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Coupled Flow Field Simulations Of Charring Ablators With Nonequilibrium Surface Chemistry, Hicham Alkandry, Iain D. Boyd, Alexandre Martin

Mechanical Engineering Faculty Publications

This paper describes the coupling of a Navier-Stokes solver to a material response code to simulate nonequilibrium gas-surface interactions. The Navier-Stokes solver used in this study is LeMANS, which is a three-dimensional computational fluid dynamics code that can simulate hypersonic reacting flows including thermo-chemical nonequilibrium effects. The material response code employed in this study is MOPAR, which uses the one-dimensional control volume nite-element method to model heat conduction and pyrolysis gas behavior. This coupling is demonstrated using a test case based on the Stardust sample return capsule. Coupled simulations are performed at three different trajectory conditions. The effects of the …

Volume Averaged Modeling Of The Oxidation Of Porous Carbon Fiber Material, Alexandre Martin

Mechanical Engineering Faculty Publications

Charring ablators remain the premium choice for space exploration missions that involve atmospheric re-entry. This type of ablative material is composed of a carbon matrix, usually made of fibers, which is then impregnated with a resin. During re-entry, the high heat flux produced by convective heating causes the material to chemically react. First, the resin pyrolyzes, and is vaporized into a gas that travels through the material, and is eventually ejected at the surface. Then, as the temperature rises, the surface of the porous matrix recess through ablative processes. For re-entry conditions typical of space exploration missions, this is mainly …

Flow-Tube Oxidation Experiments On The Carbon Preform Of Pica, Francesco Panerai, Alexandre Martin, Nagi N. Mansour, Steven A. Sepka, Jean Lachaud

Mechanical Engineering Faculty Publications

Oxidation experiments on the carbon preform of a phenolic-impregnated carbon ablator were performed in the NASA Ames ow-tube reactor facility, at temperatures between 700 and 1300 K, under dry air gas at pressures between 103 and 104 Pa. Mass loss, volumetric recession and density changes were measured at different test conditions. An analysis of the diffusion/reaction competition within the porous material, based on the Thiele number, allowed us to identify low temperature and low pressure conditions to be dominated by in-depth volume oxidation. Experiments above 1000 K were found at transition conditions, where diffusion and reaction occur at similar scales. …

Multi-Dimensional Modeling Pyrolysis Gas Flow Inside Charring Ablators, Haoyue Weng, Alexandre Martin

Mechanical Engineering Faculty Publications

Using an ablative thermal/material response code, the importance of three-dimensionality for modeling ablative test-article is addressed. In particular, the simulation of the pyrolysis gas flow inside a porous material is presented, using two different geometries. The effects of allowing the gas to flow out of the side wall are especially highlighted. Results show that the flow inside the test-article is complex, and that the 0D or 1D assumption made in most Material Response (MR) codes might not be valid for certain geometries.

2,2',5',6-Tetrachloro-4-[(1S)-1-Methylpropoxy]Biphenyl, Hans-Joachim Lehmler, Huimin Wu, Sean Parkin

Chemistry Faculty Publications

In the title molecule, C₁₆H₁₄Cl₄O, the dihedral angle between the least-square planes of the benzene rings is 84.40 (7)°. No unusual intermolecular interactions are present.

Estimations Of The Magnetic Field Strength In The Torus Of Ic 5063 Using Near-Infrared Polarimetry, E. Lopez-Rodriguez, C. Packham, S. Young, Moshe Elitzur, N. A. Levenson, R. E. Mason, C. Ramos Almeida, A. Alonso-Herrero, T. J. Jones, E. Perlman

Physics and Astronomy Faculty Publications

An optically and geometrically thick torus obscures the central engine of active galactic nuclei (AGN) from some lines of sight. From a magnetohydrodynamical framework, the torus can be considered to be a particular region of clouds surrounding the central engine where the clouds are dusty and optically thick. In this framework, the magnetic field plays an important role in the creation, morphology and evolution of the torus. If the dust grains within the clouds are assumed to be aligned by paramagnetic alignment, then the ratio of the intrinsic polarization and visual extinction, P(per cent)/A_v, is a …

