Digital Commons Network^™

Mechanism Of Improved Miscibility Of Co2–Oil Systems By Multiester-Headgroup Surfactants, Ning Xu, Yanling Wang, Baojun Bai, Yu Zhang, Wenjing Shi, Zhaonian Zhang, Wenhui Ding, Peixu Ma, Zan Gao

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

In the pursuit of carbon neutrality, the CO₂-enhanced oil recovery provides dual benefits by enabling both carbon sequestration and incremental oil production. However, its application is limited by high minimum miscibility pressure. CO₂-philic and oil-affinitive surfactants have emerged as an effective, low-dosage, and cost-efficient strategy to reduce the minimum miscibility pressure. In this study, macroscopic phase behavior experiments combined with molecular dynamics simulations were employed to systematically elucidate the influence of multiester-head surfactants on CO₂–oil miscibility. Using a modified pressure–volume–temperature apparatus equipped with optical power monitoring, we determined that multiester-head surfactants reduced the first-contact …

Uptake And Fate Of Silver And Zinc Engineered Nanoparticles In Maize Under Single And Binary Dosing Soil Ecosystems, Lei Xu, Qingbo Yang, Xingmao Ma, Honglan Shi, John Yang, Hu Yang, Samira Mahdi, Ying Wang, Young Shin Jun

Chemistry Faculty Research & Creative Works

Recent agricultural applications of engineered metallic nanoparticles (ENPs) have raised concerns about their uptake and fate in plants. To understand this critical issue, this study investigated the fate and uptake of silver (Ag) and zinc oxide (ZnO) ENPs in maize (Zea mays L.) after single or binary ENP exposure in soil. Results indicated that both Zn and Ag elemental concentrations in roots increased with increasing ENP dosage. Ag NPs in the tissues were detected, but not Zn NPs. Ag NP concentration was 3 times higher in the roots than in the shoots at low Ag NP dosing, while Ag NP …

Rioi: A Microwave-Photonic Rf-Interferometric Interrogation Technique For Enhanced Fiber Optic Sensing, Chen Zhu, Ruimin Jie, Chenxi Huang, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

Fiber optic interferometric (FOI) sensors are widely recognized for their high sensitivity, design flexibility, and multiplexing capabilities, making them ideal for applications ranging from structural health monitoring to biomedical diagnostics. However, conventional optical-domain interrogation techniques are often limited by the performance constraints of spectrometers. In this work, we present a radiofrequency (RF)-interferometric optical interrogation (RIOI) method for FOI sensors. This approach leverages microwave photonic (MWP) processing to encode the optical interference phase into an RF signal, which is then combined with a reference RF signal to produce a microwave-domain interferogram. By tracking spectral shifts in the RF domain, RIOI achieves …

Sulfuric Acid Mist Generation, Calculation, And Suppression Mechanism And Methods In Electrowinning: A Review, Ashish Kakoria, Mirza Muhammad Zaid, Guang Xu

Mining Engineering Faculty Research & Creative Works

This review discusses the events of acid mist production at the final stage of hydrometallurgical metal production in copper electrowinning. This review entails the complete process of oxygen bubble generation on the anode and its stages to form into acid mist at the surface of the electrolyte. When these bubbles burst at the solution/air interface, fine acid-containing liquid droplets become airborne and spread throughout the workspace, with the impact factors suppressing the acid mist produced during the process. Also, parameters such as bubble size, temperature, surface tension, and visco-elasticity also affect the acid mist. Sulfuric acid affects the tank houses …

Electroenzymatic Cascades For Nitrogen Upgrading: Beyond Ammonia Towards Value-Added Nitrogen Chemicals, Rohit G. Jadhav, Vamshi Krishna Kamaja, Wassim El Housseini, Monica Brachi, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

