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Fluorescent Biosensor-Guided Engineering Of Enzyme Cascades For Electrochemical Applications, Nathan J. Ricks, Monica Brachi, Fnu Arun, Egor Baiarashov, Shelley D. Minteer, Ming C. Hammond Mar 2026

Fluorescent Biosensor-Guided Engineering Of Enzyme Cascades For Electrochemical Applications, Nathan J. Ricks, Monica Brachi, Fnu Arun, Egor Baiarashov, Shelley D. Minteer, Ming C. Hammond

Chemistry Faculty Research & Creative Works

Substrate channeling is a strategy for enhancing flux and yield in enzymatic cascades and is increasingly relevant for applications in biocatalysis, biotechnology, and bioelectrochemical systems. However, efforts to engineer channeling are limited by the lack of high-throughput methods to evaluate and optimize channeling efficiency. Here, we present a fluorescence-based screening assay to rapidly assess substrate channeling in a model system involving fumarase and malate dehydrogenase, two sequential enzymes from the Krebs cycle. By expressing genetic fusions in Escherichia coli, quantifying intermediate (malate) and product (NADH) formation in lysate using orthogonal fluorescent readouts, and comparing product-to-intermediate ratios, we screened a library …

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Sustainable Pathways For Fish Waste Oil Valorization Into Biofuel: Process Synthesis And Case Study, Hany A. Elazab, Radhi H. Alazmi, Abdelrahman El-Bagalaty, Hossam Tammam, Mahmoud El-Sayed, Mohamed Omar, Fathi Shokry, Mamdouh A. Gadalla, Fatma H. Ashour, Thokozani Majozi Mar 2026

Sustainable Pathways For Fish Waste Oil Valorization Into Biofuel: Process Synthesis And Case Study, Hany A. Elazab, Radhi H. Alazmi, Abdelrahman El-Bagalaty, Hossam Tammam, Mahmoud El-Sayed, Mohamed Omar, Fathi Shokry, Mamdouh A. Gadalla, Fatma H. Ashour, Thokozani Majozi

Chemical and Biochemical Engineering Faculty Research & Creative Works

Biodiesel is a promising, sustainable alternative to fossil fuels such as petrol and diesel. Currently, biodiesel can be produced from edible plant oils and non-edible sources and wastes. Notably, fish waste oil is a sustainable resource for transesterification reactions to produce biodiesel. This research proposes a general process design methodology to investigate the potential of biodiesel production from fish waste oil as a pathway for waste-to-energy. The methodology integrates Pinch Analysis principles and process simulation to optimize the energy efficiency of a process design. Real data are collected on fish waste from fish industries in Egypt, focusing on three regions …

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Failure Of Infrastructure Systems: A Multilevel Network Analysis Of Decision-Making And Influential Behavioral Constructs, Tamima Elbashbishy, Radwa Eissa, Islam H. El-Adaway, Jeffrey S. Russell Mar 2026

Failure Of Infrastructure Systems: A Multilevel Network Analysis Of Decision-Making And Influential Behavioral Constructs, Tamima Elbashbishy, Radwa Eissa, Islam H. El-Adaway, Jeffrey S. Russell

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

High-profile failures of infrastructure systems are often attributed to design flaws. However, these incidents can also stem from a broader set of interconnected decisions made by stakeholders involved in the planning, management, and operation of these systems. While ethical guidelines and professional codes are designed to prevent such failures, cognitive biases may undermine adherence. Previous research efforts, primarily focused on ethical violations using case studies, have overlooked how behavioral ethics constructs and professional conduct could drive these breaches. This paper addresses this knowledge gap by (1) conducting an analysis of three system failure cases at the micro, meso, and macro …

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Methodology For Surface Defect Assessment In 3d Concrete Printing Using Computer-Vision And Ultrasonic Testing Considering Structural Build-Up, Seongho Han, Eunjong Ahn, Myoungsu Shin, John S. Popovics, Kamal H. Khayat Mar 2026

Methodology For Surface Defect Assessment In 3d Concrete Printing Using Computer-Vision And Ultrasonic Testing Considering Structural Build-Up, Seongho Han, Eunjong Ahn, Myoungsu Shin, John S. Popovics, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study quantifies how interlayer time gaps and mixture rheology jointly influence interfacial integrity and mechanical performance in 3D concrete printing (3DCP). Two mixtures incorporating identical binders, but differing limestone fineness (4 and 50 μm) were printed with interlayer delays of 0, 2, and 5 min, corresponding to stacking rates of approximately 9, 0.5, and 0.2 m/h. The finer limestone mixture exhibited higher plastic viscosity (13.2 vs. 11.5 Pa s) and faster structural buildup (58 vs. 38 Pa/min), resulting in accelerated early stiffening. Deposition yield stress derived from buildup measurements remained low for 0–2 min (1400–1500 Pa for the higher-thixotropy …