The X-Ray Properties Of Optically Selected Clusters Of Galaxies, A. K. Hicks, G. W. Pratt, M. Donahue, E. Ellingson, M. Gladders, H. Böhringer, H. K. C. Yee, Renbin Yan, J. H. Croston, D. G. Gilbank

Physics and Astronomy Faculty Publications

We present the results of Chandra and Suzaku X-ray observations of nine moderate-redshift (0.16 < z < 0.42) clusters discovered via the Red-sequence Cluster Survey (RCS). Surface brightness profiles are fitted to β-models, gas masses are determined, integrated spectra are extracted within R₂₅₀₀, and X-ray temperatures and luminosities are inferred. TheL_X–T_X relationship expected from self-similar evolution is tested by comparing this sample to our previous X-ray investigation of nine high-redshift (0.6 < z < 1.0) optically selected clusters. We find that optically selected clusters are systematically less luminous than X-ray selected clusters of similar X-ray temperature at both moderate and high z. We are unable to constrain evolution in the L_X–T_X relation with these data, but find it consistent with no evolution, within relatively large uncertainties. To investigate selection effects, we compare the X-ray properties of our sample to those of clusters in the …

Topography-Guided Spreading And Drying Of 6,13-Bis(Triisopropylsilylethynyl)-Pentacene Solution On A Polymer Insulator For The Field-Effect Mobility Enhancement, Chang-Min Keum, Jin-Hyuk Bae, Min-Hoi Kim, Hea-Lim Park, Marcia M. Payne, John E. Anthony, Sin-Doo Lee

Chemistry Faculty Publications

We report on the enhancement of the field-effect mobility of solution-processed 6,13-bis(triisopropylsilylethynyl)-pentacene (TIPS-pentacene) by unidirectional topography (UT) of an inkjet-printed polymer insulator. The UT leads to anisotropic spreading and drying of the TIPS-pentacene droplet and enables to spontaneously develop the ordered structures during the solvent evaporation. The mobility of the UT-dictated TIPS-pentacene film (0.202 ± 0.012 cm²/Vs) is found to increase by more than a factor of two compared to that of the isotropic case (0.090 ± 0.032 cm²/Vs). The structural arrangement of the TIPS-pentacene molecules in relation to the mobility enhancement is described within an …

Studies Of Ngc 6720 With Calibrated Hst/Wfc3 Emission-Line Filter Images. Iii. Tangential Motions Using Astrodrizzle Images, C. R. O'Dell, Gary J. Ferland, W. J. Henney, M. Peimbert

Physics and Astronomy Faculty Publications

We have been able to compare with astrometric precision AstroDrizzle processed images of NGC 6720 (the Ring Nebula) made using two cameras on the Hubble Space Telescope. The time difference of the observations was 12.925 yr. This large time base allowed the determination of tangential velocities of features within this classic planetary nebula. Individual features were measured in [N II] images as were the dark knots seen in silhouette against background nebular [O III] emission. An image magnification and matching technique was also used to test the accuracy of the usual assumption of homologous expansion. We found that homologous …

Spin Switching And Magnetization Reversal In Single-Crystal Ndfeo3, Shujuan Yuan, W. Ren, F. Hong, Y. B. Wang, J. C. Zhang, L. Bellaiche, Gang Cao

Physics and Astronomy Faculty Publications

We report an experimental and computational study of single-crystal NdFeO₃, which features two inequivalent magnetic sublattices, namely, Fe and Nd sublattices that are coupled in an antiparallel fashion. This paper reveals that a strong interaction between 3d and 4f electrons of the two sublattices along with a spin-lattice coupling drives an extremely interesting magnetic state that is highly sensitive to the orientation and history of weak magnetic field. The following phenomena are particularly remarkable: (1) sharply contrasting magnetization M(T) along the a and c axes; (2) a first-order spin switching along the a …

5,5'-Dichloro-2,2'-Dimethoxybiphenyl, Hans-Joachim Lehmler, Huimin Wu, Sean Parkin

Chemistry Faculty Publications

In the title molecule, C₁₄H₁₂Cl₂O₂, the dihedral angle between the least-square planes of the benzene rings is 62.17 (6)°. Both methoxy groups are slightly out of the plane of the benzene rings to which they are attached, making dihedral angles of 4.22 (18) and 18.82 (16)°.

