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Doctoral Dissertations

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Petrography, Diagenesis And Environment Of Deposition Of The Gasconade Formation, Lower Ordovician, Southern Missouri, Abd El-Aziz El-Hady A. Borahay Jan 1973

Petrography, Diagenesis And Environment Of Deposition Of The Gasconade Formation, Lower Ordovician, Southern Missouri, Abd El-Aziz El-Hady A. Borahay

Doctoral Dissertations

"The Gasconade Formation (Lower Ordovician) has been studied in the surface and subsurface in the Ozarks of Missouri and northeastern Oklahoma. The formation is mostly dolomite with a sandstone member at the base (Gunter) and frequent occurrences of chert bodies of different shapes particularly in the middle part.

The dolomite crystals in the lower and upper parts are subhedral to euhedral of equicrystalline to two-size fabric and range in size from 300-600 microns, and subhedral to anhedral of variable fabric and smaller size in the middle part. A sequence of cloudy and clear areas, named zoning, characterizes the euhedral crystals. …


Film Boiling Of Benzene, Freon 113, Freon 11, And Normal Pentane From Horizontal Surfaces At Atmospheric Pressure, Richard Stanley Kistler Jan 1973

Film Boiling Of Benzene, Freon 113, Freon 11, And Normal Pentane From Horizontal Surfaces At Atmospheric Pressure, Richard Stanley Kistler

Doctoral Dissertations

"A film boiling study was conducted with five different area flat plates at atmospheric pressure for benzene, Freon 113, Freon 11, and n-pentane. The heat transfer surface was horizontal for all tests.

The data were compared to the correlations commonly used for heat transfer. The common correlations were found to be in error for small surface sizes, but adequate for all fluids except benzene for the largest surface, a semi-empirical equation which correlates the available data as a function of surface diameter was derived and discussed"--Abstract, page iii.


Measurement Of Molecular Diffusivities Of Liquid Alkane Systems, James W. Moore Jan 1973

Measurement Of Molecular Diffusivities Of Liquid Alkane Systems, James W. Moore

Doctoral Dissertations

"An unsteady-state porous frit method of diffusion coefficient measurement, recently developed in this laboratory, was improved and expanded upon. The experimental technique has been refined and documented. The unsteady-state diffusion of an initially 0.5 N NaCl solution into pure water (effective diffusivity -1.480 x 10-5 cm2/sec) was employed as the calibration standard. An overall calibration precision of ±4% was obtained. Diffusion times of two hours or less were used for the non-aqueous diffusivity measurements. The validity of this measurement technique was confirmed by the agreement of the measured self-diffusion coefficient of n-heptane (25⁰C) with literature values.

A …


Parameter Identification Applied To Linear Quadratic Differential Games, John D. Corrigan Jan 1973

Parameter Identification Applied To Linear Quadratic Differential Games, John D. Corrigan

Doctoral Dissertations

"A two player zero-sum linear quadratic differential game is investigated for the case in which one of the players has incomplete a priori knowledge of the parameters of his opponent's dynamic system. This incomplete system parameter information game is shown to be playable since the ignorant player can make limiting estimates of the unknown parameters from the relative controllability condition for the game. Performance from the ignorant player's point of view is suboptimal.

It is also shown that parameter identification techniques can be applied by the ignorant player in order to directly identify the smart player's closed-loop parameters in the …


Approaches To The Synthesis Of Azabullvalene, Thomas Rudolph Steinheimer Jan 1973

Approaches To The Synthesis Of Azabullvalene, Thomas Rudolph Steinheimer

Doctoral Dissertations

"Three approaches to the synthesis of the heretofore unknown azabullvalene, the pi electron equivalent heterocyclic congener of bullvalene itself, are described. Two of the schemes are based upon the assumption that the most convenient method for the introduction of the nitrogen atom is via thermal rearrangement of the appropriate azide.

The first involved the generation of the homobarrelene carbon skeleton and sub sequent decomposition of its azide. This compound arises formally as the product of the Diels-Alder addition of acetylene to the bicyclic valence isomer of tropyl azide (cyclohepta-1, 3, 5- trienyl-7-azide). In order to achieve this goal, Diels-Alder additions …


Linear Stability Of Non-Parallel Flow In The Entrance Region Of Ducts, Francis Chung-Ti Shen Jan 1973

Linear Stability Of Non-Parallel Flow In The Entrance Region Of Ducts, Francis Chung-Ti Shen

Doctoral Dissertations

"An investigation is made of the linear stability of the developing flow of an incompressible fluid in the entrance region of annular ducts, circular tubes, and parallel-plate channels. Small axisymmetric disturbances for annular duct and tube flows and small two-dimensional disturbances for channel flow are considered in the analysis. In formulating the stability problems, account is taken of the transverse velocity component of the mainflow. This results in the modified Orr-Sommerfeld equations, one for annular duct and tube flows and the other for channel flow. The mainflow velocity fields utilized in the stability analysis are those from the solutions of …


