Digital Commons Network^™

Pilot Study Of Nutrient Loading In A Wet Detention Lake, Eric C. Gurr

Electronic Theses and Dissertations

Florida is surrounded by water, and its many internal lakes and rivers have long been recognized for their excellent fishing and boating. This notoriety draws land developers to the lake shores to establish residential and commercial infrastructure. This land development brings with it flood plain alteration, water level stabilization, and increased nutrients which cause adverse impacts to our lakes. In response, the United States Environmental Protection Agency (EPA) passed the Federal Clean Water Act (CWA) in 1972 which set the framework for the water quality standards for the entire United States. As a result of the CWA many point sources …

Eino: An Intelligent Tutor For The University Of Central Florida Infinity Web Applets, James Hollister

Electronic Theses and Dissertations

This study investigated the various methods involved in creating an intelligent tutor for the University of Central Florida Infinity Web Applets (UCF Infinity Web Applets). After conducting research into various methods, two major methods emerged and they are: solving the problem for the student and helping the student when they become stymied and unable to solve the problem. A storyboard was created to show the interactions of the student and system along with a list of features that were desired to be included in the tutoring system. From the storyboard and list of features, an architecture was created to handle …

An Investigation Of Size Exclusion And Diffusion Controlled Membrane Fouling, Colin Michael Hobbs

Electronic Theses and Dissertations

The reduction of membrane productivity (i.e. membrane fouling) during operation occurs in virtually all membrane applications. Membrane fouling originates from the method by which membranes operate: contaminants are rejected by the membrane and retained on the feed side of the membrane while treated water passes through the membrane. The accumulation of these contaminants on the feed side of the membrane results in increased operating pressures, increased backwashing frequencies, increased chemical cleaning frequencies, and increased membrane replacement frequencies. The most significant practical implication of membrane fouling is increased operating and maintenance costs. As such, membrane fouling must be properly managed to …

Self-Assembled Lipid Tubules: Structures, Mechanical Properties, And Applications., Yue Zhao

Electronic Theses and Dissertations

Self-assembled lipid tubules are particularly attractive for inorganic synthesis and drug delivery because they have hollow cylindrical shapes and relatively rigid mechanical properties. In this thesis work, we have synthesized lipid tubules of 1,2-bis(tricosa-10,12-dinoyl)-sn-glycero-3-phosphocholine (DC8,9PC) by self-assembly and polymerization in solutions. We demonstrate for the first time that both uniform and modulated molecular tilt orderings exist in the tubule walls, which have been predicted by current theories, and therefore provide valuable supporting evidences for self-assembly mechanisms of chiral molecules. Two novel methods are developed for studying the axial and radial deformations of DC8,9PC lipid tubules. Mechanical properties of DC8,9PC tubules …

Comparison Of Thm Formation During Disinfection: Ferrate Versus Free Chlorine For Different Source Waters, Adhem Mukattash

Electronic Theses and Dissertations

The objective of the study was to compare the trihalomethanes (THMs) produced from ferrate with hypochlorite and to determine how different the THM production would be for a given degree of disinfection (3 log reduction in Heterotrophic Plate Count (HPC)). Different water samples were collected from Lake Claire, Atlantic Ocean, and secondary effluent from an advanced wastewater treatment plant. THM formation was determined using a standard assay over 7 days at room temperature. In addition samples were tested for Total Coliform Escherichia coli (TC/E.coli), and heterotrophic bacteria using HPC by spreadplating on R2A agar. Dissolved organic carbon (DOC) was measured …

Microwave Synthesis Of Nanocrystalline Hydroxy Apatite And Comparison Of Its Biomechanical Properties With Tio2 Structures, Saurabh Verma

Electronic Theses and Dissertations

Nanocrystalline hydroxyapatite (HAp) powder of size 10-20 nm was synthesized applying microwave radiation using calcium nitrate tetrahydrate and sodium phosphate dibasic anhydrous as the starting materials. Microwave power of 600 W and Ca/P ratio of 1.66 in the starting chemicals served as the major factors in the synthesis of nanocrystalline HAp powder. Phase composition and evolution were studied using X-ray diffraction (XRD) technique. Morphology, agglomeration and particle-size of the synthesized powder were studied using Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) techniques. Energy Dispersive Spectrum (EDS) was used to determine the elemental composition of the powder. Thermal properties …

