices. Due to …

C-Jun Nh2-Terminal Kinase Signaling Controls Cellular Mechanisms Of Guided Cortical Interneuron Migration, Skye Eleanor Smith

Graduate Theses, Dissertations, and Problem Reports (ETD)

The cerebral cortex is an intricately organized brain structure responsible for high-level functions including sensory perception, movement, memory, language, and cognition. During corticogenesis, cortical excitatory neurons and inhibitory interneurons migrate from their respective progenitor zones into the developing cerebral cortex, deposit in the correct cortical layer, and establish connections with their appropriate synaptic partners. The balance between excitation and inhibition is critical for cortical circuitry development and function. Aberrant migration of inhibitory interneurons can alter the formation of cortical circuitry and lead to several neurodevelopmental disorders including epilepsy, autism spectrum disorder, and schizophrenia. Therefore, elucidating the mechanisms responsible for inhibitory …

Neuromechanical Tuning For Arm Motor Control, Russell Lee Hardesty Jr

Graduate Theses, Dissertations, and Problem Reports (ETD)

Movement is a fundamental behavior that allows us to interact with the external world. Its importance to human health is most evident when it becomes impaired due to disease or injury. Physical and occupational rehabilitation remains the most common treatment for these types of disorders. Although therapeutic interventions may improve motor function, residual deficits are common for many pathologies, such as stroke. The development of novel therapeutics is dependent upon a better understanding of the underlying mechanisms that govern movement. Movement of the human body adheres to the principles of classic Newtonian mechanics. However, due to the inherent complexity of …

Literature Review On Modeling Of Density Difference Pumping Strategy For Geothermal Applications, Lucas A. Ware

Graduate Theses, Dissertations, and Problem Reports (ETD)

The utilization of geothermal ground heat sources has been demonstrated at both large and small scales across the world. However, methods of extraction of the hot working fluids are often a source of energy inefficiency and high capital expense. Current techniques to extract geothermal fluids rely on mechanically and electrically driven down-hole components that require maintenance on a regular basis. In providing a solution, one approach that reduces complexity, decreases maintenance, and allows access to fluids at greater depth is an airlift approach. The airlift approach relies on injection of gas at a depth within a geothermal well to lift …

Optimizing The Production And Injection Wells Flow Rates In Geothermal Field Using Artificial Intelligence, Muhammet Salih Ariturk

Graduate Theses, Dissertations, and Problem Reports (ETD)

In a geothermal field, power plants are designed for long-term electricity generation. Therefore, it is crucial to predict the future production and injection flow rates of the wells to determine the capacity of a power plant. In the designing of such power plants, calculations and estimations are based on the current future production, and injection flow rates and pressures in the geothermal field. Prediction of future production and injection flow rates also assist in building surface facilities with cost-efficient power plants. The most common problem in a power plant in geothermal fields is the inability to accurately estimate future expected …