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Articles 541 - 570 of 32986
Full-Text Articles in Entire DC Network
Hardware Without Humanware: Robot Adoption, Talent Structure Degradation, And Firm Innovation, Wenhao Sun, Zhenyu Wu, Chevy-Hanqing Fang
Hardware Without Humanware: Robot Adoption, Talent Structure Degradation, And Firm Innovation, Wenhao Sun, Zhenyu Wu, Chevy-Hanqing Fang
Business and Information Technology Faculty Research & Creative Works
Contrary to the prevailing view that automation complements skilled labor in advanced economies, this study examines the unintended consequences of robot adoption in emerging markets. Drawing on strategic human capital theory, we exploit China's manufacturing sector as a natural experiment to identify the causal impact of industrial intelligence on firm-level innovation. Using a unique dataset of more than 90,000 public and private firms from the National Enterprise Innovation Database (2008–2014), we uncover a counterintuitive result: robot adoption significantly reduces firm innovation, which is notably more pronounced for private-owned firms and those with weaker innovation capabilities. Mediation analyses further show that …
One Size Doesn’T Fit All: Navigating Gendered Ageism In Older Women’S Entry Into Entrepreneurship, Yanying Chen, Zijie Song, Chevy-Hanqing Fang
One Size Doesn’T Fit All: Navigating Gendered Ageism In Older Women’S Entry Into Entrepreneurship, Yanying Chen, Zijie Song, Chevy-Hanqing Fang
Business and Information Technology Faculty Research & Creative Works
Though older women may choose entrepreneurship as a way to escape discrimination in the labor market, they may face other forms of discrimination in the entrepreneurial domain. Drawing on intersectionality theory, we posit that older women encounter amplified discrimination due to the stereotype-consistent implications from gender and age norms, namely gendered ageism. Using 815,428 individual observations pooled across country–year surveys from 56 countries between 2009 and 2018, we found that older women were least likely to enter entrepreneurship. And this intersectional disadvantage could be mitigated by weakening the normative exclusion and possessing resource endowments that signal capability. However, strategies focused …
Gubernatorial Re-Election Incentives, Local Investment Bias, And Pension Fund Performance, Hongxian Zhang, Liang Guo, Jun Hao, Yu Liu
Gubernatorial Re-Election Incentives, Local Investment Bias, And Pension Fund Performance, Hongxian Zhang, Liang Guo, Jun Hao, Yu Liu
Business and Information Technology Faculty Research & Creative Works
We investigate the impact of gubernatorial re-election incentive and political factors on US public pension funds from 1990 to 2022. Our empirical analysis finds no significant overall relationship between gubernatorial re-election incentives and local bias in the full sample. However, the effect of gubernatorial re-election incentives on local bias is influenced by a state's level of corruption. Specifically, in states within the lowest corruption quantile, governors eligible for re-election tend to prioritize local investments to gain consistent support. In contrast, in states within the highest corruption quantile, heightened scrutiny may encourage re-election-eligible governors to adopt conservative investment policies that do …
Counterfactual Indeterminacy Bias In Family Firm Research, Chevy-Hanqing Fang, James J. Chrisman, Alfredo De Massis
Counterfactual Indeterminacy Bias In Family Firm Research, Chevy-Hanqing Fang, James J. Chrisman, Alfredo De Massis
Business and Information Technology Faculty Research & Creative Works
Ever since scholars recognized that family firms are heterogeneous, many studies have attempted to compare different types of family firms without ensuring that the source of heterogeneity is unique to family firms. When the source of heterogeneity among family firms resembles the source of heterogeneity among nonfamily firms, the problem of counterfactual indeterminacy bias can lead to misleading or irrelevant findings that fail to distinguish the effects of family influence from factors that affect all firms. We delineate common forms of this bias and offer recommendations to prevent it in research on family firm behavior and performance.