A Neat Approach To Genetic Programming, Adelein Rodriguez

Electronic Theses and Dissertations

The evolution of explicitly represented topologies such as graphs involves devising methods for mutating, comparing and combining structures in meaningful ways and identifying and maintaining the necessary topological diversity. Research has been conducted in the area of the evolution of trees in genetic programming and of neural networks and some of these problems have been addressed independently by the different research communities. In the domain of neural networks, NEAT (Neuroevolution of Augmenting Topologies) has shown to be a successful method for evolving increasingly complex networks. This system's success is based on three interrelated elements: speciation, marking of historical information in …

Reversion Of Poly-Phosphates To Ortho-Phosphates In Water Distribution Systems, Avinash Shekhar

Electronic Theses and Dissertations

Orthophosphates and polyphosphates are rarely present at significant levels in raw water source but are purposefully added to the water in various forms to inhibit corrosion, iron oxidation (red water), or calcium carbonate precipitation (scale formation). Orthophosphates serve as building blocks for polyphosphates, which includes structures in linear chain, branched chains (metaphosphate) and "glassy" polyphosphate polymers. The advantage of polyphosphates over ortho phosphates lies in the fact that they slowly revert to orthophosphates and thus provide corrosion inhibition action over longer period of time in distribution systems. A study was completed for Tampa Bay Water on water distribution systems in …

Temperature Inside The Landfill: Effects Of Liquid Injection And Ambient Temperature, Amit Kumar

Electronic Theses and Dissertations

This study represents an analysis of comprehensive temperature and moisture content data collected from the anaerobic portion of a bioreactor landfill at the New River Regional Landfill, Florida, USA. The main focus of the study was the analysis of effects of the liquid injection on the temperature inside the landfill. When the leachate or groundwater at lower temperature than the landfilled waste is injected into the landfill, it has an initial cooling effect on the waste until the biological activity, enhanced by the additional moisture, releases heat. This cooling effect was tested in the study to determine whether it could …

Using Electrochemical Monitoring To Predict Metal Release In Drinking Water Distribution Systems, Rajendra D. Vaidya

Electronic Theses and Dissertations

Corrosion of distribution system piping and home plumbing materials is a major concern in the water community. Iron release adverse affects aesthetic water quality and the release of copper and lead is regulated by the Lead and Copper rule (LCR) and can adversely affect consumer health. Corrosion control is typically done by pH regulation and/or addition of corrosion inhibitors. Monitoring of corrosion control is typically done after the fact by monitoring metal release, functional group concentration of the selected chemical species or water quality. Hence, the associated laboratory analyses create a significant delay prior to the assessment of corrosion in …

Self-Consistent Analyses For Potential Conduction Block In Nerves By An Ultrashort High-Intensity Electric Pulse, R. P. Joshi, A. Mishra, Q. Hu, K. H. Schoenbach, A. Pakhomov

Bioelectrics Publications

Simulation studies are presented that probe the possibility of using high-field (>100kV ∕ cm), short-duration (∼50ns) electrical pulses for nonthermal and reversible cessation of biological electrical signaling pathways. This would have obvious applications in neurophysiology, clinical research, neuromuscular stimulation therapies, and even nonlethal bioweapons development. The concept is based on the creation of a sufficiently high density of pores on the nerve membrane by an electric pulse. This modulates membrane conductance and presents an effective "electrical short" to an incident voltage wave traveling across a nerve. Net blocking of action potential propagation can then result. A continuum approach based …

Nondestructive Evaluation Of Rc Structures Strengthened With Frp Laminates Containing Near-Surface Defects In The Form Of Delaminations, Mahmut Ekenel, John J. Myers

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Fiber reinforced polymer (FRP) composites are being utilized in a wide range of application areas in structural rehabilitations because these materials are less affected by corrosive environmental conditions and known to provide longer life with less maintenance. However, there are still some concerns about FRP strengthened reinforced concrete (RC) structures, such as the presence of near-surface defects. Currently limited data exists regarding this issue. the presence of near-surface defects in the form of delaminations between the fiber reinforced polymer (FRP) laminate and concrete substrate can significantly affect the structural integrity and stiffness of the structural section. These defects should be …

