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The Effects Of Supplementation Of Rumen-Protected Choline On Some Blood And Milk Metabolites In The Transition Period Of Dairy Cattle, Ni̇yazi̇ Alan, Mustafa Salman Jan 2019

The Effects Of Supplementation Of Rumen-Protected Choline On Some Blood And Milk Metabolites In The Transition Period Of Dairy Cattle, Ni̇yazi̇ Alan, Mustafa Salman

Turkish Journal of Veterinary & Animal Sciences

The aim of this study was to investigate nonesterified fatty acid (NEFA), beta-hydroxy butyric acid (BHBA), and milk urea nitrogen (MUN) profiles for dairy cows fed with rumen-protected choline (RPC) during the transition period. A total of 30 dairy cows were allocated to one control and two experimental groups (10 animals per group) and were fed from 3 weeks before calving to 21 days in milk. The control was fed only the basal diet. Treatment groups 1 and 2 were fed a basal diet containing 60 and 120 g/head/day RPC, respectively. The differences between groups were insignificant for MUN levels …


Cointegration Analysis Of Wild And Farmed Sea Bream And Sea Bass Prices In Turkey, Mehmet Saltuk Arikan, Ahmet Cumhur Akin, Mustafa Bahadir Çevri̇mli̇, Mustafa Agah Teki̇ndal Jan 2019

Cointegration Analysis Of Wild And Farmed Sea Bream And Sea Bass Prices In Turkey, Mehmet Saltuk Arikan, Ahmet Cumhur Akin, Mustafa Bahadir Çevri̇mli̇, Mustafa Agah Teki̇ndal

Turkish Journal of Veterinary & Animal Sciences

Market integration is an indicator of the extent to which different products are interrelated, and the presence of market integration between products suggests that they are substitutes. The objective of this study was to determine the market interaction between wild and farmed products of two fish species, namely sea bream and sea bass. For this purpose, the relationship between the producer price time series of cultured sea bream, wild sea bream, cultured sea bass, and wild sea bass in the period of 2009-2017 was tested using the cointegration analysis technique. It was found that the wild sea bream and sea …


Serodiagnostic Potential Of Brucella Outer Membrane And Periplasmic Proteins, Aitbay Bulashev, Orken Akibekov, Zhanbolat Suranshiyev, Bakytkali Ingirbay, Saule Eskendirova Jan 2019

Serodiagnostic Potential Of Brucella Outer Membrane And Periplasmic Proteins, Aitbay Bulashev, Orken Akibekov, Zhanbolat Suranshiyev, Bakytkali Ingirbay, Saule Eskendirova

Turkish Journal of Veterinary & Animal Sciences

The aim of this study was to evaluate the serological diagnostic potential of the Brucella recombinant outer membrane (rOMP25, rOMP31) and periplasmic proteins (rBP26, rSOD) in a comparative way using an indirect enzyme-linked immunosorbent assay (i-ELISA). Rabbit and/or mouse antibodies to Brucella whole cell and/or soluble protein preparations recognized all recombinant proteins used, which confirms the expression of target antigens in E. coli in active form. The recombinant proteins showed different antigenicity to antibodies of cattle kept on a brucellosis-affected (endemic) farm and/or a new focus of infection. Thus, the presence of anti-Brucella antibodies was confirmed by i-ELISA/rSOD in 79% …


Morphometric Analysis Of The Skulls Of Domestic Cattle (Bos Taurus L.) And Water Buffalo (Bubalus Bubalis L.) In Turkey, Ermi̇ş Özkan, Abu Bakar Siddiq, Ki̇fayet Oya Kahveci̇oğlu, Muhsi̇n Öztürk, Vedat Onar Jan 2019

Morphometric Analysis Of The Skulls Of Domestic Cattle (Bos Taurus L.) And Water Buffalo (Bubalus Bubalis L.) In Turkey, Ermi̇ş Özkan, Abu Bakar Siddiq, Ki̇fayet Oya Kahveci̇oğlu, Muhsi̇n Öztürk, Vedat Onar

Turkish Journal of Veterinary & Animal Sciences

A total of 20 domestic cattle (Bos taurus L.) and 15 water buffalo (Bubalis bubalis L.) skulls were analyzed in this study. All of the specimens belonged to female individuals. Using a total of 27 craniometric measurements from each of the skulls, 9 indices were calculated. Although there were statistically significant differences between the linear measurements of the skulls of both species, while calculating the indices with their ratios, the values of the measurements of the facial area were determinative in the craniology. Among these indices, the facial index 1 value was statistically significant (P < 0.01) in the comparison of these two species. On the other hand, while considering the orbit and foramen magnum measurements, in contrast with the transversal measurement, the height was more determinant for their index and form.


