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Kinetic Control And Trapping In The Supramolecular Polymerization Of M-Terphenyl Bis-Urea Macrocycles, Sophya V. Garashchuk, Gamage Isuri P. Wijesekera, Isabella G. Rushton, Vaibhavi A. Samant, Fahidat A. Gbadamosi, Dr. Md Faizul Islam, Sophya V. Garashchuk, Prof. Dr. Linda S. Shimizu Apr 2025

Kinetic Control And Trapping In The Supramolecular Polymerization Of M-Terphenyl Bis-Urea Macrocycles, Sophya V. Garashchuk, Gamage Isuri P. Wijesekera, Isabella G. Rushton, Vaibhavi A. Samant, Fahidat A. Gbadamosi, Dr. Md Faizul Islam, Sophya V. Garashchuk, Prof. Dr. Linda S. Shimizu

Faculty Publications

Herein, we examine pathway complexity in the supramolecular polymerization of a novel m-terphenyl bis-urea macrocycle. Designed to induce kinetically metastable states, the macrocycle‘s concentration-dependent aggregation was studied via 1H NMR and IR spectroscopy in THF and CHCl₃. Temperature-dependent UV-Vis spectroscopy in water/THF revealed a cooperative nucleation-growth mechanism, indicated by a shift in λmax to longer wavelengths upon cooling. Morphological studies using DLS, AFM, and SEM demonstrated fibrous aggregate formation. Thermal hysteresis observed in assembly-disassembly cycles indicated kinetically trapped species, with cooling governed by kinetic control and heating by thermodynamic processes. Deviations in ΔH values during cooling, compared to van′t …


From Victimization To Offense: A Scoping Review Of Attachment Theory And Social Learning Theory In Explaining Hypersexual Behaviors In Male Sexual Offenders With Histories Of Childhood Sexual Abuse, Madison R. Rivers Apr 2025

From Victimization To Offense: A Scoping Review Of Attachment Theory And Social Learning Theory In Explaining Hypersexual Behaviors In Male Sexual Offenders With Histories Of Childhood Sexual Abuse, Madison R. Rivers

Senior Theses

The association between childhood sexual abuse (CSA) and hypersexual behaviors in both juvenile and adult male sexual offenders has been investigated; however, a clear theoretical framework explaining this connection remains debated. This review aims to evaluate which theoretical frameworks—such as Social Learning Theory and Attachment Theory—best explain the link between CSA and hypersexuality in male sexual offenders. A systematic search and analysis of existing literature was conducted, including studies on the psychological, behavioral, and developmental impacts of CSA on hypersexual behaviors. Both Social Learning Theory and Attachment Theory were critically assessed, particularly focusing on the pathways from victimization to offending …


Beyond The Cell: The Impact Of Parental Incarceration On Children Based On The Factors Of Age, Gender, And Race, Ella M. Zeigler Apr 2025

Beyond The Cell: The Impact Of Parental Incarceration On Children Based On The Factors Of Age, Gender, And Race, Ella M. Zeigler

Senior Theses

Incarceration is a life-changing event. It is humbling to be surrounded by three cement walls and a row of metal bars reaching from the floor to the ceiling. Millions of individuals are impacted by the adverse effects of incarceration, but millions more feel the effect of their incarceration as well. There are obvious negative impacts on those who have personally experienced incarceration, but one of the largest impacts is widely overlooked; one that comes from beyond the cell. This thesis considers the variation in the impact of parental incarceration on children, specifically based on the factors of age, gender and …


Suspended Agency And The Habitus Of Waiting In A Migrant Shelter In Tijuana, Liam K. Ogden Iii Apr 2025

Suspended Agency And The Habitus Of Waiting In A Migrant Shelter In Tijuana, Liam K. Ogden Iii