The global transition toward sustainable chemical manufacturing demands technologies that leverage natural carbon and nitrogen cycles while minimizing reliance on sacrificial reagents and fossil resources. These biogeochemical cycles are fundamental to life, and enzymes catalyze many of their key transformations. Bio electrochemical, specifically electroenzymatic, systems offer a promising route to sustainable synthesis by enabling selective redox transformations powered by electricity. However, whereas carbon-cycle enzymes are now well established in bio electrochemical synthesis, enzymes from the nitrogen cycle remain comparatively underexplored. Moreover, the nitrogen cycle alone does not access many value-added nitrogen-containing products, which require additional C-N bond formation and organic …

Quantum Scattering Of Hc5n And Para-H2 On A New Potential Energy Surface, Shan Gao, François Lique, Ernesto Quintas-Sánchez, Richard Dawes, Jérôme Loreau

Chemistry Faculty Research & Creative Works

In the interstellar medium (ISM), non-local thermodynamic equilibrium situations are common due to low density, and one needs to consider the effect of molecular collisions in order to interpret the observations. Among the species detected in the ISM, cyanopolyynes, with the general molecular formula HC_2n+1N (n = 1, 2, …), are characterized by large dipole moments and small rotational constants and constitute an indispensable class of candidates for the sensitive tracers of local density and temperature. We present a study of the collisional (de-) excitation of HC₅N by para-H₂ (p-H₂) in its ground …

Mental Models Of Autonomy And Sentience Shape Reactions To Ai, Janet V.T. Pauketat, Daniel Burton Shank, Aikaterina Manoli, Jacy Reese Anthis

Psychological Science Faculty Research & Creative Works

Narratives about artificial intelligence (AI) entangle autonomy, the capacity to self-govern, with sentience, the capacity to sense and feel. AI agents that perform tasks autonomously and companions that recognize and express emotions may activate mental models of autonomy and sentience, respectively, provoking distinct reactions. To examine this possibility, we conducted three pilot studies (N = 374) and four preregistered vignette experiments describing an AI as autonomous, sentient, both, or neither (N = 2,702). Activating a mental model of sentience increased general mind perception (cognition and emotion) and moral consideration more than autonomy, but autonomy increased perceived threat more than sentience. …

Characterizing User-Reported Risks Across Llm Chatbots, Lingyao Li, Renkai Ma, Zhaoqian Xue, Junjie Xiong

Computer Science Faculty Research & Creative Works

As Large Language Models (LLMs) become increasingly integral to daily life, users are engaging with multiple LLM chatbots for various needs; however, prior research on LLM risks often remains lab-based or focuses on single LLMs like ChatGPT or singular risks like privacy. To gain a multi-risk, cross-chatbot understanding of user experiences, we analyze Reddit discussions around seven major LLM chatbots using the NIST AI Risk Management Framework. We find that user-reported risks are unevenly distributed and chatbot-specific: ChatGPT is associated with safety and fairness concerns, Gemini with privacy, and Claude with security and resilience. Less frequent risks, such as explainability …

Quantitative Phase-Field Modeling Of Nonequilibrium Microstructural Evolution In Rapid Solidification For Additive Manufacturing, Leiji Li, Fei Xiao, Ying Zhou, Xiaorong Cai, Chongfeng Zhang, Jinzhong Gao, Xiaopeng Shen, Tianchi Zhu, Sihan Wang, Yijia Gu, Xuejun Jin

Materials Science and Engineering Faculty Research & Creative Works

Fusion-based metal additive manufacturing (AM) relies on layer-by-layer deposition and rapid solidification, where the material transitions swiftly from liquid to solid. A key phenomenon during this process is solute trapping, a nonequilibrium effect governed by a velocity-dependent partition coefficient, which critically influences microstructure kinetics, morphology, and phase formation. In this study, we employ a recently proposed quantitative phase field (PF) model to systematically explore solute trapping, solute drag, and their impacts on pattern formation during rapid solidification at AM-relevant velocities, in both one and two dimensions. Our simulations reveal a growth mode transition from planar to cellular to dendritic, and …

Evaluating Fine-Scale Air-Quality Heterogeneity Using A Low-Cost Multipollutant Sensor Network In Twin Cities, Minnesota, Varuni Abhayaratne, Weixing Hao, Chen Ye, Anjana Yatawara, Philip K. Hopke, Jiayu Li, Yang Wang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