Snake Envenomation In Two Cattle: Clinical/Laboratory Aspects And Treatment Using Equine-Derived Antivenin Of Viperidae, Nuri̇ Altuğ, Cafer Tayer İşler Jan 2019

Snake Envenomation In Two Cattle: Clinical/Laboratory Aspects And Treatment Using Equine-Derived Antivenin Of Viperidae, Nuri̇ Altuğ, Cafer Tayer İşler

Turkish Journal of Veterinary & Animal Sciences

In this case report, specific antivenin treatment for Viperidae snake envenomation in two cattle was defined for the first time. The diagnosis of snake envenomation was made according to the history and clinical findings. Clinical examination revealed systemic (tachycardia, dyspnea, cyanosis, hypersalivation, ruminal hypotony) and local (swelling of the leg and head) findings depending on the location of snake bites. Laboratory analysis determined granulocytic leukocytosis, monocytosis, decreased iron binding capacity, and increased CK and LDH enzyme activities. In the specific treatment of cases, equine-derived polyvalent antivenin containing antitoxic immunoglobulins against Viperidae species was administered. Additionally, 5% dextrose, antibiotics, dexamethasone, antihistamines, …


Molecular Detection And Phylogenetic Analysis Of The Honeybee (Apis Mellifera) Sacbrood Virus In Turkey, Gülnur Kalayci, Abdurrahman Anil Çağirgan, Kemal Pekmez, Buket Özkan, Murat Kaplan Jan 2019

Molecular Detection And Phylogenetic Analysis Of The Honeybee (Apis Mellifera) Sacbrood Virus In Turkey, Gülnur Kalayci, Abdurrahman Anil Çağirgan, Kemal Pekmez, Buket Özkan, Murat Kaplan

Turkish Journal of Veterinary & Animal Sciences

Sacbrood virus (SBV) is widely distributed in honeybees. It is an infectious and contagious disease, which affects both the larvae and adult stages of honeybees (Apis mellifera). This study reports the detection of sacbrood virus in Turkey in 2017. Phylogenetic analysis based on partial sequences encoding the polyprotein gene was carried out in SBV-infected bees from four different apiaries. Phylogenetic analysis revealed noteworthy results. Although European-South American, Asian, and Korean genotypes have a maximum of 5.3% variance with each other, the variation rates between them and the Turkish genotype were 10.4%, 11.4%, and 12.5%, respectively. Sequences of Turkish isolates did …


Molecular Detection Of Anaplasma Spp. In Blood And Milk Of Dairy Cattle In The Philippines, Angelito Pangan Dela Cruz, Remil Linggatong Galay, Kristina Andrea Claveria Sandalo, Flor Marie Immanuelle Rafallo Pilapil-Amante, Tetsuya Tanaka Jan 2019

Molecular Detection Of Anaplasma Spp. In Blood And Milk Of Dairy Cattle In The Philippines, Angelito Pangan Dela Cruz, Remil Linggatong Galay, Kristina Andrea Claveria Sandalo, Flor Marie Immanuelle Rafallo Pilapil-Amante, Tetsuya Tanaka

Turkish Journal of Veterinary & Animal Sciences

Anaplasmosis has become a major concern in the cattle industry throughout the world due to its great economic impact. The causative agents, Anaplasmaspecies, are primarily transmitted by ticks, occurring intracellularly within blood cells, with some species being zoonotic. In this study, the presence of Anaplasma spp. was investigated in the blood and milk of dairy cattle in the Philippines. Blood and milk samples were collected from 98 dairy cattle from selected farms in five provinces in the southern part of Luzon Island in the Philippines. After DNA extraction, a conventional PCR for the control gene actin was performed, followed by …


Environmental Predictors For The Distribution Of The Caspian Green Lizard, Lacerta Strigata Eichwald, 1831, Along Elevational Gradients Of The Elburz Mountains In Northern Iran, Anooshe Kafash, Sohrab Ashrafi, Annemarie Ohler, Benedikt Rudolf Schmidt Jan 2019

Environmental Predictors For The Distribution Of The Caspian Green Lizard, Lacerta Strigata Eichwald, 1831, Along Elevational Gradients Of The Elburz Mountains In Northern Iran, Anooshe Kafash, Sohrab Ashrafi, Annemarie Ohler, Benedikt Rudolf Schmidt

