Digital Commons Network^™

Control Of Fe(Iii) Site Occupancy On The Rate And Extent Of Microbial Reduction Of Fe(Iii) In Nontronite, Deb P. Jaisi, Ravi K. Kukkadapu, Dennis D. Eberl, Hailiang Dong

United States Department of Energy: Publications

A quantitative study was performed to understand how Fe(III) site occupancy controls Fe(III) bioreduction in nontronite by Shewanella putrefaciens CN32. NAu-1 and NAu-2 were nontronites and contained Fe(III) in different structural sites with 16 and 23% total iron (w/w), respectively, with almost all iron as Fe(III). Mössbauer spectroscopy showed that Fe(III) was present in the octahedral site in NAu-1 (with a small amount of goethite), but in both the tetrahedral and the octahedral sites in NAu-2. Mössbauer data further showed that the octahedral Fe(III) in NAu-2 existed in at least two environments- trans (M1) and cis (M2) sites. The microbial …

Development Of High-Temperature Ferromagnetism In Sno2 And Paramagnetism In Sno By Fe Doping, A. Punnoose, J. Hays, A. Thurber, M. H. Engelhard, Ravi K. Kukkadapu, C. Wang, V. Shutthanandan, S. Thevuthasan

United States Department of Energy: Publications

We report the development of room-temperature ferromagnetism in chemically synthesized powder samples of Sn_1−xFe_xO₂ (0.005≤ x ≤0.05) and paramagnetic behavior in an identically synthesized set of Sn_1−xFe_xO. The ferromagnetic Sn_0.99Fe_0.01O₂ showed a Curie temperature T_C=850 K, which is among the highest reported for transition-metal-doped semiconductor oxides. With increasing Fe doping, the lattice parameters of SnO₂ decreased and the saturation magnetization increased, suggesting a strong structure-magnetic property relationship. When the Sn_0.95Fe_0.05O₂ was prepared at different temperatures between …

Influence Of Calcite And Dissolved Calcium On Uranium(Vi) Sorption To A Hanford Subsurface Sediment, Wenming Dong, William Ball, Chongxuan Liu, Zheming Wang, Alan Stone, Jing Bai, John M. Zachara

United States Department of Energy: Publications

The influence of calcite and dissolved calcium on U(VI) adsorption was investigated using a calcite-containing sandy silt/clay sediment from the U. S. Department of Energy Hanford site. U(VI) adsorption to sediment, treated sediment, and sediment size fractions was studied in solutions that both had and had not been preequilibrated with calcite, at initial [U(VI)] ) 10^-7-10^-5 mol/L and final pH ) 6.0- 10.0. Kinetic and reversibility studies (pH 8.4) showed rapid sorption (30 min), with reasonable reversibility in the 3-day reaction time. Sorption from solutions equilibrated with calcite showed maximum U(VI) adsorption at pH 8.4 ± 0.1. …

Influence Of Sediment Bioreduction And Reoxidation On Uranium Sorption, Chongxuan Liu, John M. Zachara, Lirong Zhong, Ravi K. Kukkadapu, Jim Szecsody, Dave Kennedy

United States Department of Energy: Publications

The influence of sediment bioreduction and reoxidation on U(VI) sorption was studied using Fe(III) oxide-containing saprolite from the U.S. Department of Energy (DOE) Oak Ridge site. Bioreduced sediments were generated by anoxic incubation with a metal-reducing bacterium, Shewanella putrefaciens strain CN32, supplied with lactate as an electron donor. The reduced sediments were subsequently reoxidized by air contact. U(VI) sorption was studied in Na- NO₃-HCO₃ electrolytes that were both closed and open to atmosphere and where pH, U(VI), and carbonate concentration were varied. Mössbauer spectroscopy and chemical analyses showed that 50% of the Fe(III)- oxides were reduced to …

Fluorescence Spectroscopy Of U(Vi)-Silicates And U(Vi)-Contaminated Hanford Sediment, Zheming Wang, John M. Zachara, Paul Gassman, Chongxuan Liu, Odeta Qafoku, Wassana Yantasee, Jeff Catalano

