Digital Commons Network^™

Development And Tribological Characterization Of Uhmwpe-Tin Composite Coatings Deposited By Electrostatic Spraying, Jarrod Keith Perez

Theses and Dissertations

The increasing demand for inert, wear-resistant, cost-efficient, environmentally friendly, and low-friction coatings has driven extensive research into polymer-based solutions. Among these, ultra-high-molecular-weight polyethylene (UHMWPE) has emerged as a strong candidate due to its low density, anticorrosion properties, self-lubricating nature, affordability, and ease of processing. However, its low load-bearing capacity limits its widespread use in high-stress tribological applications. To overcome this limitation, this project investigates the development and characterization of UHMWPE composite coatings reinforced with titanium nitride (TiN) particles at varying concentrations (2.5, 5, and 10 wt%) to enhance their mechanical properties and wear resistance.

Binary Solid/Liquid Equilibrium Of Mixtures Of Thermally Robust Salts And Molecular Compounds For Use As Heat Transfer Fluids, Jared Ridge Mathews

Honors Theses

Fossil fuels, contributors to climate change that may bear catastrophic consequences, power the entire world. The human species is almost entirely dependent on fossil fuels for energy, but other sources of renewable and environmentally friendly energy must be developed. Concentrated solar power (CSP) is a promising source of renewable energy with hampered potential—better heat transfer fluids (HTFs) are needed for it to be economically feasible. Currently, the HTFs in industrial use are predominantly either synthetic oils or nitrate-based molten salts. Synthetic oils are only stable up to 400 °C, and molten salts often have high melting temperatures, making them prone …

Spin Coater Design With Pid Algorithm Using Polynomial Regression Approach And Bias Tuning For Tio2 Deposition Process, Geo Surya Andika, Nofrijon Sofyan, Donanta Dhaneswara, Akhmad Herman Yuwono

Journal of Materials Exploration and Findings

The thin-film deposition technique using spin coating offers a cost-effective alternative to Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD). The spin-coating process requires precise control of the motor drive system to ensure that the rotational speed, measured in rotations per minute (RPM), aligns with the set point and remains stable. This study presents the design and development of a spin coater prototype to achieve uniform thin-film deposition. The control method employed utilizes a Proportional-Integral-Derivative (PID) algorithm, incorporating a polynomial approach with bias tuning. The PID control was chosen to achieve stable operation in a non-linear system. The performance …

Incorporating Recycled And Repurposed Plastic Into 100% Reclaimed Asphalt Pavement, Basant Bhatt

Graduate Theses and Dissertations (2019 - present)

The increasing awareness of sustainability in the asphalt industry has driven the use of recycled materials like reclaimed asphalt pavement (RAP) and waste plastic. This study examines the incorporation of recycled polypropylene (rPP), recycled high-density polyethylene (rHDPE), and recycled low-density polyethylene (rLDPE) at 0.3%, 0.6%, and 0.8% dosages into 100% RAP, along with the warm mix asphalt additive Evotherm® P25. Laboratory tests were conducted to evaluate the mechanical and durability performance of the modified asphalt mixtures while rutting and fatigue life were evaluated using mechanistic-empirical (ME) analysis in PerRoad software. Both plastic type and dosage had a statistically significant impact …

Multifunctional Pvdf Ionogels With Magnetic Nanoparticles For Electroactive And Magnetic Actuation, Alfredo Carrillo Valverde

Chemical Engineering Undergraduate Honors Theses

The fast development of compact and multifunctional electronics has driven interest in smart materials capable of responding to multiple stimuli. Ionogels, polymers that have been swollen with ionic liquids (IL), offer several favorable electrochemical and thermal properties due to their intrinsic ion conductivity, wide electrochemical window, non-flammability, and high thermal stability. However, their poor mechanical properties (e.g., modulus and strength) limit their use in applications. In this work, multifunctional PVDF ionogel composites were made by blending magnetically responsive iron oxide nanoparticles (Fe₃O₄ MNPs) into the polymer matrix. The influence of MNP concentration (9-21 wt%) on composition, ionic …

