Digital Commons Network^™

Determination Of Ligustrazine In Rat Serum By Polymer Monolithic Micro-Extraction Combined With Ultra High Performance Liquid Chromatography-Tandem Mass Spectrometry, Danling Sun, Xitian Peng, Maomin Peng, Xian Zhang, Hong Xia, Zhimin Xu, Xizhou Hu

Faculty Publications

This study focused on developing an effective and environmentally friendly method to measure ligustrazine in rat serum by using polymer monolith micro-extraction (PMME) technique. A poly (methacrylic acid-ethylene glycol dimethacrylate) material was used to extract ligustrazine through hydrophobic and ion-exchange interaction. Qualitative and quantitative analysis was performed by a liquid chromatography and tandem mass spectrometry. After optimization of several PMME conditions, the developed method exhibited excellent extraction performance to the ligustrazine. Good linearity was acquired ranging from 10 to 2,000 ng mL-1, and the limit of detection of the proposed method was 0.14 ng mL-1. The recoveries measured by spiking …

Envrtype: A Software To Interplay Enviromics And Quantitative Genomics In Agriculture, Germano Costa-Neto, Giovanni Galli, Humberto Fanelli Carvalho, Jose Crossa, Roberto Fritsche-Neto

Faculty Publications

Envirotyping is an essential technique used to unfold the nongenetic drivers associated with the phenotypic adaptation of living organisms. Here, we introduce the EnvRtype R package, a novel toolkit developed to interplay large-scale envirotyping data (enviromics) into quantitative genomics. To start a user-friendly envirotyping pipeline, this package offers: (1) remote sensing tools for collecting (get_weather and extract_GIS functions) and processing ecophysiological variables (processWTH function) from raw environmental data at single locations or worldwide; (2) environmental characterization by typing environments and profiling descriptors of environmental quality (env_typing function), in addition to gathering environmental covariables as quantitative descriptors for predictive purposes (W_matrix …

Hydrothermal Synthesis And Structural Investigation Of A Crystalline Uranyl Borosilicate, Kristen A. Pace, Vladislav V. Klepov, Mark D. Smith, Travis Williams, Gregory Morrison, Jochen A. Lauterbach, Scott T. Misture, Hans Conrad Zur Loye

Faculty Publications

The relevance of multidimensional and porous crystalline materials to nuclear waste reme-diation and storage applications has motivated exploratory research focused on materials discovery of compounds, such as actinide mixed-oxoanion phases, which exhibit rich structural chemistry. The novel phase K1.8 Na1.2 [(UO2)BSi4 O12 ] has been synthesized using hydrothermal methods, rep-resenting the first example of a uranyl borosilicate. The three-dimensional structure crystallizes in the orthorhombic space group Cmce with lattice parameters a = 15.5471(19) Å, b = 14.3403(17) Å, c = 11.7315(15) Å, and V = 2615.5(6) Å3, and is composed of UO6 octahedra linked by [BSi4 O12 ]5− chains to …

Protocols For Assessing Transformation Rates Of Nitrous Oxide In The Water Column, Annie Bourbonnais, Claudia Frey, Xin Sun, Laura A. Bristow, Amal Jayakumar, Nathaniel E. Ostrom, Karen L. Casciotti, Bess B. Ward

Faculty Publications

Nitrous oxide (N2O) is a potent greenhouse gas and an ozone destroying substance. Yet, clear step-by-step protocols to measure N2O transformation rates in freshwater and marine environments are still lacking, challenging inter-comparability efforts. Here we present detailed protocols currently used by leading experts in the field to measure water-column N2O production and consumption rates in both marine and other aquatic environments. We present example 15N-tracer incubation experiments in marine environments as well as templates to calculate both N2O production and consumption rates. We discuss important considerations and recommendations regarding (1) precautions to prevent oxygen (O2) contamination during low-oxygen and anoxic …

Genes Related To Redox And Cell Curvature Facilitate Interactions Between Caulobacter Strains And Arabidopsis, Louis Berrios, Bert Ely

Faculty Publications

Bacteria play an integral role in shaping plant growth and development. However, the genetic factors that facilitate plant-bacteria interactions remain largely unknown. Here, we demonstrated the importance of two bacterial genetic factors that facilitate the interactions between plant-growth-promoting (PGP) bacteria in the genus Caulobacter and the host plant Arabidopsis. Using homologous recombination, we disrupted the cytochrome ubiquinol oxidase (cyo) operon in both C. vibrioides CB13 and C. segnis TK0059 by knocking out the expression of cyoB (critical subunit of the cyo operon) and showed that the mutant strains were unable to enhance the growth of Arabidopsis. In addition, disruption of …