Reflections On Linear B, (Part 15): Sign 81 In Linear A And The Egyptian Four-Headed Ram God, Gerald Leonard Cohen
Reflections On Linear B, (Part 15): Sign 81 In Linear A And The Egyptian Four-Headed Ram God, Gerald Leonard Cohen
Arts, Languages and Philosophy Faculty Research & Creative Works
This article makes several tentative suggestions, including:
1. Linear A sign 81 (antecedent of Linear B81) may be an abbreviated image (two heads) of the four-headed Egyptian ram god Banebdjedet, with the horizontal line designating his horns shifted downward to the middle of the character.
2. A few other Linear A characters (e.g., sign 305) may represent slight alterations of sign A81.
3. Linear A82 includes two sets of three short horizontal lines. Those might signify brightness, and in the case of Banebdjedet the brightness would be his wisdom.
Pahina: Precision-Aware Hierarchical In-Network Aggregation For Edge Distributed Training, Yingpu Nian, Bo Yi, Qiang He, Xingwei Wang, Geyong Min, Keqin Li, Sajal K. Das
Pahina: Precision-Aware Hierarchical In-Network Aggregation For Edge Distributed Training, Yingpu Nian, Bo Yi, Qiang He, Xingwei Wang, Geyong Min, Keqin Li, Sajal K. Das
Computer Science Faculty Research & Creative Works
The rise of edge intelligence is driving distributed machine learning toward a new paradigm of edge-collaborative computing. To overcome the severe communication bottleneck in this paradigm, In-Network Aggregation is a critical enabling technology. However, its effectiveness is fundamentally undermined by the profound resource heterogeneity of edge networks. Specifically, edge devices, adapting to hardware constraints, operate at varying numerical precisions, leading to significant data inflation as gradients are aggregated. Compounding this, unevenly distributed network resources and traditional, precision-oblivious routing strategies often misallocate critical, high-precision gradients to low-quality paths. This mismatch creates severe network congestion, crippling the efficiency of distributed training. To …
Fairrfl: Fair And Robust Federated Learning In The Presence Of Selfish Clients, Andrea Augello, Ashish Gupta, Giuseppe Lo Re, Sajal K. Das
Fairrfl: Fair And Robust Federated Learning In The Presence Of Selfish Clients, Andrea Augello, Ashish Gupta, Giuseppe Lo Re, Sajal K. Das
Computer Science Faculty Research & Creative Works
Federated Learning (FL) is a paradigm that enables collaborative machine learning without disclosing the local data of the participants. However, in real-world FL deployment scenarios, some unscrupolous clients may alter the training process to skew the global model towards their local optimum, unfairly prioritizing their data distribution. Their influence can degrade overall model performance for normal clients and reduce fairness in the system. We call this novel category of misbehaving clients 'selfish'. This work proposes a Fair and Robust strategy for aggregation in the Federated Learning (FL) server to mitigate the effect of Selfish clients (FairRFL). FairRFL incorporates a novel …
Future Mining: Learning For Safety And Security, Md Sazedur Rahman, Mizanur Rahman Jewel, Sanjay Madria
Future Mining: Learning For Safety And Security, Md Sazedur Rahman, Mizanur Rahman Jewel, Sanjay Madria
Computer Science Faculty Research & Creative Works
Mining industry is rapidly transforming into an AI-driven cyber-physical ecosystem where safety and operational reliability depend on robust perception, resilient communication, trustworthy distributed intelligence and continuous monitoring of miners and equipment. Real-world mining environments impose severe constraints like poor illumination, dust, occlusion, GPS-denied conditions, irregular underground topologies, and intermittent connectivity. These factors degrade perception quality, disrupt situational awareness, impair trajectory prediction and weaken the reliability of distributed learning systems. Emerging cyber-physical threats, including backdoor triggers, sensor spoofing, label-flip attacks and poisoned model updates, further jeopardize operational safety, particularly as mines increasingly adopt autonomous vehicles, humanoid assistance, and federated learning for …
Qura: Reinforcement Learning Based Routing For Quantum Networks, Tasdiqul Islam, Engin Arslan, Md Arifuzzaman
Qura: Reinforcement Learning Based Routing For Quantum Networks, Tasdiqul Islam, Engin Arslan, Md Arifuzzaman
Computer Science Faculty Research & Creative Works
