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Doctoral Dissertations

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Engineering Microenvironments To Modulate Calcium Information Processing In Neuronal Cells, Kinsey Cotton Kelly Jan 2013

Engineering Microenvironments To Modulate Calcium Information Processing In Neuronal Cells, Kinsey Cotton Kelly

Doctoral Dissertations

Tissue engineered microenvironments were constructed to test the effects glial cells have on calcium information processing, and to mimic conditions in vivo for tumor invasion and residual cancer after resection of tumor. Submaximal, nM, glutamate (GLU) stimuli were applied to the engineered environments, and the resulting calcium dynamic behavior of neuronal cells was measured to help predict and interpret chaotic systems in the experimental realm. Calcium is a key signaling ion which signals through the N-methyl-D-aspartate (NMDA) glutamate receptor on the neuronal membrane. GLU binding to the NMDA receptor (NMDAR) causes a large and dynamic increase in neuronal intracellular calcium. …


Characterization Of Nano-Scaled Metal-Hydrides Confined In Nano-Porous Carbon Frameworks, David Edward Peaslee Jan 2013

Characterization Of Nano-Scaled Metal-Hydrides Confined In Nano-Porous Carbon Frameworks, David Edward Peaslee

Doctoral Dissertations

"Metal hydrides are currently being studied to provide hydrogen for use in fuel cells and for transportation applications. Hydrogen can be stored in chemical compounds at higher density and lower volume than liquid H₂ or compressed gas. Thermodynamic properties of metal hydrides differ between bulk and nano-sized particles. Many metal hydrides with useful volumetric and gravimetric capacities have high decomposition temperatures, but when placed in nano-sized frameworks (or templates) desorption and adsorption temperatures can be fine-tuned to meet engineering requirements for real-world systems. Additionally, some metal hydrides have shown a change in the decomposition pathway when infiltrated into these frameworks, …


Privacy-Preserving Friend Recommendations In Online Social Networks, Bharath Kumar Samanthula Jan 2013

Privacy-Preserving Friend Recommendations In Online Social Networks, Bharath Kumar Samanthula

Doctoral Dissertations

"Online social networks, such as Facebook and Google+, have been emerging as a new communication service for users to stay in touch and share information with family members and friends over the Internet. Since the users are generating huge amounts of data on social network sites, an interesting question is how to mine this enormous amount of data to retrieve useful information. Along this direction, social network analysis has emerged as an important tool for many business intelligence applications such as identifying potential customers and promoting items based on their interests. In particular, since users are often interested to make …


Development Of Unsaturated Flow Functions For Low Impact Development Stormwater Management Systems Filter Media And Flow Routines For Hydrological Modeling Of Permeable Pavement Systems, Iulia Aurelia Barbu Jan 2013

Development Of Unsaturated Flow Functions For Low Impact Development Stormwater Management Systems Filter Media And Flow Routines For Hydrological Modeling Of Permeable Pavement Systems, Iulia Aurelia Barbu

Doctoral Dissertations

Low Impact Development - Stormwater Management (LID-SWM) systems are relatively new technologies that were developed in order to meet the water quality criteria imposed by the Clean Water Act. LID-SWM is also used to replicate the natural hydrology of developed sites. However, the hydrological benefits of LID systems cannot be accurately predicted with the existing simulation models. Currently used software packages represent LID systems as storage units and do not specifically represent water routing through the systems' hydraulically restrictive sublayers. Since the LID's functionality at system level is not fully understood, the relationships of design variables and the systems' hydrological …


Verification Of Information Flow Security In Cyber-Physical Systems, Rav Akella Jan 2013

Verification Of Information Flow Security In Cyber-Physical Systems, Rav Akella

Doctoral Dissertations

"With a growing number of real-world applications that are dependent on computation, securing the information space has become a challenge. The security of information in such applications is often jeopardized by software and hardware failures, intervention of human subjects such as attackers, incorrect design specification and implementation, other social and natural causes. Since these applications are very diverse, often cutting across disciplines a generic approach to detect and mitigate these issues is missing. This dissertation addresses the fundamental problem of verifying information security in a class of real world applications of computation, the Cyber-physical systems (CPSs). One of the motivations …


Detecting And Locating Electronic Devices Using Their Unintended Electromagnetic Emissions, Colin Stagner Jan 2013

Detecting And Locating Electronic Devices Using Their Unintended Electromagnetic Emissions, Colin Stagner