What Is Refractory Organic Matter In The Ocean?, Federico Baltar, Xosé A. Alvarez-Salgado, Javier Arístegui, Ronald Benner, Dennis A. Hansell, Gerhard J. Herndl, Christian Lønborg

Faculty Publications

About 20% of the organic carbon produced in the sunlit surface ocean is transported into the ocean’s interior as dissolved, suspended and sinking particles to be mineralized and sequestered as dissolved inorganic carbon (DIC), sedimentary particulate organic carbon (POC) or “refractory” dissolved organic carbon (rDOC). Recently, the physical and biological mechanisms associated with the particle pumps have been revisited, suggesting that accepted fluxes might be severely underestimated (Boyd et al., 2019; Buesseler et al., 2020). Perhaps even more poorly understood are the mechanisms driving rDOC production and its potential accumulation in the ocean. On the basis of …

Activating Mutations In Braf Disrupt The Hypothalamo-Pituitary Axis Leading To Hypopituitarism In Mice And Humans, Angelica Gualtieri, Nikolina Kyprianou, Louise C. Gregory, Maria Lillina Vignola, James G. Nicholson, Rachael Tan, Shin-Ichi Inoue, Valeria Scagliotti, Pedro Casado, James Blackburn, Fernando Abollo-Jimenez, Eugenia Marinelli, Rachael E.J. Besser, Wolfgang Högler, I. Karen Temple, Justin H. Davies, Andrey Gagunashvili, Iain C.A.F. Robinson, Sally A. Camper, Shannon W. Davis, Pedro R. Cutillas, Evelien F. Gevers, Yoko Aoki, Mehul T. Dattani, Carles Gaston-Massuet

Faculty Publications

Germline mutations in BRAF and other components of the MAPK pathway are associated with the congenital syndromes collectively known as RASopathies. Here, we report the association of Septo-Optic Dysplasia (SOD) including hypopituitarism and Cardio-Facio-Cutaneous (CFC) syndrome in patients harbouring mutations in BRAF. Phosphoproteomic analyses demonstrate that these genetic variants are gain-of-function mutations leading to activation of the MAPK pathway. Activation of the MAPK pathway by conditional expression of the Braf^V600E/+ allele, or the knock-in Braf^Q241R/+ allele (corresponding to the most frequent human CFC-causing mutation, BRAF p.Q257R), leads to abnormal cell lineage determination and terminal differentiation of …

What Is Refractory Organic Matter In The Ocean?, Federico Baltar, Xosé A. Alvarez-Salgado, Javier Arístegui, Ronald Benner, Dennis A. Hansell, Gerhard J. Herndl, Christian Lønborg

Faculty Publications

About 20% of the organic carbon produced in the sunlit surface ocean is transported into the ocean’s interior as dissolved, suspended and sinking particles to be mineralized and sequestered as dissolved inorganic carbon (DIC), sedimentary particulate organic carbon (POC) or “refractory” dissolved organic carbon (rDOC). Recently, the physical and biological mechanisms associated with the particle pumps have been revisited, suggesting that accepted fluxes might be severely underestimated (Boyd et al., 2019; Buesseler et al., 2020). Perhaps even more poorly understood are the mechanisms driving rDOC production and its potential accumulation in the ocean. On the basis of …

Temperature Dependence Of Density And Viscosity Of Biobutanol-Gasoline Blends, Daniel Trost, Adam Polcar, Dorin Boldor, Divine Bup Nde, Artur Wolak, Vojtĕch Kumbár

Faculty Publications

Butanol seems to be an eligible fuel for compensating for the increasing fuel consumption. Biobutanol could be produced from local sources in the place of use. Its properties show similar results to gasoline, so biobutanol could be added as a biocomponent into fuels. Important properties, in the case of blending biobutanol into gasoline, are its fluid properties and their dependence on the temperature. Therefore, in this paper, the volumetric mass density and viscosity of the selected ratios between biobutanol and gasoline (0, 5, 10, 85, 100 vol.%) were tested over the temperature range from -10 °C up to 40 °C. …

Microwave-Assisted Lignin Liquefaction In Hydrazine And Ethylene Glycol: Reaction Pathways Via Response Surface Methodology, Divine B. Nde, Mohamad Barekati-Goudarzi, Pranjali D. Muley, Lavrent Khachatryan, Dorin Boldor