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Data-Driven Non-Precipitation Echo Removal Of Nexrad Radars Based On A Random Forest Classifier Using Polarimetric Observations And Goes-16 Data, Munsung Keem, Bong Chul Seo, Witold F. Krajewski, Sangdan Kim Mar 2026

Data-Driven Non-Precipitation Echo Removal Of Nexrad Radars Based On A Random Forest Classifier Using Polarimetric Observations And Goes-16 Data, Munsung Keem, Bong Chul Seo, Witold F. Krajewski, Sangdan Kim

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Highlights: What are the main findings? A Random Forest-based model using dual-polarimetric radar features achieves >99% accuracy in classifying precipitation and non-precipitation echoes. Multi-scale spatial variability features enhance discrimination between genuine precipitation and spurious echoes. Fusion of GOES-16 infrared satellite data with NEXRAD radar effectively removes non-precipitation echoes with precipitation-like signatures, including wind turbine clutter. A CAPPI scan strategy improves near-radar precipitation detection by recovering valid echoes misclassified at the lowest elevation due to side-lobe interference and limited sampling volume. What are the implications of the main findings? The model's robustness to noise and overfitting, combined with minimal hyperparameter tuning, …

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Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser Mar 2026

Intramolecular Nonbonding Interactions And Geared Phenyl Twisting In Para-Disubstituted 1,4-Diphenylazines: Electron Correlation Effects On Molecular Conformations And Enantiomerization, Kaidi Yang, Harmeet Bhoday, Rainer Glaser

Chemistry Faculty Research & Creative Works

The results are reported of potential energy surface (PES) analyses of six symmetrical azines Yp − Ph − RC=N − N=CR − Ph − Yp, namely, the benzaldehyde azines 1H, 2H, and 8H with R = H and the acetophenone azines 1M, 2M, and 8M with R = Me. The Y substituents Cl (1), Br (2), and Me (8) were studied because sets of polymorphs I (C2-symmetry, azine twist τ ≈ 135 ± 10°, disrotatory phenyl twists ϕi ≠ 0°) and II (Ci-symmetry, τ = 180°, conrotatory ϕi ≠ 0°) were crystallized for these three azines. The …

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Advancing Activated Carbon Production: Utilizing Pine Pruning Biochar Via Induction Heating With Co2and Iron-Based Catalysts, Ahmet Erdem, Muthanna H. Al-Dahhan, Ahmed Jasim Mar 2026

Advancing Activated Carbon Production: Utilizing Pine Pruning Biochar Via Induction Heating With Co2and Iron-Based Catalysts, Ahmet Erdem, Muthanna H. Al-Dahhan, Ahmed Jasim

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study introduces an induction heating approach for producing activated carbon from biochar obtained by thermal degradation of pine pruning waste from timber-related industries, using CO2 and iron-based catalysts as activation agents. Activation experiments were performed using a 10 kW high-frequency induction system (28–40 kHz) under continuous CO₂ flow (15 mL min−1), with electric current intensities of 200, 300, 400, and 500 A (corresponding to 700–1100°C) and durations of 30, 60, and 90 min, employing 45 g of iron-based catalysts (Fe–Ni–Ti–C, 85:6:3:6 wt.%) per 3 g biochar (15:1 w/w). Mass loss increased from 13.7 % (200 A, …

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March 2026 Cafe Newsletter, Missouri University Of Science And Technology Mar 2026

March 2026 Cafe Newsletter, Missouri University Of Science And Technology

CAFE Faculty Newsletters

Center for Advancing Faculty Excellence (CAFE) newsletter March 2026

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New Insights Into Dynamic Evolution Of Colloidal Network Structure During Early-Age Hardening Of Cementitious Materials, Hengrui Liu, Kaiyin Zhao, Shipeng Zhang, Hanghua Zhang, Shuangshuang Liu, Lucen Hao, Hongyan Ma, Kamal Khayat, Chi Sun Poon Mar 2026