Senior Theses

This thesis explores idea of suspended agency and the development of a habitus of waiting within a women and children’s migrant shelter in Tijuana, Mexico. Relying on ten days of participant observation and an interview with a shelter director, I examine the lived experiences of residents, workers, and myself as a researcher navigating humanitarian space. Shelters are designed to be short term spaces, but migrants are often forced into long-term, uncertain stays due to restrictive border policies and structural barriers, resulting in a social stasis defined by boredom, anxiety, and monotony within the shelter. Drawing on Bourdieu’s concept of habitus …


A Score For The Outdoors: A Study Of Hayao Miyazaki's Environmentalism And Joe Hisaishi's Score In Princess Mononoke, Jasper E. Vasilevskis Apr 2025

A Score For The Outdoors: A Study Of Hayao Miyazaki's Environmentalism And Joe Hisaishi's Score In Princess Mononoke, Jasper E. Vasilevskis

Senior Theses

This honors thesis explores the role of composer Joe Hisaishi’s score in relation to director Hayao Miyazaki’s environmental perspective in Princess Mononoke (1997). Miyazaki’s belief that, regardless of the target audience, a story cannot be told without presenting “the ecological issues”[1] leads to the production of films that have rhetoric in support of environmental appreciation and conservation embedded throughout. When read through an environmentalist lens, Princess Mononoke becomes a critique of “human-centric” thinking, instead supporting an ideology similar to “deep ecology,” which considers humans to be intrinsically linked to nature. Despite Hisaishi and Miyazaki’s close collaboration that leads to …


The Usc Sports Sorority: A Podcast Highlighting The Experiences Of Sjmc Alumnae Working In Sports Media, Griffin Goodwyn Apr 2025

The Usc Sports Sorority: A Podcast Highlighting The Experiences Of Sjmc Alumnae Working In Sports Media, Griffin Goodwyn

Senior Theses

Women’s sports are on the rise, as indicated by increased media interest and television viewership records across the professional and collegiate ranks. This trend coincides with one specific to the sports media industry, where more women are pursuing careers in that space – and being recognized for their contributions in ways they have not in previous decades.

My project examines both trends in the form of a podcast, featuring interviews with eight alumni and two current students who have sports media experience and ties to the University of South Carolina’s School of Journalism and Mass Communications. The podcast consists of …


Accommodations For Teachers With Disabilities, Macy Gault Apr 2025

Accommodations For Teachers With Disabilities, Macy Gault

The Journal of Law and Education

No abstract provided.


Lockdown Lessons: How Remote Proctoring Continues To Discriminate Against Disabled Students In A Post-Covid Era, Abigail Johanson Apr 2025

Lockdown Lessons: How Remote Proctoring Continues To Discriminate Against Disabled Students In A Post-Covid Era, Abigail Johanson

The Journal of Law and Education

No abstract provided.


The Dischargeability Of Student Loans Through Bankruptcy: Does The Undue Hardship Standard Adversely Burden Consumer Debtors?, Jitwan Floyd Apr 2025

The Dischargeability Of Student Loans Through Bankruptcy: Does The Undue Hardship Standard Adversely Burden Consumer Debtors?, Jitwan Floyd

The Journal of Law and Education

No abstract provided.


The Impact Of The National Teacher Shortage On The Right To An Adequate Education, Anslee Wood Apr 2025

The Impact Of The National Teacher Shortage On The Right To An Adequate Education, Anslee Wood

The Journal of Law and Education

No abstract provided.


Host Range And Efficiency Of Plating Determination Of Phages Infecting Caulobacter And Non-Caulobacter Species, Christopher Scott Apr 2025

Host Range And Efficiency Of Plating Determination Of Phages Infecting Caulobacter And Non-Caulobacter Species, Christopher Scott

Senior Theses

Seven bacteriophages were studied to determine their host range among Caulobacter and non-Caulobacter bacteria. Recently, Caulobacter-associated phages have been shown to have broader host ranges than previously believed. Thus, it is crucial to thoroughly verify the range of bacteria strains that these phages can infect. To understand the extent of each phage’s host range, phage lysates were spotted on bacterial lawns to determine whether lysis could occur. Host-range analyses in this project conclude that these Dolichocephalovirinae phages were able to infect multiple genera and species of host bacteria. Plating efficiency experiments were also conducted to compare the phage’s …