United States Department of Energy: Publications

Time-resolved U(VI) laser fluorescence spectra (TRLFS) were recorded for a series of natural uranium-silicate minerals including boltwoodite, uranophane, soddyite, kasolite, sklodowskite, cuprosklodowskite, haiweeite, and weeksite, a synthetic boltwoodite, and four U(VI)-contaminated Hanford vadose zone sediments. Lowering the sample temperature from RT to ~5.5 K significantly enhanced the fluorescence intensity and spectral resolution of both the minerals and sediments, offering improved possibilities for identifying uranyl species in environmental samples. At 5.5 K, all of the uranyl silicates showed unique, well-resolved fluorescence spectra. The symmetric O = U = O stretching frequency, as determined from the peak spacing of the vibronic bands …

Oxidative Remobilization Of Biogenic Uranium(Iv) Precipitates: Effects Of Iron(Ii) And Ph, Lirong Zhong, Chongxuan Liu, John M. Zachara, David Kennedy, James E. Szecsody, Brian Wood

United States Department of Energy: Publications

The oxidative remobilization of uranium from biogenic U(IV) precipitates was investigated in bioreduced sediment suspensions in contact with atmospheric O2 with an emphasis on the influence of Fe(II) and pH on the rate and extent of U release from the solid to the aqueous phase. The sediment was collected from the U.S. Department of Energy Field Research Center (FRC) site at Oak Ridge, Tennessee. Biogenic U(IV) precipitates and bioreduced sediment were generated through anaerobic incubation with a dissimilatory metal reducing bacterium Shewanella putrefaciens strain CN32. The oxidative remobilization of freshly prepared and 1-yr aged biogenic U(IV) was conducted in 0.1 …

Enzymology Of Electron Transport: Energy Generation With Geochemical Consequences, Thomas J. Dichristina, James K. Fredrickson, John M. Zachara

United States Department of Energy: Publications

Dissimilatory metal-reducing bacteria (DMRB) are important components of the microbial community residing in redox-stratified freshwater and marine environments. DMRB occupy a central position in the biogeochemical cycles of metals, metalloids and radionuclides, and serve as catalysts for a variety of other environmentally important processes including biomineralization, biocorrosion, bioremediation and mediators of ground water quality. DMRB are presented, however, with a unique physiological challenge: they are required to respire anaerobically on terminal electron acceptors which are either highly insoluble (e.g., Fe(III)- and Mn(IV)-oxides) and reduced to soluble end-products or highly soluble (e.g., U(VI) and Tc(VII)) and reduced to insoluble end-products. To …

Relationship Of Stream Flow Regime In The Western Lake Superior Basin To Watershed Type Characteristics, N. E. Detenbeck, V. J. Brady, D. L. Taylor, V. M. Snarski, S. L. Batterman

United States Environmental Protection Agency: Publications

To test a conceptual model of non-linear response of hydrologic regimes to watershed characteristics, we selected 48 secondand third-order study sites on the North and South Shores of western Lake Superior, MN(USA) using a random-stratified design based on hydrogeomorphic region, fraction mature forest, and fraction watershed storage (lakeCwetland area/watershed area). We calculated several commonly used hydrologic indices from discharge and velocity estimates, including daily flow indices, overall flood indices, low flow variables, and ratios or ranges of flow percentiles reflecting the nature of cumulative frequency distributions. Four principal components (PCs) explained 85.9 and 88.6% of the variation of flow metrics …

Regional Scale Evidence For Improvements In Surface Water Chemistry 1990-2001, B. L. Skjelkvåle, J. L. Stoddard, D. S. Jeffries, K. Tørseth, T. Høgåsen, J. Bowman, J. Mannio, D. T. Monteith, R. Mosello, M. Rogora, D. Rzychon, J. Vesely, J. Wieting, A. Wilander, A. Worsztynowicz

United States Environmental Protection Agency: Publications

The main aim of the international UNECE monitoring program ICP Waters under the Convention of Long-range Transboundary Air Pollution (CLRTAP) is to assess, on a regional basis, the degree and geographical extent of the impact of atmospheric pollution, in particular acidification, on surface waters. Regional trends are calculated for 12 geographical regions in Europe and North America, comprising 189 surface waters sites. From 1990-2001 sulphate concentrations decreased in all but one of the investigated regions. Nitrate increased in only one region, and decreased in three North American regions. Improvements in alkalinity and pH are widely observed. Results from the ICP …

Test 1866: John Deere 5225 Diesel 9-Speed, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA

The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data.