New Insights Into Dynamic Evolution Of Colloidal Network Structure During Early-Age Hardening Of Cementitious Materials, Hengrui Liu, Kaiyin Zhao, Shipeng Zhang, Hanghua Zhang, Shuangshuang Liu, Lucen Hao, Hongyan Ma, Kamal Khayat, Chi Sun Poon

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The evolution of microstructure in cementitious materials during their transition from fluid to solid state plays a critical role in determining their ultimate mechanical strength and overall performance. This hydration stage primarily involves a dynamic densification process occurring within the colloidal network. However, the field of cement-based materials currently lacks a comprehensive theoretical framework and associated parameters capable of effectively characterizing the specific structural regions within this network. In this study, we propose an Improved Particle Linkage (IPL) theory for describing the strength, types, and quantities of particle linkages within colloidal network. The IPL theory classifies the internal network structure …

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A Borophosphate Glass Doped With Cobalt Oxide Improves Skeletal Muscle Structure And Function In Myopathic Mice, Jacob A. Kendra, Alexandra G. Naman, Rebekah L. Blatt, Carla D. Zingariello, Richard K. Brow, Steven S. Segal, Aaron B. Morton Mar 2026

A Borophosphate Glass Doped With Cobalt Oxide Improves Skeletal Muscle Structure And Function In Myopathic Mice, Jacob A. Kendra, Alexandra G. Naman, Rebekah L. Blatt, Carla D. Zingariello, Richard K. Brow, Steven S. Segal, Aaron B. Morton

Materials Science and Engineering Faculty Research & Creative Works

Skeletal muscle myopathy remains a significant cause of disability with limited treatment strategies. Advancements in tissue engineering have led to the development of borophosphate bioactive glasses (BPBGs) capable of enhancing skeletal muscle structure and function. Using a mouse model of severe myopathy (D2.mdx), we investigated muscle force, regeneration, angiogenesis and inflammation at 14, 70 and 140 days post-treatment (dpt). Tibialis anterior (TA) muscles of D2.mdx mice that received a single injection of cobalt oxide-doped BPBG (CoO-TRIM) particles exhibit greater active force, myofiber size, and regeneration through 70 dpt compared to control D2.mdx mice injected with Saline. Vascular endothelial growth factor …

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Applying Direct Numerical Simulations To Investigate Wave Forcing Against A Vertical Wall, Hunter Boswell, Frank D. Han, Gaurav Savant, Guirong Yan, Wouter Mostert Mar 2026

Applying Direct Numerical Simulations To Investigate Wave Forcing Against A Vertical Wall, Hunter Boswell, Frank D. Han, Gaurav Savant, Guirong Yan, Wouter Mostert

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Current engineering standards lack the ability to predict the peak impact forces of breaking waves impinging directly upon coastal structures. In this study solitary waves impacting vertical and tapered walls are investigated. To capture the detailed physics of the wave profile that impacts the wall, two-dimensional direct numerical simulations are applied to model the wave traveling over a simplified bathymetry consisting of an initially uniform depth, followed by a uniform beach ramp and then terminating in a uniform depth inshore region and vertical wall. Such an approach can simulate wave runup on land and then the impact with the vertical …

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Electroactive Pvdf/Ti3c2tx Mxene Functionalized Nanofiber Mats With High Surface Potential For High-Efficiency Indoor & Outdoor Submicron Pm(0.3-2)Μm Filtration, Ashish Kakoria, Mirza Muhammad Zaid, Aamir Iqbal, Mahsa Moradi, Lina Zheng, Guang Xu Mar 2026

Electroactive Pvdf/Ti3c2tx Mxene Functionalized Nanofiber Mats With High Surface Potential For High-Efficiency Indoor & Outdoor Submicron Pm(0.3-2)Μm Filtration, Ashish Kakoria, Mirza Muhammad Zaid, Aamir Iqbal, Mahsa Moradi, Lina Zheng, Guang Xu

Mining Engineering Faculty Research & Creative Works

Fine PM0.3-2.0 rapidly penetrates the respiratory system and causes health problems. Commercial filters remove 0.3 μm particles at ∼95 % efficiency but impose high pressure drops that make breathing difficult. We fabricate a novel electrospun PVDF-Ti3C2Tx nanofiber mat for PM0.3–2.0 filtration. Where a high electric field stretched PVDF and PVDF-Ti3C2Tx solutions into ultrafine fibers that were collected as porous nanofibrous mats. PVDF was chosen for its electroactive behavior and high dielectric constant, enabling efficient electrostatic filtration. The incorporation of Ti3C2Tx MXene enhances surface charge density and interfacial polarization, …

