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Articles 241 - 270 of 29124
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Hold Paramount The Health, Safety, And Welfare Of The Public And The Planet, Daniel B. Oerther
Hold Paramount The Health, Safety, And Welfare Of The Public And The Planet, Daniel B. Oerther
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
No abstract provided.
Tip Penetration Test For Rapid In-Line Assessment Of Static Yield Stress During 3d Concrete Printing Process, Ali Fasihi, Nicolas A. Libre
Tip Penetration Test For Rapid In-Line Assessment Of Static Yield Stress During 3d Concrete Printing Process, Ali Fasihi, Nicolas A. Libre
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The static yield stress of printable cementitious materials is a critical parameter governing the shape stability and buildability of 3D printed concrete structures. Among various testing techniques, the penetration test has emerged as a promising method for in-situ measurement of static yield stress during printing process. However, the applicability of the penetration test for in-line monitoring of static yield stress remains limited due to the necessity for substantial material thickness. To address this challenge, this study proposes a novel tip penetration test, which enables static yield stress determination without the requirement for full cone submergence, thereby facilitating assessment of thin …
Rheological And Micro Properties Of High-Viscosity Binder-Incorporated Polyphosphoric Acid And Rock Asphalt, Feng Ma, Xinye Jiang, Zhen Fu, Chongxin Zhu, Jenny Liu, Ke Shi, Yalu Wen, Yao Zhang
Rheological And Micro Properties Of High-Viscosity Binder-Incorporated Polyphosphoric Acid And Rock Asphalt, Feng Ma, Xinye Jiang, Zhen Fu, Chongxin Zhu, Jenny Liu, Ke Shi, Yalu Wen, Yao Zhang
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
To enhance the performance of high-viscosity modified asphalt (HVMA), polyphosphoric acid (PPA) and North American rock asphalt (NA-RA) were incorporated into styrene-butadiene-styrene (SBS)/crumb rubber (CR) composite modified asphalt, resulting in two distinct types of HVMA. The two HVMA types were evaluated at various dosages using a dynamic shear rheometer (DSR), bending beam rheometer (BBR), fluorescence microscope (FM), and Fourier infrared spectroscopy (FT-IR) tests. These tests provided both macroscopic and microscopic insights into their properties. The findings indicated that both PPA and NA-RA modify the asphalt's internal structure, enhancing its temperature resistance. PPA primarily improved high-Temperature performance, while NA-RA enhanced low-Temperature …
A Rapid Field Moisture Measurement Unit For Compaction Acceptance Of Unbound Materials, Chuanjun Liu, Xiong Zhang, Jenny Liu
A Rapid Field Moisture Measurement Unit For Compaction Acceptance Of Unbound Materials, Chuanjun Liu, Xiong Zhang, Jenny Liu
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The moisture content (MC) was a critical parameter that needed to be monitored in geomaterial compaction. Nuclear density gauges (NDGs) had been the practice in MC and density measurement for decades but had become less desirable due to cost, regulatory, and safety concerns. Meanwhile, lightweight deflectometers (LWDs), proposed as an alternative to NDGs, did not have a function of MC measurement. This study aimed to identify a rapid field moisture analyzer to work with LWDs for evaluating the compaction acceptance of unbound materials in situ. The study started with evaluating the effectiveness and practicability of two existing moisture analyzers recommended …
Influence Of Wicking Geotextile Installation On Moisture Migration In Silt Under Rainfall Infiltration, Yipeng Guo, Dahao Zou, Min Hu, Xiong Zhang, Fang Xu, Yongjie Zhang, Jiejing Chen
Influence Of Wicking Geotextile Installation On Moisture Migration In Silt Under Rainfall Infiltration, Yipeng Guo, Dahao Zou, Min Hu, Xiong Zhang, Fang Xu, Yongjie Zhang, Jiejing Chen
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Silt is widely used in subgrade construction in the middle and lower reaches of the Yellow River in China due to limited availability of high-quality fill. However, its high moisture sensitivity and low strength often lead to pumping, settlement, and deformation. This study investigates the hydraulic performance of a wicking geotextile in silt under simulated rainfall infiltration using one-dimensional soil column experiments. Three installation configurations were evaluated: (i) a control sample (CS) without geotextile, (ii) an embedded sample (ES) with the geotextile fully installed as a capillary barrier, and (iii) a surface-exposed sample (SES) with the geotextile extended to the …