Turkish Journal of Zoology

Within its range, the Caspian green lizard, Lacerta strigata, occurs in the Elburz Mountains (northern Iran) at elevations from below sea level to approximately 2700 m a.s.l. To determine the environmental factors affecting the distribution of this lizard, we used an ensemble approach to model the distribution of the Caspian green lizard (Lacerta strigata) in Iran using four algorithms (generalized boosted model, maximum entropy, generalized linear model, random forest). Results revealed that low-elevation habitats between the Elburz Mountains and the Caspian Sea are the most suitable habitats for the species. The normalized difference vegetation index (NDVI), annual precipitation (both with …


The Effect Of Anesthetic (2-Phenoxyethanol) Application On Some Biochemical And Hematological Parameters In Russian Sturgeon (Acipenser Gueldenstaedtii) And Siberian Sturgeon (Acipenser Baerii) During Transport, Selçuk Duman Jan 2019

The Effect Of Anesthetic (2-Phenoxyethanol) Application On Some Biochemical And Hematological Parameters In Russian Sturgeon (Acipenser Gueldenstaedtii) And Siberian Sturgeon (Acipenser Baerii) During Transport, Selçuk Duman

Turkish Journal of Veterinary & Animal Sciences

Experiments were carried out to determine the effect of 2-phenoxyethanol to reduce stress response during the transportation of Russian and Siberian sturgeons. In transportation experiment 1 (TE$_{1}$), Siberian sturgeons (687.2 ± 17.41 g) were stocked in tanks and transported for 90 min (stocking density = 65 ± 0.71 kg/$m^{3}$). Before transport, 0.5 mg/L 2-phenoxyethanol was applied to the first group (TE$_{1-A}$, n = 285) but not to the second group (TE$_{1-B}$, n = 287). In transportation experiment 2 (TE2), Russian sturgeons (1873 ± 159 g) were divided into two groups and stocked in tanks as they have a density of …


A Neglected Causative Agent In Diabetic Foot Infection: A Retrospective Evaluation Of 13 Patients With Fungal Etiology, Anil Murat Ozturk, Meltem Taşbakan, Di̇lek Yeşi̇m Meti̇n, Can Yener, Serhat Uysal, Ilgin Yildirim Şi̇mşi̇r, İlgen Ertam, Hüsnü Pullukçu, Bi̇lgi̇n Arda, Şevki̇ Çeti̇nkalp Jan 2019

A Neglected Causative Agent In Diabetic Foot Infection: A Retrospective Evaluation Of 13 Patients With Fungal Etiology, Anil Murat Ozturk, Meltem Taşbakan, Di̇lek Yeşi̇m Meti̇n, Can Yener, Serhat Uysal, Ilgin Yildirim Şi̇mşi̇r, İlgen Ertam, Hüsnü Pullukçu, Bi̇lgi̇n Arda, Şevki̇ Çeti̇nkalp

Turkish Journal of Medical Sciences

Clinicians often neglect fungal infections and do not routinely investigate deep tissue from the wound for fungal culture and sensitivity due to insufficient information in the literature. In this study, we aimed to evaluate fungal etiology of invasive fungal diabetic foot which is rarely reported in the literature.Materials and methods: The patients who were unresponsive to antibiotic therapy and those with positive fungal in bone or deep tissue culture were enrolled in the study. Detailed hospital records were retrieved for demographics and clinical features. Results: A total of 13 patients who were diagnosed with invasive fungal diabetic foot (ten females, …


Iron Supplementation Should Be Given In Breath-Holding Spells Regardless Of Anemia, Gürkan Gürbüz, Peren Perk Yücel, Turgay Çokyaman, Özge Berfu Gürbüz Jan 2019

Iron Supplementation Should Be Given In Breath-Holding Spells Regardless Of Anemia, Gürkan Gürbüz, Peren Perk Yücel, Turgay Çokyaman, Özge Berfu Gürbüz

Turkish Journal of Medical Sciences

The purpose of this retrospective study was to determine the effectiveness of oral iron therapy in breath-holding spells and evaluation of electrocardiographical changes.Materials and methods: Three hundred twelve children aged 1-48 months and diagnosed with breath-holding spells between January 2017 and April 2018 were included. Patients' laboratory findings were compared with 100 patients who had one simple febrile seizure.Results: Cyanotic breath-holding spells were diagnosed in 85.3% (n = 266) of patients, pallid spells in 5.1% (n = 16), and mixed-type spells in 9.6% (n = 30). Sleep electroencephalograms were applied for all patients, 98.2% (n = 306) of which were …


Gonadotrophin Stimulation Of Ewes That Are Not Pregnant Following Multiple Matings During The Season, Şükrü Dursun Jan 2019

