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Nanoscale Spectroscopy In Energy And Catalytic Applications, Yi Ding
Nanoscale Spectroscopy In Energy And Catalytic Applications, Yi Ding
Electronic Theses and Dissertations
Emerging societal challenges such as the need for more sustainable energy and catalysis are requiring more sensitive and versatile measurements at the nanoscale. This is the case in the design and optimization of new materials for energy harvesting (solar cells) and energy storage devices (batteries and capacitors), or for the development of new catalysts for carbon sequestration or other reactions of interest. Hence, the ability to advance spectroscopy with nanoscale spatial resolution and high sensitivity holds great promises to meet the demands of deeper fundamental understanding to boost the development and deployment of nano-based devices for real applications. In this …
Asteroid Surfaces: The Importance Of Cohesive Forces, Keanna Jardine
Asteroid Surfaces: The Importance Of Cohesive Forces, Keanna Jardine
Electronic Theses and Dissertations
Adhesive forces play a significant role on airless bodies due to their weak gravities. Investigating adhesion at the surface of asteroids and their constituent components is vital to understanding their formation and evolution. Previous research has been done to understand the interaction of micron-sized spheres to planar surfaces and sphere-to-sphere interactions, which have been used to develop models of asteroid surfaces. Our investigation experimentally investigates adhesion through atomic force microscopy (AFM) measurements between JSC-1 simulant particles and several AFM tips, including a typical pyramidal gold tip and microspheres of sizes 2 μm and 15 μm. The samples of JSC-1 consist …
Remediation Of Chlorinated Alkanes By Zero Valent Iron With Vitamin B12 And Utilization Of A Modified Gradual Release Of Responsibility Model In A Large Enrollment Chemistry Course, Nicole Lapeyrouse
Electronic Theses and Dissertations
The following dissertation looks at addressing environmental contaminants in the environment and the integration of an active learning style in an introductory chemistry course. It begins with addressing the concern for chlorinated propanes and ethane in the environment and the importance of looking into environmental remediation applications. This research looks at incorporating vitamin B12 as an environmentally friendly catalyst in the presence of zero valent iron for the reduction of chlorinated propanes and ethane. Chapter 2 presents the analytical methods and conditions in which samples were run. The results from these experiments are discussed in length in Chapter 3. Our …
Exploring Multi-Scale Variation Of Fish Community Diversity In A Dynamic Coastal Estuary, Brittany Troast
Exploring Multi-Scale Variation Of Fish Community Diversity In A Dynamic Coastal Estuary, Brittany Troast
Electronic Theses and Dissertations
Examining diversity over multiple spatial and temporal scales affords the opportunity to develop a mechanistic understanding of the factors influencing community diversity dynamics, and how these may shift in a changing world. This thesis first examines multi-decadal fish community diversity metrics across a coastal biogeographic transition zone to quantify changes in species assemblages, assess relationships between fish community diversity and the abiotic environment, and capture potential shifts in the location of a putative biogeographic break. Results of this chapter indicate not only a change in fish community composition, but also a shift in the location of the biogeographic transition zone. …
A Complete Approach To Predict Biodistribution Of Nanomaterials Within Animal Species From In-Vitro Data, Edward Price
A Complete Approach To Predict Biodistribution Of Nanomaterials Within Animal Species From In-Vitro Data, Edward Price
Electronic Theses and Dissertations
Smart drug-design for antibody and nanomaterial-based therapies allows for optimization of drug efficacy and more efficient early-stage pre-clinical trials. The ideal drug must display maximum efficacy at target tissue sites, but to track and predict distribution to these sites, one must have a mechanistic understanding of the kinetics involved with the individual cells of the tissue itself. This process can be tracked through biological simulations coupled with in-vitro approaches, which result in a rapid and efficient in-depth understanding of drug transport within tissue vasculature and cellular environment. As a result, it becomes possible to predict drug biodistribution within live animal …
Trouble In Paradise: Impacts Of Theme Park Tourism On The Mental Health Of Employees In Orlando, Florida, Lea Harvey
