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“Con Ăn Cơm Chưa?” (“Have You Eaten Yet?”): Foodways, Identity, And Generational Place-Making For Vietnamese Women In Memphis, Alana Freimanis May 2026

“Con Ăn Cơm Chưa?” (“Have You Eaten Yet?”): Foodways, Identity, And Generational Place-Making For Vietnamese Women In Memphis, Alana Freimanis

Electronic Theses and Dissertations

This qualitative study examines the role of food within community tactics for mobilization and negotiation. In order to do so, this study employs a mixed-methods approach of semi-structured interviews, participant observations, and archival analysis, to answer questions around how participants subvert historically racialized narratives around Vietnamese immigrant’s labor, family, and identity. Specifically, how do Vietnamese American women in Memphis use food labor to negotiate racialized immigrant identities and mobilize cultural and community power within the constraints of gendered expectations, class position, and racial stereotypes? Furthermore, this research focuses on Vietnamese women’s positionality, centering women chefs and community leaders as the …


Health And Care: Childhood Among The Classic Period Maya At Buenavista Del Cayo, Belize, Lindsey Hall May 2026

Health And Care: Childhood Among The Classic Period Maya At Buenavista Del Cayo, Belize, Lindsey Hall

Electronic Theses and Dissertations

Three deposits of perinates, infants, and young children within two non-residential superstructures of Buenavista del Cayo, Belize, display evidence of daily maintenance and care. A total of ten subadult individuals, aged 39.4 weeks gestation to 3 years, from the archaeological site of Buenavista were recovered during 2018 excavations. Signs of care and daily maintenance include survivorship through the vulnerable neonatal period (first twenty-eight days) and transition into infancy, survivorship with potential pinprick lesions on external and internal zygomatic, parietal, and pars basilaris, and intentional maintenance of the body after death. Identification of care and daily maintenance at Buenavista informs the …


Mining The Body: Racial Capitalism And The Embodied Sacrifice Zone, Regina Marie Young May 2026

Mining The Body: Racial Capitalism And The Embodied Sacrifice Zone, Regina Marie Young

Electronic Theses and Dissertations

Mining the Body: Racial Capitalism and the Sacrifice Zone of the Body examines 20th and 21st-century American literature, excavating the ways in which mining not only extracted resources from the earth, but also mined the bodies of their workers for their labor, often ignoring safety in the name of economy. This extraction of coal and of labor, along with its attendant exploitations, sparked unionization and labor movements throughout the century, as miners were frequently at the forefront of asserting their rights in response to this treatment. Using a framework that relies on both environmental criticism, such as Rob Nixon’s Slow …


Right (Or Wrong) To Bear Arms: Regional-Campus Women Students' Perceptions Of Campus Carry, Daniel Christian May 2026

Right (Or Wrong) To Bear Arms: Regional-Campus Women Students' Perceptions Of Campus Carry, Daniel Christian

Electronic Theses and Dissertations

Campus carry legislation remains one of the most contested higher education policy issues in the United States, particularly in states where concealed carry permit holders may legally carry firearms on public college campuses. Although prior research has included women as one of many demographics, there is a dearth of scholarship that focuses on college women exclusively to investigate their response to campus carry. This gap is concerning given documented gender differences in attitudes toward gun policy and the disproportionate impact of sexual violence and safety concerns on women in collegiate settings.

To fill a gap in the literature, the proposed …


Computational Modeling Of Lamina Cribrosa Biomechanics, Lydia Schwartz May 2026

Computational Modeling Of Lamina Cribrosa Biomechanics, Lydia Schwartz

Electronic Theses and Dissertations

The lamina cribrosa is a critical structural component of the optic nerve head and is believed to play a central role in the development of glaucoma. Understanding how its geometry and microarchitecture influence the mechanical behavior is essential for improving computational models of the optic nerve head. However, the complex structure of the lamina cribrosa presents a difficult challenge for experimental and computational investigations. In this study, two computational modeling approaches were developed to investigate the influence of structural representation on lamina cribrosa biomechanics. A curvature-based continuum model was used to examine the effects of the anterior surface geometry, parameterized …


Iterative Decoding For Sccpm With Markov And Hidden Markov Sources, Zhijie Guo May 2026

Iterative Decoding For Sccpm With Markov And Hidden Markov Sources, Zhijie Guo

Electronic Theses and Dissertations

Continuous Phase Modulation (CPM) is an excellent digital modulation scheme recognized for its constant envelope property, continuous phase transitions, and inherent memory. These characteristics enable excellent spectral and power efficiency, allow compatibility with nonlinear amplifiers, and make CPM particularly attractive for power- and bandwidth-constrained applications such as satellite and deep space communications. Serially Concatenated Continuous Phase Modulation (SCCPM) with iterative decoding further improves error performance, and its flexibility enables it to evolve alongside state-of-the-art channel coding technologies and show significant potential for performance enhancement.