Quantum routing deals with identifying a set of quantum repeaters to use to create entanglement between distant endpoints. Previous approaches proposed shortest-path and linear programming methods to find a solution to this problem. While the shortest path approach results in suboptimal performance, linear programming takes too long to find a solution as the network size and constraints increase. In this paper, we apply Deep Q-Reinforcement Learning (DQRL) to optimize routing in quantum networks both in terms of execution time and performance. The proposed Quantum Routing Algorithm (QuRA) first chooses which request to schedule among all requests. It then determines which …
Fleet: A Federated Learning Emulation And Evaluation Testbed For Holistic Research, Osama Abu Hamdan, Hao Che, Engin Arslan, Md Arifuzzaman
Fleet: A Federated Learning Emulation And Evaluation Testbed For Holistic Research, Osama Abu Hamdan, Hao Che, Engin Arslan, Md Arifuzzaman
Computer Science Faculty Research & Creative Works
Federated Learning (FL) presents a robust paradigm for privacy-preserving, decentralized machine learning. However, a significant gap persists between the theoretical design of FL algorithms and their practical performance, largely because existing evaluation tools often fail to model realistic operational conditions. Many testbeds oversimplify the critical dynamics among algorithmic efficiency, client-level heterogeneity, and continuously evolving network infrastructure. To address this challenge, we introduce the Federated Learning Emulation and Evaluation Testbed (FLEET). This comprehensive platform provides a scalable and configurable environment by integrating a versatile, framework-agnostic learning component with a high-fidelity network emulator. FLEET supports diverse machine learning frameworks, customizable real-world network …
Feddot: Defending Federated Learning Against Overwhelming Targeted Attacks, Priyesh Ranjan, Ashish Gupta, Federico Coro, Sajal K. Das
Feddot: Defending Federated Learning Against Overwhelming Targeted Attacks, Priyesh Ranjan, Ashish Gupta, Federico Coro, Sajal K. Das
Computer Science Faculty Research & Creative Works
Federated Learning (FL), which facilitates collaborative model training and protects users' privacy, has drawn great interest from the research community. With FL, participants train their models on local data and submit the corresponding updates for aggregation to a server. While concealing the identities of the participants, FL may attract adversaries in order to hamper the underlying model. In this paper, we propose an FL framework, FedDOT, to defend against adversaries performing targeted attacks. FedDOT incorporates two powerful defense algorithms, Maximum Spanning Tree based attacker detection (MSTAD) and Densest graph-based attacker detection (Density-AD), which leverage correlation between weight updates and graph …
You Only Need One Stage: Novel-View Synthesis From A Single Blind Face Image, Taoyue Wang, Xiang Zhang, Xiaotian Li, Huiyuan Yang, Lijun Yin
You Only Need One Stage: Novel-View Synthesis From A Single Blind Face Image, Taoyue Wang, Xiang Zhang, Xiaotian Li, Huiyuan Yang, Lijun Yin
Computer Science Faculty Research & Creative Works
We propose a novel one-stage method, NVB-Face, for generating consistent Novel-View images directly from a single Blind Face image. Existing approaches to novel-view synthesis for objects or faces typically require a high-resolution RGB image as input. When dealing with degraded images, the conventional pipeline follows a two-stage process: first restoring the image to high resolution, then synthesizing novel views from the restored result. However, this approach is highly dependent on the quality of the restored image, often leading to inaccuracies and inconsistencies in the final output. To address this limitation, we extract single-view features directly from the blind face image …
Dynamic Hub-Aware Knowledge Distillation For Efficient Traffic Flow Forecasting, Xiangjie Kong, Can Shu, Wenchao Weng, Zhenzhen Zhao, Guojiang Shen, Lei Wang, Sajal K. Das
Dynamic Hub-Aware Knowledge Distillation For Efficient Traffic Flow Forecasting, Xiangjie Kong, Can Shu, Wenchao Weng, Zhenzhen Zhao, Guojiang Shen, Lei Wang, Sajal K. Das
Computer Science Faculty Research & Creative Works