Trouble In Paradise: Impacts Of Theme Park Tourism On The Mental Health Of Employees In Orlando, Florida, Lea Harvey
Electronic Theses and Dissertations
Tourism is a topic that has gained much attention within the realm of anthropology over the past few decades. Anthropological research of the tourism industry has been largely devoted to the study of the tourist gaze and its subsequent sociocultural impacts as well as the benefits that travelers reap from their colonialist excursions. However, the voices of those who form the foundation of this industry, the laborers, remain almost entirely absent from said discourse. Furthermore, there is a lack of anthropological consideration for the relationship between tourism and mental health experiences of employees within the tourism industry. One specific region …
Tails In The Wind: An Exploratory Examination Of Media Reports On Nonhuman Animals Throughout Hurricane Maria In Puerto Rico, Nathan Jagoda
Tails In The Wind: An Exploratory Examination Of Media Reports On Nonhuman Animals Throughout Hurricane Maria In Puerto Rico, Nathan Jagoda
Electronic Theses and Dissertations
On September 20th, 2017, category four Hurricane Maria rattled Puerto Rico, causing extensive damage throughout the island. While the experiences, injuries, and deaths of humans resulting from Hurricane Maria have received both scholarly consideration and large amounts of attention from media sources, one critical area that has been overlooked by many, particularly academics, are the ways in which various media sources have reported on, described and discussed nonhuman animals impacted by the storm. This study aimed to address this gap by analyzing media reports of nonhuman animals throughout the days before, during, and after Hurricane Maria in Puerto Rico. Mixed …
Developing And Validating The Secondary Literacy Professionals Needs Assessment Matrix, Analexis Kennedy
Developing And Validating The Secondary Literacy Professionals Needs Assessment Matrix, Analexis Kennedy
Electronic Theses and Dissertations
The purpose of this study was to develop and validate a needs assessment matrix for secondary specialized literacy professionals that identified the professional learning needs of literacy coaches. This tool was developed in order to inform school districts and secondary specialized literacy professionals about the types of professional learning support they will need for them to effectively meet the literacy needs of teachers in secondary schools. The Secondary Literacy Professionals Needs Assessment Matrix (SLPNAM) was created using a variety of methods. A synthesis of literature regarding school improvement, adolescent literacy, 21st century skills, adult learning, literacy coaching and the 2017 …
Visual-Textual Video Synopsis Generation, Aidean Sharghi Karganroodi
Visual-Textual Video Synopsis Generation, Aidean Sharghi Karganroodi
Electronic Theses and Dissertations
In this dissertation we tackle the problem of automatic video summarization. Automatic summarization techniques enable faster browsing and indexing of large video databases. However, due to the inherent subjectivity of the task, no single video summarizer fits all users unless it adapts to individual user's needs. To address this issue, we introduce a fresh view on the task called "Query-focused'' extractive video summarization. We develop a supervised model that takes as input a video and user's preference in form of a query, and creates a summary video by selecting key shots from the original video. We model the problem as …
Utilizing Asynchronous Online Modules To Educate Preservice Teachers To Address Bullying Behaviors For Elementary Students With Autism Spectrum Disorder, Jaime Best
Electronic Theses and Dissertations
Due to social and communication deficits, individuals with Autism Spectrum Disorder (ASD) are targeted for school bullying more than other populations. With an increased number of individuals with ASD being served in general education classrooms, teachers are at the front line of defense for this vulnerable population. Many teachers and preservice teachers lack experience and self-confidence when dealing with situations related to individuals with ASD in their inclusive classrooms. While research on educating preservice teachers to deal with bullying behaviors is limited, the importance of providing high-quality teacher preparation programs for upcoming teachers remains at the upmost importance. The purpose …
Teaching Online And Cyberbullying: Examining Higher Education Cyberbullying Policies In The Florida State University System, Joseph Raditch
Teaching Online And Cyberbullying: Examining Higher Education Cyberbullying Policies In The Florida State University System, Joseph Raditch