This dissertation investigates SCCPM systems with binary Markov and Hidden Markov Model (HMM) data sources and …


Development And Evaluation Of Ros-Responsive Thioketal-Capped Mesoporous Silica Nanoparticles For Dual Drug Delivery Of Moxifloxacin And Curcumin In Wound Healing, Saiganesh Pothuraju May 2026

Development And Evaluation Of Ros-Responsive Thioketal-Capped Mesoporous Silica Nanoparticles For Dual Drug Delivery Of Moxifloxacin And Curcumin In Wound Healing, Saiganesh Pothuraju

Electronic Theses and Dissertations

Chronic infected wounds remain a major clinical challenge because elevated reactive oxygen species (ROS) in the wound microenvironment sustain inflammation, damage regenerating tissue, and limit the effectiveness of conventional antimicrobial and anti-inflammatory therapy. To address this problem, this study aimed to develop ROS-responsive thioketal-capped mesoporous silica nanoparticles (TK-MSNs) for the dual delivery of moxifloxacin (MOX) and curcumin (CUR) to support the management of infected wounds. Mesoporous silica nanoparticles (MSNs) were synthesised using tetraethyl orthosilicate (TEOS) and cetyltrimethylammonium bromide (CTAB), followed by template removal, amino-functionalization with 3-aminopropyltriethoxysilane (APTES), and sequential loading of MOX and CUR. ROS-responsive capping was then achieved using …


With Equity And Inclusivity For All: Self-Reported Preparedness Of Band Directors To Teach Students With Exceptional Needs, Kendra Jenkins Lee May 2026

With Equity And Inclusivity For All: Self-Reported Preparedness Of Band Directors To Teach Students With Exceptional Needs, Kendra Jenkins Lee

Electronic Theses and Dissertations

The traditional memory theory of personal identity relies on an implicit storage model of memory to explain how the self persists over time. This model assumes that memories endure as stable representations that can be accurately retrieved, and that such representational continuity grounds diachronic identity. However, contemporary cognitive science demonstrates that remembering is an active and reconstructive process. Each act of recall reorganizes and transforms prior experience during the window of ecphory. This reconstructive reality poses a significant philosophical challenge. If memory is inherently unstable and transformable, it cannot straightforwardly ground the kind of continuity the theory requires.

In this …


The “Meta-Country” Of Morgan Wallen: Authenticity Signaling In Contemporary Country Music, Ryley Fallon May 2026

The “Meta-Country” Of Morgan Wallen: Authenticity Signaling In Contemporary Country Music, Ryley Fallon

Electronic Theses and Dissertations

Country music artist Morgan Wallen has dominated sales charts and streaming numbers on digital platforms such as Facebook, Instagram, and TikTok. Wallen has also crafted his own image of what it means to be “country,” distilling it into the usual, hyper-recognizable motifs of whiskey and trucks while transitioning them onto new media platforms. In addition, Wallen maintains his small-town Tennessee boy image despite conquering massive digital landscapes. This thesis argues that Morgan Wallen exemplifies a new phase of country music, “metacountry.” “Meta-country,” as detailed in this thesis, refers to the continuation of country music’s commercialization into the digital space in …


The Tugaloo Effect: Preliminary Analyses Of Population Genomics And Parasitism In Salamanders Of Northeast Georgia, Tyler Lewis Brock May 2026

The Tugaloo Effect: Preliminary Analyses Of Population Genomics And Parasitism In Salamanders Of Northeast Georgia, Tyler Lewis Brock

Electronic Theses and Dissertations

The Tugaloo River is a 50-mile-long stretch of river that serves as an important political and biogeographical boundary in far northeastern Georgia and northwestern South Carolina. The extreme topography, complex geological and hydrological history, and unique assemblage of soils, flora, and fauna of the Tugaloo region make it a prime candidate for study. I used the diverse salamander community there to conduct two studies. Study 1 investigated how the population genomics of select species in the genera Desmognathus and Plethodon were impacted by ancient drainage modifications from the Pleistocene which included not only the Tugaloo River but also the Tallulah, …