Flexible Microelectrode-Based Impedance Immunosensor For Rapid Detection Of E. Coli O157:H7, Sonatan Kumar Biswas

Graduate Theses and Dissertations

Abstract Food contamination poses a significant threat to public health, the economy, and human health worldwide, occurring at any stage of the food supply chain, from farm to fork. Escherichia coli 0157:H7, recognized as one of the principal causes of foodborne illness, poses a considerable risk to food safety. The primary objective of this investigation is to devise a flexible microelectrode-based immunosensor capable of swiftly identifying E. coli O157:H7 cells without the need for incubation in a pure culture environment. In the development of the biosensor, the gold electrode (composed of 50% Au) underwent an initial coating process involving 2-aminoethanethiol/cysteamine, …

Additive Manufacturing Of Zinc-Based Biomaterials: Fabrication, Performance And Property Evaluation, S. Bandekian, M. Zolfaghari Baghbaderani, J. Drelich, S. Sharif, A.F. Ismail, H. R. Bakhsheshi-Rad

Michigan Tech Publications

The use of zinc and its alloys in additive manufacturing has become an important focus in interventional medical field. This is because zinc as an implant is naturally degradable, has solid mechanical characteristics, and is biocompatible. Biodegradable Zn-based metals made with additive manufacturing offer significant advantages in creating personalized medical implants. This review aims to provide an overview of different types of additive manufacturing methods and processes that can be used in the fabrication of Zn-based medical implants. It offers a comprehensive understanding of additive-manufactured Zn-based alloys for interventional surgeries. The study also summarizes the relationships between degradation properties, mechanical …

Manipulating Martensitic Transformation And Residual Stress Development In Stress Superposed Incremental Forming Of Ss304, Elizabeth M. Mamros, Fabian Maaß, Thomas Gnaupel-Herold, A. Erman Tekkaya, Brad L. Kinsey, Jinjin Ha

Faculty Journal Articles

Stress superposition is one of the strategies used in metal deformation processes to increase the material formability, decrease the required forming forces, and create highly customized components. To investigate the effects of tensile and compressive stresses superposed to the single point incremental forming (SPIF) process, experiments and numerical simulations were conducted for a stainless steel 304 (SS304) truncated square pyramid geometry. Tensile stresses were superposed in-plane on the specimen blank by a custom hydraulic frame, and compressive stresses were incorporated via a polyurethane die. Identified parameters for a martensitic transformation kinetics model for SS304 were used in a two-step finite …

Effects Of Processing And Microstructure On The Oxidation Of Zrb2-Sic In Co2, Marharyta Lakusta, Jeremy L. Watts, William G. Fahrenholtz, David W. Lipke

Materials Science and Engineering Faculty Research & Creative Works

Oxidation kinetics and oxide scale microstructures were compared for ZrB2-30 vol% SiC composites fabricated by hot press sintering of powders and by pressure less sintering of additively manufactured billets. Oxidation in CO₂ was conducted at temperatures up to 1400 °C with durations up to 900 h. All specimens exhibited parabolic oxidation kinetics. Materials with similar composition but different processing histories exhibited differences in oxidation behavior that become evident at extended durations (200–900 h) and higher temperatures (1200–1400 °C). Oxidation rates generally increased with grain size, e.g., at 1000 °C for 200 h, oxide scale thickness increased from 36 to …

Intermediate Stage Densification Kinetics Of High-Entropy Ceramics During Spark Plasma Sintering, Steven M. Smith, William G. Fahrenholtz, Greg E. Hilmas, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

The intermediate stage densification kinetics of (Hf, Nb, Ta, Ti, Zr) B2 and (Hf, Nb, Ta, Ti, Zr) C were studied using a Coble creep rate model. (Hf, Nb, Ta, Ti, Zr) B2 was synthesized by boro/carbothermal reduction and (Hf, Nb, Ta, Ti, Zr) C was synthesized by carbothermal reduction. Both ceramics were densified by spark plasma sintering at 1700–1850°C. The activation energies for densification were 575 ± 53 kJ/mol for the high-entropy boride and 646 ± 4 kJ/mol for the high-entropy carbide. The densification mechanisms were grain boundary diffusion for the high-entropy boride and lattice diffusion for the high-entropy …