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An Adaptive Immersive Training Framework For Miner Self-Escape Readiness In Underground Mining Emergencies, Muhammad Azeem Raza, Samuel Frimpong, Saima Ghazal Mar 2026

An Adaptive Immersive Training Framework For Miner Self-Escape Readiness In Underground Mining Emergencies, Muhammad Azeem Raza, Samuel Frimpong, Saima Ghazal

Mining Engineering Faculty Research & Creative Works

Underground mining environments are complex and hazardous operations where emergencies continue to happen. Underground mine emergencies require rapid, high-stakes decision-making under conditions of uncertainty, stress, and limited visibility. Conventional mine emergency training largely relies on instruction-based approaches which provide insufficient exposure to the cognitive and behavioral demands of real underground emergency situations. There has been an identified need to train miners for knowledge, skills, abilities, and other characteristics (KSAOs). This study proposes an Adaptive Immersive Training Framework (AITF), a cognitively grounded architecture that integrates cognitive task analysis (CTA), KSAOs, and situational awareness assessment for miner self-escape training and readiness. The …

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Microstructural Evolution Of Zirconium Diboride Irradiated With 5–10 Mev Au Ions At Room Temperature And 570 °C, Narrie Loftus, José Olivares, Miguel Crespillo, Esther Enríquez Pérez, Jeremy Watts, Eric W. Bohannan, Gregory Hilmas, William Fahrenholtz, Joseph Graham Mar 2026

Microstructural Evolution Of Zirconium Diboride Irradiated With 5–10 Mev Au Ions At Room Temperature And 570 °C, Narrie Loftus, José Olivares, Miguel Crespillo, Esther Enríquez Pérez, Jeremy Watts, Eric W. Bohannan, Gregory Hilmas, William Fahrenholtz, Joseph Graham

Materials Science and Engineering Faculty Research & Creative Works

Zirconium diboride was irradiated with 5 MeV Au2 + , 7 MeV Au4+ and 10 MeV Au3+ ions at room temperature and 570 °C to doses from 1 to 8 displacements per atom (dpa). Grazing incidence X-ray diffraction (GIXRD) analysis revealed no secondary phase formation. Rietveld analysis of the GIXRD data indicated an accumulation of microstrain at low dpa and room temperature. Dislocations observed in transmission electron microscopy (TEM) cross-sections are likely the main contributor to the microstrain. High dpa and high-temperature samples exhibit lower lattice distortion than lower dpa samples, suggesting the presence of enhanced defect …

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Thermally Stable Sic Particulate-Reinforced Sic Composites Up To 2000 ℃ Fabricated By Precursor Impregnation And Pyrolysis Method, Jian Gu, Vu Viet Hung, Lun Feng, William G. Fahrenholtz, Daejong Kim, Seyoung Kim, Sea Hoon Lee Mar 2026

Thermally Stable Sic Particulate-Reinforced Sic Composites Up To 2000 ℃ Fabricated By Precursor Impregnation And Pyrolysis Method, Jian Gu, Vu Viet Hung, Lun Feng, William G. Fahrenholtz, Daejong Kim, Seyoung Kim, Sea Hoon Lee

Materials Science and Engineering Faculty Research & Creative Works

The thermo-mechanical properties of SiC particulate-reinforced SiC composites (SiC-PRCs), fabricated using precursor impregnation & pyrolysis (PIP) process, were analyzed up to 2000 ℃. The relative density of the SiC-PRCs after 4 PIP cycles was 88.6 %. The number of PIP cycles required decreased to nearly half compared with the conventional PIP method by using ultra-high concentration slurries up to 70 vol%. In addition, room-temperature bending strength (215 MPa) and Young's modulus (269 GPa) improved as the solid loading of the slurry increased. The bending strength increased to 232 MPa at 2000 ℃ in Ar. Despite the thermal deterioration of the …

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A Software Package For Generating Robust And Accurate Potentials Using The Moment Tensor Potential Framework, Josiah Roberts, Biswas Rijal, Simon Divilov, Jon Paul Maria, William G. Fahrenholtz, Douglas E. Wolfe, Donald W. Brenner, Stefano Curtarolo, Eva Zurek Mar 2026