Doctoral Dissertations

"Electronically-initiated explosives can have unintended electromagnetic emissions which propagate through walls and sealed containers. These emissions, if properly characterized, enable the prompt and accurate detection of explosive threats. The following dissertation develops and evaluates techniques for detecting and locating common electronic initiators. The unintended emissions of radio receivers and microcontrollers are analyzed. These emissions are low-power radio signals that result from the device's normal operation. In the first section, it is demonstrated that arbitrary signals can be injected into a radio receiver's unintended emissions using a relatively weak stimulation signal. This effect is called stimulated emissions. The performance of stimulated …


Numerical Modeling Of Heat Transfer And Fluid Flow In Laser Metal Deposition By Powder Injection, Zhiqiang Fan Jan 2013

Numerical Modeling Of Heat Transfer And Fluid Flow In Laser Metal Deposition By Powder Injection, Zhiqiang Fan

Doctoral Dissertations

"Laser metal deposition is an additive manufacturing technique which allows quick fabrication of fully-dense metallic components directly from Computer Aided Design (CAD) solid models. A self-consistent three-dimensional model was developed for the laser metal deposition process by powder injection, which simulates heat transfer, phase changes, and fluid flow in the melt pool, The governing equations for solid, liquid and gas phases in the calculation domain have been formulated using the continuum model. The free surface in the melt pool has been tracked by the Volume of Fluid (VOF) method, while the VOF transport equation was solved using the Piecewise Linear …


Risk Analysis: Comparative Study Of Various Techniques, Hanan Mohammad Altabbakh Jan 2013

Risk Analysis: Comparative Study Of Various Techniques, Hanan Mohammad Altabbakh

Doctoral Dissertations

"Researchers in the safety field are facing more challenges everyday with the expanding modern socio-technical systems. Safety analysis such as hazard analysis, accident causation analysis, and risk assessment are being revisited to overcome the shortcoming of the conventional safety analysis. With increasingly complex human system interaction in today's modern systems, new safety challenges are being faced that needed to be assessed and addressed. Managers and engineers face the challenge to choose from the vast amount of techniques available and utilize the correct one. Indeed, new or improved risk assessment tools that can address these complexities are needed. One of the …


Establishing Well Operability Limits For Frac Pack Sandface Well Completions Using A Screen Erosion Model And Well Completion Score Card, Rickey Hendrix Jan 2013

Establishing Well Operability Limits For Frac Pack Sandface Well Completions Using A Screen Erosion Model And Well Completion Score Card, Rickey Hendrix

Doctoral Dissertations

"Completion quality has a direct impact upon the maximum production rate at which a frac pack well should be operated. Best practices for frac pack well completions ensure the highest possible quality for the well completion. A novel frac pack well completion score card was developed based on best practices for frac pack well completions identified through consultation with industry experts. The score card systematically combines and assesses completions data readily available standard completion reports. The outcome of the score card process is a numerical completion quality rating, which combines all well design and frac pack operations information.

The completion …


A Comparison Of Two Teaching Methods For Pediatric Medication Administration: Multimedia And Text-Based Modules, Renee Granados Jan 2013

A Comparison Of Two Teaching Methods For Pediatric Medication Administration: Multimedia And Text-Based Modules, Renee Granados

Doctoral Dissertations

A Comparison of Two Teaching Methods for Pediatrics: Multimedia and Text-based Modules to Teach Pediatric Medication Administration

Nurse educators are in a position to design and develop effective methods that consider the cognitive structures and how the mind processes information to teach pediatric medication content to nursing students. The majority of methods teaching medication administration use only one mode: the visual mode. One mode to present leaning material does not take advantage of the additive effects of using two modes to present learning material.

The purpose of the study was to compare the effectiveness of two teaching methods to present …


Changes In Perceived Teacher Self-Efficacy And Burnout As A Result Of Facilitated Discussion And Self-Reflection In An Online Course Designed To Prepare Teachers To Work With Students With Autism, Monica Boomgard Jan 2013

Changes In Perceived Teacher Self-Efficacy And Burnout As A Result Of Facilitated Discussion And Self-Reflection In An Online Course Designed To Prepare Teachers To Work With Students With Autism, Monica Boomgard

Doctoral Dissertations

A growing number of students with Autism Spectrum Disorder (ASD) who display complex learning needs present challenges to educators who struggle to meet their educational needs. Teaching is stressful and additional instructional challenges may increase teacher vulnerability to burnout, leading to a greater likelihood of attrition. Increasing teachers' knowledge of strategies specific to students with ASD within online professional development may create needed support networks increasing self-efficacy and decreasing perceived stress. The purpose of this study was to examine the changes special and general education teachers' perceived self-efficacy and burnout as a result of facilitated discussion and self-reflection embedded in …