Real-time traffic forecasting acts as a critical enabling service for IoT-driven Intelligent Transportation Systems (ITS). While existing Spatiotemporal Graph Neural Networks (STGNNs) achieve superior forecasting accuracy, their intensive computational complexity and high latency create a deployment bottleneck for resource-constrained IoT edge devices. To address this resource-accuracy mismatch, we propose a novel framework termed Dynamic Hub-Aware Knowledge Distillation (DHKD). Unlike traditional uniform distillation paradigms, DHKD introduces a topology-aware strategy to transfer knowledge from a complex teacher to a lightweight Spatiotemporal Multi-Layer Perceptron (STMLP) student model. Specifically, we design a dynamic hub-aware gating (DHAG) mechanism that adaptively identifies time-varying pivotal sensing nodes …
Dcmm-Transformer: Degree-Corrected Mixed-Membership Attention For Medical Imaging, Huimin Cheng, Xiaowei Yu, Shushan Wu, Luyang Fang, Chao Cao, Jing Zhang, Tianming Liu, Dajiang Zhu, Wenxuan Zhong, Ping Ma
Dcmm-Transformer: Degree-Corrected Mixed-Membership Attention For Medical Imaging, Huimin Cheng, Xiaowei Yu, Shushan Wu, Luyang Fang, Chao Cao, Jing Zhang, Tianming Liu, Dajiang Zhu, Wenxuan Zhong, Ping Ma
Computer Science Faculty Research & Creative Works
Medical images exhibit latent anatomical groupings, such as organs, tissues, and pathological regions, that standard Vision Transformers (ViTs) fail to exploit. While recent work like SBM-Transformer attempts to incorporate such structures through stochastic binary masking, they suffer from non-differentiability, training instability, and the inability to model complex community structure. We present DCMM-Transformer, a novel ViT architecture for medical image analysis that incorporates a Degree-Corrected Mixed-Membership (DCMM) model as an additive bias in self-attention. Unlike prior approaches that rely on multiplicative masking and binary sampling, our method introduces community structure and degree heterogeneity in a fully differentiable and interpretable manner. Comprehensive …
Utility-Preserving Federated Graph Learning With Dual-Perspective Fairness, Renqiang Luo, Huafei Huang, Shuo Yu, Fengqi Yu, Feng Xia, Sajal K. Das, Chengqi Zhang
Utility-Preserving Federated Graph Learning With Dual-Perspective Fairness, Renqiang Luo, Huafei Huang, Shuo Yu, Fengqi Yu, Feng Xia, Sajal K. Das, Chengqi Zhang
Computer Science Faculty Research & Creative Works
Fairness-aware federated graph neural networks (FedGNNs) necessitate consideration of both the server and the clients. However, fairness-aware methods struggle to enhance dual-perspective (i.e., server and clients) fairness without sacrificing utility due to the distributed learning framework. As a consequence, the utility sacrifices of fairness-aware graph learning methods are even exacerbated in federated frameworks. In this work we propose F3GL, a dual-perspective fairness federated graph learning method that enhances both global (for the server) and local fairness (for clients) while preserving utility. Through theoretical analysis, we delineate the similarity between original sensitive features and those after convolution under different spectra. Our …
Explaining The Unseen: Multimodal Vision-Language Reasoning For Situational Awareness In Underground Mining Disasters, Mizanur Rahman Jewel, Mohamed Elmahallawy, Sanjay Kumar Madria, Samuel Frimpong
Explaining The Unseen: Multimodal Vision-Language Reasoning For Situational Awareness In Underground Mining Disasters, Mizanur Rahman Jewel, Mohamed Elmahallawy, Sanjay Kumar Madria, Samuel Frimpong
Computer Science Faculty Research & Creative Works
Underground mining disasters produce pervasive darkness, dust, and collapses that obscure vision and make situational awareness difficult for humans and conventional systems. To address this, we propose MDSE, Multimodal Disaster Situation Explainer, a novel vision-language framework that automatically generates detailed textual explanations of post-disaster underground scenes. MDSE has three-fold innovations: (i) Context-Aware Cross-Attention for robust alignment of visual and textual features even under severe degradation; (ii) Segmentation-aware dual pathway visual encoding that fuses global and region-specific embeddings; and (iii) Resource-Efficient Transformer-Based Language Model for expressive caption generation with minimal compute cost. To support this task, we present the Underground Mine …
Aim5b: Ai Integrated Semantic Framework For 5g And Beyond Network Management, Thanveer Sulthana, Ava Sharif Jourabchi, Venkat Rao Manavarthi, Jayadithya Nalajala, Ankitha Srirama Reddy, Baek Young Choi, Sejun Song