A Software Package For Generating Robust And Accurate Potentials Using The Moment Tensor Potential Framework, Josiah Roberts, Biswas Rijal, Simon Divilov, Jon Paul Maria, William G. Fahrenholtz, Douglas E. Wolfe, Donald W. Brenner, Stefano Curtarolo, Eva Zurek

Materials Science and Engineering Faculty Research & Creative Works

We present the Plan for Robust and Accurate Potentials (PRAPs), a software package for training and using moment tensor potentials (MTPs) in concert with the Machine Learned Interatomic Potentials (MLIP) software package. PRAPs provides an automated workflow to train MTPs using active learning procedures, and a variety of utilities to ease and improve workflows when utilizing the MLIP software. PRAPs was originally developed in the context of crystal structure prediction, in which one calculates convex hulls and predicts low energy metastable and thermodynamically stable structures, but the potentials PRAPs develops are not limited to such applications. PRAPs produces two potentials, …

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Superhard Refractory High-Entropy Diborides, M. D. Hossain, N. S. Mcilwaine, N. O. Marquez-Rios, A. C. Feltrin, V. Chawla, R. A. Mayanovic, W. G. Fahrenholtz, D. Penumadu, E. Zurek, D. W. Brenner, D. E. Wolfe, S. Divilov, H. Eckert, S. Curtarolo Mar 2026

Superhard Refractory High-Entropy Diborides, M. D. Hossain, N. S. Mcilwaine, N. O. Marquez-Rios, A. C. Feltrin, V. Chawla, R. A. Mayanovic, W. G. Fahrenholtz, D. Penumadu, E. Zurek, D. W. Brenner, D. E. Wolfe, S. Divilov, H. Eckert, S. Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

Using first-principles calculations and companion experimental validations, we demonstrate that the valence electron concentration (VEC) can be used to self-consistently parameterize the bonding characteristics of high-entropy diborides (HEBs) and in turn predict their mechanical properties. When VEC is 10.0 per formula unit (f.u.), HEBs enter the superhard category where Hv>40GPa because bonding states are optimally filled to resist shear deformation. Conversely, above or below a VEC of 10.0, the hardness decreases due to the filling of antibonding or the emptying of bonding states of the HEBs, respectively. This result is supported by analyses of the electronic structure, bonding, antibonding, …

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Warrior Bot, Relational Bot, Blameworthy Bot: How A Student Design Team Anthropomorphize Their Combat Robot Creations, Daniel Burton Shank, Frederick F. Sunkpal, Nova Lee Young, Karli Hoerstkamp, David Wright, Merilee A. Krueger, Carleigh J. Davis Mar 2026

Warrior Bot, Relational Bot, Blameworthy Bot: How A Student Design Team Anthropomorphize Their Combat Robot Creations, Daniel Burton Shank, Frederick F. Sunkpal, Nova Lee Young, Karli Hoerstkamp, David Wright, Merilee A. Krueger, Carleigh J. Davis

Psychological Science Faculty Research & Creative Works

How do robot designers anthropomorphize their own creations? Because robot designers have the ability to alter the robot, identify as its creator, and understand their robot's internal makeup, their process of anthropomorphism and its outcomes may be different from that of the typical robot user. We investigate this research question in the domain of combat robots, where anthropomorphism is critical to decision-making, communication, and trust in high-stakes, high-emotion combat situations faced by robot-soldier teams. We conducted an in-depth case study of a university's student-led Combat Robotics Design Team over the design, construction, testing, and competition phases for their competitive combat …

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Understanding Human Arm Stiffness Modulation In Overground Phri: The Roles Of Kinematics, Perturbation, And Trunk Sway, Mohsen Mohammadi Beirami, Sambad Regmi, Devin Michael Burns, Yun Seong Song Mar 2026

Understanding Human Arm Stiffness Modulation In Overground Phri: The Roles Of Kinematics, Perturbation, And Trunk Sway, Mohsen Mohammadi Beirami, Sambad Regmi, Devin Michael Burns, Yun Seong Song

Psychological Science Faculty Research & Creative Works

This study examines human arm kinematics during overground physical human-robot interaction (pHRI). Previous work showed humans adjust arm stiffness with changing trajectory uncertainty, but the roles of arm kinematics and muscle activation remained unclear. Building on a preliminary study, we analyzed arm movements with more participants (10 individuals) to achieve more reliable findings and examined two potential influences that arose in the preliminary study: the robot's perturbation effect (a brief hand push) and left-to-right trunk sway. Using a linear mixed-effects model, we evaluated the effects of participant, block, and trajectory condition on arm angles. Results showed minimal kinematic contribution to …