There is growing interest and effort in deploying low-cost sensors (LCSs) to understand fine-scale spatiotemporal heterogeneity of ambient air pollutants in urban areas. The Assessing Urban Air Quality project conducted by the Minnesota Pollution Control Agency deployed 45 low-cost air-quality monitors (AQMesh, Environmental Instruments Ltd.) in the Minneapolis/St. Paul metropolitan area network. Hourly averaged pollutant concentrations or mixing ratios for carbon monoxide (CO), ozone (O₃), nitrogen dioxide (NO₂), nitric oxide (NO), and sulfur dioxide (SO2), as well as particulate matter (PM), including PM1, PM2.5, and PM10, were obtained. The network data from June 2019 to June …

Sex-Based Effects Of Shock Energy Exposure In Warfighters, Melissa Sutter, Catherine Johnson

Mining Engineering Faculty Research & Creative Works

Personal armors were initially designed to fit against the male torso, as men previously filled roles requiring them, thus not made to accommodate the female anatomy. As a result, armor worn by female warfighters tends to have non-form fit in the waist, armpit, bust, and collarbone areas, causing reduced coverage. Shifting, riding up, air gaps, breathing difficulty, and physical discomfort have also been observed. Although this has been documented, the impact on the armor's protective capabilities has not been well studied. To address this, this study compared the protective capabilities of unisex armor for male and female warfighters from shock …

Indirect Carbonation Of Fbc Ash For Sustainable Production Of Caco3 And Reactive Pozzolanic Residues, Suhawn Ju, Heejung Jun, Seongho Han, Minseok Kim, Soohyun Song, Mingi Cho, Sukhoon Pyo, Jinyoung Yoon

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study investigates the potential of indirect carbonation for CO₂ sequestration and high-purity CaCO₃ production using fluidized bed combustion (FBC) fly ash (FFA) and bottom ash (FBA). XRF and XRD analyses revealed high reactive CaO contents derived from lime, portlandite, and anhydrite. Calcium extraction using 1- mol NH₄Cl achieved markedly higher efficiency than deionized (DI) water, yielding up to 17,586 mg/L of Ca²⁺ and producing 10.2 wt.% and 8.4 wt.% CaCO₃ from FFA and FBA, respectively, with CO₂ capture capacities of 45.0 and 36.8 kg per ton of ash. The precipitated CaCO₃ exhibited …

Exploring Scms And Fibers For Structural Build-Up In 3d Printing Using Penetration Test, Shiva Kumar Goud Kasani

Miners Solving for Tomorrow Research Conference

Additive manufacturing with cementitious materials advances rapidly, but predicting structural build-up is critical for 3D printed structure buildability. Various supplementary cementitious materials (SCMs) and fibers are commonly used to enhance structural build-up in 3D printing. Evaluating their effects is necessary for successful printing. In this research, this effect is studied for common SCMs, including fly ash and silica fume, and fibers including polypropylene (0.375% and 0.75% by volume), steel (0.75% and 1.5% by volume), and hemp fibers (0.375% and 0.75% by volume). The Structural build-up was quantified through continuous static yield stress measurements (via vane rheometer, penetration, and slump) during …

Synthesis And Hydrothermal Evaluation Of Poly(Styrene Phosphonate) For Conformance Control In Geothermal Reservoirs, Sara Mccauley

Miners Solving for Tomorrow Research Conference

As atmospheric carbon dioxide levels continue to rise, geothermal energy has emerged as a promising energy alternative to fossil fuels. A barrier to widespread implementation and energy production efficiency is macro-heterogeneity of the rock matrix. Cracks, void spaces, and flow conduits divert fluid flow away from unswept portions of the geothermal reservoir and can cause cooling of the reservoir. Flow heterogeneity has been treated in oil reservoirs by injecting hydrogel particles that travel preferentially to ultra-high permeability zones and selectively block fluid flow in these regions. We are applying polymer hydrogels that withstand hydrothermal conditions of 225 up to 275°C …