The Atomic Absorption Determination Of Ultra-Trace Tellurium In Rocks Utilizing High Sensitivity Sampling Systems, Richard D. Beaty Jan 1973

The Atomic Absorption Determination Of Ultra-Trace Tellurium In Rocks Utilizing High Sensitivity Sampling Systems, Richard D. Beaty

Doctoral Dissertations

"The sampling boat and the graphite furnace have been shown to possess the required sensitivity to detect tellurium at ultra-trace levels, in a variety of sample types, by atomic absorption. In the sampling boat approach, tellurium in sample solutions is chemically separated and concentrated by extraction into methyl isobutyl ketone before measurement. For samples exhibiting extraction interferences or excessively high background absorption, a preliminary separation of tellurium by coprecipitation with selenium is described. Using this technique, tellurium can be quantitatively detected down to 5 nanograms and linear response is observed to 100 nanograms. Relative standard deviations of better than 7% …


Rock Fragmentation By Subsurface Thermal Inclusions - A Finite Element Study, Mahendrakumar Ramkrishna Patel Jan 1973

Rock Fragmentation By Subsurface Thermal Inclusions - A Finite Element Study, Mahendrakumar Ramkrishna Patel

Doctoral Dissertations

"Although rock tunneling machines are being used extensively with performance and cost advantages over traditional drill and blast methods, their usefulness for hard rock excavation is far from being practical due mainly to the inability of present day mechanical cutters to penetrate these rocks economically. Among various novel techniques that are being investigated, internal heating methods seem to be the most promising. This investigation is concerned with a feasibility study of thermal rock fragmentation using heat to create in-depth thermal inclusions.

The three-dimensional problem of in situ rock fragmentation involves parallel rows of equidistant holes drilled to a constant depth. …


A Study Of The Dynamic Loading Of Hydrodynamically Lubricated Journal Bearings, Nader Khorzad Jan 1973

A Study Of The Dynamic Loading Of Hydrodynamically Lubricated Journal Bearings, Nader Khorzad

Doctoral Dissertations

"The analytical and experimental investigation presented here examined the response of a full journal bearing to a unidirectional dynamic load. Frequency response of the bearing at different eccentricity ratios was investigated. It was concluded that the response of the bearing varies with eccentricity. The experimental data obtained was compared to an analytical model which considered inertial, damping, and elastic characteristics of the lubricant film. An investigation of film pressure revealed that the pressure due to journal center acceleration is smaller than the hydrodynamic and squeeze-film pressures"--Abstract, page 1.


Numerical Simulation Of Heat, Mass, And Momentum Transfer In An Atmospheric Boundary Layer, Darrell W. Pepper Jan 1973

Numerical Simulation Of Heat, Mass, And Momentum Transfer In An Atmospheric Boundary Layer, Darrell W. Pepper

Doctoral Dissertations

"Considerable interest has developed in recent years to understand transport phenomena in thermally stratified boundary layers. More complete knowledge in this field is needed to improve the prediction of the diffusion of air pollutants in the lower atmosphere as well as in forecasting air-water circulation for weather conditions.

The atmospheric boundary layer is modeled using the equations of continuity, momentum, energy, and concentration. Closure of this set of partial differential equations is hindered by the turbulence terms. Using turbulence kinetic energy, the system of equations is closed by internally determining the exchange coefficients of heat, mass, and momentum along with …


Auger Satellites Of The L₂₃ Auger Emission Bands Of Al, Si, And P, John Junior Melles Jan 1973

Auger Satellites Of The L₂₃ Auger Emission Bands Of Al, Si, And P, John Junior Melles

Doctoral Dissertations

"In this study a detailed investigation of the high energy satellites of the L23 Auger emission bands of Al, Si, and P was made. The satellites are interpreted as arising from double ionization of the L23 shell rather than from a plasmon gain process. The parent-satellite energy separations, ΔE, between like structures were determined and were found to be consistently smaller than the volume plasmon energies measured for the same samples. A comparison of Si and SiO revealed no evidence that ΔE for Si is dependent on the volume plasmon energy of the sample.

The satellite threshold excitation …


Paleozoic Stratigraphy As An Ore Control Of Hydrothermal, Base-Metal, Sulfide Deposits In New Mexico, John Samuel Sullivan Jr. Jan 1973

Paleozoic Stratigraphy As An Ore Control Of Hydrothermal, Base-Metal, Sulfide Deposits In New Mexico, John Samuel Sullivan Jr.

Doctoral Dissertations

"Until now the concept or regional stratigraphic control of hydrothermal ore deposits has not received much attention in the literature as a possible exploration guide for locating additional ore bodies. This concept is applied on a regional scale to Paleozoic strata in thirteen mining districts with hydrothermal base-metal deposits in a 35,300 square mile area or southwest New Mexico.