Recipe For Resistance: Oral Histories Of Queer Foodways In The Us South, Astrid Janie Knox-Mcconnell May 2026

Recipe For Resistance: Oral Histories Of Queer Foodways In The Us South, Astrid Janie Knox-Mcconnell

Electronic Theses and Dissertations

This thesis examines the emerging question of what constitutes “queer food.” It asks how this concept takes on a distinct regional form in the United States South. Drawing on oral histories, archival materials, and cookbooks, it argues that queer southern foodways are not only a subset of queer food studies, but also a distinct cultural and political formation shaped by southern histories of race, labor, family, and survival. The thesis makes the case that queer southern foodways function simultaneously as protest, utopian practice, and aesthetic pleasure. Through the act of cooking, eating, and sharing food, queer southerners articulate alternative social …


Foundations And Scope Of Moral Standing, Vikas Beniwal May 2026

Foundations And Scope Of Moral Standing, Vikas Beniwal

Electronic Theses and Dissertations

This thesis investigates the foundational grounds of moral standing. I contend that sentience, while frequently cited as the primary criterion, lacks sufficient justification when asserted as a necessary condition. I propose an alternate feature as sufficient grounds of moral standing.


On The Importance Of Proportionality In Congressional Redistricting, Guélan Kossi Zaour May 2026

On The Importance Of Proportionality In Congressional Redistricting, Guélan Kossi Zaour

Electronic Theses and Dissertations

Which party benefits the most from partisan gerrymandering? Extant literature attempting to measure this phenomenon is largely atheoretical, primarily focused on designing tools that could be used in court cases. I argue that measuring the partisan consequences of gerrymandering should require deeper conceptualization of the notion of fairness. I make the normative claim that proportionality, which I define as the alignment between a party’s share of the vote and its share of congressional districts in a given state, should be used as a standard of fairness. Using the redist R package, I measured the partisan consequences of gerrymandering by generating …


Perceptions Of Educators To Recognize And Respond To Suicidal Ideation Of Secondary Students, Clary Aaron May 2026

Perceptions Of Educators To Recognize And Respond To Suicidal Ideation Of Secondary Students, Clary Aaron

Electronic Theses and Dissertations

This qualitative phenomenological study explored how secondary teachers in East Tennessee perceive district-provided suicide prevention training and its role in supporting students experiencing suicidal ideation. Eleven middle and high school teachers who had previously made a crisis referral participated in semi-structured interviews. The study examined teachers’ experiences, perceived strengths and limitations of training, and needed resources. Findings revealed that teachers felt confident recognizing warning signs, especially behavioral changes, when strong student relationships existed. However, training was often described as repetitive, generic, and minimally engaging. Social media and limited support systems were seen as major stressors for students. Teachers emphasized relationship-centered …


“The Distance And Time Difference Aren’T Helping”: Family Communication Practices Of African Graduate Students Adapting To A New Country, Hummuh Abubakar May 2026

“The Distance And Time Difference Aren’T Helping”: Family Communication Practices Of African Graduate Students Adapting To A New Country, Hummuh Abubakar

Electronic Theses and Dissertations

This qualitative study examined how international graduate students maintained long-distance communication with family members while adapting to life in the United States. Drawing on semi-structured interviews with seven international students, the research explored how participants sustained emotional closeness, manage disclosure, and select communication media across geographic distance. Guided by Communication Privacy Management Theory and Media Richness Theory, the study analyzed how students regulated private information and strategically used video calls, voice calls, and messaging platforms to meet relational and emotional needs. Findings revealed four primary themes: reliance on digital communication technologies; the emotional and psychological functions of family communication; structural …


Parent Engagement And Advocacy In Individualized Education Programs In Rural Appalachian School Districts, Mollie Rutledge May 2026

Parent Engagement And Advocacy In Individualized Education Programs In Rural Appalachian School Districts, Mollie Rutledge

Electronic Theses and Dissertations

The purpose of this phenomenological study was to explore parent engagement and parent advocacy in the Individualized Education Program (IEP) development and implementation in rural Appalachian school districts. Parent engagement and parent advocacy in Individualized Education Program (IEP) development and implementation are persistent challenges in special education. By intentionally grounding this research in rural Appalachia, the researcher responded to calls for education research that is attentive to the complexity and diversity of rural communities. Parents in rural areas face unique challenges related to poverty, isolation, and limited resources that can influence their engagement and advocacy in the IEP process. The …