Augmented, Not Replaced: The Impact Of Ai On Equity Research Analysts, Lawrence Carrea Apr 2025

Augmented, Not Replaced: The Impact Of Ai On Equity Research Analysts, Lawrence Carrea

Senior Theses

The adoption of AI tools into professional workflows has the chance to revolutionize major industries such as the financial services industry. Because equity research is a space that is heavily dependent on data aggregation, forecasting, and report generation, there is a threat of AI replacing human analysts in the next five years. The goal of this study is to determine how the adoption of AI tools will affect the equity research career field. To achieve this goal, a mixed-method approach is employed through a quantitative and qualitative survey. Results from the survey indicate that most finance professionals are already using …


Methods Comparison For Collecting Subjective Valence And Arousal Judgements, Esha Gandhi Apr 2025

Methods Comparison For Collecting Subjective Valence And Arousal Judgements, Esha Gandhi

Senior Theses

Human emotion and affect are critical for regulating behavior, guiding decision-making and facilitating social communications. In everyday language, emotion and affect are interchangeable. However, in psychology, they are conceptualized as two distinct constructs. Emotion refers to discrete, prototypical subjective experiences elicited by specific stimuli. Affect, in contrast, refers to more elementary feelings that can be described along two continuous dimensions: valence (positive-negative) and arousal (low-high). According to the circumplex model (Russell, 1980), emotion can be represented within a two-dimensional core affective space defined by valence and arousal. Although valence and arousal are conceptually interrelated, most studies measure them separately using …


Between Borders And Belief: Perspectives Of Aid Workers On Religion In A Migrant Shelter In Mexico, Kendall O. Roy Apr 2025

Between Borders And Belief: Perspectives Of Aid Workers On Religion In A Migrant Shelter In Mexico, Kendall O. Roy

Senior Theses

This thesis seeks to understand the significance of religion in the Central American migration context through the eyes of humanitarian aid workers. It is based on interviews that I conducted in May of 2024 with staff members at a migrant shelter in Mexico, analysis of prior scholarship, and building upon an understanding of relevant religious history in Latin America. I will delve into trends that the aid workers observed in areas such as religious practices and beliefs of migrants, shelter functions that addressed and nurtured spiritual well-being, and the influence of the Church as an institution on humanitarian aid work. …


Toward Gender Parity In The South Carolina Appellate Judiciary, Anna M. Bishop Apr 2025

Toward Gender Parity In The South Carolina Appellate Judiciary, Anna M. Bishop

Senior Theses

In April 2023, former Chief Justice Kay Hearn retired from the Supreme Court of South Carolina, leaving the state without a woman justice on its highest court until June 2024. During this time, South Carolina was the only state in the nation to lack a female presence on its court of last resort. This lack of women was detrimental, as women judges provide crucial insight and experience to the courts on which they serve.

Through a literature review, I examine the importance of women on the bench and how different state judicial selection mechanisms affect the gendered makeup of state …


The “Blurred Lines” Between Copyright Law And Its Role In The Music Industry, Caroline Mcdonald Apr 2025

The “Blurred Lines” Between Copyright Law And Its Role In The Music Industry, Caroline Mcdonald

Senior Theses

This thesis examines the dynamic relationship between copyright law and the music industry by analyzing three landmark cases: Bright Tunes Music Corp. v. Harrisongs Music, Ltd., Williams v. Gaye, and Skidmore v. Zeppelin. Through these case studies, the paper explores how courts assess copyright infringement using the tests of extrinsic and intrinsic similarity, as well as identifies the weight of expert testimony in court, and the role of legal tools such as the inverse-ratio rule. Each case illustrates different implications for artists: from the threat of subconscious plagiarism to the controversial expansion of protectable musical elements, and finally, a shift …