The rocks at the stratigraphic position of the ore-zones are characterized as massive- to thick-bedded with less than 5 percent chert present. The rocks are abundantly to moderately fractured. Fine- to medium-grained dolomite is the dominant host-rock in the lower Paleozoic …


Premartensitic Elasticity Of Fe-Ni Invars, Bryce Linn Shriver Jan 1973

Premartensitic Elasticity Of Fe-Ni Invars, Bryce Linn Shriver

Doctoral Dissertations

"The premartensitic temperature dependence of ultrasonic wave propagation in Fe-30 pct Ni polycrystals and Fe-32 pct Ni single crystals was measured by using a continuous wave technique. As the temperature was lowered to within 10°C of the Ms, a nonlinear decrease of the relative shear velocity was observed. This effect is related to dislocation stacking fault instabilities which may trigger the martensitic phase transformation. In addition, the single crystals show a frequency dependence of the shear elastic constant C' well above the Ms. The dispersion is believed to be caused by fluctuations in the anisotropic molecular …


Tchebycheff Approximation On A Discrete Point Set: Algorithms Old And New, William Edward Mcbride Jan 1973

Tchebycheff Approximation On A Discrete Point Set: Algorithms Old And New, William Edward Mcbride

Doctoral Dissertations

"Several linear and nonlinear algorithms for solving the discrete Tchebycheff problem are compared in this study. The Lawson algorithm is compared with two more well-known methods of linear Tchebycheff approximation. A new acceleration scheme for the Lawson algorithm is introduced and its performance is tested with an already existing acceleration technique. The new version is found to be better than the previous one but not as effective as the traditional Exchange method.

A nonlinear version of Lawson's algorithm is proposed for the solution of problems having approximating functions which are varisolvent. Some linear theorems of Lawson are extended to the …


Hall Effect Measurements Of The Net Ionic Mobility In Nacl, Nabr And Nai, Suman Kumar Hukku Jan 1973

Hall Effect Measurements Of The Net Ionic Mobility In Nacl, Nabr And Nai, Suman Kumar Hukku

Doctoral Dissertations

"Ac Hall effect measurements of the net ionic mobility, µH, in "pure" NaCl, NaBr and Nal were made over their intrinsic temperature ranges extending up to about 250⁰ C below the crystal melting point. A well characterized detector system was employed which provided a mobility sensitivity ≥ 2 x 10-4 cm2 · V-1 · s-1. Complementary electrical conductivity, σ, data was also collected. The charge transport was assumed to be due to Schottky defects and both cation and anion contributions were considered. The high temperature anion contribution to mobility was clearly demonstrated by …


Petrography, Chemical Composition, And Stratigraphic Setting Of The Coals Of North-Central Missouri, William Keith Wedge Jan 1973

Petrography, Chemical Composition, And Stratigraphic Setting Of The Coals Of North-Central Missouri, William Keith Wedge

Doctoral Dissertations

"Under a grant from the National Air Pollution Control Administration, the Missouri Geological Survey undertook a core drilling program to learn more about the coals in north-central Missouri. The stratigraphic setting and chemical and petrographic characteristics of 43 complete samples of coal recovered from 13 diamond drill holes in the exploration program in north-central Missouri are major contributions of this study. These samples represent twelve different coal beds of the Atokan and Desmoinesian Series of the Pennsylvanian System of Missouri and range in thickness from 9.6 to 44.4 inches. They have an average thickness of 20.4 inches and a combined …


Nucleate Boiling From Polymer Coated Surfaces., David Franklin Warner Jan 1973

Nucleate Boiling From Polymer Coated Surfaces., David Franklin Warner

Doctoral Dissertations

"This study consisted of an examination of both the effects of nucleate boiling on polymer coated surfaces and the effects of the polymer coated surfaces on the nucleate boiling curve. The nucleate boiling curve (the curve resulting from plotting heat transferred per unit area versus the temperature difference between the boiling surface and the liquid pool) of the polymer coated surfaces were compared with the nucleate boiling curve of gold-plated surfaces with no polymer coat and it was found that the thicker the polymer coat, the more the curve deviated from that of the metal uncoated surfaces.

All surfaces were …


The Effect And Compensation Of Time-Base Perturbations In Analog Recording Systems, Clifford D. Skouby Jan 1972

The Effect And Compensation Of Time-Base Perturbations In Analog Recording Systems, Clifford D. Skouby

Doctoral Dissertations

"The mean square error between recorded and reproduced signals is used as an error measure to determine the effects of time-base perturbations on an analog singal. The mean square error caused by time-base perturbations is shown to be proportional to the product of the square of the signal bandwidth and the time-base error variance for the case of low pass signal. When the signal is band pass, there is shown to be an additional error term which is proportional to the square of the signal center frequency and the time-base error variance.