Generative Artificial Intelligence In Aircraft Design Optimization, Xiaosong Du
Generative Artificial Intelligence In Aircraft Design Optimization, Xiaosong Du
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Aircraft design optimization is essential for improving aircraft performance (such as reduced fuel consumption and lowered noise), which leads to more efficient, sustainable, and affordable aircraft. Conventional aircraft design adopts physics-based simulation models, but iteratively evaluating simulation models is computationally intensive, or even practically impossible. Meanwhile, artificial intelligence (AI) emerges as a revolutionary game changer in the modern engineering industry, including aircraft design optimization. Generative AI (genAI), one of the groundbreaking AI methods, has been advancing aircraft design optimization from various aspects, including intelligent parameterization, predictive modeling, training facilitation, and constraints handling. However, there is a lack of a review …
Hybrid Sensing For Near-Earth Space Domain Awareness: Leveraging Space-Based Assets For Augmenting Optical Ground Observations, Smriti Nandan Paul, Hang Woon Lee
Hybrid Sensing For Near-Earth Space Domain Awareness: Leveraging Space-Based Assets For Augmenting Optical Ground Observations, Smriti Nandan Paul, Hang Woon Lee
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Because of recent advancements in space technologies, easier and more economical access to space, and an increase in commercial interests, the near-Earth space environment has witnessed an exploding number of objects being put into orbit. In particular, the low Earth orbit (LEO) region is at an increased risk of orbital collisions from large satellite constellation projects. Thus, monitoring LEO objects for space domain awareness and space traffic management has become increasingly imperative. In this paper, we use the concept of limited-CDF (cumulative distribution function) surface and mutual information for designing sensor tasking algorithms focusing on regular observation of known catalog …
Modeling And Characterizing The Electron Backscatter In A Cylindrical Anode-Based Distributed X-Ray Source, Jordan Fox, Seth Kilby, Hyoung Koo Lee, Ayodeji Alajo, Ashish Avachat
Modeling And Characterizing The Electron Backscatter In A Cylindrical Anode-Based Distributed X-Ray Source, Jordan Fox, Seth Kilby, Hyoung Koo Lee, Ayodeji Alajo, Ashish Avachat
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
Upcoming advancements in computed tomography architectures warrants the investigation of new X-ray source designs and the impacts that electron backscatter can have on these designs. One such design being investigated is a distributed, cylindrical anode-based X-ray source. For such a distributed X-ray source, we developed a modeling pipeline for simulating electron optics and transport to characterize the quality of the primary X-ray beam and the electron backscatter behavior. We report our results on the energy distributions of the bremsstrahlung spectra; electron backscatter ratio; and spatial, temporal, and energy distributions of backscattered electrons that return to the anode.
Full Core Fuel Burnup Assessment Of The Itu Triga Mark Ii Research Reactor Using Gamma Spectroscopy, Z. Boduroglu, A. Kaya, O. Erbay, I. A. Reyhancan, M. S. Kiziltas, T. Akyurek
Full Core Fuel Burnup Assessment Of The Itu Triga Mark Ii Research Reactor Using Gamma Spectroscopy, Z. Boduroglu, A. Kaya, O. Erbay, I. A. Reyhancan, M. S. Kiziltas, T. Akyurek
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
This study investigates the burnup distribution of fuel elements in the ITU TRIGA Mark II research reactor core through gamma spectroscopy using137Cs as a burnup indicator. Non-Destructive Assay (NDA) techniques were employed to analyze fuel depletion, utilizing a specialized fuel investigation system installed above the reactor pool. The results indicate that the highest burnup values, exceeding 5 %, were concentrated in the inner core rings (B and C) due to intense neutron flux exposure, while the outer rings (D, E, F) exhibited lower burnup levels. To address this asymmetric distribution, a proposed fuel reshuffling strategy was analyzed, aiming …
