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Determination Of The Temperature Coefficients Of Selected Material Constants Of Dilithium Tetraborate, Gregory S. Weaver

Theses and Dissertations

The first and second order temperature coefficients of the material constants c^E₁₁, c^E₁₂, c^E₄₄, c^E₆₆, and e¹⁵ of dilithium tetraborate (Li₂B₄O₇) have been measured over a temperature range of 20°C to 150°C. An improved resonator method was used to measure the fundamental zero mass loading antiresonant frequencies of selected pure-mode orientations of Li₂B₄O₇. Material constants extraction was performed using a linear least squares matrix method. The resulting material constant curves were fit with a third …

A Modified Lrt-Based Spread-Spectrum Receiver Using Spatial And Temporal Processing, Jeffrey L. Cutcher

Theses

The problem of demodulating a direct-sequence (DS) spread-spectrum signal in the presence of single-tone or narrow-band interference and multi-path is discussed. A likelihood-ratio test (LRT) receiver is presented which consists of a whitening filter and a RAKE correlator.

A modified LRT receiver structure is then considered where the whitening filter is replaced by an antenna array with corresponding tap coefficients. The array spatially removes the interference by estimating it's angle-of-arrival. Using the array has an advantage over the original LRT receiver when a narrow-band interference is present. Both receivers are identical in performance under the single-tone interference model.

A third …

A Defect Detection Algorithm For Sequential And Parallel Computers, Ralf Hross

Theses

The comparison of images containing a single object of interest, where one of them contains a model object, is frequently used for defect detection/identification. This is often a problem of interest to industrial applications. To make this task more efficient, the implementation on parallel computers should be a major objective. This thesis introduces sequential and parallel versions of an algorithm that compares original(reference) and processed images in the time and frequency domains. The emphasis is on parallel implementation. This comparison may help to detect changes in images. Extracted data is also compared to database data in an attempt to pinpoint …

Laser Scanning In-Situ Photoelectrochemical Microscopictechnique And Its Applications, Zugeng Lin, Jinkua You, Xiangdong Zhuo, Chun Zhang, Yong Yang

Journal of Electrochemistry

The main factors of the laser scanning in-situ photoelectrochemical microscopic measurement system which is set up in our lab have been discusaed in this paper. Some applications of this technique for in-situ study of modification and processing of semiconductor electrodes, monitoring of electro deposition process of semiconducting material and redox reaction occurring at metal oxide electrodes have also been presented. The results have shown that the technique is very powerful that for studing local photoelectrochemical properties of semiconductors and metal oxide electrodes. These provide important information on the micro structural and electronic properties in the solid/electrolyte interface.

Studies On Low Temperature Performance Of Rechargeable Mh-Ni Batteries, Wenkuan Zhang, Jingxian Shi, Yuwan Lou, Qiusheng Duan

Journal of Electrochemistry

The Dependence of low temperature performance on the alloy composition and electrolyte component for rechargeable MH-Ni batteries is studied, the suitable composition of alloy and electrofyte are founds.

An Indirect Electrochemical Oxidation Of Toluene──Anodic Oxidation Of Mn(Ⅱ) On The Lead Electrode, Zhonghua Wang, Qingmin Hua, Guacai Chen, Zhongquan Wang, Yunan Qiu, Xingguo Yan

Journal of Electrochemistry

The electrochemical oxidation of Mn(Ⅱ) to Mn(Ⅱ) in concentrated H₂SO₄ (2 ~ 8 mol⋅L^-1) at lead electrode has been studied. It is found that the electrode surface is oxidized to PbO₂ in a direct electrochemical reaction, then PbO₂ formed reacts with Mn(Ⅱ) in a chemical reaction. Some effects involves current density, concentration of H₂SO₄, temperature and conversionwere evaluated. The rule of electrogenerated Mn(Ⅲ) in flow electrolysis cell were determined at several conditions. The current efficiency at greater than 90% is obtained in general.

Electrochemically Modified Glassy Carbon Electrode And Determination Of Copper By Anodic Stripping Voltammetry, Jinrui Xu, Yie Liu, Xiurun Zhuang, Tomoo Miwa, Toyohide Takeuchi

Journal of Electrochemistry

This paper reported the glassy carbon electrode modified by cyclic voltammetrybetween -0.1 and +1.5 V (vs. SCE) in an aqueous solution containing catechol, for maldehyde and talium hydroxide. The modified electrode can be applied to the determination of copper(Ⅱ) in water, and its sensitivity is about 35 times higher than that of unmedified glassy carbon electrode, The quantitative limit with this modified electrode is 0.1 ng/ml.

