Digital Commons Network^™

Transfer-Learning-Enhanced Regression Generative Adversarial Networks For Optimal Evtol Takeoff Trajectory Prediction, Shuan Tai Yeh, Xiaosong Du

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Electric vertical takeoff and landing (eVTOL) aircraft represent a crucial aviation technology to transform future transportation systems. The unique characteristics of eVTOL aircraft include reduced noise, low pollutant emission, efficient operating cost, and flexible maneuverability, which in the meantime pose critical challenges to advanced power retention techniques. Thus, optimal takeoff trajectory design is essential due to immense power demands during eVTOL takeoffs. Conventional design optimizations, however, adopt high-fidelity simulation models in an iterative manner resulting in a computationally intensive mechanism. In this work, we implement a surrogate-enabled inverse mapping optimization architecture, i.e., directly predicting optimal designs from design requirements (including …

Exploring The Coronal Magnetic Field With Galactic Cosmic Rays: The Sun Shadow Observed By Hawc, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, K. P. Arunbabu, D. Avila Rojas, R. Babu, E. Belmont-Moreno, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, P. Colín-Farias, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, C. De León, D. Depaoli, R. Diaz Hernandez, J. C. Diaz-Velez, M. Durocher, M. A. Duvernois, K. Engel, C. Espinoza, K. L. Fan, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, A. Gonzalez Munoz, M. M. Gonzalez, J. A. Goodman, J. P. Harding, D. Huang, F. Hueyoyl-Zahuantitla, A. Iriarte, S. Kaufmann, A. Lara, J. Lee, H. Leon Vargas, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, E. Moreno, M. Mostafa, A. Nayerhoda, L. Nellen, T. Niembro, R. Noriega-Papaqui, N. Omodei, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, J. Ryan, H. Salazar, D. Salazar-Gallegos, A. Sandoval, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Turner, F. Urena-Mena, E. Varela, L. Villasenor, Xiaojie Wang, I. J. Watson, E. Willox, S. Yun-Carcamo, H. Zhou

Physics Faculty Research & Creative Works

Galactic cosmic rays (GCRs) are charged particles that reach the heliosphere almost isotropically in a wide energy range. In the inner heliosphere, the GCR flux is modulated by solar activity so that only energetic GCRs reach the lower layers of the solar atmosphere. In this work, we propose that high-energy GCRs can be used to explore the solar magnetic fields at low coronal altitudes. We used GCR data collected by the High-Altitude Water Cherenkov observatory to construct maps of GCR flux coming from the Sun's sky direction and studied the observed GCR deficit, known as Sun shadow (SS), over a …

The Bridge Newsletter Spring 2024, Missouri University Of Science And Technology

The Bridge Newsletter

• ASCE MidAmerica Student Symposium
• Bridge team wins sixth consecutive competition
• White awarded 2024 Fulbright Prize
• El-Adaway inducted into ISU Hall of Fame
• Williams signs on with The Kansas City Glory Women’s National Football team

Surface Coating Method For Cement-Based Materials To Improve Chloride Ion Penetration Resistance Using Amine-Based Co2 Solvent, Seongho Han, Tae Hoon Han, Jae Hong Kim

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The application of coatings on concrete surfaces serves as a protective shield, guarding the structure against chlorides and averting corrosion of the reinforcement, consequently enhancing its durability. This study investigates the resistance of cement mortar samples to chloride ion penetration when coated with an amine-based carbon dioxide (CO2) solvent. Various factors, including monoethanolamine (MEA) concentrations of 1, 10, and 30 wt.%; water-to-cement ratios (w/cm) of 0.35, 0.4, and 0.5; coating timings on day 3 and day 27; and pre-conditioning methods such as air drying, are investigated for their impact on the performance of chloride penetration resistance. Specifically, pre-conditioning significantly enhanced …

Statistical And Machine Learning Analysis In Brain-Imaging Genetics: A Review Of Methods, Connor L. Cheek, Peggy Lindner, Elena L. Grigorenko

Engineering Management and Systems Engineering Faculty Research & Creative Works

Brain-imaging-genetic analysis is an emerging field of research that aims at aggregating data from neuroimaging modalities, which characterize brain structure or function, and genetic data, which capture the structure and function of the genome, to explain or predict normal (or abnormal) brain performance. Brain-imaging-genetic studies offer great potential for understanding complex brain-related diseases/disorders of genetic etiology. Still, a combined brain-wide genome-wide analysis is difficult to perform as typical datasets fuse multiple modalities, each with high dimensionality, unique correlational landscapes, and often low statistical signal-to-noise ratios. In this review, we outline the progress in brain-imaging-genetic methodologies starting from early massive univariate …

