Digital Commons Network^™

Lead Sources Detected In Manila's Air After The Phase-Out Of Leaded Gasoline, Grace Betito, Paola Angela Bañaga, Maria Obiminda L. Cambaliza, Melliza Templonuevo Cruz, James Bernard Simpas, Mengli Chen, Jariya Kayee, Armin Sorooshian, Rachel A. Braun, Alexander B. Macdonald

Ateneo Atmospheric Physics Laboratory

Abstract

The global phase-out of leaded gasoline marked a major milestone in pollution control, yet modern uses of lead (Pb) continue to pose significant health risks, especially in low- and middle-income countries. In the Philippines, significant data gaps still exist despite increasing exposure. This study presents to the best of our knowledge, the first Pb isotopic fingerprinting of atmospheric aerosols in Metro Manila, Philippines, covering fine (0.56–1 μm) and coarse (5.6–10 μm) fractions, collected in 2018–2019. Results show that local sources, mainly industrial activities (45–62 %) and fossil fuel combustion (30–45 %), are now the dominant contributors to airborne Pb, …

(R2136) Dimensionless Modeling And Analytical Insights Into Botanical Biofiltration Systems For Voc Reduction, N. Jeeva, K. M. Dharmalingam, M. Veeramuni

Applications and Applied Mathematics: An International Journal (AAM)

This paper investigates the mathematical modeling of volatile organic compound (VOC) removal using a botanical biofiltration system, an effective biological treatment method. It examines mass balance concentrations in the gas and biofilm phases, highlighting their significance in VOC degradation and indoor air quality enhancement. The governing equations of the proposed model are converted into a dimensionless form, resulting in second-order nonlinear differential equations. Derived from mass transfer and reaction kinetics principles, these equations incorporate specific boundary conditions to capture gas-biofilm interactions and VOC removal dynamics in biofiltration. The modified Adomian decomposition method (MADM) is utilized to derive analytical solutions for …

Generating Predictive Gene Expression Signatures For Alzheimer's Disease Using Postmortem Brain Tissue, Ashley Duche

Pharmaceutical Sciences (PhD) Dissertations

Background: Alzheimer’s Disease (AD) is a progressive neurodegenerative disorder characterized by the accumulation of amyloid-beta (Aβ) plaques and tau protein aggregates. These pathological features develop in specific brain regions, but why some areas are more vulnerable to early AD-related changes remains unclear. To address this, predictive gene expression signatures were developed to explore the molecular mechanisms underlying regional susceptibility to AD pathology.

Methods: This was performed using postmortem brain (PMB) tissue from participants in the Religious Orders Study and Memory and Aging Project (ROSMAP), Mayo Clinic, and Mount Sinai Brain Bank (MSBB) to generate gene expression signatures from six brain …

Large Language Models As Machines Of Beauty: Cognitive Averaging, Latent Space Geometry, And The Entropic Foundations Of Aesthetic Preference, Daniel Plate, James Hutson

Faculty Scholarship

This study advances the position that large language models (LLMs) and human perceptual systems are governed by a shared computational drive toward prototypicality, entropy reduction, and aesthetic coherence. Drawing on developmental evidence that infants exhibit early preferences for facial symmetry and averageness, the analysis situates aesthetic preference within broader research on processing fluency and predictive coding, emphasizing that biological perception rewards stimuli that reduce uncertainty and support efficient information compression. This foundation is used to examine how LLMs, through cross-entropy optimization, perplexity minimization, and latent space clustering, converge on high-density representational regions that operate as statistical prototypes of linguistic and …

From Static Prediction To Mindful Machines: A Paradigm Shift In Distributed Ai Systems, Rao Mikkilineni, W. Patrick Kelly

Barowsky School of Business | Faculty Scholarship

A special class of complex adaptive systems—biological and social—thrive not by passively accumulating patterns, but by engineering coherence, i.e., the deliberate alignment of prior knowledge, real-time updates, and teleonomic purposes. By contrast, today’s AI stacks—Large Language Models (LLMs) wrapped in agentic toolchains—remain rooted in a Turing-paradigm architecture: statistical world models (opaque weights) bolted onto brittle, imperative workflows. They excel at pattern completion, but they externalize governance, memory, and purpose, thereby accumulating coherence debt—a structural fragility manifested as hallucinations, shallow and siloed memory, ad hoc guardrails, and costly human oversight. The shortcoming of current AI relative to human-like intelligence is therefore …