EXPLANATION OF THE TEST PROCEDURES

Purpose

The purpose of …

Nebraska Summary 572: Case-Ih Jx1095c Diesel 12-Speed, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA

The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data.

EXPLANATION OF THE TEST PROCEDURES

Purpose

The purpose of …

Preconditioning Of Primary Human Endothelial Cells With Inflammatory Mediators Alters The “Set Point” Of The Cell, Youichiro Wada, Hasan H. Otu, Shengqian Wu, Md. Ruhul Abid, Hitomi Okada, Towia Libermann, Tatsuhiko Kodama, Shu-Ching Shih, Takashi Minami, William C. Aird

Department of Electrical and Computer Engineering: Faculty Publications

Endothelial cells are highly sensitive to changes in the extracellular milieu. Sepsis results in activation of inflammatory and coagulation pathways. We hypothesized that sepsis-associated mediators may alter the response capacity (so-called “set point”) of endothelial cells. Human umbilical vein endothelial cells (HUVEC) were preincubated in the presence or absence of tumor necrosis factor (TNF)-α, lipopolysaccharide (LPS), hypoxia, hyperthermia, and/or high glucose; treated with or without thrombin for 4 h; and then processed for RNase protection assays of selected activation markers. Priming with TNF-α and LPS significantly inhibited thrombin-mediated induction of vascular cell adhesion molecule-1, intercellular adhesion molecule-1, tissue factor, and …

Self-Assembly Of Nanoparticles On Live Bacterium: An Avenue To Fabricate Electronic Devices, Vikas Berry, Ravi F. Saraf

Ravi Saraf Publications

Lysine-capped gold nanoparticles can be electrostatically assembled on the surface of Bacillus cerius, a Gram-Positive bacterium. The conductivity of the “gold-plated” bacteria assembly immobilized between electrodes is a function of the humidity experienced by the nanoparticles.

Observations Of The Small-Scale Variability Of Precipitation Using An Imaging Radar, Robert D. Palmer, Boon Leng Cheong, Michael Hoffman, Stephen J. Frasier, F.J. Lopez-Dekker

Department of Electrical and Computer Engineering: Faculty Publications

For many years, spatial and temporal inhomogeneities in precipitation fields have been studied using scanning radars, cloud radars, and disdrometers, for example. Each measurement technique has its own advantages and disadvantages. Conventional profiling radars point vertically and collect data while the atmosphere advects across the field of view. Invoking Taylor’s frozen turbulence hypothesis, it is possible to construct time-history data, which are used to study the structure and dynamics of the atmosphere. In the present work, coherent radar imaging is used to estimate the true three-dimensional structure of the atmosphere within the field of view of the radar. The 915-MHz …

The U.S. Air Force Remotely Piloted Aircraft And Unmanned Aerial Vehicle Strategic Vision, U.S. Air Force

United States Air Force: Publications

The U.S. Air Force Remotely Piloted Aircraft and Unmanned Aerial Vehicle Strategic Vision (hereafter referred to as The Strategic Vision) examines the future role of Air Force remotely piloted aircraft (RPAs) and unmanned aerial vehicles (UAVs) and their integration with other Air Force and joint systems. The Strategic Vision is presented in five sections.

Searching For Protein Classification Features, Jennifer A. Smith

Electrical and Computer Engineering Faculty Publications and Presentations

A genetic algorithm is used to search for a set of classification features for a protein superfamily which is as unique as possible to the superfamily. These features may then be used for very fast classification of a query sequence into a protein superfamily. The features are based on windows onto modified consensus sequences of multiple aligned members of a training set for the protein superfamily. The efficacy of the method is demonstrated using receiver operating characteristic (ROC) values and the performance of resulting algorithm is compared with other database search algorithms.

