Digital Commons Network^™

Stereochemistry Of Styrylpyridine Photodimers, Stephen Edward Burkle

Doctoral Dissertations

No abstract provided.

Dynamic Probabilistic Systems With Continuous Parameter Markov Chains And Semi-Markov Processes, Christopher Tin Htun Lee

Doctoral Dissertations

No abstract provided.

The Synthesis And Stereochemistry Of Some Nitrogen Heterocycles, David Allan Walsh

Doctoral Dissertations

No abstract provided.

A Data Unfolding Technique As Applied To Ultrasoft X-Ray Detectors Utilized In A Sounding Rocket Experiment, John Thomas Apostolos

Doctoral Dissertations

No abstract provided.

The Labeling Perspective And Juvenile Delinquency, Richard Lyman Davis

Doctoral Dissertations

No abstract provided.

Mechanism Of Viral Inactivation In Estuarine Water, Edward Martin Carney

Doctoral Dissertations

No abstract provided.

The Flux And Energy Spectrum Of Fast-Neutrons And Gamma-Rays At Balloon Altitudes, David Michael Klumpar

Doctoral Dissertations

No abstract provided.

Laser Inactivation Of The Generative Nucleus In Amaryllis Pollen, Caroline Shea Murphy

Doctoral Dissertations

No abstract provided.

Sound Propagation In A Liquid Overlying A Viscoelastic Halfspace, Allen H. Magnuson

Doctoral Dissertations

No abstract provided.

Reproductive Behavior And Squab Development In Atherosclerosis Susceptible White Carneau And Atherosclerosis Resistant Show Racer Pigeons, David Brannigan

Doctoral Dissertations

No abstract provided.

Temperature-Dependence Of The Electron-Sodium And Electron-Rubidium Spin-Exchange Cross-Sections, Steven Joseph Davis

Doctoral Dissertations

No abstract provided.

Neutron Measurements In Space With Ogo-Vi Satellite, Shadrach Okechukwu Ifedili

Doctoral Dissertations

No abstract provided.

The Occurrence Of Choline In The Marine Dinoflagellate, Amphidinium Carteri, Richard Francis Taylor

Doctoral Dissertations

No abstract provided.

Homicide, Suicide, And Role Relationships In New Hampshire, John A. Humphrey

Doctoral Dissertations

No abstract provided.

A Study Of Gas-Surface Interactions Through Sticking Coefficient, Condensation Coefficient And Sublimation Rate Measurements, Charles E. Bryson Iii

Doctoral Dissertations

"The behavior of the sticking coefficient of CO₂ on an H₂O substrate as a function of time is interpreted in terms of a microscopic nucleation theory. For a substrate temperature near 75 K and an incident flux near 10¹³ molecule cm⁻² sec⁻¹, a critical cluster size of four molecules and and activation energy of nucleation of 22 ± 2.4 Kcal mole⁻¹ is obtained. The analysis treats the nucleation processes as continuous rather than as a discontinuous process at some critical temperature.

In addition the same molecular beam apparatus used for the above experiment was used to measure the condensation …

Charge Transfer Between Oˉ Ions And O₂ Molecules In The Ground State And Singlet Delta Excited State, Ronald Floyd Mathis

Doctoral Dissertations

"A crossed-beam apparatus has been built and used to study charge transfer between O⁻ ions and O₂ molecules in the ground state and in the metastable, singlet delta, excited state. The energy of the incident ions ranged from 10 to 10,000 eV.

The cross section for charge transfer between O⁻ and ground state O₂ was found to peak at about 5 keV, as predicted on the basis of the Rapp and Francis theory. At the lower energies there is good agreement with the previous measurements of Snow et al., and Rutherford and Turner, who also used crossed beam techniques. The …

Investigation Of Roof Shales In Illinois Coal Mines, Peter J. Conroy

Doctoral Dissertations

"This thesis describes an investigation of the relationships among the composition, physical properties and the performance of roof shales in Illinois coal mines. The study included cataloging the physical and mineralogical properties of typical roof shales, determining the interrelationships of the properties and defining the factors in the rock which effect deterioration. From the results, a classification system has been developed which may provide a means for evaluating coal mine roof stability.