Photoelectrochemical And Spectroelectrochemical Studies Oniron Oxide Ultrafine Particles, Maizhi Yang, Yongjun Ji, Wen Zhang, Shengmin Cai, Xiaojiang Lu, Zhongqun Tian, Jin Luo

Journal of Electrochemistry

In this paper, Raman spectra, photocurrent and the UV-VIS reflectance aremeasured for studying the α-Fe₂O₃ ultrafine particles adsorbed on Pt electrode. The blue shifts of Raman peaks demonstrate the size quantization effect for the particles of 50 nm in diameter ascompared with the bulk material. With the changing of the potential, the photocurrent decrcases as the UV-VIS reflectance increases, and vice-versa. Therefore, the potential not only affects the hargetransfer direcdtion in the interface of electrode/redox couple, but also influences the light absortion onthe surface of particles. According to the results of photoelectrochemistry, we suggest that the cathodic …

Horseradish Peroxidase/Poly-O-Phen Ylenediamine Mem Brane Electrode: Preparation And Properties, Dong Wei, Huihuang Wu

Journal of Electrochemistry

A horseradish peroxidase (HRP)/poly-o-phenylenediamine (PPD) membrane electrode was prepared by electropolymerization of o-phenylenediamine on glassy carbon in pH 7.0 phosphate buffer, the process of the enzyme immobilization was studied. The enzyme electrode obtained exhibits the activity to catalyze the electroreduction of hydrogen peroxide in the absence of any electron transfer mediator. The red uction reaction occurs in the potential range of PPD redoxprocess, it was believed that the polymer participates in electron transfer of the enzyme. The enzyme reaction kinetics at rotating HRP/PPD electrode was analysed, and the factors influencing kinetic parameters were discussed.

The Reduction Of Oxygen To Hydrogen Peroxide At The Poly(O-Phenylenediamine)-Filmed Electrode, Zhaoe Lu, Tiangeng Zhong, Guanyong Zhang

Journal of Electrochemistry

The poly(o-phenylenediamine) (PPD) filmed graphite electrode was formed by electro-polymerization of o-phenylenediamine in acidified (pH=1) 0.2 mol·L^-1 Na₂SO₄ solution using the cyclic voltammetric methed. The catalytic effect of the electrcareduction of oxygen in acid olution was demonstrated by the voltammogram of the electrode in the oxygen saturated acid solutionof Na₂SO₄. The current efficiency of the reduction of oxygen to hydrogen peroxide was determined by the electrolysis in a divided cell under the condition of constant current. The various effectsinfluencing the accmulation of H₂O₂ in the catholyte were discussed.

Studies On Coordination Behavior Of Dimethyl Sulfoxide In Complex Of Rare Earth With Cryptand, Shichang Liu, Tianpei Zhu

Journal of Electrochemistry

Electrochemical reduction reaction in the course of the titration of Eu(2.2.2) and Eu(2.2) using strong bonding solvent, DMSO, in C₂H₄Cl₂ has been investigated by cyclic voltammetry. The greater the concentration of strong bonding solvent, the more negative the half-wave potentials for the reduction reaction are. The coordination number of Eu(2.2.2) and Eu(2.2) which are 2 and 3 respectively, with DMSO can be calculated, according to the relations between half-wave potentials and the variety of concentration of DMSO.

The Electrochemical Reduction Of 2-Ethylanthraquinone (2eaq), Yaobin Zhu

Journal of Electrochemistry

The process of electrochemical reduction of 2EAQ in DMSO is studied using CVand ESR methods in this work, Pt, Pd and some implanted materials are used as electrodes. The quasi-rever-sible property of two electron transfer steps and their following homogeneous chemical reactions are illustrated. The mechanism of the electrochemical red uction of 2EAQ and the kinetic parameters of the related steps are obtained. Having measured the influence of water content in the system, the effect of the proton donor is discussed. After comparising the experimental results with each other these experiments gives us the idea that the replacement of metal …

Bandwidth And Additive Bandwidth Of Graphs, Maria Kujawski

Honors Capstone Projects and Theses

No abstract provided.