The Price Of Priorities: How Human Choices Fuel Climate And Ecological Decline, Keisha Hickman

Biological Sciences Undergraduate Honors Theses

This thesis examines the ways in which human priorities and behaviors contribute to the escalating climate crisis and ecological systems. We will first analyze the role of social media in shaping public discourse on climate change and critically evaluate the priorities of institutions that have the means to assist in wildlife conservation. Both speak to the current behaviors of humankind prioritizing their own entertainment over meaningful efforts to mitigate climate change and preserve biodiversity. We will then shift to exploring the profound impact of human population growth and its associated activities on other species and ecosystems. Finally, the thesis will …

Full Issue, The Mcnair Team

McNair Scholars Research Journal

No abstract provided.

El Poder Del Bilingüismo Y La Ciencia, Isabella Winslow

World Languages and Cultures

This project is an explanation of the importance of bilingualism, science, and our responsibility as humans within this environment. As living beings on this planet, we have a responsibility to respect and protect it. Over the course of the last several hundred years, we humans have made countless advancements. We have created unimaginable technology and discovered incredible resources produced by the land. However, in the process of doing so, we have damaged and continue to damage our environment. Reefs in the ocean have been bleached by increases in acidity, thousand year old glaciers have melted, forests have been destroyed by …

Onset Of Strong Iceland-Scotland Overflow Water 3.6 Million Years Ago, Matthias Sinnesael, Boris Theofanis Karatsolis, Paul N. Pearson, Anne Briais, Sidney R. Hemming, Leah J. Levay, Tom Dunkley Jones, Ying Cui, Anita Di Chiara, Justin P. Dodd, Deepa Dwyer, Deborah E. Eason, Sarah A. Friedman, Emma Hanson, Katharina Hochmuth, Halima E. Ibrahim, Claire E. Jasper, Saran Lee-Takeda, Danielle E. Leblanc, Melody R. Lindsay, David D. Mcnamara, Sevasti E. Modestou, Margaret A. Morris, Bramley J. Murton, Suzanne Oconnell, Gabriel Pasquet, Sheng Ping Qian, Yair Rosenthal, Sara Satolli, Takuma Suzuki, Thena Thulasi, Bridget S. Wade

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

North Atlantic Deep Water (NADW), the return flow component of the Atlantic Meridional Overturning Circulation (AMOC), is a major inter-hemispheric ocean water mass with strong climate effects but the evolution of its source components on million-year timescales is poorly known. Today, two major NADW components that flow southward over volcanic ridges to the east and west of Iceland are associated with distinct contourite drift systems that are forming off the coast of Greenland and on the eastern flank of the Reykjanes (mid-Atlantic) Ridge. Here we provide direct records of the early history of this drift sedimentation based on cores collected …

Millennial-Timescale Thermogenic Co2 Release Preceding The Paleocene-Eocene Thermal Maximum, Shijun Jiang, Ying Cui, Yasu Wang, Maurizia De Palma, B. David A. Naafs, Jingxin Jiang, Xiumian Hu, Huaichun Wu, Runjian Chu, Yangguang Gu, Jiuyuan Wang, Yizhou Huang, Miquela Ingalls, Timothy J. Bralower, Shiling Yang, James C. Zachos, Andy Ridgwell

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Geologic records support a short-lived carbon release, known as the pre-onset excursion (POE), shortly before the Paleocene-Eocene Thermal Maximum (PETM; ~ 56 Ma). However, the source and pace of the POE carbon release and its relationship to the PETM remain unresolved. Here we show a high-temporal-resolution stratigraphic record spanning the POE and PETM from the eastern Tethys Ocean that documents the evolution of surface ocean carbon cycle, redox and eutrophication, confirming the global nature of the POE. Biomarkers extracted from the sedimentary record indicate a smaller environmental perturbation during the POE than that during the PETM in the eastern Tethys …