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The Effect Of Reduction Of Input-Parameters On Data-Driven Prediction Of Critical Heat Flux In Rod Bundles Using Extended Parameters For Reactor Thermal–Hydraulic Safety, Rehan Zubair Khalid, Atif Khan, Farooq Ahmad, Muthanna H. Al-Dahhan, Atta Ullah Mar 2026

The Effect Of Reduction Of Input-Parameters On Data-Driven Prediction Of Critical Heat Flux In Rod Bundles Using Extended Parameters For Reactor Thermal–Hydraulic Safety, Rehan Zubair Khalid, Atif Khan, Farooq Ahmad, Muthanna H. Al-Dahhan, Atta Ullah

Chemical and Biochemical Engineering Faculty Research & Creative Works

Accurate prediction of the critical heat flux (CHF) is a key pillar for ensuring both the safety and economic performance of nuclear reactors. While machine learning (ML)-based methodologies have demonstrated considerable success in predicting CHF, most existing studies have been confined to simplified geometries, such as single tubes. Conversely, limited attention has been devoted to CHF prediction in realistic reactor environments, particularly within rod bundle configurations, where complex multiphase flow and heat transfer phenomena prevail. In this work we develop different AI models based on large dataset operating conditions as well as the complex geometric features of rod bundles. The …

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Applying Two-Stage Risk-Based Market Structures For Energy Hub-Based Plug-In Electric Vehicles Using Information Decision Gap Theory And A Hybrid Recurrent Convolutional Network, A. Heidari, R. C. Bansal, R. Bo Mar 2026

Applying Two-Stage Risk-Based Market Structures For Energy Hub-Based Plug-In Electric Vehicles Using Information Decision Gap Theory And A Hybrid Recurrent Convolutional Network, A. Heidari, R. C. Bansal, R. Bo

Electrical and Computer Engineering Faculty Research & Creative Works

This paper investigates the optimal operation of an energy hub engaged in both day-ahead and real-time trading. A two-stage optimization framework Information Gap Decision Theory (IGDT) for day-ahead bidding and stochastic programming with Monte Carlo scenarios for real-time recourse is applied. Risk-neutral, risk-averse, and risk-taking strategies are considered to capture different risk preferences. The hub integrates combined heat and power, renewable energy, plug-in electric vehicles, and vehicle-to-grid and grid-to-vehicle technologies. Price and load forecasts are generated using a hybrid recurrent convolutional network (HRCN). Results highlight the trade-off between risk management and economic performance: costs are 16.5 % higher in the …

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Microwave Dielectric Properties Of Geopolymer Precursor Powders, Linh T. Duong, Abu Naser Rashid Reza, Kristen M. Donnell, Christopher R. Shearer Mar 2026

Microwave Dielectric Properties Of Geopolymer Precursor Powders, Linh T. Duong, Abu Naser Rashid Reza, Kristen M. Donnell, Christopher R. Shearer

Electrical and Computer Engineering Faculty Research & Creative Works

Geopolymers are sustainable structural materials with properties similar to ordinary Portland cement concrete. To better understand the fundamental reaction mechanisms of geopolymers, a microwave materials characterization approach is used. In this research work, the dielectric properties (permittivity and loss factor) of common precursor powders used to make geopolymers (GPPs)—fly ash, lime, metakaolin, silica fume, slag, and zeolite—are measured over the S- and X-band frequency ranges (i.e., 2.0–4.0 GHz and 8.2–12.4 GHz, respectively). The physical characteristics, elemental composition, mineralogical properties, and phase characterization of the GPPs are then correlated to dielectric properties. Permittivity of GPP, classified as pozzolanic or latent hydraulic, …

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Positive Solutions For Nonlinear Fractional Differential Equations With A Disturbance Parameter On An Infinite Interval, Zhaocai Hao, Lu Song, Martin Bohner, Qianqian Gu, Panzhen Liu Feb 2026

Positive Solutions For Nonlinear Fractional Differential Equations With A Disturbance Parameter On An Infinite Interval, Zhaocai Hao, Lu Song, Martin Bohner, Qianqian Gu, Panzhen Liu

Mathematics and Statistics Faculty Research & Creative Works

This paper studies a class of integral boundary value problems of fractional differential equations with a disturbance parameter on an infinite interval. By applying the upper-lower solution method and fixed point index theory, the influence of the disturbance parameter on the existence of positive solutions is rigorously analyzed. We have obtained that the boundaryvalue problem admits at least twopositive solutions, one positivesolution or no solution. An example is provided to validate the results. The results of this study provide a significant complement and refinement to some existing findings.