Gonadotrophin Stimulation Of Ewes That Are Not Pregnant Following Multiple Matings During The Season, Şükrü Dursun

Turkish Journal of Veterinary & Animal Sciences

In this study, the aim was to obtain pregnancy following synchronization and to increase profitability in ewes that did not become pregnant during the breeding season after at least 3 matings. Nonpregnant Middle Anatolian Merino ewes (n = 117) were given a progesterone sponge for 9 days. At the time of sponge removal, the ewes received 250 IU pregnant mare serum gonadotropin (PMSG) + 125 µg prostaglandin F2α (PGF2α). Two days later, they were injected with either human chorionic gonadotropin (hCG) (Group I, n = 48) or gonadotropin-releasing hormone (GnRH) (Group II, n = 43), or remained as a control …


Chemical Composition And In Vitro Rumen Fermentation Of Ensiled Sugar Industry Coproducts, Zohreh Zarnegar, Seyed Hadi Ebrahimi, Abbas Ali Naserian, Reza Valizadeh Jan 2019

Chemical Composition And In Vitro Rumen Fermentation Of Ensiled Sugar Industry Coproducts, Zohreh Zarnegar, Seyed Hadi Ebrahimi, Abbas Ali Naserian, Reza Valizadeh

Turkish Journal of Veterinary & Animal Sciences

he current study aims to compare sugar beet leaves (SBLs) ensiled with sugar beet pulp (SBP), sugarcane molasses (SM), or rock candy juice (RCJ) using an in vitro gas production technique. Treatments in the first group included 10% SBP (control 1) and control 1 plus 5% SM or RCJ. In the second group, there were 3 treatments, including 20% SBP (control 2) and control 2 plus 10% SM or RCJ. The silages with no added soluble carbohydrate (SC) sources had significantly higher (P < 0.001) pH, buffer value index, and ammonia nitrogen values than the other treatments. However, there was no significant difference between RCJ and SM in their effect on these variables. Adding both levels of SC sources caused an increase in dry matter digestibility compared to those that only included SBL and SBP (P < 0.001). Maximal and rate of gas production from slowly fermentable fraction (a$_{2}$) were significantly greater when the substrate contained 85%, 10%, and 5% SBL, SBP, and SC sources, respectively. Using dried SBP and SC sources for the preservation of fresh SBL is recommended; however, with higher levels of SC, the silage may be at risk of spoilage, and it must be less exposed to air.


Combination Of Amylopectin And Chromium Form Improves Energy Storage And Reduces Muscle Fatigue In Rats During Exhaustive Exercise, Mehmet Irmak, Nurhan Şahi̇n, Cemal Orhan, Mehmet Tuzcu, Patrick Brice Defo Deeh, Meltem Yardim, Armağan Hayirli, James Komorowski, Kazi̇m Şahi̇n Jan 2019

Combination Of Amylopectin And Chromium Form Improves Energy Storage And Reduces Muscle Fatigue In Rats During Exhaustive Exercise, Mehmet Irmak, Nurhan Şahi̇n, Cemal Orhan, Mehmet Tuzcu, Patrick Brice Defo Deeh, Meltem Yardim, Armağan Hayirli, James Komorowski, Kazi̇m Şahi̇n

Turkish Journal of Veterinary & Animal Sciences

This study evaluated the effects of amylopectin (A) and chromium (Cr) forms alone or in combination on energy storage, muscle fatigue-related biochemical markers, and expression of peroxisome proliferator-activated receptors (PPAR-γ) and glucose transporter-2 and -4 (GLUT-2 and GLUT-4) in rats during exhaustive exercise. Thirty-five male Wistar rats were divided into 5 groups (n = 7) as follows: 1) exhaustive exercise (E); 2) E+A; 3) E+A+chromium picolinate (CrPic); 4) E+A+chromium histidinate (CrHis), and 5) E+A+CrPic+CrHis. Rats received 0.0316 g of amylopectin and 11.06 µg of elemental Cr kg$^{-1}$ body weight given as CrPic and CrHis per day. The mean duration of …


Determination Of Growth And Toxin Production Potential Of Staphylococcus Aureus And Clostridium Perfringens During Döner Production Process, Funda Yilmaz Eker, Kami̇l Bostan Jan 2019

Determination Of Growth And Toxin Production Potential Of Staphylococcus Aureus And Clostridium Perfringens During Döner Production Process, Funda Yilmaz Eker, Kami̇l Bostan