Electronic Theses and Dissertations
The cyberbullying phenomena has been recorded as affecting students and faculty alike in the K-12 and higher education systems. Cyberbullying in higher education has negative effects to the institution and its stakeholders, including faculty turn over and student suicide. While these responses are highly publicized, the effects of cyberbullying on the online classroom remain relatively untouched by researchers. There are very few resources available to faculty who teach online courses for creating strategies to combat cyberbullying in that context. Furthermore, many states, including Florida, defer conduct policies and their enforcement to the individual institution. While there are many aspects of …
The Challenges And Barriers Facing Successful Lean Implementation In The Qatari Manufacturing Organizations, Abdulwahab Alyousef
The Challenges And Barriers Facing Successful Lean Implementation In The Qatari Manufacturing Organizations, Abdulwahab Alyousef
Electronic Theses and Dissertations
The success of Toyota, the inventor of Lean Systems has drawn the attention of academics, researchers, and executives in the last decades. However, existing lean research is largely focused on developed economies in Europe, the Americas, and in Southeast Asia with little focus on the Arab world in general and Qatar specifically. There has been an emergence of manufacturing organizations and Small and Medium- sized Enterprises (SME) in Qatar recently which was the focus of this research. Despite the many attempts to implement lean in organizations, there have been a large number of failed attempts. This research aims to study …
Multi-Level Optimization With Pricing Strategy Under Boundedly Rationality User Equilibrium, Guanxiang Yun
Multi-Level Optimization With Pricing Strategy Under Boundedly Rationality User Equilibrium, Guanxiang Yun
Electronic Theses and Dissertations
We study multi-level optimization problem on energy system, transportation system and information network. We use the concept of boundedly rational user equilibrium (BRUE) to predict the behaviour of users in systems. By using multi-level optimization method with BRUE, we can help to operate the system work in a more efficient way. Based on the introducing of model with BRUE constraints, it will lead to the uncertainty to the optimization model. We generate the robust optimization as the multi-level optimization model to consider for the pessimistic condition with uncertainty. This dissertation mainly includes four projects. Three of them use the pricing …
Solution Of Linear Ill-Posed Problems Using Overcomplete Dictionaries, Pawan Gupta
Solution Of Linear Ill-Posed Problems Using Overcomplete Dictionaries, Pawan Gupta
Electronic Theses and Dissertations
In this dissertation, we consider an application of overcomplete dictionaries to the solution of general ill-posed linear inverse problems. In the context of regression problems, there has been an enormous amount of effort to recover an unknown function using such dictionaries. While some research on the subject has been already carried out, there are still many gaps to address. In particular, one of the most popular methods, lasso, and its variants, is based on minimizing the empirical likelihood and unfortunately, requires stringent assumptions on the dictionary, the so-called, compatibility conditions. Though compatibility conditions are hard to satisfy, it is well …
Designing Calorie Counter Smartphone Applications For Effective Weight Loss, Sharlin Milliard
Designing Calorie Counter Smartphone Applications For Effective Weight Loss, Sharlin Milliard
Electronic Theses and Dissertations
Poor dietary choices and lack of physical activity are two main contributing factors for the increasing prevalence of overweight and obesity in the United States. Overweight and obese individuals are at risk for developing major life-threatening diseases. Weight loss is an effective means for reversing these adverse health effects, and smartphone applications (apps) may be an effective means for supporting weight loss outside of formal clinical settings. This study involved identifying factors that contribute to effective weight loss to compare with functionality commonly found in a sample of calorie counter apps. A content analysis was performed using a design framework …
Catalytic Properties Of Defect-Laden 2d Material From First-Principles, Tao Jiang
Catalytic Properties Of Defect-Laden 2d Material From First-Principles, Tao Jiang
Electronic Theses and Dissertations