The Development And Evaluation Of A Group Therapy Program For Perinatal Loss In Rural Appalachia, Hope O'Neill May 2026

The Development And Evaluation Of A Group Therapy Program For Perinatal Loss In Rural Appalachia, Hope O'Neill

Electronic Theses and Dissertations

Perinatal loss can have vast adverse psychological consequences and has limited psychotherapeutic options to assist with those outcomes. Currently, there is no gold standard psychotherapy for the treatment of perinatal grief. Group therapy has proven to be an effective modality for various populations and has been shown to be beneficial for perinatal loss and the subsequent psychological outcomes. This study utilized a previously conducted systematic review to develop and evaluate a group psychotherapy for perinatal loss. The ten sessions of the group were completed by two participants and several constructs were explored pre- and post-intervention: grief, depression, anxiety, post-traumatic stress, …


Academic Self-Efficacy Of Black, White, And Hispanic Students Pursuing Professional Education Degrees And Licensure At An Hbcu In Midwest Ohio, Nathan Boles May 2026

Academic Self-Efficacy Of Black, White, And Hispanic Students Pursuing Professional Education Degrees And Licensure At An Hbcu In Midwest Ohio, Nathan Boles

Electronic Theses and Dissertations

The purpose of this comparative quantitative study was to determine, using three self-efficacy scales, General Self-Efficacy (GSE), Academic Self-Efficacy (ASE), and Educational Self-Efficacy (ESE), the differences in academic and educational self-efficacy among Black, White, and Hispanic students seeking a Professional Education degree and licensure at a Historically Black College and University in Midwest Ohio. Pre-service students’ self-efficacy and goal commitment can affect their likelihood of graduating with a license and may directly affect the number of novice teachers of color in the classroom. The literature examines factors that disrupt students’ self-efficacy, academic confidence, and persistence through the theoretical frameworks of …


Stochastic Universal Differential Equations For Epidemiological Modeling: Uncertainty Quantification In Disease Transmission Dynamics, Alice Menaya Armah-Bonney May 2026

Stochastic Universal Differential Equations For Epidemiological Modeling: Uncertainty Quantification In Disease Transmission Dynamics, Alice Menaya Armah-Bonney

Electronic Theses and Dissertations

Epidemic forecasting requires not only predictions of expected case counts, but also quantification of uncertainty, although existing surrogate modeling frameworks for agent-based models remain fundamentally deterministic. In this thesis a Stochastic Universal Differential Equation framework is presented that extends the deterministic Universal Differential Equation approach by incorporating a learnable stochastic diffusion term, enabling calibrated probabilistic forecasts while preserving the mechanistic interpretability and computational efficiency of the deterministic baseline. In doing so, a two-phase training algorithm is introduced to ensure stable convergence and the framework is validated against the ensemble output from ExaEpi, an exascale agent-based model of a COVID-19 outbreak …


Perceptions Of Effective Co-Teaching Partnerships In High School Inclusive Classrooms, Korri-Lee S. Wood May 2026

Perceptions Of Effective Co-Teaching Partnerships In High School Inclusive Classrooms, Korri-Lee S. Wood

Electronic Theses and Dissertations

The purpose of this qualitative study was to examine the characteristics and contextual factors that general education and special education teachers perceive as essential for effective co-teaching partnerships in high school inclusive classrooms. The study, which involved in-depth interviews with general and special education teachers in co-teaching partnerships, was conducted within a constructivist paradigm to shed light on interpersonal, communicative, and systemic variables that contribute to a positive, productive co-teaching experience. Purposeful sampling was employed to select general and special education teachers who were part of co-teaching partnerships. Thematic analysis was used to analyze data from semi-structured interviews, and an …


University Student Mental Health: Service Utilization, Equity Gaps, And Strategies To Improve Access, Richard Mutua Kilonzo May 2026

University Student Mental Health: Service Utilization, Equity Gaps, And Strategies To Improve Access, Richard Mutua Kilonzo

Electronic Theses and Dissertations

 

Student mental health and access to care are pressing concerns in higher education. This study assesses mental health outcomes and access to campus mental health services at East Tennessee State University. Survey data from the 2023–2024 Healthy Minds Study were analyzed to report the prevalence of depression, anxiety, and suicidal ideation across the student population. The study evaluates disparities in these outcomes and barriers to care across student groups, with particular attention to equity-impacted students, especially sexual and gender minority students.