Adipose Stem Cell Response To Borophosphate Bioactive Glass, Nada A. Abokefa, Bradley A. Bromet, Rebekah L. Blatt, Makenna S. Pickett, Richard K. Brow, Julie A. Semon

Materials Science and Engineering Faculty Research & Creative Works

Silicate and Borate Bioactive Glasses Have Been Reported to Create Alkaline Conditions by Rapidly Releasing Ions When Reacting in Aqueous Solution. at Certain Levels, This Alkaline Solution Can Negatively Affect Cell Viability. Adding Phosphate Ions to the Glass Composition Can Control the Degradation Rate of Bioactive Glasses and Create a Neutral PH Environment. This Study Evaluated a Series of Boro phosphate Bioactive Glasses (BPBGs) with Nominal Molar Compositions 16Na₂O_-24CaO-XB₂O₃-(60-X) P₂O₅, Where X = 0, 40, or 60. the Phosphate (X0) Glass (PBG) Produced an Acidic Solution When Dissolved …

Effect Of Pre-Heating On Residual Stresses And Deformation In Laser-Based Directed Energy Deposition Repair: A Comparative Analysis, Usman Tariq, Sung Heng Wu, Muhammad Arif Mahmood, Michael M. Woodworth, Frank W. Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Laser-Directed Energy Deposition (DED), a Metal Additive Manufacturing Method, is Renowned for its Role in Repairing Parts, Particularly When Replacement Costs Are Prohibitive. Ensuring that Repaired Parts Avoid Residual Stresses and Deformation is Crucial for Maintaining Functional Integrity. This Study Conducts Experimental and Numerical Analyses on Trapezoidal Shape Repairs, Validating Both the Thermal and Mechanical Models with Experimental Results. Additionally, the Study Presents a Methodology for Creating a Toolpath Applicable to Both the DED Process and Abaqus CAE Software. the Findings Indicate that Employing a Pre-Heating Strategy Can Reduce Residual Stresses by over 70% Compared to No Pre-Heating. However, Pre-Heating …

L-Ergothioneine Slows The Progression Of Age-Related Hearing Loss In Cba/Caj Mice, Mark A. Bauer, Parveen Bazard, Alejandro A. Acosta, Nidhi Bangalore, Lina Elessaway, Mark Thivierge, Moksheta Chellani, Xiaoxia Zhu, Bo Ding, Joseph P. Walton, Robert D. Frisina

Chemical and Biochemical Engineering Faculty Research & Creative Works

The naturally occurring amino acid, l-ergothioneine (EGT), has immense potential as a therapeutic, having shown promise in the treatment of other disease models, including neurological disorders. EGT is naturally uptake into cells via its specific receptor, OCTN1, to be utilized by cells as an antioxidant and anti-inflammatory. In our current study, EGT was administered over a period of 6 months to 25–26-month-old CBA/CaJ mice as a possible treatment for age-related hearing loss (ARHL), since presbycusis has been linked to higher levels of cochlear oxidative stress, apoptosis, and chronic inflammation. Results from the current study indicate that EGT can prevent aging …

Cooperative And Bifunctional Adsorbent-Catalyst Materials For In-Situ Vocs Capture-Conversion, Sukanta K. Mondal, Peter Aina, Ali A. Rownaghi, Fateme Rezaei

Chemical and Biochemical Engineering Faculty Research & Creative Works

Volatile Organic Compounds (VOCs) Are Gases that Are Emitted into the Air from Products or Processes and Are Major Components of Air Pollution that Significantly Deteriorate Air Quality and Seriously Affect Human Health. Different Types of Metals, Metal Oxides, Mixed-Metal Oxides, Polymers, Activated Carbons, Zeolites, Metal-Organic Frameworks (MOFs) and Mixed-Matrixed Materials Have Been Developed and Used as Adsorbent or Catalyst for Diversified VOCs Detection, Removal, and Destruction. in This Comprehensive Review, We First Discuss the General Classification of VOCs Removal Materials and Processes and Outline the Historical Development of Bifunctional and Cooperative Adsorbent-Catalyst Materials for the Removal of VOCs from …

Future Of Process Safety: Insights, Approaches, And Potential Developments, Hossein Abedsoltan, Amirhesam Abedsoltan, Zeinab Zoghi

Chemical and Biochemical Engineering Faculty Research & Creative Works

This review explores the evolving landscape of process safety, emphasizing the integration of digitalization and advanced technologies. It assesses the role of the industrial Internet of Things, artificial intelligence, and machine learning (ML) in enhancing safety protocols. The paper examines predictive analytics, sensor technology advancements, and digital twins' contributions to safety optimization. It also discusses the future perspectives of risk management approaches, including proactive safety management systems, quantitative risk assessment techniques, and human reliability analysis. This comprehensive analysis provides insights into future developments and challenges in process safety.