Wacsaw: An Adaptive, Statistical Method To Classify Movement Into Sleep And Wakefulness States, Austin Vandegriffe, V. A. Samaranayake, Matthew S. Thimgan

Mathematics and Statistics Faculty Research & Creative Works

Wearable actimeters can improve our understanding of sleep in the natural environments. Current algorithms may produce inaccuracies in specific individuals and circumstances, such as quiet wakefulness. New hardware allows data collection at higher frequencies enabling sophisticated analytical methods. We have developed a novel statistical algorithm, the Wasserstein Algorithm for Classifying Sleep and Wakefulness (WACSAW), to identify behavioral states from recordings of everyday movement. WACSAW employs optimal transport techniques to identify segments with differing activity variability. Functions characterizing the segments' movement distributions were clustered into two groups using a k-nearest neighbors and labeled as sleep or wake based on their proximity …

Optimization In The Synthesis Of Dual Ionic-Liquid-Functionalized Cellulosic Materials, Megan L. Franke

Honors College Theses

There is a growing urgency to develop sustainable alternatives to petroleum-based materials as concerns about environmental impact and resource depletion intensify. Among renewable biopolymers, cellulose stands out as one of the most abundant and versatile organic compounds on Earth. As the structural backbone of plant cell walls, it provides rigidity and mechanical strength, while its abundance, biodegradability, and tunable chemistry make it an attractive candidate for sustainable materials. Beyond its traditional uses in textiles, paper, and food additives, cellulose has been increasingly investigated in polymer chemistry for advanced

applications. The present study aims to optimize synthetic routes to dual ionic …

(R2125) Impact Of Convective Condition And Inclined Magnetic Field On Casson Nanofluid With Bioconvection In Porous Medium, Touseef Fayaz, O. Otegbeye, Md. Sharifuddin Ansari

Applications and Applied Mathematics: An International Journal (AAM)

This paper presents an analysis on steady magnetohydrodynamic boundary layer flow of Casson nanofluid with microorganisms near an expandable boundary in a porous medium. The flow behaviour is analysed by incorporating impacts of magnetic field applied in a direction which makes an angle α∗ with the boundary and convective conditions in temperature, nanoparticle concentration and microorganism density at boundary. Non-dimensionalised nonlinear and coupled system of ordinary differential equations are solved by exercising a numerical algorithm termed as spectral local-linearization method. The considered numerical algorithm is found to be convergent and capable of yielding accurate results. Graphical sketches of solutions obtained …

Bridging Conservation And Disaster Recovery: A Dual Study On Wetland Program Plans Evaluation And Midwest Post Disaster Recovery Assessment, Rao Nargis Jahan

Community and Regional Planning Program: Theses

Wetlands provide essential ecological, social, and economic benefits for our society. In the United States, states and tribes play crucial roles in wetland protection, restoration, and management. However, no research has systematically measured state-level wetland planning efforts towards national conservation goals. This study is the first to comprehensively evaluate how state-level Wetland Program Plans (WPPs) align with national missions, particularly the "no-net-loss" of wetlands goal. Our research assesses the EPA-approved state-level WPPs from 42 out of 50 states in the United States during the period from 2015 to 2024. Using a protocol of 30 indicators across five categories, this study …

Upcycling Commodity Polymers To Advanced Materials For Energy And Environmental Sustainability, Anthony Griffin-Espinoza

Dissertations

Synthetic polymers play an essential role in nearly every aspect of our lives. Extending beyond single-use packaging, polymeric material design has progressed to attain tailorable architectures granting exceptional performance across advanced applications, including carbon-fiber reinforced polymer composites for aerospace, conductive materials for soft electronics, and drug carriers for biomedicine. While highly promising, intricately designed polymers needed to achieve excellent performance often have limited processability, complex synthetic methods, and expensive precursors. Furthermore, due to a lack of recyclability, commodity polymer waste streams result in both environmental impacts and a substantial loss of economic value. This dissertation focuses on developing robust strategies …

The Malonate Template: The Key To Unlocking Novel Amino Acids, Thomas Owens

Dissertations

The “Malonate Template” provides access to various amino acids, all from a common intermediate. Herein, demonstrates the use of the malonate template to establish a synthetic route to both 2-thiohistidine and 2-thio-3-N-methyl-histidine from a benzyl methyl malonate derived intermediate. Furthermore, efforts exploiting the applicability of the malonate template for the of both 2-thiohistidine and 2-thio-3-N-methyl-histidine as a suitable alternative to methods previously described by Erdelmeier are described.