Post-Combustion Of Carbon Residues From Biomass / Rdf Co-Firing During Dry Ash Removal, Fulvio Bassetti, Daniele Coppola, Daniele Ricci, Osvalda Senneca

World of Coal Ash Proceedings

No abstract provided.

Examination Of Precursors In Fly Ash For Development Of An Engineered Geopolymer Concrete, Fernando Soto, Kunal Kupwade-Patil, Milap Dhakal, Shathabish Narasegowda

World of Coal Ash Proceedings

No abstract provided.

Method Of Ameliorating Oxidative Stress And Supplementing The Diet, Boyd E. Haley, Niladrl Narayan Gupta

Chemistry Faculty Patents

A method of supplementing a diet and ameliorating oxidative stress in a mammal includes administering a pharmaceutically effective amount of lipid soluble, hydrophobic active compounds having a chemical structure . . .

To see the remainder of this abstract, please download this patent.

Magnetic And Crystal Structures Of Sr2Iro4: A Neutron Diffraction Study, Feng Ye, Songxue Chi, Bryan C. Chakoumakos, Jaime A. Fernandez-Baca, Tongfei Qi, Gang Cao

Center for Advanced Materials Faculty Publications

We report a single-crystal neutron diffraction study of the layered Sr₂IrO₄. This work unambiguously determines the magnetic structure of the system and reveals that the spin orientation rigidly tracks the staggered rotation of the IrO₆ octahedra in Sr₂IrO₄. The long-range antiferromagnetic order has a canted spin configuration with an ordered moment of 0.208(3) μ_B/Ir site within the basal plane; a detailed examination of the spin canting yields 0.202(3) and 0.049(2) μ_B/site for the a axis and the b axis, respectively. It is intriguing that forbidden nuclear reflections …

Classification And Analysis Of Emission-Line Galaxies Using Mean Field Independent Component Analysis, James T. Allen, Paul C. Hewett, Chris T. Richardson, Gary J. Ferland, Jack A. Baldwin

Physics and Astronomy Faculty Publications

We present an analysis of the optical spectra of narrow emission-line galaxies, based on mean field independent component analysis (MFICA), a blind source separation technique. Samples of galaxies were drawn from the Sloan Digital Sky Survey (SDSS) and used to generate compact sets of ‘continuum’ and ‘emission-line’ component spectra. These components can be linearly combined to reconstruct the observed spectra of a wider sample of galaxies. Only 10 components – five continuum and five emission line – are required to produce accurate reconstructions of essentially all narrow emission-line galaxies to a very high degree of accuracy; the median absolute deviations …

Strongly Localized Magnetization Modes In Permalloy Antidot Lattices, J. Sklenar, V. S. Bhat, Lance E. De Long, O. Heinonen, J. B. Ketterson

Physics and Astronomy Faculty Publications

Antidot lattices (ADLs) patterned into soft magnetic thin films exhibit rich ferromagnetic resonance (FMR) spectra corresponding to many different magnetization modes. One of the predicted modes is highly localized at the edges of the antidots; this mode is difficult to detect experimentally. Here we present FMR data for a permalloy thin film patterned into a square array of square antidots. Comparison of these data with micromagnetic simulations permits identification of several edge modes. Our simulations also reveal the effect of the antidot shape on the mode dispersion.

Suppression Of Dielectronic Recombination Due To Finite Density Effects, D. Nikolić, T. W. Gorczyca, K. T. Korista, Gary J. Ferland, N. R. Badnell

Physics and Astronomy Faculty Publications

We have developed a general model for determining density-dependent effective dielectronic recombination (DR) rate coefficients in order to explore finite-density effects on the ionization balance of plasmas. Our model consists of multiplying by a suppression factor those highly-accurate total zero-density DR rate coefficients which have been produced from state-of-the-art theoretical calculations and which have been benchmarked by experiment. The suppression factor is based upon earlier detailed collision-radiative calculations which were made for a wide range of ions at various densities and temperatures, but used a simplified treatment of DR. A general suppression formula is then developed as a function of …

Erratum: 'Improved He I Emissivities In The Case B Approximation', R. L. Porter, Gary J. Ferland, P. J. Storey, M. J. Detisch

Physics and Astronomy Faculty Publications

No abstract provided.