Quantification Of Steroid Sex Hormones Using Solid-Phase Extraction Followed By Liquid Chromatography-Mass Spectrometry, Youssef Filali-Meknassi, Muriel Auriol, Craig D. Adams, Rao Y. Surampalli

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

In this study, the occurrence of trace amounts of natural and synthetic steroid estrogens in the aquatic environment was studied using liquid chromatography coupled with electrospray mass spectrometry, following solid-phase extraction (SPE). the SPE was performed with C18 and NH2 cartridges. the first objective was to develop a reliable method for analyzing steroid estrogens (resulting from human and animal excretions) in different matrices. the method developed was then applied to quantify the occurrence of natural and synthetic hormones (estrone [E1], 17β-estradiol [βE2], 17α-estradiol [αE2], estriol [E3], and 17α-ethinylestradiol [EE2]) in environmental samples in surface water and wastewater treatment plant (WWTP) …

Test 1895: John Deere 7830 Autoquad-Plus 20-Speed, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA

The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data.

EXPLANATION OF THE TEST PROCEDURES

Purpose

The purpose of …

Biodegradation And Characterization Of A Bio-Based Polyester, Benjamin Edward Stevens

LSU Master's Theses

Anaerobic biodegradation in sewage sludge and aerobic biodegradation in compost of polyhydroxybutyrate (PHB) were investigated to determine degradation kinetics and identify changes in polymer properties. To determine the impact of a natural plasticizer on biodegradation, tributyl citrate (TBC) was blended with some test specimens. For comparison to another bioplastic, polylactic acid (PLA) was biodegraded in the anaerobic study. Evolved gaseous carbon was measured to assess biodegradability according to ASTM standards D5210 and D5338. Mass loss experiments were performed to facilitate determination of degradation kinetics. Melt-pressed plates of the bioplastic with five different initial mass-to-surface-area ratios (plate thicknesses of 0.24, 0.5, …

Passive Alignment Of Micro-Fluidic Chips Using The Principle Of Elastic Averaging, Sitanshu Gurung

LSU Master's Theses

This thesis presents a novel design for a passive alignment feature for vertically stacking chips in a micro fluidic device. Each chip is the size of a standard microscopic slide (75mm—25mm) and is a highly specialized functional unit designed and fabricated to process fluidic samples. The fluidic samples in the device flows from one chip to another using inter connecting holes 500μm-100μm in diameter. Hence an alignment of better than 100μm between chips is necessary to allow for the interconnecting holes to overlap so as to provide with a path for the fluid to flow. The feature to be used …

Krylov Subspaces From Bilinear Representations Of Nonlinear Systems, Marissa Condon, Rossen Ivanov

Articles

For efficient simulation of state-of-the-art dynamical systems as arise in all aspects of engineering, the development of reduced-order models is of paramount importance. While linear reduction techniques have received considerable study, increasingly nonlinear model reduction is becoming a significant field of interest. From a circuits and systems viewpoint, systems involving micromachined devices or systems involving mixed technologies necessitate the development of reduced-order nonlinear models. From a control systems viewpoint, the design of controllers for nonlinear systems is greatly facilitated by nonlinear model reduction strategies. To this end, the paper proposes two novel model-reduction strategies for nonlinear systems. The first involves …

Evaluation Of Consolidation Parameters Of Cohesive Soils Using Pcpt Method, Rohit Raj Pant

LSU Master's Theses

The piezocone penetration test (PCPT) has emerged as most widely used in situ method for obtaining soil profile as well as physical properties. The PCPT method provides three independent and nearby continuous measurements with the depth; they are: tip stress (qc), sleeve friction (fs) and pore pressure (u1, u2, or u3). These measurements have been successfully used to correlate various soil properties such as undrained shear strength, unit weight and consolidation parameters. This study presents the evaluation of the PCPT interpretation methods for their capability to reasonably estimate the consolidation parameters namely constrained modulus, overconsolidation ratio and vertical coefficient of …

Influence Of Temperature On The Performance Of Wetlands Treating Chlorinated Volatile Organic Compounds, Maria G. Murillo

