Digital Commons Network^™

Comprehensively Improved Electrochemical Performance Of Lithium-Sulfur Batteries By “Chemical Anchors” And Lithium Anode Modification, Zhipeng Zeng

Graduate Theses, Dissertations, and Problem Reports (ETD)

Lithium-sulfur battery is considered to be one of the most promising contenders for the next generation high-energy storages due to their high theoretical energy density (~2600 W h kg^-1). However, a series of issues, especially for the dissolution of lithium polysulfides (LiPSs) with their “shuttle effect” and dendrite formation on the lithium anode, greatly limit their widely commercial applications. Starting from a brief overview of conventional methods to solve these problems, the achievements spotlighted in this research work mainly focus on the structure design of cathode materials by employing “chemical anchors” to effectively suppress the diffusion of LiPSs, …

Modulation Of Semiconductor Photoconversion With Surface Modification And Plasmon, Joeseph Martin Bright

Graduate Theses, Dissertations, and Problem Reports (ETD)

Semiconductor devices are the basis of modern technology. Semiconductor-based photoconversion devices that convert light into electrical signals have shown potential for light energy harvesting and conversion, environmental remediation, and sensors for detection of light, chemicals, and biological substances. Despite this potential for use in many applications, semiconductor photoconversion devices need further improvement in the photoconversion performance. This photoconversion improvement may be manifested as increased photoconversion efficiencies for light harvesting devices for power generation such as photovoltaics and photoelectrochemical (PEC) cells or improved photoconversion modulation to increase the sensitivity of semiconductor photoconversion-based sensors. In addition, alternative semiconductor materials to semiconductors that …

Potential Benefits From Practices In Construction Waste Material Controls, Abdulaziz Alwadhenani

Graduate Theses, Dissertations, and Problem Reports (ETD)

Construction waste is generated from the various construction activities of building, maintaining, renovating, and demolishing infrastructure facilities. These materials include, but are not limited to, concrete, rubble, fiberglass, asphalt, bricks, wood, and scrap metals. In the last few decades, there has been a significant increase in the volume of construction and demolition (C&D) waste materials in the United States (U.S.). Between 1990 and 2017, the total increase in debris generation has surpassed 320%. According to U.S. solid waste management statistics, more than 50% of C&D waste has been and continues to be transported to landfills. The disposal of C&D waste …

A Qualitative Case Study Research Investigation Of Youth Outcomes During An Appalachian Water-Quality Citizen Science Program, Jessica Kaplan

Graduate Theses, Dissertations, and Problem Reports (ETD)

Citizen science has grown in the past decades to not only include everyday people in research, but also varying levels of engagement with diverse opportunities for participant learning and growth. However, few studies reflect the actual learning outcomes of educational citizen science specifically in youth. This single case study research study focuses on assessing learning and other outcomes of an environmental education, collaborative citizen science program with youth in Morgantown, West Virginia. In this study, a water quality monitoring citizen science program focused on Deckers Creek in Morgantown, WV was adapted for a high school afterschool club. Potential outcomes of …

Investigation Of Particle Measurement In Different Dilution Ratios With Gasoline Direct Injection And Port Fuel Injection, John Adam Phillips

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ambient air quality has been a concern in the United States since the mid-1900’s, forcing legislations like the Air Pollution Control Act and Clean Air Act necessary to bring focus on air pollution and quality. The Environmental Protection Agency (EPA) continues to update the requirements for more efficient vehicles and emissions sampling methods. Today the EPA has implemented regulations on modern spark ignited engines without any major focus on the type of injection technologies being used. While particle matter (PM) is a requirement to measure for a vehicle certification, more research should focus on the particle number (PN) measurements that …

Adolescent Adventures In Geology: Impacts Of Geoscience-Focused Stem Education Combined With Recreation Activities On Adolescents’ Perceived Self-Efficacy, Lauren Janowicz

Graduate Theses, Dissertations, and Problem Reports (ETD)

Quality, informal learning techniques combined with outdoor adventure recreation, or adventure STEM programming, is a potentially powerful complement to and extension of formal education (Fu et al., 2015). To address this underexplored field, West Virginia University (WVU) and the United States Geological Survey (USGS) partnered to create a geology STEM, outdoor adventure recreation camp. This thesis research project employed qualitative directed content analysis to examine the potential impacts of this adventure STEM program on participants’ perceptions of their outdoor recreation (OR) self-efficacy (Bandura, 1994; Mittelstaedt et al., 2009). Semi-structured interviews were conducted with 15 adolescent participants with an average age …

