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A Molecular Orbital Treatment Of Chemical Reactivity, M Donald Jordan Jr.

Doctoral Dissertations

No abstract provided.

Imperfections Within Ti₂O₃ And Tio₂ Phases In The Titanium-Oxygen System, Tatsuhiko Ejima

Doctoral Dissertations

“The hexagonal-rhombohedral Ti₂O₃ phase in the Ti-O system extends from 32.5 to 34.5% oxygen b.w., with the exact composition of Ti₂O₃ nearly in the middle of the phase. Seven samples of different composition within that phase were made, and the lattice constants (a and c) and the density of each sample were determined.

The plots of the constants against the composition of the samples revealed a deviation from Vegard’s rule when approaching the exact composition of Ti₂O₃. The lattice constants of this compound, obtained by graphical interpolation were; a_{25 …}

Hydrogen Overvoltage On Titanium, Sheng-Tai Shih

Doctoral Dissertations

"The hydrogen overvoltage has been defined as the difference between the potential of the working electrode (cathode) and the theoretical reversible value for the same solution. This definition brings out the difficulty involved in the measurement of the "theoretical reversible potential for the same solution” as the potential of the hydrogen electrode in such a solution is usually different from the value of a standard reversible hydrogen electrode, for which the activity of hydrogen ions is set as being “1” and the potential arbitrarily set as being “0”. Besides, it is sometimes necessary to add addition agents to the solution …

Geochemical Prospecting Applied To The Illinois-Kentucky Fluorspar Area, Matthew Peter Nackowski

Doctoral Dissertations

"This study was completed to determine whether geochemical methods of prospecting could be applied to the search for fluorspar deposits in the Illinois-Kentucky fluorspar district.

During the course of the study, aspects of the geochemical cycle of fluorine under the climatic environment encountered were noted in the zone of weathering.

The Illinois-Kentucky fluorspar district supplies a large portion of the fluorite consumed in the United States. The producing deposits are of two geologic types. The vein deposits occur as nearly vertical tabular lenses or pods which occupy fractures. These deposits may reach the bedrock surface, but in any case, the …

Shaped Charges: Their Mechanism And Applications In Mining, Pranlal Girdharlal Sheth

Doctoral Dissertations

"A shaped charge, confined or unconfined, is a unit of explosive material with a cavity or hollow at the base. It behaves differently than an ordinary charge, and, when detonated, has been found to produce curious effects of concentrating the force of the explosive on an area opposite the cavity"--Introduction, page 1.

Precise Lattice Parameter Determinations Of Diamond Silicon And Germanium By The Asymmetric Method, Esrefettin Zeki Aka

Doctoral Dissertations

"The construction of the apparatus for production of powder patterns at a definite temperature and the technique for evaluation of x-ray powder patterns by the asymmetric method are described in detail, and the mode of error elimination is discussed.

A new scanning device is designed for use in x-ray diffraction work.

A modified method is described for the determination of densities of solids, which eliminates some of the difficulties interfering with other similar methods thus far proposed. Formulae are derived for the calculation of density as well as for reduction of density at a desired temperature.

The following conclusion are …

Pyrochemical Changes In Missouri Halloysite, Frank Joseph Zvanut

Doctoral Dissertations

"For centuries it has been known that the application of heat to a clay or a clay body produces changes that make it an entirely different substance from the original raw clay. Ever since the earliest civilizations produced crude building brick by baking formed clay bodies in the sun's rays, mankind has been speculating on the nature of the changes that convert soft, friable, plastic clays into hard, strong, non-plastic, rock-like masses. It has been only within the last two decades, however, that progress has been made in the solution of problems dealing with the resultant products in fired clay …