LSU Master's Theses

Various studies have presented models to predict the performance of constructed wetlands at different temperatures focused on the removal of conventional pollutants, and common configuration of constructed wetlands. Investigations on the effect of temperature on the performance of constructed wetlands treating chlorinated volatile organic compounds are limited to microcosm studies. This study is meant to come up with kinetic and energy balance input data for mathematical models that can be used to predict the performance of upflow constructed treatment wetlands treating chlorinated ethenes and ethanes at different ambient temperatures. Bench scale continuous upflow columns will be conducted to investigate the …

Photo-Control Of Antisense Activity In Cell Culture Using Caged Oligodeoxynucleotides, Mindi Huguet Faubion

LSU Master's Theses

Antisense oligodeoxynucleotides (AS ODNs) are short single-stranded pieces of DNA that are designed to hybridize with messenger RNA and thus offer a powerful technique for controlling gene expression. Phosphorothioate AS ODNs are a well-established modification of the traditional phosphodiester structure that increase the in vitro half-life of AS ODN activity. In this work, we describe a method for controlling the hybridization activity of PS ODNs in cell culture with a photo-reversible mechanism. The influence of a photocaging compound, 1-(4,5-dimethoxy-2-nitrophenyl)diazoethane (DMNPE) on hybridization of ISIS 2302, a 20-mer PS ODN, was modeled using a molecular beacon assay. Based on this model, …

Fabrication Of Perforated Polymer Membranes Using Imprinting Technology, Anish Roychowdhury

LSU Master's Theses

The goal of the present study was to fabricate perforated membrane structures in polymers with the pore diameter ranging from 10 ìm down to the sub ìm scale. The perforated membrane structure plays an important role in many biological systems. Thus the ability to reproduce such architecture will help with the study of biological systems by mimicking biological cell membrane-like structures and open new vistas in the study of transport behavior in cell biology and the separation of biological vesicles. Such structures also have potential uses as components in polymer optics and modular micro/nanofluidic devices. Use of polymer substrates is …

Level Basin Approaches To Improve Water Management In Surface Irrigation For Northeast Louisiana, Luis R. Ocampo Briceno

LSU Master's Theses

In the state of Louisiana surface irrigation is widely used due to the low start-up cost, typically high rainfall, and soil conditions. Irrigation scheduling is an important practice to achieve water use efficiency in agriculture. The objectives of this study were to compare three different methods to determine crop evapotranspiration (ETc) for soybeans in addition to, evaluate a computer based irrigation scheduling program using real scale fields. Weather variables, soil moisture and irrigation water use collected during the summer months of 2005 and 2006 at a production agriculture farm in northeast Louisiana were studied. The ETc estimates obtained using atmometers …

Fabrication Of Single Walled Carbon Nanotube (Sw-Cnt) Cantilevers For Chemical Sensing, Jui-Ching Hsu

LSU Master's Theses

With the discovery of carbon nanotubes (CNTs), many applications have been implemented based on their unique electronic, mechanical, chemical and optoelectronic properties. One area of applications is in gas sensors for detecting, oxygen, flammable and toxic gases. In our work, the focus is on the fabrication of carbon nanotube (CNT) cantilever sensors for integration with CMOS readout chip which offer increased sensitivity. The higher surface-to-bulk ratio enhances the property and performance of the gas sensor by nanocantilevers. In this work, we present the detection method based on the change in capacitance of the single walled carbon nanotube (SWCNT) cantilever. Carbon …

Magnetically Induced Release Of Fluorescein Isothiocyanate (Fitc) From Polymer Nanoparticle Composites (Pncs), Michelle Urbina

LSU Master's Theses

Magnetically induced drug release can be used as a site-specific, minimally invasive pharmaceutical treatment. Its purpose is to increase the efficacy of drug therapies to diseased or damaged tissue and to decrease the amount of unnecessary damage to healthy, surrounding tissue. To prove the concept of drug release by a magnetic field, this study focused on the release of a fluorescent molecule from magnetic polymeric nanoparticle composites (PNCs) via induction of an alternating current (AC) magnetic field. Fluorescent magnetic PNCs used were 250 ?m or less in size, and were made of poly(methyl methacrylate) (PMMA) containing either the magnetic material …

Production Well Operations Optimization In Water Distribution System Using Genetic Algorithm, Vineet Katiyar