Nondestructive Burnup Evaluation And Gamma Spectroscopy Analysis Of Spent Fuel Elements In The Itu Triga Mark Ii Research Reactor, A. Kaya, O. Erbay, Z. Boduroglu, I. A. Reyhancan, M. S. Kiziltas, T. Akyurek
Nondestructive Burnup Evaluation And Gamma Spectroscopy Analysis Of Spent Fuel Elements In The Itu Triga Mark Ii Research Reactor, A. Kaya, O. Erbay, Z. Boduroglu, I. A. Reyhancan, M. S. Kiziltas, T. Akyurek
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
This study presents a comprehensive burnup analysis of all fuel elements in the ITU TRIGA Mark II research reactor core using non-destructive assay (NDA) techniques based on gamma spectroscopy. Two distinct fuel inspection systems were employed to measure the gamma activity, with137Cs used as the primary burnup indicator due to its strong correlation with fuel depletion. The results show a clear burnup pattern, with higher values in the inner core rings that gradually decreases toward the outer rings. This asymmetric burnup distribution underscores the need for reactor core reconfiguration, for which an optimized layout is proposed. Additionally, gamma …
Integrated Computational And Experimental Investigation Of Groups V And Vi Metals In (M,Hf,Ti,Zr)B2-(M,Hf,Ti,Zr)C Ceramics, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Integrated Computational And Experimental Investigation Of Groups V And Vi Metals In (M,Hf,Ti,Zr)B2-(M,Hf,Ti,Zr)C Ceramics, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Materials Science and Engineering Faculty Research & Creative Works
Dual-phase compositionally complex ultra-high temperature ceramics were formulated by incorporating different Groups V and VI metals such as V, Nb, Ta, Cr, Mo, or W into a base composition containing the Group IV elements, Hf, Ti, and Zr. Metal distribution was predicted using first-principles-based thermodynamics simulations and compared with experimental results. Moreover, phase stability, microstructure, and mechanical properties were evaluated for all of the ceramics. Compositions containing Cr, V, Nb, or Ta formed dual-phase ceramics containing only one boride and one carbide phase, while compositions containing Mo or W developed an additional third phase. The experimental metal distribution trends generally …
Co-Calcination Of Limestone And Clay Enhances The Performance Of Limestone Calcined Clay Cement (Lc3), Oluwadamilare Charles Adesina, Sahil Surehali, Avinaya Tripathi, Kayla Lauren Lee, Bryan K. Aylas-Paredes, Aditya Kumar, Narayanan Neithalath
Co-Calcination Of Limestone And Clay Enhances The Performance Of Limestone Calcined Clay Cement (Lc3), Oluwadamilare Charles Adesina, Sahil Surehali, Avinaya Tripathi, Kayla Lauren Lee, Bryan K. Aylas-Paredes, Aditya Kumar, Narayanan Neithalath
Materials Science and Engineering Faculty Research & Creative Works
Limestone-calcined clay cements (LC3) reduce the environmental impact of cement production and accelerate the industry transition toward carbon neutrality. While conventional LC3 with 50% clinker replacement (LC3-50) demonstrate long-term performance comparable to ordinary Portland cement (OPC) in concrete, early-age performance is generally compromised. This study explores for the first time, joint thermal treatment—that is, co-calcination—of limestone (LS) and bulk kaolinitic clay in mass ratios of 1:1 to 1:4 under a calcination regime specifically designed to ensure activation of the clay mineral. The co-calcination converts a small fraction of LS to metastable CaO, thus providing an …
Inclusion Engineering Through Deoxidation Practice Optimization For Enhanced Mechanical Properties Of Cast Cr-Ni-Mo Steel, Kingsley T. Amatanweze, Viraj A. Athavale, Simon Lekakh, Ronald J. O'Malley, Laura N. Bartlett
Inclusion Engineering Through Deoxidation Practice Optimization For Enhanced Mechanical Properties Of Cast Cr-Ni-Mo Steel, Kingsley T. Amatanweze, Viraj A. Athavale, Simon Lekakh, Ronald J. O'Malley, Laura N. Bartlett
Materials Science and Engineering Faculty Research & Creative Works
Deoxidation is an integral part of steelmaking, as it determines steel castability, cleanliness, and porosity levels of the final product. Steel quality is critical to its performance and can be sabotaged by impurities such as non-metallic inclusions and porosity. This study investigates the effects of four distinct deoxidation practices, using Al, Al-Ca, Zr-Ca, and Mn-Si respectively, on tensile strength, tensile ductility and impact toughness of a Cr-Ni-Mo steel. These deoxidation reactions were modeled on a commercially available thermodynamic software and possible inclusion product phases were predicted. The casting samples were studied on a scanning electron microscope (SEM) utilizing energy dispersive …