Role Of Race And Ethnicity In The Development, Diagnosis, And Treatment Of Gestational Diabetes Mellitus, Gabrielle D. Shupard Apr 2025

Role Of Race And Ethnicity In The Development, Diagnosis, And Treatment Of Gestational Diabetes Mellitus, Gabrielle D. Shupard

Senior Theses

Gestational diabetes mellitus (GDM) is the most common metabolic disorder of pregnancy, and rates of this disease have been steadily increasing over the past ten years. GDM disproportionately impacts racial and ethnic minorities at higher rates than their Caucasian counterparts. In this study, the PRECEDE model framework was employed during a literature review to gain a greater understanding of the complex risk factors contributing to differences in the development, diagnosis, and treatment of GDM among these population subgroups. The second part of this study concentrated on reviewing the extent to which current literature evaluates the role of race and ethnicity …


Hybrid Machine Learning And Comparison Error Minimization For Frequency Domain-Based Rapid State Estimation In Structures Subjected To High-Rate Boundary Change, James Scheppegrell Apr 2025

Hybrid Machine Learning And Comparison Error Minimization For Frequency Domain-Based Rapid State Estimation In Structures Subjected To High-Rate Boundary Change, James Scheppegrell

Theses and Dissertations

Dynamic forces and evolving structural boundary conditions pose challenges for various structural systems such as aircraft, orbital infrastructure, and energy harvesting devices. The design, evaluation, and functionality, of such systems can be aided through the collection and analysis of data. However, real-time decision-making for systems experiencing high-rate changes can pose unique challenges, if assessments are to be made accurately and rapidly enough to be relevant. In cases where the systems are well-defined and thoroughly understood, monitoring the frequency response can be instrumental in determining the state of structures subjected to high-rate structural boundary condition changes. This study focuses on investigating …


Equity In Maternal Journeys: Maternal Health Care Experiences Among Black Mothers In South Carolina, Julisa Grace Tindall Apr 2025

Equity In Maternal Journeys: Maternal Health Care Experiences Among Black Mothers In South Carolina, Julisa Grace Tindall

Theses and Dissertations

Black women in the United States experience disproportionately adverse maternal health outcomes, particularly in the Southeast. This dissertation examines the maternal health care experiences and resilience strategies of Black mothers in South Carolina through a qualitative study grounded in critical race theory, Black feminist thought, resilience theory, and ecological systems theory. It highlights the pervasive influence of structural racism while amplifying the resourcefulness and agency of Black mothers. The first manuscript develops a conceptual framework to explore the structural, social, and interpersonal mechanisms influencing Black maternal health care experiences. The second manuscript employs grounded theory to investigate Black mothers’ lived …


Unveiling Narrative In Liszt’S Dante Sonata Through Topical Analysis, Jasmine Olivia Harry Apr 2025

Unveiling Narrative In Liszt’S Dante Sonata Through Topical Analysis, Jasmine Olivia Harry

Theses and Dissertations

Narrative theory and its application in music have increasingly captured the interest of musicologists. Despite this growing attention, the analytical model remains relatively new compared to more established methods. Continued exploration and application are necessary to demonstrate its value alongside traditional theoretical frameworks. This dissertation employs narrative theory to examine the ironic comedy archetype in Franz Liszt’s Dante sonata, utilizing a bottom-up approach to construct a detailed musical narrative across three analytical tiers. Chapter two, representing the primary level, analyzes the sonata-fantasy macro-structure, uncovering key themes and the dynamic interplay between contrasting dichotomies. Chapter three, the secondary level, investigates semiotics, …


Contemporary Voices Of China: Biographical Introduction Of Four Contemporary Chinese Composers And Their Chinese Language Art Songs, Xintian Xu Apr 2025

Contemporary Voices Of China: Biographical Introduction Of Four Contemporary Chinese Composers And Their Chinese Language Art Songs, Xintian Xu

Theses and Dissertations

This document primarily explores the rich developmental journey of Chinese modern art songs from the early 20th century to the present. It provides an overview of the lives, compositional activities, and contributions to Chinese art songs of four contemporary composers: Zheng Qiufeng, Wang Liping, Lu Zaiyi, and Zhao Jiping. To provide more specific resources, this study includes a table of selected works by the four composers, detailing the composer, song title, poet/lyricist, vocal range, and difficulty level. This section aims to serve as a practical reference for researchers, performing artists, and music educators interested in Chinese art songs.