Adaptive Parallel Downloader For Large Genomic Datasets, Rasman Mubtasim Swargo

Miners Solving for Tomorrow Research Conference

Modern next-generation sequencing (NGS) projects routinely generate terabytes of data that researchers download from public repositories such as SRA and ENA. Existing download tools typically employ static concurrency settings, leading to inefficient bandwidth utilization and prolonged download times under dynamic network conditions. We introduce FastBioDL, a parallel downloader for large biological datasets with an adaptive concurrency controller. FastBioDL frames downloading as an online optimization problem, using a utility function and gradient descent to adjust the number of concurrent socket streams during runtime. This approach maximizes throughput while minimizing resource overhead. Evaluations on public genomic datasets show that FastBioDL achieves up …

Challenges And Best Practices Of Regional Innovation Ecosystems, Mahnaz Asgari Sooran

Miners Solving for Tomorrow Research Conference

Many places around the world are developing regional innovation ecosystems to spur regional economic. Many innovation ecosystems fail or barely maintain their initial momentum after a few years. In this paper, we identified challenges and best practices facing innovation ecosystems interviews with the innovation ecosystem stakeholders. We employed the MIT REAP (Regional Entrepreneurship Acceleration Program) model to categorize the five main stakeholders of the innovation ecosystem: entrepreneurs, universities, industry, risk capital, and government. Our initial results indicated the following: (a) Access to capital and talented workforce; (b) Stakeholder discovery process is one of the critical areas to understand the basic …

Introducing Gridtrees For Streaming, Scalable Hierarchical Data Visualization, Nathan Tibbetts

Miners Solving for Tomorrow Research Conference

File browsing in the consumer sphere has seen very little advancement in recent years, although attempts have been made to improve upon it. With the goal of multi-level visual file browsing in mind, we present a prototype GridTree, a dynamic, recursive, stable, spatial layout data structure based on subdividing grids, represented as a hierarchy of maps whose granularity increases with depth. We motivate this work with characteristics we have identified as important for viability of a multi-level file-browser, which have become our design goals. We touch on the underlying logic of a GridTree and identify its complexity. We briefly discuss …

Simulating Thermal Diffusion Through Image-Derived Microstructures Of Ceramic Matrix Composites, Matik Heskin

Miners Solving for Tomorrow Research Conference

Thermal energy transport in materials can be effectively modeled using finite element software such as COMSOL. Experimentally measured or NIST–JANAF thermal conductivity data can be used to represent material behavior within these simulations. For heterogeneous or composite materials, effective properties are often approximated using rule-of-mixtures calculations. However, this overlooks the nuanced effects caused by complex microstructural geometry. To address this limitation, imaging and coding tools such as MATLAB can be used to process scanning electron microscopy (SEM) images. By thresholding the images to distinguish constituent materials, a representative mesh can be generated and imported into an FEM program. This approach …

Thermal Mirage: Towards Robust Thermal Perception Via Gan-Guided Diffusion, Nuzaer Omar

Miners Solving for Tomorrow Research Conference

Thermal object detection systems are critical for safety sensitive applications due to their reliability under adverse conditions. However, existing robustness evaluations in thermal domain primarily focuses on physical or sensor-level perturbations, overlooking vulnerabilities from semantically realistic scene and object manipulations. We introduce Thermal Mirage, a generative framework that leverages GAN-guided diffusion to expose weaknesses in thermal detectors through controlled object and context level perturbations. Our approach learns class-conditional thermal priors via a GAN and uses diffusion to transform object appearances into ambiguous or low-saliency patterns. Simultaneously, a context module degrades scene conditions by simulating harsher night environments. Integrated with a …

Human Intention Prediction Using Cnn And Lstm Networks In Physical Human–Robot Interactions, Khosro Ghorbani Zadeh