Post-Calcium Treatment Evolution Of Alumina (Al2o3) Inclusions Morphology, Naziru I. Fuseini, Ronald J. O'Malley, Todd P. Sander, Jeffrey D. Smith, Haiming Wen, Laura N. Bartlett
Post-Calcium Treatment Evolution Of Alumina (Al2o3) Inclusions Morphology, Naziru I. Fuseini, Ronald J. O'Malley, Todd P. Sander, Jeffrey D. Smith, Haiming Wen, Laura N. Bartlett
Materials Science and Engineering Faculty Research & Creative Works
The post-calcium morphological evolution of Al2O3 inclusions formed under high-oxygen supersaturation (~1000 ppm) was investigated through time-resolved sampling and quenching of aluminum-killed, calcium-treated steel. SEM-EDS analysis revealed the formation of angular two-phase CaO·Al2O3–CaS inclusions within 1 minute, gradually transforming into spherical liquid 12CaO·7Al2O3 and CaO·Al2O3 with a thin CaS layer around it. The 3D morphology of the CaS phase of the complex CaO·Al2O3–CaS inclusions observed at 1 minute appeared as a cone-cap attached to the partially modified CaO·Al2O3. This …
Thermodynamic Analysis Of Metal Segregation In Two Metal Boride-Carbide Ceramics Containing V With Cr, Hf, Ti, Or Zr, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Thermodynamic Analysis Of Metal Segregation In Two Metal Boride-Carbide Ceramics Containing V With Cr, Hf, Ti, Or Zr, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Materials Science and Engineering Faculty Research & Creative Works
Dual-phase carbide-boride ceramics in different vanadium-Me (Me = Cr, Hf, Ti, and Zr) binary systems were synthesized by boro/carbothermal reduction under stoichiometric and carbon-deficient conditions and densified by spark plasma sintering. Thermodynamic analysis was used to evaluate the influence of composition on the phase stability and metal segregation between phases, along with the resulting effects on microstructure and hardness. Pairing vanadium with Group IV elements (Hf, Ti, and Zr) consistently formed one boride and one carbide phase, while the Cr-V system formed a monoboride phase and a carbon-deficient carbide. Metal segregation trends depended on composition. Vanadium preferentially segregated to the …
Zirconium And Hafnium Interdiffusion Study In Zrb2–Hfb2 System, Yue Zhou, Ana C. Feltrin, William G. Fahrenholtz, Gregory E. Hilmas
Zirconium And Hafnium Interdiffusion Study In Zrb2–Hfb2 System, Yue Zhou, Ana C. Feltrin, William G. Fahrenholtz, Gregory E. Hilmas
Materials Science and Engineering Faculty Research & Creative Works
Interdiffusion of Zr and Hf in the diboride system was investigated. High-purity zirconium diboride (ZrB2) and hafnium diboride (HfB2) were prepared by a combination of boro-/carbothermal reduction synthesis and densification by spark plasma sintering. The bulk ceramics had relative densities of 99.3% for ZrB2 and 99.7% for HfB2, and both ceramics were phase-pure by x-ray diffraction analysis. Diffusion couples of ZrB2 and HfB2 were annealed at temperatures ranging from 2000°C to 2200°C for times from 4 to 12 h. Zr and Hf elemental concentration profiles were measured using energy dispersive spectroscopy …
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Chemical and Biochemical Engineering Faculty Research & Creative Works
Soil stabilization is crucial in geotechnical engineering, yet conventional methods are often time-consuming, resource-intensive, and environmentally unsustainable. Despite growing interest in Machine Learning (ML) and optimization tools for mix design, few studies integrate these methods with decision-making techniques and environmental assessment to support practical implementation. This study proposes a hybrid data-driven framework for predicting strength, optimizing mix compositions, and evaluating environmental impacts via life cycle assessment of cement-stabilized soft soils. Six ML models were evaluated, and the top-performing eXtreme Gradient Boosting (XGB) model was further improved using the Grey Wolf Optimizer (GWO). The optimized XGB-GWO model, integrated with a polynomial …