Findings indicate widespread psychological distress alongside persistent barriers, including long wait times, limited-service availability, and stigma-related concerns. These barriers …


Bergsonian Blend: Subjective Temporality Within Modernist Aesthetics Of Mental Illness, Lydia Victoria Gervais May 2026

Bergsonian Blend: Subjective Temporality Within Modernist Aesthetics Of Mental Illness, Lydia Victoria Gervais

Electronic Theses and Dissertations

Henri Bergson was a modernist French philosopher who wrote extensively on the topic of the lived experience of time, which he called durée, or duration. His contemporary, Sigmund Freud, was developing psychoanalytic theory in a growing field of psychological study, which serves as a prominent ancestor to modern psychiatry and current psychoanalytical literary studies. Fiction writers of the 1900s absorbed the zeitgeist of melded chronology and consciousness, interweaving themes of time and trauma in their works. Utilizing Henri Bergson’s durée as a philosophical framework, I examine the moralization of time-consciousness in connection with mental illness and investigate representations of …


The Influence Of Intervention Strategies On Students With Disabilities Who Exhibit Challenging Behaviors In Rural Public Schools: Teacher Perceptions, Ben B. Robertson May 2026

The Influence Of Intervention Strategies On Students With Disabilities Who Exhibit Challenging Behaviors In Rural Public Schools: Teacher Perceptions, Ben B. Robertson

Electronic Theses and Dissertations

This phenomenological qualitative study addressed rural teachers' perceptions of the influence of intervention strategies on students with disabilities who exhibit challenging behaviors. The purpose of this study was to examine teachers’ perceptions of the effect of intervention strategies on academic achievement, student behavior outcomes, and teacher self-efficacy through the lens of Bandura’s Social Cognitive Theory. This theory is a complex, dynamic interaction among people, their behaviors, and their environments. Data collection included 14 individual interviews, conducted on Zoom with educators from one school district in Southern Virginia, including seven general education teachers and seven special education teachers. Data analysis strategies …


Machine-Learning Landslide Susceptibility And Runout Modeling In The Nolichucky River Gorge After Hurricane Helene, Grace Braver May 2026

Machine-Learning Landslide Susceptibility And Runout Modeling In The Nolichucky River Gorge After Hurricane Helene, Grace Braver

Electronic Theses and Dissertations

Extreme rainfall from Hurricane Helene (September 2024) triggered widespread landslides across the southern Appalachian region, highlighting the need for rapid landslide susceptibility assessments that capture both landslide initiation and downstream runout. Traditional susceptibility models often focus solely on initiation zones, limiting their ability to identify which slopes will generate destructive landslides or where material will travel. This study addresses that gap by (1) integrating Geographic Information System (GIS)-based machine learning susceptibility modeling using ArcGIS Pro: Maximum Entropy (MaxEnt) and Random Forest-Based and Boosted Classification and Regression (FBBC) and (2) the U.S. Geological Survey (USGS) Grfin (Growth, Flow, and Inundation) runout …


Media Portrayal Of High-Profile Female Victims Of Sexual Harassment, Chinenye Nwaneri May 2026

Media Portrayal Of High-Profile Female Victims Of Sexual Harassment, Chinenye Nwaneri

Electronic Theses and Dissertations

This rhetorical study investigated how the Nigerian media portray high-profile female victims of sexual harassment. The research was undertaken in response to concerns that media narratives often reinforce gender stereotypes and influence public perceptions of victims. Focusing on the sexual harassment allegations made by senator Natasha Akpoti-Uduaghan against Senate president Godswill Akpabio, the study analyzed newspaper coverage from Daily Trust and Vanguard between February and December 2025. Using Critical Discourse Analysis within the framework of Feminist Media Theory, the research examined how language and framing shaped the representation of the female accuser. The findings reveal that media coverage constructed the …


"Am I A Man Or A Muppet": A Rhetorical Analysis Of Generative Ai’S Representation Of Gender, Jessica Boaz May 2026

"Am I A Man Or A Muppet": A Rhetorical Analysis Of Generative Ai’S Representation Of Gender, Jessica Boaz