Two dimensional (2D) materials offer excellent opportunities for application as catalysts for energy needs. Their catalytic activity depends on the nature of defects, their geometry and their electronic structure. It thus important that the characteristics of defect-laden 2D materials be understood at the microscopic level. My dissertation focuses on theoretical and computational studies of several novel nanoscale materials using state-of-the-art techniques based on density functional theory (DFT) with the objective of understanding the microscopic factors that control material functionality. My work has helped establish defect-laden hexagonal boron nitride (dh-BN) as a promising metal-free catalyst for CO2 hydrogenation. Firstly, I showed …
Sub-Terahertz Spin Pumping From An Insulating Antiferromagnet, Priyanka Vaidya
Sub-Terahertz Spin Pumping From An Insulating Antiferromagnet, Priyanka Vaidya
Electronic Theses and Dissertations
The combination of the spin transfer torque and spin Hall effects, or their reciprocal dynamical spin pumping and inverse spin Hall effects, respectively, enable reading and controlling the magnetization state in spintronics devices which are at the verge of mass commercialization as the next generation of energy-efficient and fast magnetic random-access memory applications with the use of ferromagnetic elements, e.g., the spin valve. However, these effects have remained elusive in antiferromagnetic-based devices up to date, despite the fascinating advantages offered by the absence of stray fields (zero net magnetization), Terahertz spin dynamics, and the widespread availability of metallic, insulating and …
Neurological Reactivity To Personalized Odors And Sounds In Combat-Related Posttraumatic Stress Disorder, Michael Gramlich
Neurological Reactivity To Personalized Odors And Sounds In Combat-Related Posttraumatic Stress Disorder, Michael Gramlich
Electronic Theses and Dissertations
Functional near-infrared spectroscopy (fNIRS) is a neurophysiological procedure that offers immense clinical utility due to its cost effectiveness, ease of use, and mobile application. Using fNIRS to measure neurological reactions to personalized trauma-related cues might strengthen diagnostic screening, tailor treatment planning, and improve detection of remission among individuals with posttraumatic stress disorder (PTSD). Odors elicit strong emotional responses but remain underutilized in clinical research. This fNIRS study examined whether personalizing combat-related odors and sounds to have a higher or lower match to distressing combat experiences increased the observed neurological effect among combat veterans with and without combat-related PTSD. This study …
A Grounded Theory Survey Study Of Teachers Perception Perpetuating The Deficit Narrative About Marginalized Students Of Color, Cavel Austin
A Grounded Theory Survey Study Of Teachers Perception Perpetuating The Deficit Narrative About Marginalized Students Of Color, Cavel Austin
Electronic Theses and Dissertations
The deficit narrative about marginalized students of color attributes their failure in school to some nature of innate cognitive deficiency, cultural, social, and familial dysfunctions among other schools of thoughts. The purpose of this grounded theory study is to provide a rich description about this phenomenon and to propose theoretical pedagogical adjustments in the classroom as it relates to educating students of color. The study applies Charmaz (2014) Constructivist approach to grounded theory methods to examine the following research questions: (RQ1) How do teachers' narratives about students of color depict their teaching experiences and (RQ2) How do teachers' narratives about …
Warrants For Right-Turn Flashing Yellow Arrow Signal Phases, Mohammed Alfawzan
Warrants For Right-Turn Flashing Yellow Arrow Signal Phases, Mohammed Alfawzan
Electronic Theses and Dissertations
The right-turn flashing yellow arrow (FYA) signal phasing is a new signal practice in the United States. The Manual on Uniform Traffic Control Devices MUTCD (2009) allocates a signal phasing section for the right-turn FYA, which requires a four-section head FYA signal. It supports multiple phases' indications that guide the motorist through permissive, protected, and/or permissive/protected phases. For this dissertation, I investigated three permissive right-turn FYA signal phases in various traffic conditions and signal timing circumstances. The first permissive right-turn FYA signal phase is the tight-turn on impeding through (RTOIT) taking place during the cross-street through traffic movement. The second …
Nanoplasmonics In Two-Dimensional Dirac And Three-Dimensional Metallic Nanostructure Systems, Alireza Safaei
Nanoplasmonics In Two-Dimensional Dirac And Three-Dimensional Metallic Nanostructure Systems, Alireza Safaei
Electronic Theses and Dissertations