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Struvite, the stable hydration product and primary strength phase in magnesium ammonium phosphate cement (MAPC), derived from wastewater treatment, has recently been utilized as a sustainable additive to Portland cement (PC). However, its impacts on cement hydration kinetics, pore refinement, rheology, and the mechanisms underlying these processes have not been comprehensively studied. This study developed Portland cement-struvite (PCS) systems by replacing PC with 3–20 % struvite (ST wt.%: PCS3–PCS20) and evaluated these processes using isothermal calorimetry, 3D micro-computed tomography (μXCT), time-dependent rheometry, X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR), and the Krstulović-Dabić (K-D) model. The FTIR/XRD confirmed the coexistence …
Nanocatalytic Enhancement Of Local Heat Transfer In Continuous-Flow Thermal Reactors, Nasser Zouli, Nujud Maslamani, Ayman Yousef, Muthanna H. Al-Dahhan
Nanocatalytic Enhancement Of Local Heat Transfer In Continuous-Flow Thermal Reactors, Nasser Zouli, Nujud Maslamani, Ayman Yousef, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
An experimental investigation was conducted to evaluate the thermal conductivity (TC) and local heat-transfer coefficients (LHTCs) of nanofluids containing alumina (Al2O3), hematite (Fe2O3), and copper oxide (CuO) nanoparticles dispersed in deionized water. A newly developed non-invasive LHTC probe was integrated into the inner wall of the test section to enable direct quantification of interfacial heat-transfer performance. The measurements were conducted under laminar and turbulent flow conditons across Reynolds numbers ranging from 1000 to 10,000. The selected nanoparticles were chosen based on their high intrinsic thermal conductivity, cost effectiveness, and, in the case …
February 2026 Cafe Newsletter, Missouri University Of Science And Technology
February 2026 Cafe Newsletter, Missouri University Of Science And Technology
CAFE Faculty Newsletters
Center for Advancing Faculty Excellence (CAFE) newsletter February 2026
Machine Learning In Peak Demand Forecasting: Foundations, Trends, And Insights, Shuang Dai, Fanlin Meng, Hongsheng Dai, Qian Wang, Xizhong Chen, Wenlei Bai, Peizhi Shi, Richard Allmendinger, Yuchen Zhang, Jian Liu
Machine Learning In Peak Demand Forecasting: Foundations, Trends, And Insights, Shuang Dai, Fanlin Meng, Hongsheng Dai, Qian Wang, Xizhong Chen, Wenlei Bai, Peizhi Shi, Richard Allmendinger, Yuchen Zhang, Jian Liu
Electrical and Computer Engineering Faculty Research & Creative Works
Peak demand forecasting involves predicting the maximum electricity demand within a specific period, which plays a key role in maintaining the efficiency and stability of power systems. The rapid evolution of power systems, driven by advanced metering infrastructure, local energy applications such as electric vehicles, and the increasing adoption of intermittent renewable energy, has introduced greater randomness and reduced predictability in peak demand. Given the pressing need to address more diverse implementation requirements across different contexts, accurate and reliable peak demand forecasting has become increasingly important. To the best of our knowledge, this study is the first to provide a …
An Improved United-Atom Potential For Molecular Dynamics Simulation Of Saturated Properties Of N-Alkanes, Wazih Tausif, Jordan Hartfield, Alex George, Zhi Liang
An Improved United-Atom Potential For Molecular Dynamics Simulation Of Saturated Properties Of N-Alkanes, Wazih Tausif, Jordan Hartfield, Alex George, Zhi Liang
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Multiple united-atom (UA) potential models have been developed in the literature to reproduce experimental saturated properties of n-alkanes using Monte Carlo simulations. When these UA potentials are employed in molecular dynamics (MD) simulations, MD simulations often give relatively poor predictions of saturated properties of n-alkanes, particularly the saturated vapor densities, due to the challenges in accurate calculation of long-range intermolecular forces beyond the cutoff distance in an inhomogeneous system. In this work, a new set of UA Lennard-Jones (LJ) interaction parameters for n-alkanes is proposed to reproduce the saturated properties, including saturated liquid and vapor densities (ρf and ρ …
Recent Advances Toward Damage-Tolerant 3d-Printed Titanium Alloys: Alloy Design Perspective, Saeid Alipour, Arezoo Emdadi, Ju Li
Recent Advances Toward Damage-Tolerant 3d-Printed Titanium Alloys: Alloy Design Perspective, Saeid Alipour, Arezoo Emdadi, Ju Li