Programming Of Floating-Gate Transistors For Nonvolatile Analog Memory Array, Haifa Abulaiha

Graduate Theses, Dissertations, and Problem Reports (ETD)

Since they were introduced, floating-gate (FG) transistors have been used as non-volatile digital memory. Recent research has shown that floating-gate transistors can be successfully used as analog memory, specifically as programmable voltage and current sources. However, their proliferation has been limited due to the complex programming procedure and the complex testing equipment. Analog applications such as field-programmable analog arrays (FPAAs) require hundreds to thousands of floating-gate transistors on a single chip which makes the programming process even more complicated and very challenging. Therefore, a simplified, compact, and low-power scheme to program FGs are necessary. This work presents an improved version …

Selective Precipitation And Recovery Of Rare Earth Elements From Acid Mine Drainage, Robyn Lauren Christoferson

Graduate Theses, Dissertations, and Problem Reports (ETD)

The ability to secure rare earth elements (REEs) in the United States is of concern due to the rapid growth in demand and the monopolistic supply chain. The demand for REEs has skyrocketed in recent years due to the development of many green technologies. The United States and many other countries are currently reliant on China for REEs, who currently control greater than 90% of the global supply. Due to the severe impact of previous Chinese export quotas, it is important to lessen the reliance on importation and explore methods of recycling REEs from secondary sources. A secondary REE source …

Representation Learning With Adversarial Latent Autoencoders, Stanislav Pidhorskyi M.S.

Graduate Theses, Dissertations, and Problem Reports (ETD)

A large number of deep learning methods applied to computer vision problems require encoder-decoder maps. These methods include, but are not limited to, self-representation learning, generalization, few-shot learning, and novelty detection. Encoder-decoder maps are also useful for photo manipulation, photo editing, superresolution, etc. Encoder-decoder maps are typically learned using autoencoder networks.
Traditionally, autoencoder reciprocity is achieved in the image-space using pixel-wise
similarity loss, which has a widely known flaw of producing non-realistic reconstructions. This flaw is typical for the Variational Autoencoder (VAE) family and is not only limited to pixel-wise similarity losses, but is common to all methods relying upon …

Adaptation Of Coal Mine Floor Rating (Cmfr) To Eastern U.S. Coal Mines, Sena Cicek

Graduate Theses, Dissertations, and Problem Reports (ETD)

Floor heave—the excessive deformation and failure of floor strata—is a serious problem for many underground coal mining operations in the U.S. There is an accepted floor heave design methodology developed for the Illinois basin coal mines (Gadde, 2009). However, for Eastern U.S. coal mines in the Appalachian region, there is not any systematic design method to assess floor heave potential. In order to prevent stability problems associated with floor failure and to ensure the safety of the miners in this region, a systematic and proactive method to assess the potential of floor stability that also takes the floor failure mechanisms …

Solution Tool To Predict Filter Cake Formation For Acid Mine Drainage (Amd) Slurries, Roberto Ecuador Martinez Ochoa

Graduate Theses, Dissertations, and Problem Reports (ETD)

Acid Mine Drainage (AMD), also known as alkaline mine drainage resulted from abandoned and active coal mining areas has been a major water pollutant in the mid-Atlantic region of the United States affecting aquatic life, recreational areas, tourism, etc. AMD results from during and post mining activities all around the US and the world containing high levels of acidic materials such as sulfate and other heavy metals.

The United States Environmental Protecting Agency (EPA) has recommended the use of different mechanisms for mitigation purposes due to considerable existing and potential damage generated by AMD. This report focuses on the usage …

Image And Video-Based Autism Spectrum Disorder Detection Via Deep Learning, Mindi Ruan

Graduate Theses, Dissertations, and Problem Reports (ETD)

People with Autism Spectrum Disorder (ASD) show atypical attention to social stimuli and aberrant gaze when viewing images of the physical world. However, it is unknown how they perceive the world from a first-person perspective. In this study, we used machine learning to classify photos taken in three different categories (people, indoors, and outdoors) as either having been taken by individuals with ASD or by peers without ASD. Our classifier effectively discriminated photos from all three categories but was particularly successful at classifying photos of people with >80% accuracy. Importantly, the visualization of our model revealed critical features that led …