Calculations are also carried out to determine the …


Trend Surface Analysis As An Aid In Exploration For Mississippi Valley Type Ore Deposits, John Siegfried Trapp Jan 1972

Trend Surface Analysis As An Aid In Exploration For Mississippi Valley Type Ore Deposits, John Siegfried Trapp

Doctoral Dissertations

"The conditions necessary for emplacement of Mississippi Valley-type mineral deposits can be expressed using mathematical symbols as a function of the pre-depositional topography of the host formation and post-depositional structure. These conditions can be observed and analyzed in the Missouri region from residual maps of trend surface analysis of the Precambrian surface. In areas where the topography prior to deposition of the ore bearing horizon has been strongly altered by the deposition of the basal Paleozoic formation the Lamotte Formation residual maps from trend surface analysis of the top of the Lamotte better illustrate these conditions. The Lamotte Formation in …


The Effect Of Impurities And Additives On The Electrowinning Of Zinc, Haruhisa Fukubayashi Jan 1972

The Effect Of Impurities And Additives On The Electrowinning Of Zinc, Haruhisa Fukubayashi

Doctoral Dissertations

"The effect of various impurities, commonly found in zinc electro-winning solutions, on the surface morphology of deposited zinc was investigated. Individual additions of the impurities Al, Ag, Cd, Co, Cr, Cu, Ge, Mn, Ni, Sb, Sn, Ti, PbO₂ , PbSO₄, and HCl were studied. In a few cases additives of animal glue, gum arabic, and Na₂SiO₃, were used individually or in combination, to determine their effect on the surface structure of the deposited zinc. Comparisons were then made with deposits from a pure electrolyte consisting of H₂SO₄ and Zn⁺², 200 and 65 g/l, respectively. The zinc was deposited on a …


Early Extracellular Events In Sp82g Dna Infection Of Competent Bacillus Subtilis, Gordon Lee Williams Jan 1972

Early Extracellular Events In Sp82g Dna Infection Of Competent Bacillus Subtilis, Gordon Lee Williams

Doctoral Dissertations

No abstract provided.


Characterization Of Several Thymine-Requiring Mutants Of Escherichia Coliy Mel, James Howard Maryanski Jan 1972

Characterization Of Several Thymine-Requiring Mutants Of Escherichia Coliy Mel, James Howard Maryanski

Doctoral Dissertations

No abstract provided.


Electromagnetic Cavity Resonances In Rotating Systems, Barbaros Celikkol Jan 1972

Electromagnetic Cavity Resonances In Rotating Systems, Barbaros Celikkol

Doctoral Dissertations

No abstract provided.


Patterns Of Conversational Interaction As Factors Of Attraction And Compliance Within Dyads, Kenneth Gavin Stuart Jan 1972

Patterns Of Conversational Interaction As Factors Of Attraction And Compliance Within Dyads, Kenneth Gavin Stuart

Doctoral Dissertations

No abstract provided.


General Exponential-Type Functions In Atomic Calculations, Robert H. Carrier Jan 1972

General Exponential-Type Functions In Atomic Calculations, Robert H. Carrier

Doctoral Dissertations

No abstract provided.


Interactions Between The Short-Tailed Shrew, Blarina Brevicauda, And The Meadow Vole, Microtus Pennsylvanicus, Daniel Hugh Hubbard Jan 1972

Interactions Between The Short-Tailed Shrew, Blarina Brevicauda, And The Meadow Vole, Microtus Pennsylvanicus, Daniel Hugh Hubbard

Doctoral Dissertations

No abstract provided.


Chemical Studies On Toxins From Gymnodinium Breve And Aphanizomenon Flos-Aquae, Maktoob Alam Jan 1972

Chemical Studies On Toxins From Gymnodinium Breve And Aphanizomenon Flos-Aquae, Maktoob Alam

Doctoral Dissertations

No abstract provided.


Tryptophan Analog Effects And Nuclease Secretion In Staphylococcus Aureus, David F. Carpenter Jan 1972

Tryptophan Analog Effects And Nuclease Secretion In Staphylococcus Aureus, David F. Carpenter

Doctoral Dissertations

No abstract provided.


The Analysis Of Trace Organics In Fresh Water By Gas Chromatography - Mass Spectroscopy, Gary John Dean Anemaet Jan 1972

The Analysis Of Trace Organics In Fresh Water By Gas Chromatography - Mass Spectroscopy, Gary John Dean Anemaet

Doctoral Dissertations

No abstract provided.


Studies On The Quantitative Enumeration Of Viruses In Water, Frederick Carlton Pearson Iii. Jan 1972

Studies On The Quantitative Enumeration Of Viruses In Water, Frederick Carlton Pearson Iii.

Doctoral Dissertations

No abstract provided.