Interfacial Defect Properties Of High-Entropy Carbides: Stacking Faults, Shockley Partial Dislocations, And A New Evans-Polanyi-Semenov Relation, Samuel E. Daigle, Stefano Curtarolo, William G. Fahrenholtz, Jon Paul Maria, Douglas E. Wolfe, Eva Zurek, Donald W. Brenner

Materials Science and Engineering Faculty Research & Creative Works

Using first principles calculations, {111} intrinsic stacking fault (ISF) energies in groups IVB, VB, and VIB high-entropy transition metal carbides (HETMCs) are shown to be predictable from an optimized rule of mixtures based on the atomic arrangement near the stacking fault. A composition-independent linear relationship is demonstrated between the ISF energies and the unstable stacking fault (USF) energies along the (112¯){111} γsurface slip path. This relationship represents a new application of the Evans-Polanyi-Semenov principle by treating the ISF and USF energies as analogous to the heat of reaction and transition state barrier in chemical reactions. Further, a full defect energy …

Tuning The Morphology Of Triblock Copolymers Via Homopolymer Blending, John F. Searles

Honors Theses

Morphology plays an important role in the physical properties of block copolymer (BCP) materials. Depending on the type of morphology and chemical composition of the blocks, BCPs are used in applications ranging from soft biomaterials for biomedical devices to rigid materials for ballistics protection. Due to incompatibility between comonomers and required block weight ratios to achieve targeted morphologies, it is generally necessary to use complex, time-consuming, and expensive synthetic techniques to prepare BCPs. As a result, there is increased interest in the development of new processing methods to tailor block copolymer morphology without the need for additional synthesis. The morphological …

Deciphering And Translating Bioinspired Structures For Engineering Materials Design Via Computational Modeling And Machine Learning, Zhangke Yang

All Dissertations

Nature has evolved extraordinary structural materials—such as nacre, bone, and the mantis shrimp’s dactyl club—that achieve remarkable combinations of strength, toughness, and impact resistance. These properties arise from sophisticated synergies between structure and composition. Inspired by these biological systems, this dissertation presents a comprehensive investigation into bioinspired materials, uncovering fundamental mechanisms and providing guidance on designing materials with superior mechanical properties.

This dissertation begins by examining the "brick-and-mortar" structure of nacre, which informs the design of layered polymer-graphene nanocomposite films. Using coarse-grained molecular dynamics simulations, I elucidate mechanisms of dynamic wave propagation and energy dissipation in these systems, providing critical …

Effect Of Audio–Sonic Waves On Heat Transfer Enhancement In A Distilled Water-Based Heat Exchanger, Agggito Pringgo Tetuko, Ayu Yuswati Sari, Silviana Simbolon, Achmad M.S. Sebayang, Nur H. Effendi, Riko Ernando, Amdy Fachredzy, Nining S. Asri, Eko A. Setiadi, Perdamean Sebayang

Makara Journal of Technology

In this research, the influence of audio–sonic waves on distilled water used as the working fluid in a shell-and-tube heat exchanger was examined. The audio–sonic wave frequencies and flow rates of the cold and hot liquids were varied as follows: 4.85, 6.78, and 13.43 kHz for the audio–sonic waves; 0.3, 0.4, and 0.5 l/min for the cold liquid; and 0.76, 1.0, and 1.5 l/min for the hot liquid. An increase in the audio–sonic wave frequency enhanced both the overall heat transfer coefficient (U) and the enhancement factor (EF). The optimum values of U and EF, measured at 300 W/m3 ·°C …

Dust Analyses In Ventilation Ducts, Karolina Vyhlidalova, Petr Vlček, Olga Rubinová, Jiří Bernard

Journal of Sustainable Construction Materials and Technologies

The paper describes the importance of monitoring the dust in the atmosphere of human life. It deals with the issue of dust in air ducts, approaching the methods that can be used to detect the amount of dust. For conditions for buildings in the Czech Republic there is created the methodology of quantitative and qualitative evaluation of dust sediment for the needs of HVAC and other building surfaces. The scale for visual evaluation was created and it has been elaborated the assessment of kind of particles contained in dust.