The method presented incorporates modifications to the biomimetic pathway described by Erdelmeier for the synthesis of 2-thiohisidine. By exploiting the biomimetic formation of 2-thiohisitidne’s mechanism via mass spectrometry, we …

Molecular Design And Engineering Of Luminophores For Aggregation Induced Electrogenerated Chemiluminescence, Jesy Alka Motchaalangaram

Dissertations

Most conventional luminophores produce intense emissions in solutions but suffer from weak emissions or quenching when aggregated in poor solvents due to intermolecular interactions, such as π-π stacking. This phenomenon is known as aggregation caused by quenching (ACQ), limits their applications in their solid state. In contrast, aggregation induced emission (AIE) is a phenomenon in which luminophores are weak- or non-emissive in solution but emit intensively in their aggregated or solid states. AIE has enabled significant advancements in various real-world applications and has inspired new areas of research. The combination of AIE with electrogenerated chemiluminescence (ECL) has resulted in a …

Predicting Cryptocurrency Prices Using Stochastic Modeling, Reem Hani Al Omari

Theses

Cryptocurrencies are digital currencies that operate independently of central banks and governments. They were designed to overcome the limitations of traditional financial systems through a decentralized, peer-to-peer electronic cash mechanism. Trading in cryptocurrencies offers several advantages, including decentralized and efficient transactions, reduced costs through the elimination of intermediaries, investment opportunities across exchanges, and seamless cross-border remittances. Modeling cryptocurrency prices is therefore essential, not only due to these advantages but also because of the substantial market capitalization of cryptocurrencies, estimated to exceed 900 billion dollars according to CoinMarketCap [6]. The main objective of this thesis is to propose a predictive framework …

Soil Organic Carbon Depth Profiles And Centennial And Millennial Decay Rates In Tidal Marsh, Mangrove And Seagrass Blue Carbon Ecosystems, Nerea Piñeiro-Juncal, Miguel Ángel Mateo, Carmen Leiva-Dueñas, Eduard Serrano, Karina Inostroza, Montserrat Soler, Eugenia T. Apostolaki, Paul Lavery, Carlos M. Duarte, Anna Lafratta, Oscar Serrano

Research outputs 2022 to 2026

The management of coastal blue carbon ecosystems can contribute to mitigate anthropogenic greenhouse gas emissions. However, limited information on soil organic carbon (OC) decay rates in tidal marsh, mangrove, and seagrass soils hinders their inclusion in climate strategies and carbon-crediting schemes. Here, we analyzed downcore OC trends in 3761 soil cores from blue carbon ecosystems worldwide. A decrease in OC content with soil depth was measured in 63% of the cores, whereas stable and increasing trends were observed in 22% and 15% of the cores, respectively. Based on 85 profiles where OC decay could be modelled, the OC decay rate …

Impacts Of Nutrient Addition And Disturbance On Coastal Dune Arthropod Communities And Trophic Interactions, Kayla Beitzel

Graduate Theses and Dissertations (2019 - present)

Coastal dune ecosystems face ongoing threats from human-mediated disturbance and altered resource availability. Because these dunes provide critical habitat for many organisms, including shorebirds, beach mice, and arthropods, changes in disturbance regimes or resource availability can impact plant communities and higher trophic levels by altering plant richness and productivity, which in turn influence arthropod abundance and diversity. To examine how disturbance and nutrient addition affect arthropod communities, we established twenty 5×5 m plots on Dauphin Island, crossing mechanical disturbance with a 10 g m⁻² addition of nitrogen, phosphorus, and potassium, replicated across five experimental blocks. Arthropods were sampled using three …