A coring apparatus was developed for obtaining in situ samples from mine roofs. Five coal mines with varying geologic and roof conditions were sampled. Precautions were taken to …

A Study Of The Pulse-Height Response Of Silicon Surface-Barrier Detectors To High-Energy Heavy Ions, Gregory Dan Smith

Doctoral Dissertations

"The pulse-height defect (PHD) of high-energy heavy ions in silicon surface-barrier detectors can be divided into three components: (1) energy loss in the gold-surface layer, (2) a nuclear-stopping defect, and (3) a defect due to recombination of electron-hole pairs in the plasma created by the heavy ion. The plasma recombination portion of the PHD was the subject of this study using the variation of the PHD with (1) the angle of incidence of incoming heavy ions, and (2) changes in the detector bias. The Tandem Van de Graaff accelerator at Argonne National Laboratory was used to produce scattered beam ions …

Considerations In The Design Of A Network Of Minicomputers, Hardy J. Pottinger

Doctoral Dissertations

"The advantages of a network consisting of a number of minicomputers coupled to a large time shared computer are described. This type of network is very useful in the areas of data acquisition, real time control of experiments, and front-end processing for computer graphics.

Problems associated with the development of a network of this type, various possible solutions, and the trade-offs involved are presented. These problems are classified into two categories: the interface between the network and the central computing facility, and the interface between the remote sites and the rest of the network.

The design constraints, rationale, and implementation …

Scavenging Of Atmospheric Particles By Water Drops, Ming-Shian Wu

Doctoral Dissertations

"In the first paper, the mechanisms of particle capture and coalescence of aerosols by a moving water drop in the atmosphere are studied using the boundary-layer flow approximation. The particle trajectory is computed by solving the equations of motion of the particle both outside and inside the boundary layer using the Adams-Moulton method. The grazing trajectory is found by a trial-and-error technique. The collision and collection efficiencies of scavenging due to particle inertia and to the velocity gradient of the flow field are then computed for water drops ranging from 0.1 to 1.0 mm in radius and for particle of …

Convergence Of Material Balance In Mathematical Simulation Of Petroleum Reservoirs, Abdul Rashid Merchant

Doctoral Dissertations

One criterion for determining the precision of pressures calculated by a simulation model is the accuracy of the material balance. A high degree of precision in the calculated pressures is a necessary condition for elimination of error in prediction of fluid migration in the reservoir. However, this condition is not sufficient to guarantee accuracy of the simulation, since inaccuracies are introduced by truncation errors, machine round-off errors, and by the use of finite difference approximations to represent nonlinear partial differential equations.

A new procedure called Error Matrix Technique has been developed for reduction of material balance errors. This reduction is …

Transient State Analysis Of Separated Flow Around A Sphere, Ching-Liang Lin

Doctoral Dissertations

"Transient state solution of the Navier Stokes equation was obtained for incompressible flow around a sphere accelerating from zero initial velocity to its terminal free falling velocity. By assuming rotational symmetry around the axis in the falling direction, the Navier Stokes equation and the continuity equation were simplified in terms of vorticity and stream function. The instantaneous acceleration of the falling sphere was calculated by considering the difference between the gravitational force and the drag force in a transient state. The governing partial differential equations were non-dimensionalized. A set of implicit finite difference equations was developed. In order to obtain …

Stability Of The Developing Laminar Flow In A Circular Tube, Lung-Mau Huang

Doctoral Dissertations

"An investigation is made of the linear stability of the developing laminar flow of an incompressible fluid in the entrance region of a circular tube. Both axisymmetric and non-axisymmetric small disturbances are considered in the analysis. The stability characteristics of the fully developed flow are also re-examined. The main flow velocity distribution used in the stability analysis is that from the solution of the linearized momentum equation. The governing equations for the disturbances and the boundary conditions constitute an eigenvalue problem which is solved by a direct numerical integration scheme along with an iteration technique. The solution starts with a …

A Stochastic Theory Of The Stepwise Growth Of Ice Crystal Surfaces, Andreas Kasimir Goroch

Doctoral Dissertations

"Previous theories have had limited success in explaining the presence of a peak in the behavior of the rate of advance of a step on an ice crystal surface with respect to temperature. In the present work we examine the temperature dependence of the advance of steps on the basal face of an ice crystal from several points of view. An alternate derivation is presented for the random motion of adsorbents on a cubic lattice with absorbing points, and this theory is applied for the advance of a step on an ice surface. The velocity of step advance according to …

Some Results On Quasi-Uniform Spaces, Karen Sylvia Carter

Doctoral Dissertations

"An example of a quasi-uniform space which is complete but not strongly complete is constructed. We also give an example to show that a T₁ space does not necessarily have a T₁ strong completion.

The definition of Cauchy filter is discussed. An alternate definition, referred to as C-filter, is considered. A construction of a C-completion is given and it is shown that if a quasi-pseudometric is complete, then the corresponding quasi-uniform structure is C-complete.