Equitable Infrastructure: Achieving Resilient Systems And Restorative Justice Through Policy And Research Innovation, Jason P. Giovannettone, Gregg P. Macey, Amir Aghakouchak, Michele Barbato, William J. Capehart, Auroop R. Ganguly, Mital Hall, Jennifer F. Helgeson, Si Han Li, Teng Wu, Guirong Yan, Farshid Vahedifard

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Recent major investments in infrastructure in the United States and globally present a crucial opportunity to embed equity within the heart of resilient infrastructure decision-making. Yet there is a notable absence of frameworks within the engineering and scientific fields for integrating equity into planning, design, and maintenance of infrastructure. Additionally, whole-of-government approaches to infrastructure, including the Justice40 Initiative, mimic elements of process management that support exploitative rather than exploratory innovation. These and other policies risk creating innovation traps that limit analytical and engineering advances necessary to prioritize equity in decision-making, identification and disruption of mechanisms that cause or contribute to …

Modeling Inflation Transmission Among Different Construction Materials, Mohamad Abdul Nabi, Islam H. El-Adaway, Rayan H. Assaad

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Cost estimating in the construction industry is challenging due to the high uncertainty associated with the supply chain, especially after the COVID-19 pandemic. Some research studies have addressed such problems by developing models that predict material cost. In fact, all material can be interconnected and interrelated with lead-lag relationships such that any inflation in one material's price can be associated with inflation in other materials' prices, referred to as transmission of inflation. Despite the latter, none of the existing studies have investigated inflation transmission among all construction materials. This paper fills this knowledge gap. The authors used a multistep research …

A Review Of Whipple Shield Ballistic Limit Equations, S. Ryan, W. (William) P. Schonberg

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Ballistic limit equations (BLEs) are semi-analytical expressions used to predict the risk posed by micrometeoroid and orbital debris (MMOD) impacts on a spacecraft. A foundational BLE, known as the new non-optimum (NNO) equation was published by Eric Christiansen of NASA Johnson Space Center in 1990 for application on Whipple shields – two-plate configurations consisting of a thin sacrificial plate located at some standoff in front of the spacecraft pressure hull or structural wall. Today, BLEs for almost all multi-plate spacecraft structures, e.g., honeycomb sandwich panels, monolithic structures with thermal insulation blankets, etc., are based on the NNO Whipple BLE. We …

Four-Way Cfd-Dem Coupling To Simulate Concrete Pipe Flow: Mechanism Of Formation Of Lubrication Layer, Tooran Tavangar, Masoud Hosseinpoor, Jeffrey S. Marshall, Ammar Yahia, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study introduced a four-way CFD-DEM coupling approach to simulate the shear-induced particle migration (SIPM) mechanism leading to formation of the lubrication layer (LL) during concrete pumping. The CFD-DEM simulations considered the coupled effect of concentration (10 %–40 %) and wide size distribution (1–17 mm) of aggregate and rheology of the mortar for forces between the suspending matrix and the particles (and vice versa), as well as force transmission directly between particles (and the pipe wall). The formation of the LL was successfully simulated through a more realistic understanding the SIPM mechanism and rheological evaluation across the pipe with comparable …

Reflections On Linear B, (Part 3): The Egyptian Cat-God Mau, Gerald Leonard Cohen

Arts, Languages and Philosophy Faculty Research & Creative Works

The cat figure in Linear B sign 80 (with antecedents) likely derives ultimately from the nightly defeat of the Egyptian god of chaos (Apep, aka Apophis) by the sun god Ra, who took the form of the divine cat Mau. An alternative interpretation is set forth in Ferrara and Weingarten 2022, which sees the cat portrayals for wool or woolen products in Cretan Hieroglyphics as traceable to the cat sound /ma/ appearing by coincidence in Greek μαλλός ‘wool’ (possibly of pre-Greek origin). Perhaps both factors played a role (multiple causation).