The Impact Of Ballet Techniques On Singing Performers, Julie H. Welch Apr 2025

The Impact Of Ballet Techniques On Singing Performers, Julie H. Welch

Theses and Dissertations

Singing performers are tasked to being a multifaceted artist using their acting and even dance skills in a performance. Voice teachers have long incorporated physical activity into training, but traditional ballet techniques—such as core tension and neck elongation—can contradict healthy singing practices. Given ballet’s deep historical connection to opera and stage performance, this study aims to examine whether integrating ballet into vocal training enhances or hinders a singer’s technique and overall performance. This investigation surveyed forty subjects who identified as teachers, singing performers, or students earning a performance degree and interviewing select subjects for further information; results will be discussed.


Approaches To Teaching Music Reading To Students With Dyslexia: A Guide For Piano Teachers, Olivia Grace Bradstreet Colomaio Apr 2025

Approaches To Teaching Music Reading To Students With Dyslexia: A Guide For Piano Teachers, Olivia Grace Bradstreet Colomaio

Theses and Dissertations

Dyslexia is the most common learning disability in the United States, affecting approximately one in five individuals. According to the DSM-V-TR, the ICD-11, and the International Dyslexia Association, dyslexia is a Specific Learning Disorder that causes issues with phonological processing, sequencing of information and information processing, word recognition, reading fluency, and other issues. Due to its prevalence, the chances of piano teachers encountering a student with dyslexia in their teaching studios is highly likely. However, there is relatively little research available for piano teachers of students with dyslexia. In the music lesson, common areas of struggle for students with dyslexia …


The Double Bar-Line: A Qualitative And Quantitative Study Of Career Readiness For Historically Black College And University Voice Performance Majors, Brian L. Fenderson Apr 2025

The Double Bar-Line: A Qualitative And Quantitative Study Of Career Readiness For Historically Black College And University Voice Performance Majors, Brian L. Fenderson

Theses and Dissertations

Historically Black Colleges and Universities (HBCUs) play a crucial role in providing higher education opportunities for African American students, including those pursuing degrees in voice performance. In recent years, there has been a noticeable lack of performance opportunities and resources available to voice performance majors at HBCUs. This document aims to explore the challenges faced by HBCU voice performance majors who hoped to pursue a career in voice performance. Through a combination of literature review, qualitative interviews, and quantitative surveys, this study will examine the experience of voice performance majors from 1990 – present day. Interviews conducted will speak on …


Transcrite Par L'Auteur: Analyzing And Performing The Piano-Vocal Scores Of Maurice Ravel's Operas, Jordan Knapp Apr 2025

Transcrite Par L'Auteur: Analyzing And Performing The Piano-Vocal Scores Of Maurice Ravel's Operas, Jordan Knapp

Theses and Dissertations

The two operas of Maurice Ravel, L’heure espagnole and L’enfant et les sortilèges, are, like most of the composer’s works, known for their innovative orchestrations and instrumental flourishes. However, the piano-vocal scores of the operas have their own unique qualities worthy of study. With the piano writing at times fiendishly difficult—standing toe-to-toe with Ravel’s solo piano music—the score demands simplification, particularly for less experienced performers serving as accompanist or rehearsal pianist for these works. Many sections of the music are impractical or even impossible for a single pianist to perform, but this study offers alternate solutions and simplifications for pianists …


Reclaiming The Body: Gender Politics And Embodied Meaning In Piano Performance And Pedagogy, Rachel Misheff Apr 2025

Reclaiming The Body: Gender Politics And Embodied Meaning In Piano Performance And Pedagogy, Rachel Misheff