Faculty Publications

Microwave assisted liquefaction (MAL) of alkali lignin in ethylene glycol (EG) in the presence of hydrazine was carried out using response surface methodology. Dielectric properties of mixtures of lignin/EG at different hydrazine concentrations were determined to enhance the understanding of the MAL process. MAL parameters were hydrazine concentration (1–3%), temperature (100-180 °C), time (5-45 min) with the maximum microwave heating power limited to 750 W. Lignin/EG ratio was fixed at 1 g:10 ml. Dielectric properties were significantly influenced by hydrazine concentration and temperature. Major products from the liquefaction process (as % of peak areas) were grouped into guaiacol and derivatives …

Surface Freshwater Fluxes In The Arctic And Subarctic Seas During Contrasting Years Of High And Low Summer Sea Ice Extent, Sarah B. Hall, Bulusu Subrahmanyam, Ebenezer S. Nyadjro, Annette Samuelsen

Faculty Publications

Freshwater (FW) flux between the Arctic Ocean and adjacent waterways, predominantly driven by wind and oceanic currents, influences halocline stability and annual sea ice variability which further impacts global circulation and climate. The Arctic recently experienced anomalous years of high and low sea ice extent in the summers of 2013/2014 and 2012/2016, respectively. Here we investigate the interannual variability of oceanic surface FW flux in relation to spatial and temporal variability in sea ice concentration (SIC), sea surface salinity (SSS), and sea surface temperature (SST), focusing on years with summer sea–ice extremes. Our analysis between 2010–2018 illustrate high parameter variability, …

Genes Related To Redox And Cell Curvature Facilitate Interactions Between Caulobacter Strains And Arabidopsis, Louis Berrios, Bert Ely

Faculty Publications

Bacteria play an integral role in shaping plant growth and development. However, the genetic factors that facilitate plant-bacteria interactions remain largely unknown. Here, we demonstrated the importance of two bacterial genetic factors that facilitate the interactions between plant-growth-promoting (PGP) bacteria in the genus Caulobacter and the host plant Arabidopsis. Using homologous recombination, we disrupted the cytochrome ubiquinol oxidase (cyo) operon in both C. vibrioides CB13 and C. segnis TK0059 by knocking out the expression of cyoB (critical subunit of the cyo operon) and showed that the mutant strains were unable to enhance the growth of …

How To Look Like A Lawyer, Ann Juliano

Faculty Publications

Law schools often claim that they are teaching students “how to think like a lawyer.” What is less touted, however, is that students are learning how to look like a lawyer. They receive this message from multiple sources (faculty, alumni, peers, the career office) concerning a variety of situations: class, interviews, moot court, trial team, symposia and conferences. For law students who are first generation, these sources may be the only avenue (apart from the entertainment industry) of determining how to look like a lawyer. For law students who are transgender or gender non-binary, dress code advice dispensed along men/women …

Discursive Power And Resistance In The Information Worlds Maps Of Lgbtqia+ Community Leaders, Vanessa Kitzie, Travis L. Wagner, Alexander N. Vera

Faculty Publications

Purpose: This qualitative study explores how discursive power shapes South Carolina LGBTQIA+ communities' health information practices and how participants resist this power. Design/methodology/approach: Twenty-eight LGBTQIA+ community leaders from South Carolina engaged in semi-structured interviews and information worlds mapping – a participatory arts-based elicitation technique – to capture the context underlying how they and their communities create, seek, use, and share health information. We focus on the information worlds maps for this paper, employing situational analysis – a discourse analytic method for visual data – to analyze them. Findings: Six themes emerged describing how discursive power operates both within and outside …

The Impact Of Short Sleep On Food Reward Processes In Adolescents, Kara Mcrae Duraccio, K. N. Krietsch, N. Zhang, C. Whitacre, T. Howarth, M. Pfeiffer, D. W. Beebe

Faculty Publications

Short sleep has been linked to adolescent obesity risk, but questions remain regarding the dietary mechanisms by which this occurs. We tested whether mildly shortening sleep influences how rewarding and appealing healthy adolescents find several kinds of foods. Eighty-eight healthy adolescents completed a within-subjects crossover sleep experiment comparing 5 days of Short Sleep (6.5 hour sleep opportunity) vs. 5 days of Healthy Sleep (9.5 hour sleep opportunity). Following each condition, adolescents completed measures of food appeal and reinforcing value of food across five food types: sweets/desserts, fruits/vegetables, lean meats/eggs, fast food entrees, and processed snacks. Adolescents averaged 2.2 hours/night longer …