Crystallographic Defects In Weyl Semimetal Laalge, Inseo Kim, Byungkyun Kang, Hyunsoo Kim, Minseok Choi

Physics Faculty Research & Creative Works

Crystallographic Defects in a Topological Semimetal Can Result in Charge Doping and Scattering Centers Which May Mask the Exotic Spectroscopic and Transport Properties, respectively. Here, We Investigate the Possible Crystallographic Defects Including Vacancy and Antisite in Weyl Semimetal LaAlGe using Hybrid-Density-Functional Theory Calculations. We Show that a Considerable Concentration of Al- and Ge-Related Defects Naturally Form during Growth Due to their Low Formation Enthalpy. Specifically, Al Can Be Easily Replaced by Ge in the I41md Phase of LaAlGe, Forming the Ge-On-Al Antisite, GeAl. the Counterpart, Al-On-Ge (AlGe), is Also Probable. the Most Abundant Defect GeAl is Donorlike, Effectively Electron Doping, …

Raising The Green Roof: Enhancing Youth Water Literacy Through Built Environment Education, Laura B. Cole, Lilian Priscilla, Laura Zangori, Beth Kania-Gosche, Joel G. Burken

Teacher Education and Certification Faculty Research & Creative Works

Green Roofs Cool Cities, Clean the Air, Provide Habitat, and Manage Stormwater. They Are Compelling Tools to Teach Interconnected Human-Ecological Systems. This Study Included the Design, Pilot, and Evaluation of a Fourth-Grade Science Unit Entitled "Raising the Green Roof", Exploring These Connections. Five Classrooms in Two Midwestern U.S. Public Elementary Schools Participated, and 4th-Grade Students (N = 73) Drew Systems Models at Three Time Points (212 Models) and Wrote their Ideas. Qualitative Content Analyses of the Models Showed that Learners Were Increasingly Combining Social Systems (Green Roof Infrastructure) with Ecological Systems (Water Cycle) Across the Unit. Students Also Increasingly Evidenced …

Semi-Annual Progress Report #14, Missouri University Of Science And Technology

Semi-Annual Progress Reports

No abstract provided.

Russian Verbs Of Sound’S Web-Scraping Results From The A.A. Zalizniak Grammatical Dictionary And The Russian National Corpus. Multi-Dimensional Scaling Techniques And Visualization Strategies, John Simmons, Irina V. Ivliyeva

Graduate Student Research & Creative Works

This project aims to enhance web extraction techniques pertaining to a specific lexical-semantic group of Russian verbs of sounds, which undergo semantic modifications at the word-formation level (affixation). Additionally, it seeks to organize search results in a manner conducive to linguistic research using Multi-Dimensional Scaling (MDS) techniques and novel visualization strategies.

The primary objective in this phase of the research was to gather, consolidate, analyze, and present a comprehensive index of all forms of verbs of sound sourced from the A.A. Zalizniak Grammatical Dictionary of the Russian language, hyperlink each verbal form in this index with the Russian National Corpus …

Rotational Spectrum, Structure, And Quadrupole Coupling Of Cyclopropylchloromethyldifluorosilane, Alexander R. Davies, Abanob G. Hanna, Alma Lutas, Gamil A. Guirgis, Garry S. Grubbs

Chemistry Faculty Research & Creative Works

Cyclopropylchloromethyldifluorosilane, C-C3H5SiF2CH2Cl, Has Been Synthesized, and its Rotational Spectrum Has Been Recorded by Chirped-Pulse Fourier Transform Microwave Spectroscopy. the Spectral Analysis of Several Isotopologues Indicates the Presence of Two Distinct Conformations in the Free-Jet Expansion, Which Are Interconvertible through a Rotation of the Chloromethyl Group. a Partial Substitution Structure is Presented for the Lower Energy Conformation and is Compared to the Equilibrium Structure Obtained from Quantum Chemical Calculations. Additionally, the Presence of the Chlorine Nucleus Leads to the Rotational Transitions Splitting into Multiple Hyperfine Components and Χaa, a Measure of the Electric Field Gradient Along the a Axis, is Unusually …

Hardness Of Single Phase High Entropy Carbide Ceramics With Different Compositions, Paul M. Brune, Gregory E. Hilmas, William G. Fahrenholtz, Jeremy Lee Watts, Caillin J. Ryan, Chris M. Desalle, Douglas E. Wolfe, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