Low-Cost Skewed Redundant Imu Configuration For State-Space Recovery In A Saturated Environment, Levi S. Hubbard

Graduate Theses, Dissertations, and Problem Reports (ETD)

Low-cost sensors for state space determination can be used successfully for ground vehicles, robots, unmanned aerial vehicles, and Internet-of-Things applications. When a high fidelity Inertial Measurement Unit (IMU) cannot be obtained for state space determination, low-cost sensors can be used to satisfactory standards, despite their limitations in capabilities, by using various implementation techniques. The research group was experimentally investigating state space information of an unstable flying vehicle for motion simulation validation. The high fidelity motion capture system would intermittently lose track of the flight vehicle which lost critical flight data.

The goal was to determine the potential of low-cost off-the-shelf …

Respiratory Flow Characteristics Of Intensive Care Healthcare Workers Performing Patient Care Activities, Shawn R. Williamson

Graduate Theses, Dissertations, and Problem Reports (ETD)

In the United States, under OSHA regulations, all respirators used in the workplace must be certified by the National Institute of Occupational Safety and Health (NIOSH). Under current NIOSH standards, loose-fitting powered air-purifying respirators (PAPR) must provide a minimum operational flow of 170 liters per minute. The objective of this study was to characterize the breathing flow rates of nine health care workers during patient care activities typically performed in a hospital's intensive care unit. This characterization will be used to determine the feasibility of lowering the minimum operational flow rate of PAPRS used in health care settings.

Each participant …

Large-Scale Modeling And Assessments Of Climate, Land Cover, And Sea Level Change Impacts On Stormwater Runoff In Coastal Urban-Natural Environments, Erfanul Huq

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation investigated the potential impacts of changing climate, land cover, and sea level on the future stormwater budget and extreme runoff in coastal urban-natural environments. Two large-scale basins, namely Florida Southeast Coasts Basin (7117 km2) and Saint Johns River Basin (24928 km2), were selected for this study. The basins represented gradients in climate, land cover, and hydrology across the Atlantic coasts of Florida and the southeast U.S. Two mechanistic hydrologic models were developed for the basins using U.S. Environmental Protection Agency (U.S. EPA)’s Storm Water Management Model (SWMM) 5.1. The models were calibrated and validated with observed historical streamflow …

Scaling-Based Robust Predictions Of Periodic Stream Water Quality Variables Across The Contiguous U.S., Mohammad Abu Zafer Siddik

Graduate Theses, Dissertations, and Problem Reports (ETD)

Stream water quality is at the core of the biological and ecological health of streams and rivers. Subject to the environmental variation and in-stream metabolic activities, key water quality indicators such as dissolved oxygen (DO), water temperature (Tw), and chlorophyll a (Chl a, an indicator of primary productivity) typically follow a concave-shaped diurnal cycle. Variation and changes in climatic drivers (e.g., solar radiation, air temperature, and pressure), land uses, and hydrologic variables lead to a high spatiotemporal variability in stream water quality. The spatiotemporal variation challenges the development of robust models for predictions across large scales (e.g., county, state, country), …

Spatio-Temporal Analysis Of Crime Incidents For Forensic Investigation, Jamie Spencer Spaulding

Graduate Theses, Dissertations, and Problem Reports (ETD)

Crime analysis and mapping has been routinely employed to gather intelligence which informs security efforts and forensic investigations. Traditionally, geographic information systems in the form of third-party mapping applications are used for analysis of crime data but are often expensive and lack flexibility, transparency, or efficiency in uncovering associations and relationships in crime. Each crime incident and article of evidence within that incident has an associated spatial and temporal component which may yield significant and relevant information to the case. Wide variations exist in the techniques that departments use and commonly spatial and temporal components of crime are evaluated independently, …

Using Ai And Machine Learning To Indicate Shale Anisotropy And Assist In Completions Design, Cole E. Palmer

Graduate Theses, Dissertations, and Problem Reports (ETD)

Operating companies in the unconventional Marcellus shale play have all faced a similar and problematic issue, while attempting to produce natural gas over the last decade. Companies have quickly realized that not every perforation along their horizontal wells are producing gas. In fact, producing perforations are only ranging from 15%-70% of the total perforations along the horizontal wellbore [1]. This unexplained issue results in millions of dollars in lost revenue per well, in addition to the sunk cost of paying for completions that are not actually yielding any produced gas.