Turkish Journal of Veterinary & Animal Sciences

Döner is a traditional meat meal that is commonly consumed in Turkey. Although it receives heat treatment during processing, some microorganisms including pathogens may remain alive. Therefore, this study was carried out to determine the changes in the number of microorganisms (total aerobic mesophilic bacteria, Enterobacteriaceae, Escherichia coli, aerobic mesophilic spore-forming bacteria, Staphylococcus-Micrococcus spp.) and survival potential of some pathogenic bacteria (Staphylococcus aureus and Clostridium perfringens) during the cooking period. Experimentally prepared döner kebabs were cooked continuously or intermittently. This process resulted in a reduction of microorganisms depending on the species and the use of low quality raw materials, and …


Loop-Mediated Isothermal Amplification In The Field: Reality Beyond The Potentiality, Donato Antonio Raele, Nicola Pugliese, Domenico Galante, Maria Assunta Cafiero Jan 2019

Loop-Mediated Isothermal Amplification In The Field: Reality Beyond The Potentiality, Donato Antonio Raele, Nicola Pugliese, Domenico Galante, Maria Assunta Cafiero

Turkish Journal of Veterinary & Animal Sciences

No abstract provided.


The Investigation Of Viability And Body Measurements For Water Buffalo Calves, Koray Çeli̇keloğlu, Serdar Koçak, Meti̇n Erdoğan, Zehra Bozkurt, Mustafa Tekerli̇ Jan 2019

The Investigation Of Viability And Body Measurements For Water Buffalo Calves, Koray Çeli̇keloğlu, Serdar Koçak, Meti̇n Erdoğan, Zehra Bozkurt, Mustafa Tekerli̇

Turkish Journal of Veterinary & Animal Sciences

The viability and body measurements of calves raised in the Livestock Research Center of Afyon Kocatepe University between 2008 and 2011 were investigated. The research was conducted on 188 calves of buffalo cows brought from different regions of Turkey. The viability of buffalo calves at 1, 3, 6, and 12 months of age was 0.95, 0.90, 0.90, and 0.89, respectively. Live weights, height at withers, rump height, body length, chest depth, chest width, rump width, and chest and cannon-bone circumferences were 30.41 kg and 72.37, 74.21, 56.52, 26.34, 15.80, 17.00, 73.13, and 12.88 cm at birth; 118.47 kg and 97.12, …


First Evidence Of Holocrine Secretory Mechanism In Granular Ducts Inmouse Mandibular Gland, Bianca Matosz, Flavia Ruxanda, Cristian Ratiu, Vlad Luca, Vasile Rus, Viorel Miclaus Jan 2019

First Evidence Of Holocrine Secretory Mechanism In Granular Ducts Inmouse Mandibular Gland, Bianca Matosz, Flavia Ruxanda, Cristian Ratiu, Vlad Luca, Vasile Rus, Viorel Miclaus

Turkish Journal of Veterinary & Animal Sciences

The mouse mandibular gland contains granular ducts, which possess a particular structure. They are termed granular ducts because they contain numerous granules in the cells lining them, having a secretory activity. We aimed to assess the secretory mechanism in granular ducts. Consequently, we harvested the mandibular glands from five male mice and processed them for histological investigations. A large number of cells appeared intact, without obvious distortions or disruptions in the cell membrane. Based on the morphological aspect, these cells either transferred the secretory product through exocytosis or were in "standby" mode. There were cells that presented prominent bulges of …


Biodiversity And Characterization Of Gram-Positive, Catalase-Positive Cocci Isolated From Pastırma Produced Under Different Curing Processes, Kübra Fettahoğlu, Kübra Çi̇nar, Mükerrem Kaya, Güzi̇n Kaban Jan 2019

Biodiversity And Characterization Of Gram-Positive, Catalase-Positive Cocci Isolated From Pastırma Produced Under Different Curing Processes, Kübra Fettahoğlu, Kübra Çi̇nar, Mükerrem Kaya, Güzi̇n Kaban

Turkish Journal of Veterinary & Animal Sciences

The aim of this study was to determine the effects of different curing temperatures (4 °C or 10 °C) and agents (KNO$_{3}$ or NaNO$_{2}$) on microbiological and physicochemical properties of pastırma and diversity of gram-positive, catalase-positive cocci (GCC$^{+}$) and also to investigate some technological properties of the strains. Four different groups of pastırma were produced applying different curing temperatures and agents. After production, $GCC^{+}$ isolated from pastırma were subjected to phenotypic and genotypic (16S rRNA sequencing) identification. Genotypically characterized strains were evaluated for their technological properties. In all groups, a$_{w}$ and pH were observed to be under 0.90 and over …