Electronic Theses and Dissertations

This thesis examines how generative artificial intelligence constructs and performs gender roles through a rhetorical analysis of the fully AI-generated podcast Fairytale Forensics. Drawing on theories of constitutive rhetoric, stereotyping, and McLuhan’s approach to the medium, this thesis investigates how AI-generated hosts interpret classic fairy tales while simultaneously reproducing and negotiating gender norms through the lens of prosopopoeia, metonymy and synecdoche. These performances rely on normative gender stereotypes that align with broader societal expectations, thereby potentially reinforcing existing cultural assumptions about masculinity and femininity. Ultimately, it demonstrates that AI-generated discourse does not merely reflect human biases but actively participates in …


Senior-Level Administrators’ Perceptions Of Deliberately Developmental Organization Principles And Employee Retention At Historically Black Colleges And Universities (Hbcus), Caprinia L. Taylor May 2026

Senior-Level Administrators’ Perceptions Of Deliberately Developmental Organization Principles And Employee Retention At Historically Black Colleges And Universities (Hbcus), Caprinia L. Taylor

Electronic Theses and Dissertations

Historically Black colleges and universities (HBCUs) have faced persistent challenges retaining qualified faculty and staff, threatening the environments they are uniquely positioned to create. High turnover, limited professional development, and inadequate support undermine employee well-being and student outcomes. This qualitative phenomenological study explored senior-level administrators’ perceptions of deliberately developmental organization (DDO) principles and their relevance to employee retention at HBCUs. Guided by DDO and organizational culture theory, the study examined how leadership practices, professional development, psychological safety, and organizational culture intersect with retention and belonging. Data were collected through semistructured interviews with participants across diverse HBCU contexts. Participants were selected …


Navigating The Shift: Supporting Health Sciences Faculty Transitioning From Industry To Asynchronous Online Education, Joshua D. Snyder May 2026

Navigating The Shift: Supporting Health Sciences Faculty Transitioning From Industry To Asynchronous Online Education, Joshua D. Snyder

Electronic Theses and Dissertations

This qualitative exploratory study examined how new online instructors in the health sciences division of a North Texas community college experienced institutional onboarding and professional development as they transitioned from industry roles into asynchronous online teaching. As community colleges expand online instruction to meet the needs of nontraditional learners, many health sciences faculty enter academic roles with strong clinical expertise but limited preparation in online pedagogy. Guided by the community of inquiry framework and self-efficacy theory, this study explored instructors’ perceptions of their preparedness for asynchronous teaching; the instructional challenges they encountered, particularly related to student engagement; and the types …


Attachment And Betrayal: Post-Infidelity Attachment Issues With A Focus On Gender, Taylor Forsythe May 2026

Attachment And Betrayal: Post-Infidelity Attachment Issues With A Focus On Gender, Taylor Forsythe

Electronic Theses and Dissertations

Infidelity represents a significant relational trauma that may disturb attachment processes such as trust, emotional intimacy, and closeness. There is a gap in the literature on how different infidelity exposures may relate to these attachment responses; more so, there is a dearth of information on the gender differences for attachment issues following any kind of infidelity. The purpose of this study aimed to examine differences in avoidant and anxious attachment across infidelity groups (no infidelity, non-sexual infidelity, sexual infidelity), and a further comparison of gender differences in those groups. Participants (N = 151) completed online surveys in a larger study …


Mechanism Of Formation Of Guanine-Guanine Crosslinks As Products Of One-Electron Oxidation Of 1-Methylguanosine In Acidic Medium, Ibrahim Braimah Mr May 2026

Mechanism Of Formation Of Guanine-Guanine Crosslinks As Products Of One-Electron Oxidation Of 1-Methylguanosine In Acidic Medium, Ibrahim Braimah Mr

Electronic Theses and Dissertations

Reactive oxygen species (ROS) from normal metabolism and environmental exposure may cause oxidative DNA damage. Guanine (G) is the most oxidizable nucleobase. One-electron oxidation (OEO) of G in produces guanine radical cation (G•⁺), which deprotonates to form guanyl radical G(-H)•.This radical exists in two tautomeric forms: G(N1-H)• and G(N2-H)•. Dimerization of guanyl radical yields G-G cross-links (D1/D2); a tautomeric form for dimer formation remains elusive. This study presents the first characterization of G• dimerization products from the OEO of 1-MeGuo in acidic medium. Photolysis at 470 nm in the presence of S₂O₈²⁻ and Ru(II)(bpy)₃²⁺ generates two major stereoisomers (D1AW* and …