Surface plasmons are collective oscillation of electrons which are coupled to the incident electric field. Excitation of surface plasmon is a route to engineer the behavior of light in nanometer length scale and amplifying the light-matter interaction. This interaction is an outcome of near-field enhancement close to the metal surface which leads to plasmon damping through radiative decay to outgoing photons and nonradiative decay inside and on the surface of the material to create an electron-hole pair via interband or intraband Landau damping. Plasmonics in Dirac systems such as graphene show novel features due to massless electrons and holes around …
Chemical Vapor Deposition Growth Of Large Area 2d Mos2 Layers: Layer Orientation Control, Heterostructure Integration, And Applications For Stretchable Sensors., Md. Ashraful Islam
Chemical Vapor Deposition Growth Of Large Area 2d Mos2 Layers: Layer Orientation Control, Heterostructure Integration, And Applications For Stretchable Sensors., Md. Ashraful Islam
Electronic Theses and Dissertations
Two-dimensional (2D)-layered MoS2 layers have exhibited a broad set of unusual and superior material properties unattainable in any traditional bulk materials, drawing significant research interests nowadays. For instance, they present excellent semiconducting properties accompanying high carrier mobility and large current ON/OFF ratio as well as extensive in-plane strain limit and thickness, projecting high suitably for emerging flexible and stretchable electronics. Such properties and applications strongly depend on the physical orientation and chemical composition of constituent 2D layers. 2D MoS2 layers chemically grown in two distinct orientations, e.g., horizontal alignment for electronics and optoelectronics, and vertical alignment for electrochemical and sensing …
Novel Solid State Lasers Based On Volume Bragg Gratings, Evan Hale
Novel Solid State Lasers Based On Volume Bragg Gratings, Evan Hale
Electronic Theses and Dissertations
Since their invention in 1960, lasers have revolutionized modern technology, and tremendous amounts of innovation and development has gone into advancing their properties and efficiencies. This dissertation reports on further innovations by presenting novel solid state laser systems based on the volume Bragg gratings (VBGs) and the newly developed holographic phase mask (HPMs) for brightness enhancement, dual wavelength operation, and mode conversion. First, a new optical element was created by pairing the HPM with two surface gratings creating an achromatic holographic phase mask. This new optical device successfully performed transverse mode conversion of multiple narrow line laser sources operating from …
Variation In Prospecting Behavior And Drivers Of Post-Fire Habitat Preference Among Juvenile Florida Scrub-Jays, David Sherer
Variation In Prospecting Behavior And Drivers Of Post-Fire Habitat Preference Among Juvenile Florida Scrub-Jays, David Sherer
Electronic Theses and Dissertations
Florida Scrub-Jays (Aphelocoma coerulescens, FLSJ; federally Threatened) are cooperatively breeding birds endemic to Florida and dependent on fire-maintained xeric oak scrub. FLSJs are year-round residents, highly territorial, and rarely disperse far from their natal territory. Lifetime reproductive success is highest among individuals breeding in early-successional habitat, usually less than 9 to 10 years post-fire. However, because scrub burns infrequently such early-successional, high-quality habitat is extremely limited and competition for it as breeding space is likely intense. Because some birds live long enough to experience habitat succession, FLSJs also occupy later-successional overgrown scrub, even though both survival and fecundity decline. Although …
Context-Centric Affect Recognition From Paralinguistic Features Of Speech, Andreas Marpaung
Context-Centric Affect Recognition From Paralinguistic Features Of Speech, Andreas Marpaung
Electronic Theses and Dissertations
As the field of affect recognition has progressed, many researchers have shifted from having unimodal approaches to multimodal ones. In particular, the trends in paralinguistic speech affect recognition domain have been to integrate other modalities such as facial expression, body posture, gait, and linguistic speech. Our work focuses on integrating contextual knowledge into paralinguistic speech affect recognition. We hypothesize that a framework to recognize affect through paralinguistic features of speech can improve its performance by integrating relevant contextual knowledge. This dissertation describes our research to integrate contextual knowledge into the paralinguistic affect recognition process from acoustic features of speech. We …