Natural Diterpenoid Alysine A Isolated From Teucrium Alyssifolium Exerts Antidiabetic Effect Via Enhanced Glucose Uptake And Suppressed Glucose Absorption, Alaatti̇n Şen, Buket Ayar, Anil Yilmaz, Özden Özgün Acar, Gurbet Çeli̇k Turgut, Gülaçti Topçu Jan 2019

Natural Diterpenoid Alysine A Isolated From Teucrium Alyssifolium Exerts Antidiabetic Effect Via Enhanced Glucose Uptake And Suppressed Glucose Absorption, Alaatti̇n Şen, Buket Ayar, Anil Yilmaz, Özden Özgün Acar, Gurbet Çeli̇k Turgut, Gülaçti Topçu

Turkish Journal of Chemistry

Teucrium species have been used in folk medicine as antidiabetic, antiinflammatory, antiulcer, and antibacterial agents. We have explored in vitro antidiabetic impacts of 2 natural diterpenoids, alysine A and alysine B, isolated from Teucrium alyssifolium. The lactate dehydrogenase (LDH) cytotoxicity assay, glucose uptake test, glucose utilization (glycogen content) test, glucose transport test, glucose absorption ($\alpha $-glucosidase activity) test, insulin secretion test, RNA isolation and cDNA synthesis assay, qPCR quantification assays, and statistical analyses were carried out in the present study. Alysine A exerted the following effects at non-cytotoxic doses: . Enhanced the glucose uptake, as much as the insulin in …


Investigation Of The Effects Of Some Water-Soluble Vitamins On Glutathione Reductase Enzyme Purified From Bovine Liver, Mehmet Riza Kivanç, Vedat Türkoğlu Jan 2019

Investigation Of The Effects Of Some Water-Soluble Vitamins On Glutathione Reductase Enzyme Purified From Bovine Liver, Mehmet Riza Kivanç, Vedat Türkoğlu

Turkish Journal of Chemistry

Glutathione reductase (GR, EC 1.8.1.7) is an antioxidant enzyme and is involved in the reducing reaction of oxidized glutathione. Glutathione and reduced glutathione are very crucial for micro- and macroorganisms because of their barrier function against radicals. Therefore, the aim of this article was to purify GR and evaluate the relationship between purified GR and vitamins. GR was purified from bovine liver using 2',5'-ADP Sepharose 4B column materials. To check the purity of each subunit of the enzyme, SDS-PAGE electrophoresis was performed and each one was 55 kDa. Afterwards, specific activity and purified ratio for the enzyme were calculated as …


Evaluation Of The Enrichment And Amplification Effect Of Pentachlorobenzene With Lower Bioconcentration In The Food Chain Before And After Modification, Ruihao Sun, Meijin Du, Yu Li Jan 2019

Evaluation Of The Enrichment And Amplification Effect Of Pentachlorobenzene With Lower Bioconcentration In The Food Chain Before And After Modification, Ruihao Sun, Meijin Du, Yu Li

Turkish Journal of Chemistry

In this paper, in order to construct a 3D quantitative structure--activity relationship (QSAR) model with the chlorobenzene (CB) molecular structure parameter as an independent variable and the octanol-water partition coefficient ($K_{OW})$ as a dependent variable, 9 kinds of CB molecules were used as training sets and 3 kinds of CB molecules were used as test sets. We adopted the QSAR module in the Sybyl-X2.0 software from the Tripos Corporation (USA). The molecular modification of the pentachlorobenzene molecule with low bioconcentration was carried out by combining a three-dimensional contour map and fractional factorial design. The results showed that the toxicity, migration, …


An Evaluation Of The Adsorption Dynamics Of Phosphate Ions Onto Fe(Ii)-Montmorillonites, Dawei Qin, Shuhua Chang, Min Qiao, Xiaotong Yuan, Wei Liu, Gang Liu Jan 2019

An Evaluation Of The Adsorption Dynamics Of Phosphate Ions Onto Fe(Ii)-Montmorillonites, Dawei Qin, Shuhua Chang, Min Qiao, Xiaotong Yuan, Wei Liu, Gang Liu

Turkish Journal of Chemistry

Fe(II)-montmorillonites (Fe(II)-MMTs) were prepared by mixing solutions of Fe(II) and montmorillonite at pH 3.5. Two different Fe(II)-MMTs were prepared and the ferrous iron contents were 40 mg/L and 80 mg/L. All samples were characterized by XRD, FT-IR, TGA, DSC, and nitrogen adsorption. By nitrogen adsorption, the pore size can be obtained in the pore diameter curve with average pore widths of 6.67 nm, 9.96 nm, and 17.07 nm, respectively. The removal rate of phosphate increased rapidly during the first 40 min, in which Fe(II)-MMT (1) and Fe(II)-MMT (2) were stronger adsorption systems than MMT. The maximum adsorption was 48.38 mg/g …