Conjugate quasi-uniform spaces are discussed. A theorem relating a transitive base of a quasi-uniform structure to a transitive base of the conjugate structure is …

Electro-Reduction Of Bromate On Mercury, Jaw-Shin Chang

Doctoral Dissertations

"The electrochemical reduction of BrO⁻₃ was studied on a stationary Hg electrode in neutral and basic solutions containing K⁺, Na⁺, and L⁺. Coulombic efficiency studies showed Br⁻ to be the predominant reduction product. The steady state kinetic parameters include Tafel slopes of ca. -0.120 V, approximate first order activity dependences for both BrO⁻₃ and the accompanying cation, and no pH dependence. A reaction scheme is proposed which involves BrO⁻₃ "bridged" to the electrode by the accompanying cation. It is suggested that the "bridging" is a result of ion-pairing in the electrical double-layer"--Abstract, page 1.

Film Boiling Of Freon 113, Normal Pentane, Cyclopentane, And Benzene From Cylindrical Surfaces At Moderate Pressures, Gary Joseph Capone

Doctoral Dissertations

"An investigation of film boiling heat transfer in saturated pools of liquid Freon 113, Normal Pentane, Cyclopentane, and Benzene was made. The fluids were boiled from copper, cylindrical heat transfer surfaces, 3 inches long, and 0.55, 0.75, and 1.00 inch in diameter. The heat transfer elements were positioned horizontally in an autoclave and tested at moderate pressures of up to a pressure of 242.5 psia for Normal Pentane.

The experimental data are discussed and compared with known film boiling correlations. The known correlations were found to be inadequate in predicting heat transfer coefficients as a function of pressure, temperature difference …

Absolute Differential Elastic And Inelastic Cross Sections In 25-140 Kev He⁺ + He Collisions, Victor Pol

Doctoral Dissertations

"The UMR heavy-ion energy-loss spectrometer has been modified to study the angular dependence of elastic and inelastic scattering for 25-140 keV He⁺ incident on He. The data were obtained as energy-loss spectra at angles from 0 to 7.3 x 10^-3 rad (c.m.) with energy-loss resolution of 0.6 to 1.0 eV and angular resolution of 1.2 x 10^-3 to 2.4 x 10^-3 rad (c.m.). From the spectra we have calculated average differential cross sections for elastic scattering, direct excitation of the individual He(n=2) states and direct excitation of the He⁺(n=2) states. By integrating the differential …

Anionic Polymerization Of A Series Of 5-Membered Cyclocarbosiloxanes, Balaraman Suryanarayanan

Doctoral Dissertations

"A study has been made on the anionic polymerization of a series of 5-membered cyclocarbosiloxanes with methyl and/or phenyl substituents. The polymerization was initiated by lithium n-butyldiphenylsilanolate in the presence of tetrahydrofuran. Six 5-membered cyclocarbosiloxanes (2,2,5,5-tetramethyl-1-oxa-2,5-disilacyclopentane; 2,2,5- trimethyl-5-phenyl-1-oxa-2,5-disilacyclopentane; 2,5-dimethyl-2,5-diphenyl- 1-oxa-2,5-disilacyclopentane; 2,2-dimethyl-5 ·,5-diphenyl-1-oxa- 2,5-disilacyclopentane; 2-methyl-2,5,5-triphenyl-1-oxa-2,5-disilacyclopentane; 2,2,5,5-tetraphenyl-1-oxa-2,5-disilacyclopentane) were synthesized. Since the chemical shifts of the protons of the cyclic monomers and the polymers formed were different, the rate of polymerization of the cyclic monomers was measured utilizing an NMR spectrometer. The effects of tetrahydrofuran concentration, initiator concentration and water concentration on the rate of polymer formation and on the molecular weight of …

Initial Surface Reactions And Nucleation Kinetics Of Boron On Atomically Clean Molybdenum Substrates, Richard Eugene Moore

Doctoral Dissertations

"A study of the chemical vapor deposition (CVD) of boron from boron triiodide (BI₃) on molybdenum has been done with field emission microscopy (FEM) and low energy electron diffraction (LEED).

A correlation of the efficiency by which BI₃ is effectively dissociated to form adsorbed boron, and the temperature of the substrate has been shown through work function measurements on the boron covered molybdenum field emitter surfaces. The boron-induced work function change of molybdenum has been shown to be in agreement with a theoretical model which predicts positive, as well as negative work functions for adsorbate-substrate systems. It …