Miners Solving for Tomorrow Research Conference

Advances in robotics and artificial intelligence have increased expectations for interactive robots in eldercare and assistive applications. A key challenge in creating safe and effective systems is accurately recognizing human intent and translating it into meaningful commands for robots to follow. Traditional physics-based models often fail to fully represent human force interactions due to their dynamic nature, while neural networks provide a promising alternative for predicting force-movement intentions. Multi-layer perceptrons (MLPs) show potential, however, they struggle with temporal dependencies and generalization. Long Short-Term Memory (LSTM) networks and Convolutional Neural Networks (CNNs) help address these limitations. This study compares these architectures …

Ai-Driven Frameworks For Mitigating Rockfall Hazards, Unstable Ground Condition And Improving Safety In Underground Mine Through Thermal Imaging, Akhrorbek Narmatov

Miners Solving for Tomorrow Research Conference

Scaling, the removal of loose rocks from excavation walls to prevent rockfalls is a critical safety procedure in underground mining operations. Approximately a quarter of fatal mining accidents are due to rockfalls. Detecting unstable rocks during scaling and assessing ground stability remain challenging due to limited visibility, dust, and environmental conditions.

Excavation disturbs the in-situ stress state, causing stress redistribution, fracture propagation, and the formation of discontinuities that lead to loose rock blocks. Ventilation airflow affects heat transfer at exposed surfaces, amplifying temperature contrasts between intact rock and fractured blocks associated with instability.

Current practices rely on manual inspection, requiring …

Robust Federated Learning With Strategic Adversaries, Manoj Twarakavi

Miners Solving for Tomorrow Research Conference

Federated Learning (FL) leverages the intelligence of untrusted distributed devices through collaborative training. This makes the training process susceptible to malicious behavior. Existing defense mechanisms largely consider an adversary who attacks a proactive FL server without any adaptability. However, they overlook the presence of a strategic adversary. To address this challenge, our work proposes a Robust Game-theoretic framework where the adversary is both strategic and is equipped with the capability of performing large-scale poisoning attacks.

Harnessing Wavefront Shaping Control For Sensing Applications, Pablo Jara

Miners Solving for Tomorrow Research Conference

Diffuse optical tomography (DOT) and functional near-infrared spectroscopy (fNIRS) enable deep, non-invasive sensing in biological tissue but are fundamentally limited by the photon budget - most injected light is lost to scattering before reaching the detector. Wavefront shaping (WFS) can enhance signal strength inside scattering media via interference, but the conventional diffusion-based sensitivity model breaks down under coherent illumination. We develop a microscopic theory of optical sensitivity that captures interference effects neglected by diffusion theory. We prove analytically that the microscopic and diffusive descriptions coincide under random illumination and identify WFS strategies that enhance sensitivity beyond this limit. The maximum …

Variational Data Assimilation With Steepest Descent Method For Coupled Time-Dependent Stokes-Darcy Model With Bjsj Interface Condition, Yafang Hei

Miners Solving for Tomorrow Research Conference

Variational data assimilation (VDA) determines the initial condition of a dynamical system by minimizing the mismatch between model predictions and observed data. This work studies VDA for the time-dependent Stokes–Darcy system with the BJSJ interface condition. The problem is formulated as a PDE-constrained optimization problem, and the first-order optimality system is derived using the Gâteaux derivative and adjoint variables. A steepest descent method is applied for efficient computation. Spatial and temporal discretizations are carried out using the finite element method and backward Euler scheme, respectively. Numerical results confirm accuracy and convergence.

Dispersive Shock And Rogue Waves In Two-Dimensional Quantum Droplets, Farhana Bristy

Miners Solving for Tomorrow Research Conference

Quantum droplets, are liquid type configurations stabilized by the balance between attractive mean-field interactions and repulsive quantum fluctuations. They provide highly flexible platforms for the quantum simulation of hydrodynamic phenomena using ultracold gases. Here, we explore the nonlinear quantum dynamics of two-dimensional quantum droplets under Riemann initial conditions. The steepness of the latter facilitates the emergence of radially symmetric dispersive shock waves (DSWs) when quantum fluctuations dominate. In particular, the ensuing DSWs travel from the potential edges toward the center where they collide and through their interference high amplitude spatially localized rogue wave structures emerge. In contrast, tuning the interactions …