Aim5b: Ai Integrated Semantic Framework For 5g And Beyond Network Management, Thanveer Sulthana, Ava Sharif Jourabchi, Venkat Rao Manavarthi, Jayadithya Nalajala, Ankitha Srirama Reddy, Baek Young Choi, Sejun Song
Computer Science Faculty Research & Creative Works
Scalable, interpretable, and intelligent network monitoring and management are critical for 5 G and future networks. This paper introduces Aim5B, an AI-integrated semantic framework for 5 G and beyond network management to address these challenges. Aim5B processes unstructured logs from key 5G core network functions, and transforms them into a knowledge graph aligned with the semantic structure of control-plane events. Leveraging a large language model (LLM), Aim5B enables natural language queries to be translated into Cypher graph queries, facilitating precise log retrieval, event analysis, temporal correlation, and statistical summarization-without relying on static parsing rules or predefined dashboards. Integrated on a …
Escher: Efficient And Scalable Hypergraph Evolution Representation With Application To Triad Counting, S. M. Shovan, Arindam Khanda, Sanjukta Bhowmick, Sajal K. Das
Escher: Efficient And Scalable Hypergraph Evolution Representation With Application To Triad Counting, S. M. Shovan, Arindam Khanda, Sanjukta Bhowmick, Sajal K. Das
Computer Science Faculty Research & Creative Works
Higher-order interactions beyond pairwise relationships in large complex networks are often modeled as hypergraphs. Analyzing hypergraph properties such as triad counts is essential, as hypergraphs can reveal intricate group interaction patterns that conventional graphs fail to capture. In realworld scenarios, these networks are often large and dynamic, introducing significant computational challenges. Due to the absence of specialized software packages and data structures, the analysis of large dynamic hypergraphs remains largely unexplored. Motivated by this gap, we propose ESCHER, a GPU-centric parallel data structure for Efficient and Scalable Hypergraph Evolution Representation, designed to manage largescale hypergraph dynamics efficiently. We also design …
Long Short-Term Memory (Lstm) -Based Neural Network Model For Optimizing Composite Manufacturing Process Using Autoclave, Sourav Bolar, Steven Corns, Nayan Pundhir, Kumbla Chandrashekhara
Long Short-Term Memory (Lstm) -Based Neural Network Model For Optimizing Composite Manufacturing Process Using Autoclave, Sourav Bolar, Steven Corns, Nayan Pundhir, Kumbla Chandrashekhara
Engineering Management and Systems Engineering Faculty Research & Creative Works
Producing high-quality fiber-reinforced composites requires precise temperature control during autoclave curing, as even small variations can lead to defects that compromise strength and reliability. At the same time, manufacturers aim to reduce energy use and shorten curing cycles without sacrificing material performance. To address these challenges, this study develops a data-driven Long Short-Term Memory (LSTM) neural network model capable of forecasting temperature evolution inside the autoclave throughout the curing cycle. The model is trained on time-series temperature data collected from multiple sensing locations, enabling it to learn the spatial and temporal trends that govern heat flow during curing. Data augmentation …
Work-In-Progress: Evaluating Feasibility Of Band Matrix Solvers For Scaling Up Extreme Learning Machine Method, Anton Akusok, Kaj Mikael Björk, Amaury Lendasse, Leonardo Espinosa Leal
Work-In-Progress: Evaluating Feasibility Of Band Matrix Solvers For Scaling Up Extreme Learning Machine Method, Anton Akusok, Kaj Mikael Björk, Amaury Lendasse, Leonardo Espinosa Leal
Engineering Management and Systems Engineering Faculty Research & Creative Works
This work presents the results of the potential of band linear system solvers for improving the scalability of the Extreme Learning Machine (ELM) method at large model sizes. The model is tested on the standard MNIST dataset with a range of solvers provided by the SciPy Python library. The results are analyzed taking into consideration the overall performance and the performance impact of band solvers across different matrix bandwidths, as well as the performance versus runtime analysis. The findings show potential in applying the proposed method to very large ELM models with narrow band matrices.