Assessment Of Long Time Approximation Equation To Determine Thermal Conductivity Of High Porous Materials With Nss Probe, Hussein Humaish, Bastien Ruet, Laurent Marmoret, Hassen Beji

Journal of Sustainable Construction Materials and Technologies

Recent economic changes have increased the focus on energy conservation in buildings. Improve insulation represents one of the biggest challenge to save energy. The TP02 Huksefux® Non Steady State Probe (NSSP) has been used to determine the thermal conductivity of the building insulation materials. Usually, the long term approximation equation (linear form) is applied to determine the thermal conductivity when using hot wire techniques. Long term approximation has been successfully used to characterize glycerol: a fluid which doesn’t present contact resistance and porosity. But, an S-shaped appears for more porous materials. So to generalize the possibility of using this method, …

Electrocatalytic Nitric Oxide Reduction To Yield Ammonia Over Fe3C Nanocrystals, Sen Lin, Lang Zhang, Tong Hou, Jun-Yang Ding, Zi-Mo Peng, Yi-Fan Liu, Xi-Jun Liu

Journal of Electrochemistry

Nitric oxide (NO), which generally originates from vehicle exhaust and industrial flue gases, is one of the most serious air pollutants. In this case, the electrochemical NO reduction reaction (NORR) not only removes the atmospheric pollutant NO but also produces valuable NH₃. Hence, through the synthesis and modification of Fe₃C nanocrystal catalysts, the as-obtained optimal sample of Fe₃C/C-900 was adopted as NORR catalyst at ambient conditions. As a result, the Fe₃C/C-900 catalyst showed an NH₃ Faraday efficiency of 76.5% and an NH₃ yield rate of 177.5 μmol·h^–1·cm^{–2 …}

Ordering Degree Regulation Of Pt2Nico Intermetallics For Efficient Oxygen Reduction Reaction, Chen-Hao Zhang, Han-Yu Hua, Jun-Hao Yang, Qian Zhang, Chang Yang, De-Li Wang

Journal of Electrochemistry

Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction (ORR). Atomic ordered intermetallic compounds (IMC) provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms, thus exhibiting superior electrocatalytic activity and durability. However, quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging. Herein, a series of ternary Pt₂NiCo intermetallic catalysts (o-Pt₂NiCo) with different ordering degree were synthesized by annealing temperature modulation. Among them, the o-Pt …

Performance Of Co2/H2O Co-Electrolysis In A Flat-Tube Solid Oxide Electrolysis Cell Stack Under Air-Free Environment, Xiao-Hui Zhong, Fei Wang, An-Qi Wu, Bei-Bei Han, Jian-Xin Wang, Wan-Bing Guan

Journal of Electrochemistry

This work investigates the transient performance and stability of CO₂/H₂O co-electrolysis in an air-free environment using a flat-tube solid oxide electrolysis cell (SOEC) stack. The results show that the transient behavior of the stack with and without blowing gas in the air electrode is almost the same. With a current density of 0.67 A·cm⁻²@750 °C, the stack operated for over 200 h under co-electrolysis conditions with no air blowing, and the voltage drop rate of the stack was approximately 0.203%/100 hours. Microstructure analysis reveals significant loss of Ni particles and formation of an insulating …

Variation Of Membrane Electrode Assembly Catalyst Layer In Unitized Regenerative Fuel Cell, Yollanda Nurcholifah, Dedi Rohendi, Edy Herianto Majlan, Nirwan Syarif, Addy Rachmat, Dwi Hawa Yulianti, Nyimas Febrika S

Journal of Electrochemistry

A unitized regenerative fuel cell (URFC) is a device that may function reversibly as either a fuel cell (FC) or water electrolysis (WE). An important component of this device is the Membrane electrode assembly (MEA). Therefore, this study aimed to compare the performance outcomes of MEA using electrodes with single and three catalyst layers. This study measured Electrochemical Surface Area (ECSA), Electrochemical Impedance Spectroscopy (EIS), X-ray Diffraction analysis (XRD), and X-ray Fluorescence (XRF). Furthermore, the round-trip efficiency (RTE) of the MEA, as well as the performance in FC and WE mode, was measured. In comparison, The ECSA values of Pt-Ru/C …