What is causing these perforations to have no produced gas? …

Energy Forensics Analysis, Rupa Das

Graduate Theses, Dissertations, and Problem Reports (ETD)

The energy consumed by a building can reveal information about the occupants and their activities inside the building. This could be utilized by industries and law enforcement agencies for commercial or legal purposes. Utility data from Smart Meter (SM) readings can reveal detailed information that could be mapped to foretell resident occupancy and type of appliance usage over desired time intervals. However, obtaining SM data in the United States is laborious and subjected to legal and procedural constraints. This research develops a user-driven simulation tool with realistic data options and assumptions of potential human behavior to determine energy usage patterns …

Understanding Academic Relevancy: Linking Practice To Classroom Through Adventure Stem Education, Alice Morgan

Graduate Theses, Dissertations, and Problem Reports (ETD)

The purpose of this research paper was to examine the relationship between vocational relevancy and adventure STEM education in the context of a four-day adventure STEM camp. Middle school students participated in a variety of adventure activities designed to teach STEM concepts. Using a concurrent triangulation mixed methods design, 246 students completed pre- and post-surveys that assessed changes in attitudes related to STEM interest, career interest, STEM career knowledge, STEM identity, STEM self-efficacy, and STEM value. Fourteen students and eight teachers participated in semi-structured interviews to further examine the role of vocational relevancy in curricula. Overall, results indicate some support …

Pulmonary Immune Responses To Respirable Elongate Mineral Particles Of Asbestiform And Non-Asbestiform Morphologies, Timur Khaliullin

Graduate Theses, Dissertations, and Problem Reports (ETD)

Inhalation exposure to asbestiform elongate mineral particles (EMPs) may cause pulmonary fibrosis, lung and pleural cancer. At the same time, epidemiological evidence for non-asbestiform EMP pathogenicity is scarce, with little if any risk of cancer, but consistent findings of pneumoconiosis and increased mortality. Globally, conditions caused by asbestos exposures contribute most to the occupational cancer burden and are responsible for the increasing mortality for occupational respiratory diseases. Immunological components of the fiber-induced lesions are extremely understudied, partly due to the lack of comparable test articles. In this study I utilized respirable preparations of asbestiform and non-asbestiform riebeckite and tremolite to …

Music And Politics In Figure Skating: American And Soviet Nationalism, Cultural Diplomacy, And Identity At The Winter Olympics, 1968–1988, Mary Bridget Golden

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis situates figure skating, music, and Cold War politics during three separate Winter Olympic Games held in 1968, 1976, and 1988, examining the impact of this intersection on the sport of figure skating. Through a survey of seven Olympic medal-winning figure skating programs in the men’s and women’s single divisions and the pairs’ division, evidence of the relationship between politics and music is examined in the musical selections of the skaters’ programs. This thesis also explores the overwhelming prominence in skating programs of musical selections that appealed to the tastes of an elite majority during the Cold War, while …

Development, Analysis And Case Studies Of Impact Resistant Steel Sets For Underground Roof Fall Rehabilitation, Dakota D. Faulkner

Graduate Theses, Dissertations, and Problem Reports (ETD)

Underground mines often experience roof falls in entries, crosscuts, and intersections of active mining sections, main travel ways, and belt entries. Roof fall heights greater than 20 ft (6 m) make re-bolting of the newly exposed roof dangerous and impractical. To protect mine personnel, belts, moving vehicles, and other equipment, mine operators typically install steel structures such as square or arch sets in the roof fall areas. Wood lagging is usually installed between the steel-sets to enclose the area and protect the entry from recurring falls. Usually the void space above the steel-sets and wood lagging is backfilled. However, backfilling …

Impacts Of Bike Sharing On Transit Ridership, Moathe Salah Aljeri

Graduate Theses, Dissertations, and Problem Reports (ETD)

Biking is an active, environmentally friendly, and sustainable transportation mode that facilitates short utilitarian and recreational trips. As such, cities around the world have been implementing bicycle sharing/renting programs at stations in a wide network so that a traveler can mount one close to their origins and drop it off at a station nearest to their destinations. In addition, bike sharing programs can solve the first-mile and last-mile connectivity problems of transit modes. Such programs also enable short trips that were previously impossible without using transit modes. This research investigated the relationship between New York City (NYC) subway ridership and …

Effects Of Supplementary Cementitious Materials On Early-Age Tensile Creep And Shrinkage Of Concrete, Lucas James Bucklen