Twisted Spatiotemporal Optical Vortex Random Fields, Milo W. Hyde Iv

Faculty Publications

We present twisted spatiotemporal optical vortex (STOV) beams, which are partially coherent light sources that possess a coherent optical vortex and a random twist coupling their space and time dimensions. These beams have controllable partial coherence and transverse orbital angular momentum (OAM), which distinguishes them from the more common spatial vortex and twisted beams (known to carry longitudinal OAM) in the literature and should ultimately make them useful in applications such as optical communications and optical tweezing. We present the mathematical analysis of twisted STOV beams, deriving the mutual coherence function and linear and angular momentum densities. We simulate the …

Are Granulins Copper Sequestering Proteins?, Anukool A. Bhopatkar, Vijayaraghavan Rangachari

Faculty Publications

Granulins (GRN 1-7) are short (~6 kDa), cysteine-rich proteins that are generated upon the proteolytic processing of progranulin (PGRN). These peptides, along with their precursor, have been implicated in multiple pathophysiological roles, especially in neurodegenerative diseases. Previously we showed that GRN-3 and GRN-5 are fully disordered in the reduced form implicating redox sensitive attributes to the proteins. Redox-based modulations are often carried out by metalloproteins in mitigating oxidative stress and maintaining metal-homeostasis within cells. To probe whether GRNs play a role in metal sequestration, we tested the metal binding propensity of the reduced forms of GRNs −3 and − 5 …

Analyses Of Countermovement Jump Performance In Time And Frequency Domains, Zhanxin Sha, Zhaoxian Zhou, Boyi Dai

Faculty Publications

This study aimed to analyze counter-movement jump (CMJ) performance in time and frequency domains. Fortyfour Division I American football players participated in the study. Kinetic variables were collected from both dominant and non-dominant legs using two force plates. Normalized peak power, normalized net impulse, and normalized peak force significantly correlated with jump height (r =.960, r =.998, r =.725, respectively with p < .05). The mean frequency component was significantly correlated with CMJ performance (r =.355 with p < .05). The reliability of the frequency variables was higher than the time domain variables. Frequency domain variables showed weaker correlations with jump height compared with time domain variables. Frequency domain analysis provides frequency components, which represent the rate of energy transmission from the eccentric phase to the end of the push-off phase. Frequency component information may provide additional information for the analyses of CMJ performance for athletes.

Changes In Soil Chemistry And Foliar Metabolism Of Himalayan Cedar (Cedrus Deodara) And Himalayan Spruce (Picea Smithiana) Along An Elevational Gradient At Kufri, Hp, India: The Potential Roles Of Regional Pollution And Localized Grazing, Rakesh Minocha, Alexandra R. Contosta, Gregory B. Lawrence, Ravinder K. Kohli, Subhash C. Minocha, Stephanie Long

Faculty Publications

We investigated changes in soil chemistry and foliar metabolism of Himalayan cedar [Cedrus deodara (Roxb. Ex Lamb.) G.Don] and Himalayan spruce [Picea smithiana (Wall.) Boiss] trees along a steep elevational gradient in the lower Himalayan Mountains at Kufri, Himachal Pradesh (HP), India. The foliar and soil samples were collected from four locations along a 300 m elevational gradient at ridge, high-, mid-, and low-elevation sites within the forested Shimla Water Catchment Wildlife Sanctuary that provides water for the city of Shimla, HP,. Observations at the time of sampling revealed that the high-elevation site was being heavily grazed. Soils collected at …

Food Processing, Dysbiosis, Gastrointestinal Inflammatory Diseases, And Antiangiogenic Functional Foods Or Beverages, Jack N. Losso

Faculty Publications

Foods and beverages provide nutrients and alter the gut microbiota, resulting in eubiosis or dysbiosis. Chronic consumption of a diet that is high in saturated or trans fats, meat proteins, reducing sugars, and salt and low in fiber induces dysbiosis. Dysbiosis, loss of redox homeostasis, mast cells, hypoxia, angiogenesis, the kynurenine pathway, transglutaminase 2, and/or the Janus kinase pathway are implicated in the pathogenesis and development of inflammatory bowel disease, celiac disease, and gastrointestinal malignancy. This review discusses the effects of oxidative, carbonyl, or glycative stress-inducing dietary ingredients or food processing-derived compounds on gut microbiota and gastrointestinal epithelial and mast …