Synthesis, Characterization, And Kinetic Studies Of Multifunctionalized Mesoporous Silica For Adsorption Of Zinc, Ali̇me Çitak Jan 2019

Synthesis, Characterization, And Kinetic Studies Of Multifunctionalized Mesoporous Silica For Adsorption Of Zinc, Ali̇me Çitak

Turkish Journal of Chemistry

The aim of this study is to evaluate the utilization of bifunctional mesoporous silica with a platinum and propylsulfonic acid group (Pt/SBA15-PrSO$_{3}$H) as an adsorbent for the removal of Zn(II) ions from aqueous solutions. The SBA15-functionalized organosulfonic acid material was synthesized with a one-step cocondensation synthesis route. The second step was Pt loading during reduction and deposition into the aqueous suspension of the bifunctional mesoporous silica synthesized by an aqueous solution of formaldehyde as the reducing agent. The propylsulfonic acid and platinum functionalized mesoporous silica were characterized by BET, thermogravimetric analysis, and X-ray diffraction methods. The adsorption properties and thermodynamic …


The Protective Effect Of N-Acetylcysteine Amide Against Paraquat-Induced Neurotoxicity, Burhan Ateş, Ni̇gar Vardi, Hakan Parlakpinar, Merve Gökşi̇n Karaaslan, İsmet Yilmaz, Nuran Ercal Jan 2019

The Protective Effect Of N-Acetylcysteine Amide Against Paraquat-Induced Neurotoxicity, Burhan Ateş, Ni̇gar Vardi, Hakan Parlakpinar, Merve Gökşi̇n Karaaslan, İsmet Yilmaz, Nuran Ercal

Turkish Journal of Chemistry

N-acetylcysteine amide (NACA) is a new antioxidant molecule with powerful radical scavenging properties. The aim of this study was to investigate neuroprotective effects of NACA against paraquat (PQ) toxicity in the midbrains of rats by using motor coordination tests and biochemical and histological analysis. Thirty adult Wistar albino rats were divided into three groups: Group 1: control (n = 10), Group 2: PQ (10 mg/kg) (n = 10), and Group 3: PQ (10 mg/kg) $+$ NACA (100 mg/kg) (n = 10). NACA was administrated intraperitoneally 30 min before PQ injection. Performance was measured for a period of 28 days. The …


Synthesis, Crystal Structure, And Characterization Of Two Heterometallic Transition Metal Citrate Complexes [M $=$ Co(Ii) And Cd(Ii)], Zeki̇ Kartal, Onur Şahi̇n, Abdülkeri̇m Yavuz Jan 2019

Synthesis, Crystal Structure, And Characterization Of Two Heterometallic Transition Metal Citrate Complexes [M $=$ Co(Ii) And Cd(Ii)], Zeki̇ Kartal, Onur Şahi̇n, Abdülkeri̇m Yavuz

Turkish Journal of Chemistry

In this study, two heterometallic transition metal complexes with the formulas [CoK$_{4}(\mu _{10}$-C$_{6}$H$_{5}$O$_{7})_{2}$]$_{n}$ and [CdK($\mu _{8}$-C$_{6}$H$_{5}$O$_{7})(\mu $-H$_{2}$O)(H$_{2}$O)]$_{n}$ were synthesized as crystalline compounds. The structures of\textbf{ }these crystalline metal complexes were characterized by their spectral analyses (FT-IR, FT-Raman, thermal analysis, magnetic properties, and single-crystal X-ray diffraction techniques). According to the spectral data of the new metal complexes obtained, both metal complexes are in the monoclinic crystal system and in the P2$_{1}$/c and P2$_{1}$ space groups, respectively. The asymmetric unit of the metal complex [CoK$_{4}(\mu _{10}$-C$_{6}$H$_{5}$O$_{7})_{2}$]$_{n}$ contains one Co(II) ion, two potassium cations, and one (C$_{6}$H$_{5}$O$_{7})$ citrate ligand, whereas that of the …


Protonation Behavior Of Dextran Amino Acid Esters, Konrad Hotzel, Lidjia Fras Zemljic, Matej Bracic, Thomas Heinze Jan 2019