Five High Entropy Carbide Ceramics, (Hf0.2,Nb0.2,Ta0.2,Ti0.2,Zr0.2)C, (Cr0.2,Hf0.2,Ta0.2,Ti0.2,Zr0.2)C, (Hf0.2,Mo0.2,Ta0.2,Ti0.2,Zr0.2)C, (Hf0.2,Ta0.2,Ti0.2,W0.2,Zr0.2)C, and (Hf0.2,Mo0.2,Ti0.2,W0.2,Zr0.2)C, Were Synthesized by Carbothermal Reduction of Oxides and Direct Current Sintering. the Five High Entropy Carbide Ceramics Were Determined to Be Nominally Phase-Pure with Relative Densities of More Than 98.9% and Mean Grain Sizes of Less Than 5 Μm. Average Vickers Hardness Values Ranged from 19.2 ± 0.4 GPa for (Hf0.2,Nb0.2,Ta0.2,Ti0.2,Zr0.2)C at a Load of 2 Kgf to 43.5 ± 0.4 GPa for (Hf0.2,Mo0.2,Ti0.2,W0.2,Zr0.2)C at a Load of 0.05 Kgf. Hardness Generally Increased with Increasing the Valence Electron Concentration and Strain as Measured by the Williamson-Hall Analysis. However, Neither …

A Tilted Broad Plume Underneath The Greenland Cratonic Keels, Dan Wang, Stephen S. Gao, Yangyang Liao, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

To advance our comprehension of the complex geological history and mantle dynamics in the north atlantic region, we employ all available broadband seismic data recorded in greenland to reveal an abnormal mantle transition zone (mtz) structure. Central and eastern greenland exhibits depressed 410 and 660 km discontinuities (d410 and d660, respectively) bordering the mtz, indicative of a substantial thermal anomaly associated with an underlying plume, surpassing the 1,800°c threshold for post-garnet phase transitions at the d660. Variations in mtz thickness across greenland stem from differing temperature anomalies at the d410 and d660, possibly linked to a tilted plume within the …

Rainbowcake: Mitigating Cold-Starts In Serverless With Layer-Wise Container Caching And Sharing, Hanfei Yu, Rohan Basu Roy, Christian Fontenot, Devesh Tiwari, Jian Li, Hong Zhang, Hao Wang, Seung Jong Park

Computer Science Faculty Research & Creative Works

Serverless Computing Has Grown Rapidly as a New Cloud Computing Paradigm that Promises Ease-Of-Management, Cost-Efficiency, and Auto-Scaling by Shipping Functions Via Self-Contained Virtualized Containers. Unfortunately, Serverless Computing Suffers from Severe Cold-Start Problems - -Starting Containers Incurs Non-Trivial Latency. Full Container Caching is Widely Applied to Mitigate Cold-Starts Yet Has Recently Been Outperformed by Two Lines of Research: Partial Container Caching and Container Sharing. However, Either Partial Container Caching or Container Sharing Techniques Exhibit their Drawbacks. Partial Container Caching Effectively Deals with Burstiness While Leaving Cold-Start Mitigation Halfway; Container Sharing Reduces Cold-Starts by Enabling Containers to Serve Multiple Functions While Suffering …

Vt-Nmr Analysis Of Rotation-Inversion Of N-(4-Hydroxybutyl)-N-(2,2,2-Trifluoroethyl) Tert-Butyl Carbamate: Utilizing The −Ch2cf3 Appendage As A Reporter On E/Z-Isomerization, Brian Jameson, Rainer Glaser

Chemistry Faculty Research & Creative Works

The rotational barrier about the CN carbamate bond of N-(4-hydroxybutyl)-N-(2,2,2-trifluoroethyl) tert-butyl carbamate 1 was determined by variable temperature (VT) 13C and 19F NMR spectroscopy. The −CH2CF3 appendage reports on rotational isomerism and allows for the observation of separate signals for the E- and Z-ensembles at low temperature. The activation barrier for E/Z-isomerization was quantified using Eyring-Polanyi theory which requires the measurements of the maximum difference in Larmor frequency Δνmax and the convergence temperature Tc. Both Δνmax and Tc were interpolated by analyzing sigmoidal functions fitted to data describing signal separation and the quality of the superposition of the E- and …

Li2mp2s6: Building-Block Approach To A Family Of 2d Non-Van Der Waals-Layered Materials And Their Water, Ammonia, And Ion Intercalation Properties, Santhoshkumar Sundaramoorthy, Nikolay Gerasimchuk, Kartik Ghosh, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