Characterization, Bio-Uptake And Toxicity Of Polymer-Coated Silver Nanoparticles And Their Interaction With Human Peripheral Blood Mononuclear Cells, Sahar Pourhoseini, Reilly T. Enos, Angela E. Murphy, Bo Cai Ph.D., Jamie Lead

Faculty Publications

Silver nanoparticles (AgNPs) are widely used in medical applications due to their antibacterial and antiviral properties. Despite the extensive study of AgNPs, their toxicity and their effect on human health is poorly understood, as a result of issues such as poor control of NP properties and lack of proper characterization. The aim of this study was to investigate the combined characterization, bio-uptake, and toxicity of well-characterized polyvinylpyrrolidone (PVP)-coated AgNPs in exposure media during exposure time using primary human cells (peripheral blood mononuclear cells (PBMCs)). AgNPs were synthesized in-house and characterized using a multimethod approach. Results indicated the transformation of NPs …

Retaining Eucalyptus Harvest Residues Promotes Different Pathways For Particulate And Mineral-Associated Organic Matter, Gabriel W. D. Ferreira, Fernanda C. C. Oliveira, Emanuelle M. B. Soares, Jorg Schnecker, Ivo R. Silva, A. Stuart Grandy

Faculty Publications

Eucalyptus plantations have replaced other (agro)ecosystems over 5.6 Mha in Brazil. While these plantations rapidly accumulate carbon (C) in their biomass, the C storage in living forest biomass is transient, and thus, longer-term sustainability relies on sustaining soil organic matter (SOM) stocks. A significant amount of harvest residues (HR) is generated every rotation and can yield SOM if retained in the field. Yet, there is little information on how managing eucalyptus HR changes SOM dynamics. We used isotopic and molecular approaches in a 3-yr field decomposition experiment where a native grassland has been replaced by eucalyptus plantations to assess how …

Using Multiple Ecological Models To Inform Environmental Decision-Making, Kristy A. Lewis, Kenneth A. Rose, Kim De Mutsert, Shaye Sable, Cameron Ainsworth, Damian C. Brady, Howard Townsend

Faculty Publications

Coastal ecosystems are experiencing degradation from compound impacts of climate change and multiple anthropogenic disturbances. These pressures often act synergistically and complicate designing effective conservation measures; consequently, large-scale coastal restoration actions become a wicked problem. The purpose of this study was to use two different food web models in a coordinated manner to inform resource managers in their assessment of the ecological effects of a large-scale marsh restoration project. A team was formed that included the model developers and outside scientists, who were asked to use available model results of the calibrated simulations of an Ecopath with Ecosim (EwE) model …

Effects Of Nutrient Management Scenarios On Marine Food Webs: A Pan-European Assessment In Support Of The Marine Strategy Framework Directive, Chiara Piroddi, Ekin Akoglu, Eider Andonegi, Jacob W. Bentley, Igor Celić, Marta Coll, Donna Dimarchopoulou, René Friedland, Kim De Mutsert, Raphael Girardin, Elisa Garcia-Gorriz, Bruna Grizzetti, P. Y. Hernvann, Johanna J. Heymans, Bärbel Müller-Karulis, Simone Libralato, Christopher P. Lynam, Diego Macias, Svetla Miladinova, Fabien Moullec, Andreas Palialexis, Ove Parn, Natalia Serpetti, Cosimo Solidoro, Jeroen Steenbeek, Adolf Stips, Maciej T. Tomczak, Morgane Travers-Trolet, Athanassios C. Tsikliras

Faculty Publications

Eutrophication is one of the most important anthropogenic pressures impacting coastal seas. In Europe, several legislations and management measures have been implemented to halt nutrient overloading in marine ecosystems. This study evaluates the impact of freshwater nutrient control measures on higher trophic levels (HTL) in European marine ecosystems following descriptors and criteria as defined by the Marine Strategy Framework Directive (MSFD). We used a novel pan-European marine modeling ensemble of fourteen HTL models, covering almost all the EU seas, under two nutrient management scenarios. Results from our projections suggest that the proposed nutrient reduction measures may not have a significant …

A Survey Of Compound Heterozygous Variants In Pediatric Cancers And Structural Birth Defects, Dustin B. Miller, Stephen R. Piccolo

Faculty Publications

Compound heterozygous (CH) variants occur when two recessive alleles are inherited and the variants are located at different loci within the same gene in a given individual. CH variants are important contributors to many different types of recessively inherited diseases. However, many studies overlook CH variants because identification of this type of variant requires knowing the parent of origin for each nucleotide. Using computational methods, haplotypes can be inferred using a process called “phasing,” which estimates the chromosomal origin of most nucleotides. In this paper, we used germline, phased, whole-genome sequencing (WGS) data to identify CH variants across seven pediatric …