Tuning Electronic Structure Via Exipatial Strain In Sr2Iro4 Thin Films, J. Nichols, Jsaminka Terzic, Emily Geraldine Bittle, Oleksandr B. Korneta, Lance E. De Long, Joseph Brill, Gang Cao, Sung S. Ambrose Seo

Physics and Astronomy Faculty Publications

We have synthesized epitaxial Sr₂IrO₄ thin-films on various substrates and studied their electronic structure as a function of lattice-strain. Under tensile (compressive) strain, increased (decreased) Ir-O-Ir bond-angle is expected to result in increased (decreased) electronic bandwidth. However, we have observed that the two optical absorption peaks near 0.5 eV and 1.0 eV are shifted to higher (lower) energies under tensile (compressive) strain, indicating that the electronic-correlation energy is also affected by in-plane lattice-strain. The effective tuning of electronic structure under lattice-modification provides an important insight into the physics driven by the coexisting strong spin-orbit coupling and electronic …

Expanded Iron Uta Spectra—Probing The Thermal Stability Limits In Agn Clouds, Gary J. Ferland, R. Kisielius, F. P. Keenan, P. A. M. Van Hoof, V. Jonauskas, Matt L. Lykins, R. L. Porter, R. J. R. Williams

Physics and Astronomy Faculty Publications

The Fe unresolved transition arrays (UTAs) produce prominent features in the ~15-17 Å wavelength range in the spectra of active galactic nuclei (AGNs). Here, we present new calculations of the energies and oscillator strengths of inner-shell lines from Fe XIV, Fe XV, and Fe XVI. These are crucial ions since they are dominant at inflection points in the gas thermal stability curve, and UTA excitation followed by autoionization is an important ionization mechanism for these species. We incorporate these, and data reported in previous papers, into the plasma simulation code Cloudy. This updated physics is subsequently employed to reconsider the …

An Probability-Based Energy Model On Cache Coherence Protocol With Mobile Sensor Network, Jihe Wang, Bing Guo, Meikang Qiu

Electrical and Computer Engineering Faculty Publications

Mobile sensor networks (MSNs) are widely used in various domains to monitor, record, compute, and interact the information within an environment. To prolong the life time of each node in MSNs, energy model and conservation should be considered carefully when designing the data communication mechanism in the network. The limited battery volume and high workload on channels worsen the life times of the busy nodes. In this paper, we propose a new energy evaluating methodology of packet transmissions in MSNs, which is based on redividing network layers and describing the synchronous data flow with matrix form. We first introduce the …

3,4',5-Trichlorobiphenyl-4-Yl 2,2,2-Trichloroethyl Sulfate, Hans-Joachim Lehmler, Xianran He, Michael W. Duffel, Sean Parkin

Chemistry Faculty Publications

Crystals of the title compound, C₁₄H₈Cl₆O₄S, are twinned by inversion, with unequal components [0.85 (3):0.15 (3)]. The asymmetric unit contains two independent molecules that are related by a pseudo-inversion center. The C_ar-O [1.393 (9) and 1.397 (9) Å] and ester S-O bond lengths [1.600 (5) and 1.590 (5) Å] of both molecules are comparable to the structurally related 2,3,5,5-trichlorobiphenyl-4-yl 2,2,2-trichloroethyl sulfate. The dihedral angles between the benzene rings in the two molecules are 37.8 (2) and 35.0 (2)°.