The Relations Among School Status Variables, Teacher Academic And Arts Curricular Emphases, And Student Academic Achievement In Grades 1, 3, And 5, Browning Michael Neddeau Jan 2013

The Relations Among School Status Variables, Teacher Academic And Arts Curricular Emphases, And Student Academic Achievement In Grades 1, 3, And 5, Browning Michael Neddeau

Doctoral Dissertations

The National Center of Education Statistics' Early Childhood Longitudinal Study, Kindergarten Class of 1998-1999 (ECLS-K) data were used to explore the curricular emphasis in schools of varying socioeconomic status in both public and private schools. Data collected between 1998 and 2003 were used in the secondary analyses of curricular emphasis in nine curriculum areas identified in the Teacher Questionnaire were grouped into academic, arts, or physical education.

The results from descriptive statistics, correlations, and multiple regressions at each grade indicated differences in academic, arts, and physical education emphases based on public or private schools and school socioeconomic status (SES). Although …


Bio-Inspired Design, Fabrication And Testing Of Bipolar Plates For Pem Fuel Cells, Nannan Guo Jan 2013

Bio-Inspired Design, Fabrication And Testing Of Bipolar Plates For Pem Fuel Cells, Nannan Guo

Doctoral Dissertations

"The flow field of a bipolar plate distributes reactants for polymer electrolyte membrane (PEM) fuel cells and removes the produced water from the fuel cells. It greatly influences the performance of fuel cells, especially the concentration losses. Two approaches were developed to improve flow field designs in this dissertation. One is inspired by the biological circulatory structures and called bio-inspired designs, which have great potential to transport reactant efficiently and hence improve fuel cell performance. Another way is using a network-based optimization model to optimize the conventional flow field configurations, i.e., pin-type, parallel and serpentine designs, to improve flow distributions …


Inverter Design And Analysis Using Multiple Reference Frame Theory, Luke Dale Watson Jan 2013

Inverter Design And Analysis Using Multiple Reference Frame Theory, Luke Dale Watson

Doctoral Dissertations

"Multiple reference frame theory allows for periodically time varying signals to be represented as a set of dc signals. In other words, every periodic signal can be expanded into a Fourier series representation. By modeling an inverter connected to a boost maximum power point tracker (MPPT) in this manner, frequency transfer properties can be preserved and harmonics throughout the system can be predicted. A state space model taking into account the dc and fundamental grid frequency is presented and used to optimize the controller gains of the system. Using information from the dq-axis values of the measured grid current and …


Polybenzoxazine Aerogels: Synthesis, Characterization, Conversion To Porous Carbons, And Energetic Composites, Shruti Mahadik-Khanolkar Jan 2013

Polybenzoxazine Aerogels: Synthesis, Characterization, Conversion To Porous Carbons, And Energetic Composites, Shruti Mahadik-Khanolkar

Doctoral Dissertations

"Aerogels are nanoporous, low-density bulk objects, consisting of three-dimensional assemblies of nanoparticle. Structured similarly, polymeric aerogels are emerging as a mechanically strong alternative to traditional silica aerogels, which are fragile. Amongst polymeric aerogels, those based on polybenzoxazine (PBO - a type of phenolic resin), are extremely robust and comprise an economic alternative to resorcinol-formaldehyde aerogels, also a class of phenolic resins, as the main source of carbon aerogels. The drawback of the PBO chemistry has been the long (days) processing time at high-temperatures (>130 ºC). Herewith, we have developed an energy- and time-efficient process to PBO aerogels by inducing …


Transport In Correlated And Uncorrelated Random Media, With Applications To Molecularly Doped Polymers, Nilanka Praveena Gurusinghe Jan 2013

Transport In Correlated And Uncorrelated Random Media, With Applications To Molecularly Doped Polymers, Nilanka Praveena Gurusinghe

Doctoral Dissertations

"The commonly observed Poole-Frenkel field dependence; of the mobility of photo-injected charges in molecularly-doped polymers has been shown to arise from the spatially-correlated, Gaussian energy distribution of transport sites encountered by charges moving through the material. Experimental current-time transients obtained for molecularly-doped polymers exhibit universality with respect to electric field and a metal-insulator-like transition from non-dispersive to dispersive transport, features usually identified with multiple trapping models that assume an uncorrelated exponential distribution of trap energies. For materials that exhibit both sets of features the possibility arises that both kinds of disorder coexist. We study here, analytically and numerically, transport in …