Performance Of Quasi-Isotropic Gf/Pet Laminates In Impact And Compression After Impact Loading, Yubo Ma, Shuoyan Niu

Research & Creative Achievement Day

The impact resistance and residual compression strength of two types of glass fiber/ polyethylene terephthalate composites are investigated in this research project. The first materials are glass fiber/ polyethylene terephthalate glycol (GF/PRTG) and the second material is glass fiber/ amorphous polyethylene terephthalate (GF/PETa). Both matrix materials are ductile thermoplastic polymers. The ductility of the matrix is expected to improve the impact resistance of the composites. The advantage of the first material is higher ductility and improved fire resistance, and the advantage of the second material is high bonding strength with the reinforcing fiber glass. Both matrixes and low cost engineered …

Panel Impact And Compressing Strength Testing, Michael A. Dietz, Wyatt N. Laborde

Research & Creative Achievement Day

Intro/Purpose: This project was conducted to investigate how a material's compressive strength is affected after being impacted while supported on three sides. This has broader implications, helping us understand how military equipment, such as battleships, have their compressive strength affected when impacted by projectiles like bullets, shrapnel, or other objects.

Methodology: This test was conducted using panels made of multiple layers of fiberglass pressed together to form a solid sheet. We then cut these sheets into multiple panels. These panels were rectangular, with a tab coming off three sides. The three tabs simulated a wall supporting the material …

Durafold Premium: Composite Folding Table, Regan G. Harvey, Hendrik J. Welti, Parker D. Buth, Stadler J. Lucas, Grace Eischens

Research & Creative Achievement Day

Current folding table designs are made to be lightweight, but the table surface made of high density polyethylene (HDPE) can break and is not repairable. Our team designed the DuraFold Premium as an alternative to the traditional folding tables. The table surface and legs use a sandwich construction consisting of top and bottom face sheets made with carbon and glass reinforcing fibers in an epoxy resin system. In between the two face sheets is a honeycomb core material. This approach results in the DuraFold Premium being extremely durable while remaining lightweight. Over the past academic year, our team has been …

Carbon Club Carrier: A Lightweight Motorized Golf Pushcart, Tanner J. Conniff, Eric M. Courneya, Alex Hilo, Max R. Kauphusman, Luis M. Rodriguez

Research & Creative Achievement Day

The Carbon Club Carrier is a lightweight, motorized golf pushcart designed to enhance convenience and ease of use for golfers. Traditional golf push carts can be cumbersome and require significant effort to maneuver across varying terrain. Our design integrates a carbon fiber frame for durability and weight reduction, coupled with an electric push-assist motor to reduce strain on the user. The use of carbon fiber composite materials ensures a strong yet lightweight structure, optimizing portability and performance. The push-assist motor system is designed to provide variable-speed assistance, allowing golfers to move their clubs effortlessly across the course. The carrier is …

A Novel Fixture Development To Characterize Compression After Impact Damage Of Unidirectional Thermoplastic Composite Laminates, Matt K. Ficker, Dominic L. Perez, Noah Misukanis, Luke E. Poglayen, Jacob Kosmoski

Research & Creative Achievement Day

Impact testing of unidirectional thermoplastic composite materials is a challenge due to the Mode I shear of the primary tows on the impact side. Thermoplastic composite products manufactured using laminate stacking are bonded together with films of polymer on both sides of oriented fiber in typically a cross-ply or quasi-isotropic stack. The resulting failure from the distortion field imposed by a hemispherical tup is debonding along the interface between layer 1 and layer 2 oriented in the layer 1 direction from impact site to edge of panel. This failure mode results when the sample is too small relative to the …

Evaluation Of Chloride Diffusion In Concrete Using Bulk Diffusion Test And Scanning Electron Microscopy, Payton Davis