Distributed Control Plane For Cross-Silo Federated Learning, Rabin Pandey

Miners Solving for Tomorrow Research Conference

Cross-silo federated learning (FL) trains shared models across geographically distributed institutions without centralizing raw data, but its reliance on wide-area networks makes round completion time highly sensitive to heterogeneous link conditions, congestion, and straggler clients. Existing SDN-based FL frameworks address this through centralized traffic engineering, an approach that breaks down when silos span independent administrative domains where no single entity can maintain complete, timely network knowledge. We replace the centralized control plane with a fully distributed overlay in which each silo gateway operates as an equal peer, continuously probing local links, exchanging EWMA-smoothed metrics via bounded gossip, and computing least-cost …

Transition Metal Chalcogenide As Multifunctional Biosenser To Detect Neurochemicals, Amitav Sen

Miners Solving for Tomorrow Research Conference

The development of highly sensitive real-time sensing platforms for selectively detecting dopamine (DA) and norepinephrine (NE) is of significant clinical importance since these are closely associated with several neurodegenerative disorders. Herein, we report copper telluride (Cu₂Te) nanostructure as a bifunctional electrocatalyst for the simultaneous detection of dopamine and norepinephrine. Cu₂Te exhibits excellent electrocatalytic activity toward both DA and NE oxidation, as demonstrated by detailed electrochemical measurements. High sensitivities of 24 and 40 µA cm⁻² µM⁻¹ for DA and NE, respectively, were obtained with a wide linear detection range of 10–200 nM and low limit of detection (LOD), 31 nM for …

Toward Sustainable 3d Printable Cementitious Materials: Low-Carbon Design With Fiber Reinforcement, Nima Mahmoudzadeh Vaziri

Miners Solving for Tomorrow Research Conference

3D printing of cementitious materials, as an emerging construction technology, faces challenges in both mechanical performance and sustainability. Conventional mixture designs rely on high cement contents, leading to increased CO2 emissions, while printed elements often exhibit brittle behavior with limited crack resistance and reduced post-cracking performance. This study investigates the development of low-carbon 3D printed cementitious composites using environmentally friendly supplementary cementitious materials (SCMs) and fillers, combined with fiber reinforcement to enhance mechanical performance. Locally available SCMs and fillers were incorporated to significantly reduce cement content (>40%) and improve sustainability. Fiber reinforcement was introduced to mitigate brittleness and enhance …

Scenario-Based Pareto Analysis For Multi-Objective Optimization Of Process Parameters To Improve Life Cycle Impacts: Case Study Of Ge Production, Dennis Dadzie

Miners Solving for Tomorrow Research Conference

Growing demand for critical minerals increases the need for clear evidence on the environmental burdens of their production. Life‑cycle assessment (LCA) quantifies impacts, but it does not by itself show how to navigate competing environmental performance improvement goals. We examine 63 process configurations for single‑crystal germanium made via chlorinated distillation using five indicators: global warming potential (GWP), water consumption (WC), fine particulate matter (FPM), terrestrial acidification (TA), and cumulative energy demand (CED). Across scenarios, WC is negatively correlated with GWP, weakly related to FPM, TA, and CED, while the other four indicators are strongly positively correlated. Pareto analysis highlights a …

Assessing Radon And Radon Progeny Deposition On Simulated Lung Filter System: Effects Of Cigarette And E-Cigarette Use Based On The Icrp Model, Manuela Isabel Arenas Alvarez

Miners Solving for Tomorrow Research Conference

This project investigates the potential interaction between radon exposure and e-cigarette aerosols, focusing on how radon progeny deposit in the lungs under combined conditions. An experimental system was developed to simulate regional lung deposition based on the International Commission on Radiological Protection (ICRP) model. The setup uses a filter-based design and a custom modular atomizer to generate stable aerosols, with four commercial plastic filters evaluated. Initial results demonstrate reproducible filtration behavior and a total deposition pattern matching ICRP predictions within 21% error. Ongoing work aims to improve agreement with regional deposition curves and enable combined radon–aerosol exposure experiments. This platform …