Study Of Artificially Disordered Optical Fibers, Herath Mudiyanselage Sumudu Rasika Kumari Herath Jan 2013

Study Of Artificially Disordered Optical Fibers, Herath Mudiyanselage Sumudu Rasika Kumari Herath

Doctoral Dissertations

"Light transmission through photo-sensitive multi-mode fibers (MMF) with controlled volume disorder is investigated. Experiment shows that a segment of disordered MMF as short as 10 cm is sufficient to distribute power uniformly over all co-propagating modes and the intensity at the output surface of the fiber follows the Rayleigh negative exponential function. To explain the experimental findings, a comprehensive theoretical model is developed with three main results. First, statistical properties of all components of the dielectric tensor are obtained and analyzed in the framework a microscopical model of photo-sensitivity in a germano-silicate glasses. Secondly, it is shown that induced birefringence …


Observability-Enhanced Dual-Filter Design For Attitude Estimation With Minimum Observations, Jason D. Searcy Jan 2013

Observability-Enhanced Dual-Filter Design For Attitude Estimation With Minimum Observations, Jason D. Searcy

Doctoral Dissertations

"Determining spacecraft attitude in real time using only magnetometer data presents a challenging filtering problem. A flexible and computationally efficient method for solving the spacecraft attitude using only an inexpensive and reliable magnetometer would be a useful option for satellite missions, particularly those with modest budgets. The primary challenge is that magnetometers only instantaneously resolve two axes of the spacecraft attitude. Typically, magnetometers are used in conjunction with other sensors to resolve all three axes. However, by using a filter over an adequately long orbit arc, the magnetometer data can yield full attitude, and in near real time. The method …


Finite-Horizon Optimal Control Of Linear And A Class Of Nonlinear Systems, Qiming Zhao Jan 2013

Finite-Horizon Optimal Control Of Linear And A Class Of Nonlinear Systems, Qiming Zhao

Doctoral Dissertations

"Traditionally, optimal control of dynamical systems with known system dynamics is obtained in a backward-in-time and offline manner either by using Riccati or Hamilton-Jacobi-Bellman (HJB) equation. In contrast, in this dissertation, finite-horizon optimal regulation has been investigated for both linear and nonlinear systems in a forward-in-time manner when system dynamics are uncertain. Value and policy iterations are not used while the value function (or Q-function for linear systems) and control input are updated once a sampling interval consistent with standard adaptive control. First, the optimal adaptive control of linear discrete-time systems with unknown system dynamics is presented in Paper I …


Numerical Analyses Of Long Carbon Fiber Reinforced Concrete Panels Exposed To Dynamic Loading, Zahra Sadat Tabatabaei Jan 2013

Numerical Analyses Of Long Carbon Fiber Reinforced Concrete Panels Exposed To Dynamic Loading, Zahra Sadat Tabatabaei

Doctoral Dissertations

"The purpose of this research was to evaluate impact and blast performance of long carbon fiber reinforced concrete experimentally and numerically. Experimental tests were conducted on plain concrete (PC), reinforced concrete, and four different types of long carbon fiber reinforced concrete (LCFRC). The results from each test were then compared to one another. This comparison indicates that adding long carbon fibers to concrete both increases the post-cracking behavior of concrete and decreases the spalls in either an impact or blast test. Among all of the fibers tested, Fiber Type B3 outperformed the other fibers, absorbing more energy during impact. Numerical …


Regional Geomorphic Analysis And Gis Susceptibility Mapping Of Landslides In The Blue Nile And The Tekeze River Basins Of Ethiopia, Elamin Hassan Dai Ismail Jan 2013

Regional Geomorphic Analysis And Gis Susceptibility Mapping Of Landslides In The Blue Nile And The Tekeze River Basins Of Ethiopia, Elamin Hassan Dai Ismail

Doctoral Dissertations

"The Plateau region of Ethiopia lies within a seismically active continental extensional regime, which is being rapidly incised by the Blue Nile and the Tekeze Rivers. Extremely large landslides pose serious hazards in this highly populated region (>27 million), which is in the process of developing its hydrologic resources. This research sought to develop cost-effective methods to compile regional landslide inventory and landslide susceptibility maps, using geomorphic tools and GIS technologies. This work also sought to evaluate the relationships between landslide dams and knickpoints, caused by channel bed incision from those caused by slope failures, by utilizing identified knickpoints …