LSU Master's Theses

The City of Chandler, Arizona lies in semi-arid area and the water resources management has been a major concern by the State citizen. There is always a need of optimizing the available water resources when the rate of demand constantly beats the rate of replenishment. In this study we have developed a management model to link the Chandler water distribution model (EPANET) with the Chandler groundwater flow model (MODFLOW) under an optimization framework (Genetic algorithm). The EPANET model supplied by the Chandler city municipal authority has several improper setting (pumping schedules, valves settings, pressure zones etc.). The original model has …

Pre-Treatment Of Dynamically Varying Waste Gas Concentrations Using Activated Carbon Prior To Biofiltration: Effect Of Cycle Length On Degree Of Load Equalization, Kodi L. Collins

LSU Master's Theses

Dynamically varying waste gas concentrations pose challenges to the operation and design of air pollution control techniques such as biofilters. Although design approaches are becoming well established for biofilters treating gases containing VOC concentrations that are constant as a function of time, many industrial processes emit gas streams contaminated with volatile organic compounds at concentrations that fluctuate with time. Application of an effective load equalization technique could eliminate some challenges associated with fluctuating pollutant concentrations. Recent research has demonstrated that granular activated carbon (GAC) can serve as a passively controlled system to provide load-equalization as a pre-treatment prior to biofiltration. …

Characterization And Analysis Of Hybrid Electronic Materials For Molecular Based Devices, Sathish Thiruvengadam

LSU Master's Theses

The goal of this work is to characterize and to analyze hybrid electronic materials (HEMs) using fluorescence (FL) spectroscopy and conductive probe-atomic force microscopy (CP-AFM) in order to investigate the electrical and optical properties of these materials. Currently, research efforts to characterize novel organic materials for the determination of molecular level transport properties are of great interest.[6] One of the most interesting organic materials is the porphyrin molecule, which exhibits behavior useful for memory applications.[4] Colloidal CdS quantum dots (Q-CdS) capped with dioctyl sulfosuccinate (AOT) and thiol functionalized porphyrin molecules are explored for their potential application to next-generation hybrid electronic …

Whole Genome Duplications And Contracted Breakpoint Graphs, Max A. Alekseyev, Pavel A. Pevzner

Faculty Publications

The genome halving problem, motivated by the whole genome duplication events in molecular evolution, was solved by El-Mabrouk and Sankoff in the pioneering paper [SIAM J. Comput., 32 (2003), pp. 754–792]. The El-Mabrouk–Sankoff algorithm is rather complex, inspiring a quest for a simpler solution. An alternative approach to the genome halving problem based on the notion of the contracted breakpoint graph was recently proposed in [M. A. Alekseyev and P. A. Pevzner, IEEE/ACM Trans. Comput. Biol. Bioinformatics, 4 (2007), pp. 98–107]. This new technique reveals that while the El-Mabrouk–Sankoff result is correct in most cases, it does not hold in …

Colored De Bruijn Graphs And The Genome Halving Problem, Max A. Alekseyev, Pavel A. Pevzner

Faculty Publications

Breakpoint graph analysis is a key algorithmic technique in studies of genome rearrangements. However, breakpoint graphs are defined only for genomes without duplicated genes, thus limiting their applications in rearrangement analysis. We discuss a connection between the breakpoint graphs and de Bruijn graphs that leads to a generalization of the notion of breakpoint graph for genomes with duplicated genes. We further use the generalized breakpoint graphs to study the Genome Halving Problem (first introduced and solved by Nadia El-Mabrouk and David Sankoff). The El-Mabrouk-Sankoff algorithm is rather complex, and, in this paper, we present an alternative approach that is based …

Effects Of Capping On Biodegradation Of Organic Contaminants In Sediments, Eun Ju Lee

LSU Doctoral Dissertations

Sediment capping remains an effective remediation technique for contaminated sediments due to its capability to contain contaminants and provide a sound habitat for indigenous biota. This research investigated the effect of capping on biodegradation of organic contaminants in Anacostia River sediments using both experimental and modeling techniques. 14C–Phenanthrene mineralization was monitored under various redox conditions in Anacostia River sediments. Mineralization of 14C–phenanthrene was strongly linked to sulfate reduction, which was the more energetic process than any other anaerobic condition in Anacostia sediments. Sulfate is a more promising terminal electron acceptor for intrinsic degradation in Anacostia River and other PAH contaminated …