Protonation Behavior Of Dextran Amino Acid Esters, Konrad Hotzel, Lidjia Fras Zemljic, Matej Bracic, Thomas Heinze

Turkish Journal of Chemistry

Dextran esters of different amino acids (glycine, $\beta $-alanine, L-ornithine, L-lysine) are investigated regarding their pK$_{a}$ values by potentiometric titration. The pK$_{a}$ values of the dextran derivatives are generally dependent on the position of the amino group in relation to the ester group, i.e. the nearer they are located in the molecule, the lower the resulting pK$_{a}$ values are, L-ornithine ester being the exception. An influence of the polymer backbone is ruled out. Stability against hydrolysis at different pH values and over longer periods at constant pH value is measured by potentiometric and polyelectrolyte titration. The $\beta $-alanine ester shows …


Anticancer And Antiangiogenesis Activities Of Novel Synthesized 2-Substituted Benzimidazoles Molecules, Adem Güner, Eli̇fsu Polatli, Tamer Akkan, Hakan Bektaş, Canan Albay Jan 2019

Anticancer And Antiangiogenesis Activities Of Novel Synthesized 2-Substituted Benzimidazoles Molecules, Adem Güner, Eli̇fsu Polatli, Tamer Akkan, Hakan Bektaş, Canan Albay

Turkish Journal of Chemistry

In this study, novel 2-substituted benzimidazoles molecules having triazole, thiadiazole, and oxadiazole rings were synthesized and were evaluated by anticancer, antioxidant/oxidant status, genotoxicity, and antiangiogenesis assays. Anticancer activity of the compounds was determined by MTT (0.5, 5, and 50 $\mu $g/mL) and lactate dehydrogenase (LDH) release assays against human prostate and breast cancer cells. Oxidative status of cells was elicited by total oxidative stress and total antioxidant capacity methods. Chick chorioallantoic membrane assay was used to evaluate the antiangiogenic activity. Genotoxicity was evaluated by the sister chromatid exchange (SCE) and micronucleus (MN) tests in lymphocyte cultured human blood. Our results …


Detection Of Lard Contamination In Five Different Edible Oils By Ft-Ir Spectroscopy Using A Partial Least Squares Calibration Model, Fazeelah Munir, Syed Ghulam Musharraf, Syed Tufail Hussain Sherazi, Muhammad Imran Malik, Muhmmad Iqbal Bhanger Jan 2019

Detection Of Lard Contamination In Five Different Edible Oils By Ft-Ir Spectroscopy Using A Partial Least Squares Calibration Model, Fazeelah Munir, Syed Ghulam Musharraf, Syed Tufail Hussain Sherazi, Muhammad Imran Malik, Muhmmad Iqbal Bhanger

Turkish Journal of Chemistry

Lard is defined as animal fat acquired from the adipose tissue of pigs and is not permitted for human consumption or external use by certain religions such as Islam and Judaism. Due to its low-cost availability for commercial use, it is often mixed with other vegetable oils mistakenly or deliberately and causes loss of consumer trust; hence, its detection in food products is essential. Consumers tend to know the authenticity of commercially available edible oils. However, edible oils are subjected to adulteration risks with lard, which breaches consumer rights. In the present study, we designed a transmission Fourier transform infrared …


Synthesis Of Smz Derivatives And Investigation Of Effects On Germination, Root, And Plant Growth Of \Textit{Arabidopsis Thaliana} L., Tuğba Güngör, Ferah Cömert Önder, Fati̇h Sezer, Aslihan Özbi̇len, Kemal Meli̇h Taşkin, Mehmet Ay Jan 2019

Synthesis Of Smz Derivatives And Investigation Of Effects On Germination, Root, And Plant Growth Of \Textit{Arabidopsis Thaliana} L., Tuğba Güngör, Ferah Cömert Önder, Fati̇h Sezer, Aslihan Özbi̇len, Kemal Meli̇h Taşkin, Mehmet Ay

Turkish Journal of Chemistry

A series of sulfonamide derivatives were synthesized by reactions with various functional groups containing benzenesulfonyl chlorides and aniline derivatives under different substitution reaction conditions. The structures of SMZ derivatives were confirmed with melting point, FT-IR, $^{1}$H NMR, $^{13}$C NMR, and LC-MS/MS techniques. In order to investigate the cytotoxic effects of these derivatives, we used a model plant species. The synthesized compounds (S1-S5) and sulfamethazine (SMZ) as a positive control were applied to Arabidopsis thaliana seeds. Our results indicated that S3 and S4 induced shorter roots and lower wet weight in plants. Plants treated with S2 and S5 showed no growth …