Enamel Coated Steel Reinforcement For Improved Durability And Life-Cycle Performance Of Concrete Structures: Microstructure, Corrosion, And Deterioration, Fujian Tang Jan 2013

Enamel Coated Steel Reinforcement For Improved Durability And Life-Cycle Performance Of Concrete Structures: Microstructure, Corrosion, And Deterioration, Fujian Tang

Doctoral Dissertations

"This study is aimed (a) to statistically characterize the corrosion-induced deterioration process of reinforced concrete structures (concrete cracking, steel mass loss, and rebar-concrete bond degradation), and (b) to develop and apply three types of enamel-coated steel bars for improved corrosion resistance of the structures. Commercially available pure enamel, mixed enamel with 50% calcium silicate, and double enamel with an inner layer of pure enamel and an outer layer of mixed enamel were considered as various steel coatings. Electrochemical tests were respectively conducted on steel plates, smooth bars embedded in concrete, and deformed bars with/without concrete cover in 3.5 wt.% NaCl …


Synthetic Aperture Radar-Based Techniques And Reconfigurable Antenna Design For Microwave Imaging Of Layered Structures, Mojtaba Fallahpour Jan 2013

Synthetic Aperture Radar-Based Techniques And Reconfigurable Antenna Design For Microwave Imaging Of Layered Structures, Mojtaba Fallahpour

Doctoral Dissertations

"In the past several decades, a number of microwave imaging techniques have been developed for detecting embedded objects (targets) in a homogeneous media. New applications such as nondestructive testing of layered composite structures, through-wall and medical imaging require more advanced imaging systems and image reconstruction algorithms (post-processing) suitable for imaging inhomogeneous (i.e., layered) media. Currently-available imaging algorithms are not always robust, easy to implement, and fast. Synthetic aperture radar (SAR) techniques are some of the more prominent approaches for image reconstruction when considering low loss and homogeneous media. To address limitations of SAR imaging, when interested in imaging an embedded …


Structural And Magnetic Properties Of Ni And Cr Substituted La₀.₇Sr₀.₃Mno₃, Thomas Franklin Creel Jr. Jan 2013

Structural And Magnetic Properties Of Ni And Cr Substituted La₀.₇Sr₀.₃Mno₃, Thomas Franklin Creel Jr.

Doctoral Dissertations

"The La₁₋ₓSrₓMn1-yByO₃ perovskite systems where B represents a 3d transition metal such as Cr, Fe, Co, Ni, Cu, and Zn, are of significant interest due to their large magnetoresistance, and electronic transport properties that change significantly, depending on values of x and which transition metal used. Their applications in technology include cathodes for solid oxide fuel cells, resistance random access memory and catalysis. At certain doping concentrations on the B-site, metal-to-semiconductor or metal-to-insulator transitions coupled with colossal magnetoresistance occur, decreasing the resistivity (up to six orders of magnitude) upon the application of an external magnetic field. …


Quantum Phase Transitions In Disordered Magnets, David Nozadze Jan 2013

Quantum Phase Transitions In Disordered Magnets, David Nozadze

Doctoral Dissertations

"We study the effects of quenched weak disorder on quantum phase transitions in disordered magnets. The presence of disorder in the system can lead to a variety of exotic phenomena, e.g., the smearing of transitions or quantum Griffiths singularities. Phase transitions are smeared if individual spatial regions can order independently of the bulk system. In paper I, we study smeared quantum phase transitions in binary alloys A₁₋ₓBₓ that are tuned by changing the composition x. We show that in this case the ordered phase is extended over all compositions x < 1. We also study the composition dependence of observables. In paper II, we investigate the influence of spatial disorder correlations on smeared phase transitions. As an experimental example, we demonstrate in paper III, that the composition-driven ferromagnetic-toparamagnetic quantum phase transition in Sr₁₋ₓCaₓ RuO₃ is smeared. When individual spatial regions cannot order but fluctuate slowly, the phase transition is characterized by strong singularities in the quantum Griffiths phase. In paper IV, we develop a theory of the quantum Griffiths phases in disordered ferromagnetic metals. We show that the quantum Griffiths singularities are stronger than the usual power-law quantum Griffiths singularities in insulating magnets. In paper V, we present an efficient numerical method for studying quantum phase transitions in disordered systems with O(N) order parameter symmetry in the large-N limit. Our algorithm solves iteratively the large-N self-consistent equations for the renormalized distances from criticality. Paper VI is devoted to the study of transport properties in the quantum Griffiths phase associated with the antiferromagnetic quantum phase transition in a metal. We find unusual behavior of transport properties which is in contrast to the normal Fermi-liquid behavior"--Abstract, page v.