Mechanical Properties Of The Intervertebral Disc As An Estimator Of Postmortem Interval, Jennifer Noelle Jackson

Electronic Theses and Dissertations

Currently, forensic scientists are only able to determine time since death (or postmortem interval) up to the first 60 hours. This is based largely on insect activity. Herein, it is proposed to use the degradation of the intervertebral disc (IVD) after death to determine a relationship between the mechanical properties of cadaveric tissue and time since death in order to extend the 60-hour window. To that end, 1 fresh human spine and 6 pig spines were each separated into sections (6 human and 48 pig), with each section having one intact disc. The sections were buried, unearthed, and cleaned, leaving …

Synthesis And Characterization Of Nanocrystalline Hydroxyapatite Powder; And The Effects Of Oxide-Based Sintering Additives On Tricalcium Phosphate, Himesh A. Bhatt

Electronic Theses and Dissertations

Calcium phosphate (CP) materials have been used extensively for bone replacement and augmentation due to their similarity to the mineral component of bone. In addition to being non-toxic, they are biocompatible, not recognized as foreign materials in vivo, and most importantly, exhibit osteoconductive behavior, being able to help in bone formation during healing. CPs form an intimate physicochemical bond with the host tissue, termed osseointegration. However the main limitation of calcium phosphates is their inherent brittle nature and poor mechanical performance under complex stress states. As a result, these materials have been used clinically only in non-load-bearing applications, primarily as …

The Effect Of Immediate Feedback And After Action Reviews (Aars) On Learning, Retention And Transfer, Michael Sanders

Electronic Theses and Dissertations

An After Action Review (AAR) is the Army training system's performance feedback mechanism. The purpose of the AAR is to improve team (unit) and individual performance in order to increase organizational readiness. While a large body of knowledge exists that discusses instructional strategies, feedback and training systems, neither the AAR process nor the AAR systems have been examined in terms of learning effectiveness and efficiency for embedded trainers as part of a holistic training system. In this thesis, different feedback methods for embedded training are evaluated based on the timing and type of feedback used during and after training exercises. …

Ascertaining The Growth Of A Company A System Dynamics Approach, Fakir Mohideen Noor Mohideen

Electronic Theses and Dissertations

Business is often about creating change for other businesses. At times, these changes affect only the company and at other times they affect the entire industry. There is a time in the life of a business when its fundamental way of functioning is questioned and is subjected to change. That change can mean an opportunity to rise to new heights, or it might even signal the beginning of the end. This fundamental change in any business is known as an inflection point. Understanding the nature of its inflection point and responding to that point suitably will help to safeguard a …

Detection Of The R-Wave In Ecg Signals, Sasanka Valluri

Electronic Theses and Dissertations

This thesis aims at providing a new approach for detecting R-waves in the ECG signal and generating the corresponding R-wave impulses with the delay between the original R-waves and the R-wave impulses being lesser than 100 ms. The algorithm was implemented in Matlab and tested with good results against 90 different ECG recordings from the MIT-BIH database. The Discrete Wavelet Transform (DWT) forms the heart of the algorithm providing a multi-resolution analysis of the ECG signal. The wavelet transform decomposes the ECG signal into frequency scales where the ECG characteristic waveforms are indicated by zero crossings. The adaptive threshold algorithms …

A New Paradigm Of Modeling Watershed Water Quality, Fan Zhang

Electronic Theses and Dissertations

Accurate models to reliably predict sediment and chemical transport in watershed water systems enhance the ability of environmental scientists, engineers and decision makers to analyze the impact of contamination problems and to evaluate the efficacy of alternative remediation techniques and management strategies prior to incurring expense in the field. This dissertation presents the conceptual and mathematical development of a general numerical model simulating (1) sediment and reactive chemical transport in river/stream networks of watershed systems; (2) sediment and reactive chemical transport in overland shallow water of watershed systems; and (3) reactive chemical transport in three-dimensional subsurface systems. Through the decomposition …

Assessment Framework For The Evaluation And Prioritization Of University Technologies For Licensing And Commercialization, Ahmad D. Rahal

Electronic Theses and Dissertations

US corporations have long recognized university related scientific research as an important source of long term economic growth and technological innovation. This dynamic involvement with industry has drastically increased the university technology transfer and licensing activities, and has stretched the human and financial resources of Technology Management and Licensing Offices of many US universities. This research provides a mechanism that can aid in the complex process of properly assessing university-owned technologies and intellectual properties, to identify those with licensing and commercialization potential for the pursuit of truly important breakthrough discoveries. This research focuses on the university technology licensing and commercialization …