Theses and Dissertations

This study examines the impact of the mind-body duality and its gendered metaphor on the lived experiences of historical and contemporary female pianists. Specifically, it explores how the principles of mind-body dualism have constructed gendered practices in piano performance and pedagogy that have both marginalized female pianists and engendered distinct embodied relationships to music. The study draws upon research from other disciplines, such as phenomenology, theories of embodiment, feminist theory, psychoanalysis, and Embodied Music Cognition, to examine how these gendered musical norms resulting from mind-body dualism functioned as forces of social inscription. This research, therefore, suggests that the body’s lived …


Designing A Genetics-Based Bibliotherapy Model For Children With Inborn Errors Of Metabolism, Kaitlyn Abagail Gmitro Apr 2025

Designing A Genetics-Based Bibliotherapy Model For Children With Inborn Errors Of Metabolism, Kaitlyn Abagail Gmitro

Theses and Dissertations

Bibliotherapy is a psychotherapy technique utilized to teach individuals about concepts through the use of literature and the arts. The primary aim of this research was to examine how a bibliotherapy model could be applied to improve diet and treatment adherence for people affected with Inborn Errors of Metabolism. Prior to this research, no paper has proposed a tailored bibliotherapy approach for genetic conditions. Through analysis of the caregiver-child relationship and disclosure process and the perceived support needs of both caregivers and providers caring for children with IEMS, our goal was to propose a bibliotherapy model to improve adherence and …


Stories Between The Stacks: Current Black Women School Librarians' Lived Experiences, Cynthia R. Johnson Apr 2025

Stories Between The Stacks: Current Black Women School Librarians' Lived Experiences, Cynthia R. Johnson

Theses and Dissertations

Black women school librarians navigate complex professional landscapes shaped by their lived experiences, intersecting identities, and systemic barriers. Despite their significant contributions to school librarianship, their perspectives remain largely absent from scholarly work. This qualitative study explored how the lived experiences and positionalities of Black women school librarians shape their practices. It addressed the critical gap in research on Black women school librarians. Grounded in Black Critical Theory (BlackCrit) and guided by Black feminist-womanist storytelling, this study employs a narrative approach to explore the experiences of four Black women school librarians in the Southeastern Region of the United States. Data …


Newborn Screening For X-Linked Adrenoleukodystrophy: Experiences, Perspectives, And Future Directions For Genetic Counseling, Sophia Salvatore Apr 2025

Newborn Screening For X-Linked Adrenoleukodystrophy: Experiences, Perspectives, And Future Directions For Genetic Counseling, Sophia Salvatore

Theses and Dissertations

There is a notable lack of research regarding genetic counseling practices for infants with screen-positive results for X-linked adrenoleukodystrophy (X-ALD) via newborn screening (NBS). The exploratory study aimed to understand the experiences of genetic counselors providing follow-up care for these infants, assess the complexities associated with NBS for X-ALD, identify potential gaps in genetic counseling practices, and describe the subsequent impact on patient care. A mixed-methods approach was utilized, incorporating an initial survey and optional semi-structured interviews with practicing genetic counselors who had seen a minimum of five cases of infants with screen-positive results for X-ALD in the last two …


Exploring Modernist Traits In The Guitar Works Of Manuel María Ponce, Michael William Bunny Apr 2025

Exploring Modernist Traits In The Guitar Works Of Manuel María Ponce, Michael William Bunny

Theses and Dissertations

Music of the early twentieth century developed drastically from that of previous eras. With Debussy’s emphasis on tone color and timbre, Stravinsky’s rhythmic complexities, and Bartók’s incorporation of folk music, the twentieth century had a far different sound to that which preceded it. Each of these composers demonstrated different practices of this new genre called modernism. However, likely due to Andrés Segovia’s dislike of modernist music, there were not many popular composers that followed this trend in the guitar world. Those composing for the guitar shied away from attributes of modernism, ensuring that their works would be played. Manuel María …