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Neuproio: A Dual-Action Solid Drug Nanoparticle Topical Formulation For Simultaneous Intraocular Pressure Reduction And Neuroprotection For Glaucoma, Lei Xu, Mu Li, Lin Qi, Tzu Chen Wang, Dong Liu, Vimalin Jeyalatha Mani, Hsin Yin Chuang, Qingbo Yang, Ruipu Mu, Samira Mahdi, Da Huang, Honglan Shi, Yang Hu, Hu Yang Feb 2026

Neuproio: A Dual-Action Solid Drug Nanoparticle Topical Formulation For Simultaneous Intraocular Pressure Reduction And Neuroprotection For Glaucoma, Lei Xu, Mu Li, Lin Qi, Tzu Chen Wang, Dong Liu, Vimalin Jeyalatha Mani, Hsin Yin Chuang, Qingbo Yang, Ruipu Mu, Samira Mahdi, Da Huang, Honglan Shi, Yang Hu, Hu Yang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Glaucoma is a leading cause of irreversible blindness, primarily due to elevated intraocular pressure (IOP) that damages the retina and optic nerve. Most topical glaucoma treatments focus solely on IOP-lowering without direct neuroprotection, as drug delivery to the posterior eye is challenging. Here, we developed NeuProIO, a dual-action solid drug nanoparticle (NP) eye drop for simultaneous IOP reduction and neuroprotection. Using flash nanoprecipitation in a multi-inlet vortex mixer, we fabricated the first NeuProIO solid drug NPs incorporating the repurposed neuroprotective agent maprotiline (MAP) and the IOP-lowering agent betaxolol (BX), forming MAP/BX NPs for synergistic glaucoma treatment. The NeuProIO improved stability …

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Rheological Modification Of Alkali-Activated Slag Mortar: Roles Of Sodium Gluconate Retarder And Dispersants, Tae Yong Shin, Seongho Han, Ryong You, Yubin Jun, Jae Hong Kim Feb 2026

Rheological Modification Of Alkali-Activated Slag Mortar: Roles Of Sodium Gluconate Retarder And Dispersants, Tae Yong Shin, Seongho Han, Ryong You, Yubin Jun, Jae Hong Kim

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Alkali-activated materials have emerged as promising low-carbon alternatives to ordinary Portland cement-based binders; however, their practical application is strictly limited by rapid setting and poor workability. To address these challenges, this study proposes an evaluation methodology combining setting time measurement, cloud point tests for chemical stability, and wide-range rheological analysis. While conventional superplasticizers like polycarboxylate ether (PCE) proved unstable in high-alkaline environments, cloud point tests revealed that polynaphthalene sulfonate (PNS) and butyl acrylate (BA) exhibited superior chemical stability. Notably, BA was identified as a novel and effective dispersant in 3.5 M KOH-activated systems, reducing yield stress of fresh mortar by …

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Hardness Of (Hf,Ti,W,Zr)B2/(Hf,Ti,W,Zr)C-Based Ceramics With Varying Wb Content, Suzana Filipović, William G. Fahrenholtz, Gregory E. Hilmas, Nina Obradović, Stefano Curtarolo Feb 2026

Hardness Of (Hf,Ti,W,Zr)B2/(Hf,Ti,W,Zr)C-Based Ceramics With Varying Wb Content, Suzana Filipović, William G. Fahrenholtz, Gregory E. Hilmas, Nina Obradović, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

Compositionally complex (Hf,Ti,Zr,W)B2/(Hf,Ti,Zr,W)C-based ceramics were produced with different boride and carbide phase contents by varying the C/B4C molar ratio used in boro/carbothermal reduction. A monoboride phase based on WB was detected in all compositions. As the C/B4C ratio was varied, the WB content decreased from 23.7 vol% for a C/B4C ratio of 6.0–15.3 vol% for a C/B4C ratio of 10.3. Further increases in the C/B4C ratio increased the WB content. The monoboride phase contained mainly W and Ti in a solid solution with the nominal composition of (W …

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Long-Range Fit: A Software Package For The Representation And Study Of Long-Range Molecular Interactions, Adrian L. Batista-Planas, Ernesto Quintas-Sánchez, Richard Dawes Feb 2026