Performance Enhancement For Rufa: Rapid Urban Forest Assessment, Nicholas Tan

Master's Theses

Urban forests are crucial to the livability and resilience of cities, offering critical ecosystem benefits such as air quality enhancement, temperature regulation, and biodiversity. Managing said urban forests is essential to ensure their sustainability and adaptability to rapidly changing environmental and climate conditions. The Rapid Urban Forest Assessment (RUFA) tool was developed to address the need for a standardized approach to evaluating and comparing urban and community forestry programs. By analyzing and aggregating tree-specific data across California, such as canopy cover, tree counts, and diversity scores, RUFA assigns a comprehensive urban forestry score for each city. This score allows for …

An Analysis Of Neuroidal Memory Formation Within D. Melanogaster, Jerry Chang

Master's Theses

The Neuroidal model poses a neurobiologically plausible theory for modeling the brain. This symbolic network has been shown to capture realistic memorization behaviors using the JOIN algorithm. The model has also been recently improved by incorporating Watts-Strogatz small-worlds within its base structure. From the efforts of neuroscience researchers, we have access to the Drosophila melanogaster (D. melanogaster) fruit fly’s connectome, which has been found to also contain small-worlds in this thesis. By synthesizing the Ocellar Ganglion (OCG) region of Drosophila, we compare a digitized version of a real-world brain with an instance of the Neuroidal model. In this thesis, we …

Synthesis Of Antibody Functionalized Polyaniline/Polystyrene/N-Gqds Composite Fibermats For Sweat Based Cortisol Biosensing Applications, Ashwin James

Honors Theses

Noninvasive, wearable biosensors capable of detecting stress biomarkers in sweat require electrodes that are flexible, conductive, insoluble in water, and highly sensitive at low concentrations of analyte. In this work, bovine serum albumin blocked and anti-cmab immobilized nitrogen doped graphene quantum dots integrated polyaniline/polystyrene composite fibermat electrodes (BSA/Anti-Cmab/N-GQDs/PANI/PS electrodes) were synthesized and evaluated as a potential platform for an electrochemical cortisol biosensor in sweat based systems. Polyaniline was utilized in order to provide electrical conductivity, while polystyrene served as a carrying polymer for mechanical support and its hydrophobicity. Composite fibermats were manufactured through Forcespinning™, followed by a secondary polyaniline graft …

Sciteuq: Toward Uncertainty-Aware Complex Scientific Table Data Extraction And Understanding, Kehinde Ajayi

Computer Science Theses & Dissertations

Scientific tables report critical research insights, data, and findings for scientific progress. Because Portable Document Format (PDF) is the de facto standard format for scientific paper publishing, there has been an emerging need for an automatic method to extract data from PDF files. A significant fraction of scientific tables exhibit complex structure and content, making it challenging for machine learning tools to accurately extract the content directly from PDF files. Despite the advancements in Table Structure Recognition (TSR), automated extraction of data from complex scientific tables remains a challenge due to variations in table structures and contents. In this dissertation, …

Aluminum As A Tracer Of Dust Deposition To The Ocean: A Case Study From The Bermuda Region, Tara Elizabeth Williams

OES Theses and Dissertations

Aluminum (Al), a major component of mineral aerosol (dust), partially dissolves in seawater and is widely used as a tracer for estimating time‐averaged dust fluxes to the ocean. Such estimates rely on dissolved Al (DAl) inventories in the surface mixed layer (SML), an assumed SML residence time of DAl (_TDAl), the fractional solubility of Al in dust (Al_S), and the mass fraction of Al in dust. In this study, dust flux estimated from seasonal, water-column DAl data from the Bermuda Atlantic Time-series Study (BATS) region are compared with direct dust flux estimated from contemporaneous measurements of …

Geochemical Analysis Of The Eagle Ford Shale In Webb And Dimmit Counties, Tx, Natalie G. Girlinghouse

Electronic Theses and Dissertations

The Late Cretaceous Eagle Ford Shale of South Texas is a mixed carbonate–siliciclastic succession that serves as both a prolific hydrocarbon source and reservoir. This study integrates chemostratigraphy, mineralogical analysis, and elemental ratio proxies to reconstruct depositional environments and assess controls on detrital influx, paleoproductivity, and redox conditions across multiple cores in Webb and Dimmit counties. Major, trace, and redox-sensitive elements were evaluated alongside Total Organic Content (TOC) and carbonate content to identify stratigraphic trends and environmental shifts.