Evaluating The Use Of Machine Learning For Road Maintenance Cost Estimation, Shahla Shirinzad, David Enke
Evaluating The Use Of Machine Learning For Road Maintenance Cost Estimation, Shahla Shirinzad, David Enke
Engineering Management and Systems Engineering Faculty Research & Creative Works
Accurate estimation of highway maintenance costs is essential for efficient resource allocation and long-term infrastructure sustainability. This study evaluates the effectiveness of advanced machine learning models, including ResNet, Transformer, and other neural network architectures, for forecasting maintenance costs using historical data from the Highway Maintenance Improvement Program (HMIP) provided by the North Carolina Department of Transportation (NC DOT). A comprehensive comparative analysis is conducted across multiple models using standard performance metrics, including R2, MAE, RMSE, and MSE. The results demonstrate that advanced architectures, particularly ResNet and Transformer, consistently outperform traditional statistical approaches and baseline machine learning models, achieving …
Digital Twin Freshness Maximization In Edge Computing, Jing Li, Jianping Wang, Weifa Liang, Quan Chen, Sajal K. Das, Xiaohua Jia
Digital Twin Freshness Maximization In Edge Computing, Jing Li, Jianping Wang, Weifa Liang, Quan Chen, Sajal K. Das, Xiaohua Jia
Computer Science Faculty Research & Creative Works
Mobile Edge Computing (MEC) shifts powerful computing resource provisioning from remote powerful data centers to the edge of core networks. Meanwhile, Digital Twin (DT) has surfaced as a promising technology to provide comprehensive and dynamic descriptions of physical objects in cyberspace with bidirectional and real-time interactions. Moreover, Internet of Things (IoT) devices have contributed abundant, heterogeneous and continuous data from interconnected devices to the explosion of DTs. With technologies evolution, there is an increasing necessity to address the freshness of both DT states and DT data, through timely synchronizations between DTs and their objects in a highly dynamic IoT environment. …
On-Device Artificial Intelligence Solutions With Applications To Smart Environments, Fabrizio De Vita, Dario Bruneo, Sajal K. Das
On-Device Artificial Intelligence Solutions With Applications To Smart Environments, Fabrizio De Vita, Dario Bruneo, Sajal K. Das
Computer Science Faculty Research & Creative Works
Recent advances in Artificial Intelligence (AI) and the increasing availability of computational power have accelerated the diffusion of Intelligent Cyber-Physical Systems (ICPSs), enabling smart applications with reasoning capabilities. However, the limited resources of embedded and Edge devices significantly constrain the complexity of deep learning models that can be effectively deployed. Traditional approaches rely on cloud-based training and edge-only inference, a paradigm that becomes inadequate when low latency, privacy, security, and high customization are required. In this context, On-device AI is emerging as a new paradigm in which both training and inference are performed directly on the device, avoiding data transfer …
A Four-Step Thermocatalytic Route For Converting Co2 Into High-Purity Oxalic Acid, Hao Feng, Muhammad Kashif Khan, Lei Li, Hongyan Ma, Xinhua Liang
A Four-Step Thermocatalytic Route For Converting Co2 Into High-Purity Oxalic Acid, Hao Feng, Muhammad Kashif Khan, Lei Li, Hongyan Ma, Xinhua Liang
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