Long-Range Fit: A Software Package For The Representation And Study Of Long-Range Molecular Interactions, Adrian L. Batista-Planas, Ernesto Quintas-Sánchez, Richard Dawes

Chemistry Faculty Research & Creative Works

Describing intermolecular forces is fundamental to modeling and predicting the behavior of molecular systems. In particular, long-range molecular interactions with electrostatic, induction, and dispersion as the main components play a critical role, especially for low-temperature and low-density regimes. Long-range interactions are often described through perturbation theory, representing the electronic charge distribution via a multipolar series of the moments and polarizability tensors corresponding to each molecule. However, while the theory is well established, obtaining the resulting analytical expressions (and their practical implementation) constitutes a highly complex and system-dependent task. To address this challenge, we developed long-range-fit (LRF), an interactive and user-friendly …

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Cationic Poly(Glucosamine)-Based Polymers Bind To Glycans With Varying Affinity Facilitating Transport Across The Glycocalyx Of Endothelial Cells, Claire Bridges, Lu Fu, Dan Wang, James D. Sterling, Susanna Liang, Shenda M. Baker, Jonathan Yeow, Megan S. Lord Feb 2026

Cationic Poly(Glucosamine)-Based Polymers Bind To Glycans With Varying Affinity Facilitating Transport Across The Glycocalyx Of Endothelial Cells, Claire Bridges, Lu Fu, Dan Wang, James D. Sterling, Susanna Liang, Shenda M. Baker, Jonathan Yeow, Megan S. Lord

Business and Information Technology Faculty Research & Creative Works

Natural polysaccharides, such as chitosan, offer promising avenues for drug delivery due to their cytocompatibility and ability to interact with cell surfaces. However, the endothelial glycocalyx, a glycan-rich extracellular matrix, presents a barrier that must be navigated for effective intracellular delivery. This study investigates how cationic poly(glucosamine)-based polymers, functionalized with guanidinium or ammonium groups, interact with key glycocalyx components including hyaluronan (HA) and heparan sulfate (HS). We demonstrate that these cationic polymers form tunable biomolecular condensates with glycans, with stronger binding observed for sulfated glycans, HS and heparin, than unsulfated HA. Derivatized chitosan polymers with varied cationic side chains exhibit …

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Use Of Gamma-Ray Spectroscopy In Thickness Gauging Of A Complex-Shaped Lead Shield, Joseph T. Graham, Brian Durtschi, Ashish Avachat, Seth Kilby Feb 2026

Use Of Gamma-Ray Spectroscopy In Thickness Gauging Of A Complex-Shaped Lead Shield, Joseph T. Graham, Brian Durtschi, Ashish Avachat, Seth Kilby

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Methods for measuring the thickness of lead shielding based on 60Co gamma-ray spectroscopy are presented. In applications where a shield's thickness is multiple mean free paths and the shield has a complex shape (i.e. cannot be approximated as a simple solid such as a slab, sphere, semi-infinite medium, etc.), the necessary buildup factors are not available. Thus, determination of shield thickness by means of the Beer–Lambert law requires separating the counts from uncollided photons from the scattered photon contribution. It is demonstrated how the 1332 keV gamma ray of 60Co can be used to precisely quantify lead thicknesses …

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Advances And Challenges In Nano-Modified Cementitious Composites: Mechanisms, Dispersion Strategies, And Impact On Mechanical Properties, Fatemeh Mohammadi Ghahsareh, Pengwei Guo, Nusrath Jaha, Yi Bao, Kamal H. Khayat, Weina Meng Feb 2026

Advances And Challenges In Nano-Modified Cementitious Composites: Mechanisms, Dispersion Strategies, And Impact On Mechanical Properties, Fatemeh Mohammadi Ghahsareh, Pengwei Guo, Nusrath Jaha, Yi Bao, Kamal H. Khayat, Weina Meng

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Nanomaterials are increasingly utilized to enhance the mechanical properties, durability, and functionality of concrete materials but face challenges such as agglomeration and uneven dispersion in cementitious systems, which can offset the intended improvements. This paper reviews the advances and challenges associated with nano-modified cementitious composites, elucidating fundamental mechanisms and highlighting strategies for overcoming the challenges through experimental and computing techniques. The reviewed contents include (1) the classification of nanomaterials commonly used in cementitious systems and the mechanisms through which they enhance the mechanical properties of cementitious composites; (2) challenges of nanomaterials such as agglomeration in water, re-agglomeration in cementitious systems, …

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