Materials Science and Engineering Faculty Research & Creative Works
Twenty-year uninterrupted endeavor of titanium alloys printing has opened up a new paradigm in metal additive manufacturing (AM) to fabricate engineering components with required strength–density–corrosion combinations. Despite the remarkable advances in titanium AM, controlling the grain structure to print the parts with engineered microstructures, tailored mechanical properties, and minimum anomalies remains challenging. Numerous approaches have been implemented to address this challenge, such as printing parameter control, post-AM heat treatments, and thermomechanical processing. In addition to the aforementioned conventional approaches, novel techniques have been proposed that require employing hybrid manufacturing or developing the printer itself. One of the novel pathways in …
Heterogeneous Catalysis Of Large Biomolecules: Insights From Platinum Particle Size In Nad+Regeneration, Jianwei Li, Samuel Robertshaw, Shouying Huang, Shelley D. Minteer, Xiaodong Wang
Heterogeneous Catalysis Of Large Biomolecules: Insights From Platinum Particle Size In Nad+Regeneration, Jianwei Li, Samuel Robertshaw, Shouying Huang, Shelley D. Minteer, Xiaodong Wang
Chemistry Faculty Research & Creative Works
Nicotinamide adenine dinucleotide (NAD+) cofactor regeneration is essential for enabling dehydrogenase-promoted biosynthesis for value-added chemicals. Heterogeneous catalytic cofactor regeneration, using supported metal catalysts, is an emerging approach and has shown great promise. However, mechanistic insight remains largely unexplored. In this work, a series of silica-supported platinum (Pt) catalysts have been prepared for NAD+ cofactor regeneration, to understand the roles of Pt particle size and structure. A turnover frequency (TOF) 'volcano plot' was obtained for Pt clusters in the range of 2.2–7.1 nm, with the maximum TOF (136 h−1) observed at 5.6 nm. Selective Pt site …
Ultrasonic Extraction-Based Analysis Of Persistent Organic Pollutants In Blubber From False Killer Whales, Michael O. Eze, Eva Borras, Mitchell M. Mccartney, Don R. Bergfelt, Kristi L. West, Sarah E. Hooper, Cristina E. Davis
Ultrasonic Extraction-Based Analysis Of Persistent Organic Pollutants In Blubber From False Killer Whales, Michael O. Eze, Eva Borras, Mitchell M. Mccartney, Don R. Bergfelt, Kristi L. West, Sarah E. Hooper, Cristina E. Davis
Chemistry Faculty Research & Creative Works
In view of the toxic effects of persistent organic pollutants (POPs), fast and effective assessment of their concentrations in marine mammals is important for understanding individual and population-level health impacts. This study developed an ultrasonic-based method that is less time-consuming, uses minimal solvent, and thus is more sustainable than the gold standard Soxhlet method for accurate analysis of organochlorine pesticides (OCs), polychlorinated biphenyls (PCBs), and benzene hexachlorides (BHC) in false killer whale blubber. This method was developed by comparing concentrations of POPs obtained using the traditional Soxhlet and novel ultrasonic extraction methods using blubber from false killer whales (n = …
Energetics Analysis Of Solitary Waves Using A Multi-Layer Model, Hunter Boswell, Frank D. Han, Guirong Yan, Wouter Mostert
Energetics Analysis Of Solitary Waves Using A Multi-Layer Model, Hunter Boswell, Frank D. Han, Guirong Yan, Wouter Mostert
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
This study investigates the performance of a vertically-Lagrangian multi-layer model on numerically simulating shoaling and breaking two-dimensional solitary waves during both the breaking and post-breaking processes. The energy dissipation of the breaking event for the multi-layer waves is analyzed and compared to prior direct numerical simulation work with the same bathymetric and wave cases. It shows very similar data collapse to shallow-water inertial theory. For post-breaking behavior, bore characteristics are compared to an experimental study of bores formed from breaking solitary waves and similar results are found. While the multi-layer method was not found to behave sufficiently well for direct …
Influence Of Co2 Curing On Carbonation Depth, Phase Composition, And Micro-Mechanical Properties Of Fbc Ash-Blended Cementitious Materials, Heejung Jun, Seongho Han, Sanghwon Wi, Jinyoung Yoon