Development Of Multiport Single Stage Bidirectional Converter For Photovoltaic And Energy Storage Integration, Amit Bhattacharjee
Development Of Multiport Single Stage Bidirectional Converter For Photovoltaic And Energy Storage Integration, Amit Bhattacharjee
Electronic Theses and Dissertations
The energy market is on the verge of a paradigm shift as the emergence of renewable energy sources over traditional fossil fuel based energy supply has started to become cost competitive and viable. Unfortunately, most of the attractive renewable sources come with inherent challenges such as: intermittency and unreliability. This is problematic for today's stable, day ahead market based power system. Fortunately, it is well established that energy storage devices can compensate for renewable sources shortcomings. This makes the integration of energy storage with the renewable energy sources, one of the biggest challenges of modern distributed generation solution. This work …
High-Dynamic-Range Foveated Near-Eye Display System, Guanjun Tan
High-Dynamic-Range Foveated Near-Eye Display System, Guanjun Tan
Electronic Theses and Dissertations
Wearable near-eye display has found widespread applications in education, gaming, entertainment, engineering, military training, and healthcare, just to name a few. However, the visual experience provided by current near-eye displays still falls short to what we can perceive in the real world. Three major challenges remain to be overcome: 1) limited dynamic range in display brightness and contrast, 2) inadequate angular resolution, and 3) vergence-accommodation conflict (VAC) issue. This dissertation is devoted to addressing these three critical issues from both display panel development and optical system design viewpoints. A high-dynamic-range (HDR) display requires both high peak brightness and excellent dark …
Room Temperature Vox Air-Bridge Bolometer Integrated With Metal-Insulator-Metal Resonant Absorbers, Seth Calhoun
Room Temperature Vox Air-Bridge Bolometer Integrated With Metal-Insulator-Metal Resonant Absorbers, Seth Calhoun
Electronic Theses and Dissertations
Spectrally-selective un-cooled micro-bolometers have many military and industrial applications for infrared sensing and imaging, e.g. target acquisition and chemical analysis. In this work, a micro-bolometer was fabricated with integrated wavelength-selective absorber based on subwavelength metal-insulator-metal (MIM) resonators. The fabricated air-bridge structure used a vanadium oxide thin film as the bolometric element. A novel aqueous deposition method of depositing vanadium oxide was investigated and compared to traditional sputtered vanadium oxide to determine achievable temperature coefficient of resistance. The MIM absorber itself was investigated as a function of the dielectric used, and the strong dependence of the resonance spectrum on dispersion was …
Role Of Tnfα Antagonists And Genetic Polymorphisms In Modulating Susceptibility To Mycobacterial Infection Among Patients With Crohn's Disease, Ahmad Qasem
Electronic Theses and Dissertations
Tumor Necrosis Factor alpha antagonists (anti-TNFα) have been extensively used for Crohn's disease (CD) treatment. Even though they may control CD symptoms initially, treatment response varies among patients, which seems to depend on single nucleotide polymorphisms (SNPs) in TNFα receptors superfamily 1A and 1B (TNFRSF1A/B). Most importantly, M. tuberculosis infection has been strongly associated with these medications, but no studies have elucidated the effects of anti-TNFα on CD associated with MAP (Mycobacterium avium subspecies paratuberculosis; a possible causative agent of CD, and closely related to M. tuberculosis). Here, we investigated the effects of recombinant inflammatory cytokines and anti-TNFα therapeutics on …
The Evaluation Of Classifier Performance On The Forensic Analysis Of Fire Debris And The Expansion Of The Substrate Database, Alyssa Allen
The Evaluation Of Classifier Performance On The Forensic Analysis Of Fire Debris And The Expansion Of The Substrate Database, Alyssa Allen
Electronic Theses and Dissertations
The current protocols in fire debris analysis rely on ignitable liquid pattern recognition and the identification of target compounds. These practices allow fire debris analysts to determine whether a sample contains or is absent of ignitable liquid residue and to classify that type of ignitable liquid based upon subjective thresholds. A statistical approach using computationally mixed datasets was devised in this research to generate an objective approach to the classification of fire debris samples and to determine error rates. Quadratic, linear, and partial least squares linear discriminant analysis (QDA, LDA, and PLS-DA) models were developed and evaluated to determine the …