The Nature Of The H2-Emitting Gas In The Crab Nebula, C. T. Richardson, J. A. Baldwin, Gary J. Ferland, E. D. Loh, C. A. Kuehn, A. C. Fabian, Philippe Salomé

Physics and Astronomy Faculty Publications

Understanding how molecules and dust might have formed within a rapidly expanding young supernova remnant is important because of the obvious application to vigorous supernova activity at very high redshift. In previous papers, we have mapped the Crab nebula (the Crab) in a rotovibrational H₂emission line, and then measured the molecular excitation temperature for a few of the brighter H₂-emitting knots that we have found to be scattered throughout the Crab's filaments. We found that H₂ emission is often quite strong, correlates with optical low-ionization emission lines and has a surprisingly high excitation temperature. Here, …

The Mathematics Of Drug Dose Individualization Should Be Built With Random-Effects Linear Models, Francisco J. Diaz, Jose De Leon

Psychiatry Faculty Publications

No abstract provided.

Derivation Of Multivariate Syndromic Outcome Metrics For Consistent Testing Across Multiple Models Of Cervical Spinal Cord Injury In Rats, Adam R. Ferguson, Karen-Amanda Irvine, John C. Gensel, Jessica L. Nielson, Amity Lin, Johnathan Ly, Mark R. Segal, Rajiv R. Ratan, Jacqueline C. Bresnahan, Michael S. Beattie

Physiology Faculty Publications

Spinal cord injury (SCI) and other neurological disorders involve complex biological and functional changes. Well-characterized preclinical models provide a powerful tool for understanding mechanisms of disease; however managing information produced by experimental models represents a significant challenge for translating findings across research projects and presents a substantial hurdle for translation of novel therapies to humans. In the present work we demonstrate a novel 'syndromic' information-processing approach for capitalizing on heterogeneous data from diverse preclinical models of SCI to discover translational outcomes for therapeutic testing. We first built a large, detailed repository of preclinical outcome data from 10 years of basic …

Ebookmobile 2.0: Revamping Services Based On User Feedback, Kathryn Lybarger

Library Presentations

No abstract provided.

Poster Session, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• The New Kentucky Nitrogen and Phosphorus Risk Assessment Tool to Protect Water Quality, Tibor Horvath and others, USDA-NRCS, Lexington, KY
• Groundwater Phosphorus in Kentucky Relative to Karst, Groundwater Sensitivity, and Groundwater Physiographic Region, Caroline Chan, Kentucky Division of Water, Frankfort, KY
• Comparison of Irrigation Scheduling Based on Daily Water Use or Plant Water Demand of Container Grown Nursery Plants, Susmitha Nambuthiri and others, Dept of Horticulture, UK
• Arsenic Species in Broiler (Gallus gallus domesticus) Litter, Soils, Maize (Zea mays L.), and Groundwater from Litter-Amended Fields, Georgia Zeigler and others, Dept Plant and Soil Science, UK
• Cyberinfrastructure …

Session 2d, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• A Stability Index for Northern Kentucky Streams, Bob Hawley and others, Sustainable Streams, LLC, Louisville, KY
• The Gunpowder and Woolper Creek Watershed Initiatives, Local Cases of a National Problem, Mark Jacobs and others, Boone County Conservation District, Burlington, KY
• Watershed-Scale Model of Carbon and Nitrogen Cycles in Streams, William Ford and Jimmy Fox, Dept of Civil Engineering, UK
• Sensor Network for Suspended Sediment Monitoring, Robert Stewart and others, Dept of Civil Engineering, UK

Session 2c, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Mercury Bioaccumulation and the Impact of Stream Basin Characteristics on Susceptible Populations: Policy Implications for Kentucky, Caroline Chan, Kentucky Division of Water, Frankfort, KY
• Asian Carp in Kentucky Waters: An Ecological Disaster? Ron Brooks, Kentucky Dept of Fish and Wildlife Resources, Frankfort, KY
• Effects of Streambed Sediments on the Fate of Selenium in Eastern Kentucky Watersheds Contaminated with Surface Coal Mining Operations, Edward Fisher and Yi-Tin Wang, Dept of Civil Engineering, UK
• Thermal Dependence of Solvation Geometries in Aqueous Nitrate Ion Solutions, Matthew Nee, Dept of Chemistry, WKU, Bowling Green, KY
• The Combined Effects of Atrazine and …