Influence Of Co2 Curing On Carbonation Depth, Phase Composition, And Micro-Mechanical Properties Of Fbc Ash-Blended Cementitious Materials, Heejung Jun, Seongho Han, Sanghwon Wi, Jinyoung Yoon
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
This study investigates the physicochemical and mechanical performance of cementitious composites incorporating fluidized bed combustion (FBC) ash under accelerated carbon dioxide (CO2) curing. FBC ash, due to its high contents of free calcium oxide (CaO) and sulfate (SO3), has been reported to cause challenges, such as volume instability and lower early-age strength. To address these limitations, CO2 curing was applied to promote accelerated carbonation and stabilize the hydration products. Cement paste and mortar samples, made with up to 40 % by cement weight replacement with FBC ash (labelled CF), were subjected to either CO2 curing …
Insight Into The Decalcification Mechanism Of Calcium Silicate Hydrate Under A Water–Heat–Salt Environment, Wei Zhang, Boya Zhang, Jia Sun, Juntao Dang, Xiangke Guo, Keliang Li, Bo Tao Huang, Biqin Dong, Hongyan Ma, Dongshuai Hou
Insight Into The Decalcification Mechanism Of Calcium Silicate Hydrate Under A Water–Heat–Salt Environment, Wei Zhang, Boya Zhang, Jia Sun, Juntao Dang, Xiangke Guo, Keliang Li, Bo Tao Huang, Biqin Dong, Hongyan Ma, Dongshuai Hou
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Understanding the decalcification mechanism of calcium silicate hydrate (C–S–H) under marine environments is crucial for concrete durability. In this study, the decalcification behavior of C–S–H under a water–heat–salt environment was systematically investigated through immersion experiments and reactive molecular dynamics simulations. Experimental results showed that elevated temperature and NaCl solution significantly accelerated Ca leaching and reduced the Ca/Si ratio of C–S–H. Simulation results further revealed that both high temperature and NaCl reduce the dissolution free energy of Ca, making its release more thermodynamically and kinetically favorable. Local structure analysis indicated that Cl– disrupts Ca–Os (O atoms in silicate tetrahedra) connection …
Robust And High-Efficiency Demodulation Of Ultra-Weak Fbg Arrays In Ofdr-Based Distributed Sensing, Zhaopeng Zhang, Yuxuan Cao, Xu Liu, Dingcheng Wang, Bo Liu, Chen Zhu
Robust And High-Efficiency Demodulation Of Ultra-Weak Fbg Arrays In Ofdr-Based Distributed Sensing, Zhaopeng Zhang, Yuxuan Cao, Xu Liu, Dingcheng Wang, Bo Liu, Chen Zhu
Electrical and Computer Engineering Faculty Research & Creative Works
A robust and high-efficiency demodulation scheme for optical frequency domain reflectometry (OFDR) based ultra-weak fiber Bragg grating (UWFBG) array detection system, originating from the Buneman frequency estimation (BFE) algorithm, is proposed and experimentally demonstrated. Due to the current limitations and imperfections of FBG inscription technology, the quasi-continuous inscription approach, along with its less-than-ideal outcomes, gives rise to problems of grating spectrum splitting and spectral distortion during the grating demodulation process. This renders the traditional approach of directly applying the BFE algorithm for grating demodulation ineffective, despite its significant enhancement of demodulation efficiency. To address this issue, we propose utilizing the …
Datamut: Deterministic Algorithms For Time-Delay Attack Detection In Multi-Hop Uav Networks, Keiwan Soltani, Federico Corò, Punyasha Chatterjee, Sajal K. Das
Datamut: Deterministic Algorithms For Time-Delay Attack Detection In Multi-Hop Uav Networks, Keiwan Soltani, Federico Corò, Punyasha Chatterjee, Sajal K. Das
Computer Science Faculty Research & Creative Works
Unmanned Aerial Vehicles (UAVs), also known as drones, have gained popularity in various fields such as agriculture, emergency response, and search and rescue operations. UAV networks are susceptible to potential security threats, such as wormhole attacks, jamming, spoofing, and false data injection. Time-Delay Attack (TDA) is a unique attack in which malicious UAVs intentionally delay packet forwarding, posing significant threats, especially in time-sensitive applications. It is challenging to distinguish malicious delay from benign network delay due to the dynamic nature of UAV networks, intermittent wireless connectivity, or the Store-Carry-Forward (SCF) mechanism during multi-hop communication. Some existing works propose machine learning-based …