A Series of Non-Van Der Waals 2D Quaternary Thiophosphates with Nominal Composition, Li2MP2S6 (M = V, Mn, Fe, Co, Ni, and Zn), Has Been Successfully Synthesized through Solid-State Metathesis Reactions by a Building Block Approach as Well as Starting with a Stoichiometric Combination of Elements. Li4-NxMxn+P2S6 (M = V, Fe, Ni, Co, and Zn; X = 0.5-1, N = 2 or 3) Crystallize in the P3̅1m Space Group, While Li2MnP2S6 Crystallizes in R3̅. All the Compounds Form a 2D Layered Structure through Edge Sharing MS6 Octahedra and P2S6 Units with Li Atoms Occupying the Interlayer Spaces. X-Ray Diffraction and Thermogravimetric …

Drone-Based Bug Detection In Orchards With Nets: A Novel Orienteering Approach, Francesco Betti Sorbelli, Federico Coró, Sajal K. Das, Lorenzo Palazzetti, Cristina M. Pinotti

Computer Science Faculty Research & Creative Works

The Use of Drones for Collecting Information and Detecting Bugs in Orchards Covered by Nets is a Challenging Problem. the Nets Help in Reducing Pest Damage, But They Also Constrain the Drone's Flight Path, Making It Longer and More Complex. to Address This Issue, We Model the Orchard as an Aisle-Graph, a Regular Data Structure that Represents Consecutive Aisles Where Trees Are Arranged in Straight Lines. the Drone Flies Close to the Trees and Takes Pictures at Specific Positions for Monitoring the Presence of Bugs, But its Energy is Limited, So It Can Only Visit a Subset of Positions. to …

Li2mp2s6: Building-Block Approach To A Family Of 2d Non-Van Der Waals-Layered Materials And Their Water, Ammonia, And Ion Intercalation Properties, Santhoshkumar Sundaramoorthy, Nikolay Gerasimchuk, Kartik Ghosh, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

A series of non-van der Waals 2D quaternary thiophosphates with nominal composition, Li₂MP₂S₆ (M = V, Mn, Fe, Co, Ni, and Zn), has been successfully synthesized through solid-state metathesis reactions by a building block approach as well as starting with a stoichiometric combination of elements. Li4-nxMxn+P2S6 (M = V, Fe, Ni, Co, and Zn; x = 0.5-1, n = 2 or 3) crystallize in the P3̅1m space group, while Li₂MnP₂S₆ crystallizes in R3̅. All the compounds form a 2D layered structure through edge sharing MS6 octahedra and P₂S …

2023 Rising Stars In Measurement Science, Shelley Minteer

Chemistry Faculty Research & Creative Works

No abstract provided.

Scanning Electrochemical Microscopy Reveals That Model Silicon Anodes Demonstrate Global Solid Electrolyte Interphase Passivation Degradation During Calendar Aging, Josefine D. Mcbrayer, Noah B. Schorr, Mila Nhu Lam, Melissa L. Meyerson, Katharine L. Harrison, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Silicon is a promising next-generation anode to increase energy density over commercial graphite anodes, but calendar life remains problematic. In this work, scanning electrochemical microscopy was used to track the site-specific reactivity of a silicon thin film surface over time to determine if undesirable Faradaic reactions were occurring at the formed solid electrolyte interphase (SEI) during calendar aging in four case scenarios: formation between 1.5 V and 100 mV with subsequent rest starting at (1) 1.5 V and (2) 100 mV and formation between 0.75 V and 100 mV with subsequent rest starting at (3) 0.75 V and (4) 100 …

Application Of The Immobilized Low-Activity Waste Glass Corrosion Model To The Static Dissolution Of 24 Statistically-Designed Alkali-Borosilicate Waste Glasses, Sebastien N. Kerisit, James J. Neeway, Charmayne E. Lonergan, Benjamin Parruzot, Jarrod V. Crum, Richard C. Daniel, Gary L. Smith, R. Matthew Asmussen

Materials Science and Engineering Faculty Research & Creative Works

Glass corrosion models that capture the complex mechanisms of the glass-water reaction enable the prediction of nuclear waste glass durability in disposal scenarios. Parameterization of such models is challenging because of the need to capture changes in corrosion behavior with time, reaction conditions, and glass composition. Here, we describe and employ the ILAW (immobilized low-activity waste) glass corrosion model (IGCM) in geochemical simulations of static dissolution tests, at two temperatures (40 °C and 90 °C), for a matrix of 24 enhanced low-activity waste (eLAW) glasses statistically designed to cover a processable composition space defined by 8 major glass components (Al …