Fuzzy Logic For Digital Phase-Locked Loop Filter Design, Daniel J. Simon, Hossny El-Sherief

Electrical and Computer Engineering Faculty Publications

The problem of robust phase-locked loop design has attracted attention for many years, particularly since the advent of the global positioning system. This paper proposes and demonstrates the use of a fuzzy PLL to estimate the time-varying phase of a sinusoidal signal. It is shown via simulation results that fuzzy PLL's offer performance comparable to analytically derived PLL's (e.g. Kalman filters and H_∞ estimators) when the phase exhibits high dynamics and high noise. The fuzzy PLL rules are optimized using a gradient descent method and a genetic algorithm

Determination Of Alas Optical Constants By Variable Angle Spectroscopic Ellipsometry And A Multisample Analysis, C. M. Herzinger, H. Yao, Paul G. Snyder, F. G. Celii, Y. C. Kao, B. Johs, John A. Woollam

Department of Electrical and Computer Engineering: Faculty Publications

Using variable angle spectroscopic ellipsometry, optical constants for AlAs (1.4-5.0 eV) are presented which are simultaneously compatible with measured data from four different samples. The below-gap index values are compatible with published prism measured values. The second derivative spectrum are compatible with published values above the direct band gap. The AlAs spectra is Kramers-Kronig self-consistent over the measured range and is compatible with published values from 0.6 to 1.4 eV. The optical constants for thin (<50 >Å) GaAs caps on AlAs are shown to be different from bulk GaAs values and require special consideration when fitting ellipsometric data. For the …

An Adaptive "Natural Law" Fuzzy Controller, Sandeep D. Sequeira

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Fuzzy control has met with a tremendous interest in applications over the past few years. Despite its application potential, a broader industrial exploitation of fuzzy control has been hindered by the lack of standard design methods for fuzzy control systems. Fuzzy controllers have had to be designed on a case-by-case basis employing heuristics and reflecting the designer's limited insight into the control object's behavior. A number of fuzzy theorists have investigated the fuzzy system theoretic problems and results reported in the literature have been encouraging.

This thesis research has explored the notion that fuzzy control, despite being a rule-based control …

Review: 'Integrated Optics: Design And Modeling,' By Reinhard Marz, Bradley D. Duncan

Electro-Optics and Photonics Faculty Publications

My overall impression is that Integrated Optics: Design and Modeling will make a fine addition to almost anyone's collection of books on integrated optics. It will, however, serve its readers better as a reference book than as a text from which to first learn the basic concepts of integrated optics. I say this because the book is written at a fairly sophisticated technical level, though the author often moves rather quickly to the "bottom line" without providing material much beyond what is first necessary to introduce a problem or concept, and then a statement of the results and/or implications. It …

Optical Constants Of GaXIn1-XP Lattice Matched To Gaas, Mathias Schubert, V. Gottschalch, Craig M. Herzinger, Huade Yao, Paul G. Snyder, John A. Woollam

Department of Electrical and Computer Engineering: Faculty Publications

The optical constants of Ga_0.51In_0.49P have been determined from 0.8 to 5.0 eV using variable-angle spectroscopic ellipsometry measurements at room temperature. The metal-organic vapor-phase-epitaxy-grown samples were x-ray analyzed to confirm lattice matching to the GaAs substrate. The effects of the native oxide were numerically removed from the data to determine the intrinsic optical constants. This is important because the optical constants reported become generally useful for modeling multiple-layer structures. A Kramers-Kronig analysis was used to reduce interference-related fluctuations in the below-gap refractive index. Near the band edge a mathematical form for excitonic absorption was included. Critical …

Microwave Detection Optimization Of Disbond In Layered Dielectrics With Varying Thickness, Stoyan I. Ganchev, Nasser N. Qaddoumi, Emarit Ranu, R. Zoughi

Electrical and Computer Engineering Faculty Research & Creative Works

The detection sensitivity optimization of air disbond in layered dielectric composites, using an open-ended rectangular waveguide, is studied both theoretically and experimentally. The sensitivity of the disbond detection is strongly influenced by the proper choice of parameters such as the operating frequency and the layered composite geometry (conductor backed or terminated by an infinite half-space of air). The capability of optimizing the measurement system parameters to detect and estimate the thickness of a disbonded layer independent of some changes in the thickness of the dielectric coating is also demonstrated. The impact of the parameters influencing detection optimization is theoretically investigated …