Doctoral Dissertations and Master's Theses

Reinforced concrete is one of the most widely used construction materials in the world with many bridges and other major infrastructure consisting of such structural elements. A primary concern impacting the durability of concrete is chloride penetration in aggressive environments such as marine or coastal areas. In such environments, chloride ions can penetrate into the pores of concrete leading to the corrosion of embedded steel reinforcement which compromises the structural integrity of concrete. To investigate the issue, a comprehensive experimental program was designed and implemented which involved the preparation and testing of 31 different concrete mixes, each incorporating varying proportions …

Advanced Manufacturing Of Multifunctional Shape Memory Polymer Composites And Self-Healing Systems, John B. Konlan

LSU Doctoral Dissertations

The need for multifunctional light weight structures for engineering applications is on the rise. Multifunctional composites are desired because of their ability to combine multiple functionalities into one structure. The advantages of a high strength-to-weight ratio of multifunctional composites make them desirable and suitable for use in energy-efficient applications. Shape-memory polymers (SMPs) have attracted interest over the past several decades because of their multifunctional nature. They have found use in many applications such as aerospace, satellites, automobiles, textiles, and biomedical devices, where lightweight and multifunctionality are key. The self-healing nature of most SMPs makes them suitable for use in lightweight …

Bioactivity And Mechanical Performance Of Centrifugally Spun Poly(D,L-Lactide)/Poly(3-Hydroxybutyrate) Submicrometric Fibers Containing Zinc Oxide And Hydroxyapatite Nanostructures, Victoria Padilla-Gainza, Heriberto Rodríguez-Tobías, Karen Lozano, Cristobal Rodriguez, Robert Gilkerson, Antonio Ledezma-Pérez, Narcedalia Anaya-Barbosa, Graciela Morales

Mechanical Engineering Faculty Publications

This study investigates the morphological, thermal, mechanical, and bioactive properties of centrifugally spun fibrous composites made from poly(D,L-lactide)/poly(3-hydroxybutyrate) (PLA/PHB) blends with zinc oxide (ZnO) and hydroxyapatite (Hap) nanoparticles. A 75/25 PLA/PHB weight ratio was chosen to balance mechanical and thermal properties. The precursor solution viscosities ranged from 0.25 to 0.50 Pa s, increasing with nanoparticle incorporation probably due to polymer-nanoparticle interactions. SEM revealed a uniform fibrous morphology, with diameters of 1.21 for PLA/PHB, 2.65 for PLA/ZnO/Hap, and 1.80 μm for PLA/PHB/ZnO/Hap. TGA showed two-step degradation for PLA/PHB fibers, while PLA/PHB/ZnO/Hap degraded in a single step at 249°C, leaving a residue …

Impact Of Repeated Washing Cycles On Surface Integrity And Mechanical Properties Of Glass Bottles, Siwat Patamakam Mr., Thitisilp Kijchavengkul, Siriyupa Netramai, Gong Yaijam

Journal of Applied Packaging Research

Glass bottles are a top choice in the global beverage industry, but their inherent brittleness poses challenges in maintaining durability. This study focused on investigating the impact of numbers of washing processes from reusing on the surface quality and mechanical properties of glass bottles after each washing cycle. Contact angle technique was used to determine surface quality of glass bottles. It was found that mechanical integrity, as reflected in internal pressure resistance values, and surface quality of glass bottles exhibited an exponential decline with each washing cycle. Furthermore, a predictive model (R² = 0.8882) was developed to estimate its …

Compositionally Complex Diborides: Competing Solubility During Sintering And Properties, Laura Silvestroni, Carlo Baldisserri, Jacopo Matteo Tabaglio, Nicola Gilli, Jeremy Watts, Steven M.I. Smith, Gregory E. Hilmas, William G. Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

An ultra-high temperature ceramic based on ZrB2, TiB2, and SiC was hot pressed to full density at 1850 °C. Addition of 5 vol% of different metal-compounds, in the form of HfC, VC, NbC or CrB2, increased the densification temperature to 1910 °C. The resulting compositionally complex ceramics had homogeneous microstructures with boride grains exhibiting core-shell features. The shell was a solid solution containing variable amounts of the three metals. Notably, TiB2 remained as a discrete phase in the reference material and in the presence of the V- and Cr- based additions, whilst it dissolved into the main ZrB2-based grains for …