Graduate Theses, Dissertations, and Problem Reports (ETD)

Determination of early-age tensile creep properties is critical for the performance of mass concrete structures at an early age. Due to the stress relaxation that tensile creep induces in concrete structures, accurate quantification of creep deformation is needed to determine the stress profile of the structure. Conventional methods of measuring tensile creep include the direct tension test where the concrete is subject to constant tensile stress. This method requires large quantities of concrete with embedded strain gauges which can only be used once. In this paper, the tensile creep parameters of concrete are found by using the restrained concrete ring …

Searches For Fast Radio Bursts Using Machine Learning, Devansh Agarwal

Graduate Theses, Dissertations, and Problem Reports (ETD)

Fast Radio bursts (FRBs) are enigmatic astrophysical events with millisecond durations and flux densities in the range 0.1-100 Jy, with the prototype source discovered by Lorimer et al. (2007). Like pulsars, FRBs show the characteristic inverse square sweep in observing frequency due to propagation through an ionized medium. This effect is quantified by the dispersion measure (DM). Unlike pulsars, FRBs have anomalously high DMs, which are consistent with an extragalactic origin. Over 100 FRBs have been published at the time of writing, and 13 have been conclusively identified with host galaxies with spectroscopically determined redshifts in the range 0.003 ≤ …

Assessment Of Unmanned Aerial Systems And Lidar For The Utility Vegetation Management Of Electrical Distribution Rights-Of-Ways, Matthew R. Walker

Graduate Theses, Dissertations, and Problem Reports (ETD)

Utility Vegetation Management (UVM) is often the largest maintenance expense for many utilities. However, with advances in Unmanned Aerial Systems (UAS; or more commonly, “drones”) and lidar technologies, vegetation managers may be able to more rapidly and accurately identify vegetation threats to critical infrastructures. The goal of this study was to assess the utility of Geodetics’ UAS-lidar system for vegetation threat assessment for 1.6 km of a distribution electric circuit. We investigated factors which contribute to accurate tree crown detection and segmentation of trees from within an UAS-lidar derived point cloud, and the factors which contribute to accurate tree risk …

Investigation Of Phonon Polaritons In An Hbn Gan Heterostructure, Catherine G. O'Hearn

Graduate Theses, Dissertations, and Problem Reports (ETD)

There have been many great advances in the generation and manipulation of optics in the visible and near infrared (IR) range over the past decade. This is largely due to plasmonic enhancement, which has led to new technology in biosensing and molecule detection, solid-state lighting, and solar energy harvesting. The field of plasmonics uses quanta of plasma oscillations, plasmons, formed from the interaction between electromagnetic radiation and free electrons to enhance optical near field magnitudes. However, there is still a large region of the electromagnetic spectrum, covering the mid-infrared (MIR) and terahertz (THz) regions, ranging from 3 μm to 1 …

Improving The Biological Control Of Persicaria Perfoliata (Polygonaceae) Using Rhinoncomimus Latipes Korotyaev (Coleoptera: Curculionidae), Jaewon Kim

Graduate Theses, Dissertations, and Problem Reports (ETD)

Persicaria perfoliata (L.) H. Gross (Polygonaceae; Mile-a-minute weed) is a rapid-growing invasive vine introduced from eastern Asia to northeastern United States in the 1930s. This vine has been invaded in disturbed areas and reforestation sites in 15 states in the U.S. and forms dense, monocultural patches that may inhibit natural forest regeneration. To control this weed, a host-specific biocontrol agent, Rhinoncomimus latipes Korotyaev (Coleoptera: Curculionidae) has been released in the P. perfoliata invaded states in the U.S. during the past 15 years. Currently, R. latipes is released by hand to the invaded area where the presence of the weed is …

Risk Assessment Of Architecture Technical Debt, Mrwan Omar Kh. Ben Idris

Graduate Theses, Dissertations, and Problem Reports (ETD)

Technical Debt (TD) is a metaphor that refers to short-term solutions in software development that may affect the software development life cycle cost. Researchers have found many TD types. These TD types include but are not limited to code debt (CD), design debt (DD), and architecture technical debt (ATD). Several methods have been used to detect technical debt, such as bad smells, software metrics, and code comments. Although TD has received many researchers’ attention, ATD has received less attention compared with CD and DD. We found a lack of tools to deal with ATD in contrast to CD and DD. …