Results reveal distinct geochemical signatures between the Upper and Lower Eagle Ford Shale, with the Lower Eagle Ford characterized by elevated Al-rich …

Bridging The Gap Between Network Science And Network Systems To Identify And Mitigate Cyber Risk: Identify And Mitigate Backdoor Attacks On Graph Neural Networks And On Complex Systems, Sabah Ettahri

Electrical & Computer Engineering Projects for D. Eng. Degree

This doctoral project aims to bridge the gap between graph theory and network science to identify and mitigate cyber risk, represented as a CY-Triangular Network that connects different networks. The CY-Triangular Framework is a cybersecurity system that integrates graph theory and network science through an interoperable learning approach. The objective of this project is to bridge the gap between two domains: network science and network systems. Accordingly, it examines one representative network from each field, focuses on a complex system network, and explores Graph Neural Networks (GNNs). The connection between these domains lies in graph theory. This research demonstrates that …

Flux Crystal Growth Of A Series Of Calcium Rare Earth Silicate Chlorides Calnsio4Cl (Ln = Pr, Nd, Sm, Eu, Gd, And Tb): Mixed Anion Materials With A Spodiosite-Type Structure, Maria Goncalves, Mark D. Smith, Hans Conrad Zur Loye

Faculty Publications

A series of calcium rare earth silicate chlorides, CaLnSiO4Cl (Ln = Pr, Nd, Sm, Eu, Gd, and Tb), was obtained as single crystals from flux crystal growth. The structures were determined by single crystal X-ray diffraction and were found to be related to the spodiosite/Wagnerite mineral structure, Ca2PO4F. The obtained compositions are variations of the spodiosite structure that result from two simultaneous elemental substitutions. Replacing one calcium for one rare earth element and the simultaneous replacement of one VO4³⁻ or PO4³⁻ with one SiO4⁴⁻. CaEuSiO4Cl was found to luminesce, and its photoluminescence spectrum is reported.

Water Circulation Beneath A Hovering Suas For Water Quality Monitoring Applications, Erin E. Hackett, Boone Fleenor, Jensine C. Coggin, Duvall Dickerson-Evans, Nikolaos Vitzilaios, Whitney E. Schuler, Paige K. Williams, Michael L. Myrick

Faculty Publications

Water quality has traditionally been measured via in situ sensors and satellites. The latter has limited applicability for smaller inland water bodies, while the former requires significant logistics, labor, and expense for routine sampling, and reactive/spurious sampling is often not feasible as a result (e.g., sampling pre-/post-storm). Consequently, small uncrewed aircraft system-based (sUAS-based) sampling has emerged as a potential solution to bridge these sampling gaps and challenges. But sampling from an sUAS is complicated by the need to pump water from depth, rather than suspending a sensor from the sUAS, due to concern over sampling sUAS-impacted waters. Here, we measure …

Thermodynamic Assessment Of The Li, Na, K, Cs | F, I Reciprocal Salt For Msr Applications, Clara M. Dixon, Mina Aziziha, Amir Mofrad, Jorge Paz Soldan Palma, Ronald E. Booth, Aiswarya Padinhare Manissery, Jack A. Wilson, Hans Conrad Zur Loye, Hunter B. Tisdale, Juliano Schorne-Pinto, Theodore M. Besmann

Faculty Publications

Gibbs energy models necessary to describe the thermochemical behavior of cesium and iodine in molten FLiNaK (46.5LiF-11.5NaF-42KF mol%), a proposed molten salt reactor coolant and fuel solvent, have been developed as they are of concern due to their high radiotoxicity and volatility. The six constituent pseudo-binary systems LiI-CsI, LiI-KI, LiI-NaI, NaI-KI, KI-CsI and NaI-CsI were evaluated using available phase equilibria and mixing enthalpy measurements. The models for the ternary reciprocal salt systems Li,Cs|F,I, Li,K|F,I, Li,Na|F,I, Na,K|F,I, Na,Cs|F,I and K,Cs|F,I were obtained by interpolation of the optimized pseudo-binary systems and parameters fit as necessary based on observed behavior. The additive (common …