Relationship Between Diet Quality Scores And The Risk Of Frailty And Mortality In Adults Across A Wide Age Spectrum, Kulapong Jayanama, Olga Theou, Judith Godin, Leah Cahill, Nitin Shivappa Mbbs, Mph, Ph.D., James Hébert, Michael David Wirth Msph, Phd, Yong-Moon Park, Teresa T. Fung, Kenneth Rockwood

Faculty Publications

Background

Beyond intakes of total energy and individual nutrient, eating patterns may influence health, and thereby the risk of adverse outcomes. How different diet measures relate to frailty—a general measure of increased vulnerability to unfavorable health outcomes—and mortality risk, and how this might vary across the life course, is not known. We investigated the associations of five dietary indices (Nutrition Index (NI), the energy-density Dietary Inflammatory Index (E-DII™), Healthy Eating Index-2015 (HEI-2015), Mediterranean Diet Score (MDS), and Dietary Approaches to Stop Hypertension (DASH)) with frailty and mortality.

Methods

We included 15,249 participants aged ≥ 20 years from the 2007–2012 cohorts …

Modeling Dynamic Correlation In Zero-Inflated Bivariate Count Data With Applications To Single-Cell Rna Sequencing Data, Zhen Yang, Yen-Yi Ho

Faculty Publications

Interactions between biological molecules in a cell are tightly coordinated and often highly dynamic. As a result of these varying signaling activities, changes in gene coexpression patterns could often be observed. The advancements in next-generation sequencing technologies bring new statistical challenges for studying these dynamic changes of gene coexpression. In recent years, methods have been developed to examine genomic information from individual cells. Single-cell RNA sequencing (scRNA-seq) data are count-based, and often exhibit characteristics such as overdispersion and zero inflation. To explore the dynamic dependence structure in scRNA-seq data and other zero-inflated count data, new approaches are needed. In this …

An Automated Tool For Comparing Phonetic Transcriptions, Dallin J. Bailey, Marisha Speights Atkins, Ishaan Mishra, Sicheng Li, Yaoxuan Luan, Cheryl Seals

Faculty Publications

Many computerized tools for comparing phonetic transcriptions have been proposed and shared in the past; however, previous tools are relatively difficult to access and incorporate into clinical and research practice, or require users to learn additional phonetic symbol systems. The purpose of this project was to develop and test a readily available web-based application for quantitatively comparing phonetic transcriptions that are input using International Phonetic Alphabet (IPA) symbols. A web-based computer application was developed to allow for IPA phonetic transcription comparison. A point-and-click keyboard was developed to provide support for character input of the full IPA, as well as most …

Thermal Decomposition Behavior Of 3d Printing Filaments Made Of Wood-Filled Polylactic Acid/Starch Blend, Yufeng Sun, Danbee Lee, Yapeng Wang, Suiliang Li, Jilai Ying, Xinping Liu, Guangyin Xu, Jaegyoung Gwon, Qinglin Wu

Faculty Publications

Dynamic thermogravimetric analysis under nitrogen environment was used to understand the thermal decomposition process of 3D printing filaments made of wood-filled polylactic acid (PLA)/starch blend. The characteristic temperatures and apparent activation energy (AAE) of the filaments with various starch contents were calculated with well-known kinetic models by Friedman, Flynn–Wall–Ozawa, Coats–Redfern, and Kissinger. With the increased starch content in the filament, the onset thermal decomposition temperatures of the filaments decreased gradually from 272.4 to 155.1°C. The thermal degradation degree became smaller, and the transitional temperature interval became larger with increased starch proportion. The AAE values of the three types of filaments …

Adverse Childhood Experiences, Psychological Distress, And Fathering Behaviors, Kevin Shafer, Scott D. Easton

Faculty Publications

Objective

This study examines the relationship between adverse childhood experiences (ACEs), internalized and externalized psychological distress, and six measures of parenting behavior among fathers in the United States.

Background

Prior research on ACEs and parenting has focused almost exclusively on mothers, specific types of childhood adversity, and the intergenerational transmission of abuse, neglect, and other traumatic experiences. This study extends the literature by considering ACEs in fathers, using a multidimensional measure of ACEs, and multiple measures of positive and negative fathering behavior.

Method

Using the ecological model of father involvement, this study is based on a national sample of more …