Designing A Document Delivery System For Ucf S Interlibrary Loan Department, Abha Y. Trivedi

Electronic Theses and Dissertations

Interlibrary Loan entails obtaining copies of library materials not found in the library's collection on behalf of the library's patrons (borrowing), as well as providing copies of library materials requested by other libraries (lending). The dynamic nature of today's library environment is well illustrated by the rapid changes occurring in the role of interlibrary loan. The vision statement of the University of Central Florida Library is: The library performs a central role of adding value to information for the academic community by creatively improving and providing information resources and services. The library strives to create an environment that encourages the …

Stormwater Irrigation Of Saint Augustine Grass: Nitrogen Balance And Evapotranspiration, Ewoud Hulstein

Electronic Theses and Dissertations

A change in surface condition of a watershed, which is usually caused by development, can have measured effects on the naturally occurring hydrologic cycle and nitrogen cycle. This could result in environmental problems, such as reduced springflow and eutrophication. In an effort to address these issues, a combination of best management practices (BMPs) can be adhered to. The practice of using excess stormwater as a source for irrigation is proposed as a BMP for the minimization of impacts by development to the hydrologic and nitrogen cycles. To study the proposed BMP, a field experiment was installed in an outdoor location …

Debris Tracking In A Semistable Background, Karthikkalathi Vanumamalai

Electronic Theses and Dissertations

Object Tracking plays a very pivotal role in many computer vision applications such as video surveillance, human gesture recognition and object based video compressions such as MPEG-4. Automatic detection of any moving object and tracking its motion is always an important topic of computer vision and robotic fields. This thesis deals with the problem of detecting the presence of debris or any other unexpected objects in footage obtained during spacecraft launches, and this poses a challenge because of the non-stationary background. When the background is stationary, moving objects can be detected by frame differencing. Therefore there is a need for …

Kentucky Water Resources Research Institute Annual Technical Report Fy 2004, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Annual Technical Reports (USGS’s 104b Grant Program)

The FY 2004 Annual Technical Report for Kentucky consolidates reporting requirements of the Section 104(b) base grant award in a single technical report that includes: 1) a synopsis of each research project supported during the period, 2) a list of related reports, 3) a description of information transfer activities, 4) a summary of student support during the reporting period, and 5) notable achievements and awards during the year.

Evaluation Of A Mechanical System For Reconstructing Soil On Surface Mined Land, John P. Fulton, Larry G. Wells

Biosystems and Agricultural Engineering Faculty Publications

The existence of excessive soil compaction has hindered the surface mining industry from returning land to pre−mining productivity after reclamation, especially on prime farmland soils. Heavy earthmoving equipment used during reclamation tends to generate root−limiting bulk densities that adversely affect plant growth thereby decreasing yields. Therefore, the purpose of this study was to evaluate a mechanism, called the ‘Soil Regenerator,’ which reconstructs soil media at minimum bulk density during surface mine reclamation. The prototype soil forming mechanism was mounted on the front of a conventional bulldozer. Soil was placed in long narrow windrows by a scraper or bulldozer. As the …

Dredging And Dredge Disposal And Reuse In Ireland, Séamus Sutton

Theses

Dredging involves raising material from a river or estuary bed to the surface and transporting it some distance for disposal or reuse. It may be required to improve navigational access, to allow for port development or for mining aggregates.

This thesis includes a literature review and a detailed study of the dredging industry in Ireland. This study is partly based on a nationwide survey undertaken on dredging and dredge disposal and reuse, the results of which are included in a dredging database created for this project. All the main stakeholders in the industry were invited to complete questionnaire forms for …

Numerical Modelling Of Sediments In Cork Harbour, Jérémy Pingon

Theses

In recent years there have been considerable developments in the new and emerging field of hydroinformatics. This relatively new discipline is concerned with the application of computer and networking technology for the planning, management and protection of water bodies.

Environmental issues in estuaries require accurate and detailed knowledge of cohesive sediment transport processes to assess different issues including water quality, pollutant dispersion, and dredging and maintenance of navigation channels.

This thesis presents a review of the main sediment properties and processes required for modelling the behaviour and transport of sediments. It also introduces a new approach to sediment properties using …