This research outlines a four-step methodology for transforming CO2 into high-purity oxalic acid. CO2 was first sequestered as KHCO3 through its reaction with aqueous KOH, followed by hydrogenation using a supported AgPd/CNT catalyst in a batch reactor at an initial H2 pressure of 60 bar and a temperature of 150°C. The formate yield reached 91.8% at optimum conditions. Potassium formate in the solid state was thermally coupled in the presence of KOH at 400°C under N2 flow, yielding potassium oxalate of up to 76% yield. The final step was the selective precipitation of potassium oxalate with ferrous …
Concerted Proton Transfer In Homogeneous And Heterogeneous Cyclic Hydrogen-Bonded Clusters Of H2o, Hf, And Hcl, Max R. Tucker, Yuan Xue, Nathan R. Speake, Eden Nickolson, Jeremy M. Carr, Gregory S. Tschumper
Concerted Proton Transfer In Homogeneous And Heterogeneous Cyclic Hydrogen-Bonded Clusters Of H2o, Hf, And Hcl, Max R. Tucker, Yuan Xue, Nathan R. Speake, Eden Nickolson, Jeremy M. Carr, Gregory S. Tschumper
Chemistry Faculty Research & Creative Works
This work examines various homogeneous and heterogeneous clusters of hydrogen-bonded (HF)x(H2O)y(HCl)z complexes, where x + y + z = 3 or 4. For each unique cyclic structure associated with the xyz permutations, the geometries of the reactant, product, and transition state (TS) for concerted proton transfer (CPT) were fully optimized using second-order Møller-Plesset perturbation theory (MP2) with a mixed basis set consisting of cc-pVTZ for H atoms and aug-cc-pVTZ for O, Cl, and F atoms (denoted haTZ). Harmonic vibrational frequencies were also computed at the same level of theory to verify the nature of the stationary points. Intrinsic …
Volatile Organic Compound Analysis Of Humboldt Penguin (Spheniscus Humboldti) Preen Oil: A Pilot Study, Dante E. Rojas, Mitchell M. Mccartney, Eva Borras, Michael O. Eze, Abigail Pietrow, Jennifer J. Valvo, Cristina E. Davis
Volatile Organic Compound Analysis Of Humboldt Penguin (Spheniscus Humboldti) Preen Oil: A Pilot Study, Dante E. Rojas, Mitchell M. Mccartney, Eva Borras, Michael O. Eze, Abigail Pietrow, Jennifer J. Valvo, Cristina E. Davis
Chemistry Faculty Research & Creative Works
Avian olfaction has gained prominence in recent decades for its roles in social communication and behavior. In penguins, the chemical characterization of preen oil remains limited. In this exploratory study, we characterized the volatile organic compound (VOC) profile of preen oil from Humboldt Penguins (Spheniscus humboldti). Preen oil from 12 captive individuals was analyzed using headspace sorptive extraction (HSSE) coupled to gas chromatography–mass spectrometry (GC–MS). Chemometric analyses examined variation in VOC profiles by sex, age class, and breeding activity. We detected 54 compounds (20 tentatively identified), including linear alcohols, methyl ketones, carboxylic acids, saturated hydrocarbons, oxygenated and nitrogen-containing organics, prenolipids, …
Synthesis Of The Naga(S1−Xsex)2 Solid Solution From Mechanically Activated Precursors, Louisiane Verger, Julien Trébosc, Santhoshkumar Sundaramoorthy, Amitava Choudhury, Olivier Hernandez, Eric Furet, Sébastien Chenu, David Le Coq, Laurent Calvez, Olivier Lafon
Synthesis Of The Naga(S1−Xsex)2 Solid Solution From Mechanically Activated Precursors, Louisiane Verger, Julien Trébosc, Santhoshkumar Sundaramoorthy, Amitava Choudhury, Olivier Hernandez, Eric Furet, Sébastien Chenu, David Le Coq, Laurent Calvez, Olivier Lafon
Chemistry Faculty Research & Creative Works
NaGaS2 and NaGaSe2 are two recently discovered compounds that crystallize in the same structure type. In this work, NaGa(S1−xSex)2 (x = 0.5, 0.75 and 1) are prepared using an alternative synthesis route, mechanochemistry followed by heat treatment. Na2S, Na2Se, Ga2S3 and Ga2Se3 are milled in stoichiometric proportions. Differential scanning calorimetry, X-ray diffraction and solid-state nuclear magnetic resonance (23Na and 71Ga) show that the compounds after milling are composed of crystalline NaGa(S1−xSex)2 with an amorphous part. …