Location Based Services In Wireless Ad Hoc Networks, Neelanjana Dutta Jan 2013

Location Based Services In Wireless Ad Hoc Networks, Neelanjana Dutta

Doctoral Dissertations

"In this dissertation, we investigate location based services in wireless ad hoc networks from four different aspects - i) location privacy in wireless sensor networks (privacy), ii) end-to-end secure communication in randomly deployed wireless sensor networks (security), iii) quality versus latency trade-off in content retrieval under ad hoc node mobility (performance) and iv) location clustering based Sybil attack detection in vehicular ad hoc networks (trust). The first contribution of this dissertation is in addressing location privacy in wireless sensor networks. We propose a non-cooperative sensor localization algorithm showing how an external entity can stealthily invade into the location privacy of …


Exploring Run-Time Reduction In Programming Codes Via Query Optimization And Caching, Venkata Krishna Suhas Nerella Jan 2013

Exploring Run-Time Reduction In Programming Codes Via Query Optimization And Caching, Venkata Krishna Suhas Nerella

Doctoral Dissertations

"Object oriented programming languages raised the level of abstraction by supporting the explicit first class query constructs in the programming codes. These query constructs allow programmers to express operations on collections more abstractly than relying on their realization in loops or through provided libraries. Join optimization techniques from the field of database technology support efficient realizations of such language constructs. However, the problem associated with the existing techniques such as query optimization in Java Query Language (JQL) incurs run time overhead. Besides the programming languages supporting first-class query constructs, the usage of annotations has also increased in the software engineering …


Sparse Group Sufficient Dimension Reduction And Covariance Cumulative Slicing Estimation, Bilin Zeng Jan 2013

Sparse Group Sufficient Dimension Reduction And Covariance Cumulative Slicing Estimation, Bilin Zeng

Doctoral Dissertations

"This dissertation contains two main parts: In Part One, for regression problems with grouped covariates, we adopt the idea of sparse group lasso (Friedman et al., 2010) to the framework of the sufficient dimension reduction. We propose a method called the sparse group sufficient dimension reduction (sgSDR) to conduct group and within group variable selections simultaneously without assuming a specific model structure on the regression function. Simulation studies show that our method is comparable to the sparse group lasso under the regular linear model setting, and outperforms sparse group lasso with higher true positive rates and substantially lower false positive …


Fundamental Properties Of Colloidal Unimolecular Polymer Particles, Minghang Chen Jan 2013

Fundamental Properties Of Colloidal Unimolecular Polymer Particles, Minghang Chen

Doctoral Dissertations

"Colloidal Unimolecular Polymer (CUP) particles are a new genre of material formed by self-assembly into spheroidal particles due to the effect of hydrophilic/hydrophobic interactions of the polymer with a change in the solvent. The particle sizes were characterized by means of Dynamic Light Scattering with corrected viscosities instead of water's viscosity. The distribution of particle size agreed well with the distribution of molecular weight proving that the polymer had undergone unimolecular collapse. The rheology study shows the presence of surface water and its significant effect on the rheology. The primary and secondary electroviscous effects were also found to play roles …


Isocyanate-Derived Organic Aerogels: Polyurethanes, Polyureas, Polyamides And Polyimides, Chakkaravarthy Chidambareswarapattar Jan 2013

Isocyanate-Derived Organic Aerogels: Polyurethanes, Polyureas, Polyamides And Polyimides, Chakkaravarthy Chidambareswarapattar

Doctoral Dissertations

"Aerogels are 3D assemblies of nanoparticles with high open porosity and high surface area, and are pursued for their low density, low thermal conductivity, low dielectric constant and high acoustic attenuation. The foundation for those exceptional properties is their complex hierarchical solid framework (agglomerates of porous, fractal secondary nanoparticles). On the down side, however, aerogels are also fragile materials. The mechanical strength of silica aerogels has been improved by crosslinking the framework with organic polymers. The crosslinking polymer has been assumed to form a conformal coating on the surface of the skeletal framework bridging covalently the elementary building blocks. However, …