Soft-Chemical Scalable One-Pot Aqueous-Medium Synthesis Of Na3(Vo)2(Po4)2f-Based Cathodes: Compositional Tuning And Electrochemical Performance In Na- And Li-Ion Batteries, Prashanth Sandineni, Subal Chandra Manna, Sutapa Bhattacharya, Santhoshkumar Sundaramoorthy, Ramesh Deokate, Milad Aghayi-Anaraki, George E. Sterbinsky, Kartik Ghosh, Amitava Choudhury
Soft-Chemical Scalable One-Pot Aqueous-Medium Synthesis Of Na3(Vo)2(Po4)2f-Based Cathodes: Compositional Tuning And Electrochemical Performance In Na- And Li-Ion Batteries, Prashanth Sandineni, Subal Chandra Manna, Sutapa Bhattacharya, Santhoshkumar Sundaramoorthy, Ramesh Deokate, Milad Aghayi-Anaraki, George E. Sterbinsky, Kartik Ghosh, Amitava Choudhury
Chemistry Faculty Research & Creative Works
One of the most important cathode materials for Na-ion batteries, Na3(VO)2(PO4)2F, and its compositional variants have been synthesized using four different and facile one-step soft chemical routes. The as-synthesized compounds, Na2.95(VO)2(PO4)2F (I), Na2.93(VO)2(PO4)2F (II), and Na2.58(VO)2(PO4)2F (IV), crystallize in the tetragonal crystal system in the P42/mnm space group, while Na3(VO)2(PO4)2F (III) crystallizes in the orthorhombic crystal system in …
Flow Regime-Independent Two-Group Interfacial Area Concentration Model For Dispersed Gas-Liquid Flows In Large-Diameter Pipes, Hossein Barati, Takashi Hibiki, Joshua P. Schlegel, Naofumi Tsukamoto
Flow Regime-Independent Two-Group Interfacial Area Concentration Model For Dispersed Gas-Liquid Flows In Large-Diameter Pipes, Hossein Barati, Takashi Hibiki, Joshua P. Schlegel, Naofumi Tsukamoto
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
In many power plants, boiling can result in two-phase flows during normal and accident conditions. Heat and mass transfers through the gas-liquid interface in a two-phase flow process are proportional to the interfacial area concentration (IAC). These calculations for nuclear systems are typically performed using advanced system analysis codes such as TRACE. TRACE uses a two-group (2G) model, where bubbles are divided into two groups according to their drag coefficients. Correlations are used to calculate the group-wise void fractions (VFs) and IACs. This study evaluates the accuracy of the TRACE 2G VF and IAC models for vertically upward dispersed flows …
Implementation Of Tritium Transport In A Gas-Liquid Contactor Cfd Simulation Of Tritium Extraction From Lead-Lithium In Ansys Fluent, Anthony G. Bowers, Subash L. Sharma, Thomas F. Fuerst
Implementation Of Tritium Transport In A Gas-Liquid Contactor Cfd Simulation Of Tritium Extraction From Lead-Lithium In Ansys Fluent, Anthony G. Bowers, Subash L. Sharma, Thomas F. Fuerst
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
Modifications to the Computational Fluid Dynamic (CFD) software ANSYS Fluent were done to quantify and characterize tritium transport in gas-liquid contactors (GLCs). A double-slit, Ergun-like equation was employed for the porous media model, with Ergun coefficients validated with Sulzer's Sulcol software. Tritium transport from PbLi within the GLC was verified against analytical models. The geometry of the CFD model was based on the MELODIE GLC experiment. The hydrodynamic CFD pressure drop results align well with Sulcol estimations and fall between the predictions of the analytical Delft-Olujić and Billet and Schultes models. In terms of mass transfer efficiency, traditional mass transfer …