Novel Kalman Filtering Method For The Suppression Of Gyroscope Noise Effects In Pointing And Tracking Systems, Marcelo C. Aigrain

Department of Electrical and Computer Engineering: Faculty Publications

A primary cause of degraded performance in pointing and tracking systems is the jitter in the line of sight. This jitter is caused by the residual angular motion of the stabilized platform within the system. A major contributor to this residual motion is the gyroscope noise. Thus, to reduce angular jitter, lower-noise gyroscopes are selected, generally at a premium cost. Another approach is to enhance the accuracy of the gyroscopes electronically (by suppressing measurement noise) before their outputs are fed into the stabilized platform control system. Optimal filtering techniques can be used for this purpose. The goal is to estimate …

Detecting Stator And Rotor Winding Faults In Three-Phase Induction Machines, Jeffrey C. Robertson, Chee Mun Ong

Department of Electrical and Computer Engineering Technical Reports

The purpose of this work is to investigate the efficiency of existing methods for on-line fault detection when applied to three-phase induction motors, spc:cifically to test known theoretical calculations of harmonics developed by certain types of faults experimentally. The work involves the development of equipment and test procedures needed and research of existing methods of fault detection. The experiments are cor~ductedb y planting a fault in a test induction machine and then performing a Fast Fourier Transform (FFT) on the line current. The processed data are then compared with those from the same test machine before the fault was planted. …

Optimal Sequence Estimation For Convolutionally Coded Signals With Binary Digital Modulation In Isi Channels, Fuqin Xiong

Electrical and Computer Engineering Faculty Publications

Decoding convolutional codes with binary digital modulation in intersymbol interference (ISI) channels is studied. The receiver structure is a whitened matched filter (WMF) whose transfer function is determined by the ISI channel. Decoding of the output sequence can be performed in two steps or one step. The two-step decoding first decodes the ISI corrupted coded sequence back to the ISI free coded sequence which is then decoded back to the uncoded message sequence. For one-step decoding, the entire encoder-channel-receiver system is modeled as a new encoder with combined memory length of the memory lengths of the original …

Generalized Sylvester Theorems For Periodic Applications In Matrix Optics, Lee W. Casperson, Anthony A. Tovar

Electrical and Computer Engineering Faculty Publications and Presentations

Sylvester's theorem is often applied to problems involving light propagation through periodic optical systems represented by unimodular 2 × 2 transfer matrices. We extend this theorem to apply to broader classes of optics-related matrices. These matrices may be 2 × 2 or take on an important augmented 3 × 3 form. The results, which are summarized in tabular form, are useful for the analysis and the synthesis of a variety of optical systems, such as those that contain periodic distributed-feedback lasers, lossy birefringent filters, periodic pulse compressors, and misaligned lenses and mirrors. The results are also applicable to other types …

Investigation Of Ground Target Detection Methods In Fully Polarimetric Wide Angle Synthetic Aperture Radar Images, Wayne B. Mclaggan

Theses and Dissertations

Target detection is a high priority of the Air Force for the purpose of reconnaissance and bombardment. This research investigates and develops methods to distinguish ground targets from clutter (i.e. foliage, landscape etc.) in Wide Angle Synthetic Aperture Radar (WASAR) images. WASAR uses multiple aspect angle SAR images of the same target scene. The WASAR data was generated from a pre-release software package (XPATCH-ES) provided by the sponsor (WL-AARA). A statistical analysis and feature extraction is performed on the XPATCH-ES data. Polarimetric and wide angle covariance matrices are estimated and analyzed. From an analysis of the wide angle covariance matrix …

A Photoelectrochemical Investigation Of Zirconium Oxide Film, Maizhi Yang, Ping Wei, Di Quarto F., Piazza S., Sunseri C.

Journal of Electrochemistry

A photoelectrochemical investigation has been carried out on zirconium initialoxide film and its oxide film grownanodically at constant rate up to different thickness. Both anodicand cathedic photocurrents on the photocurrent spectrum depended on the potential, but had littlerelation with the forming anedic films or measuring solutions. Photocurrent spectrum and photocurrenttransients suggested that the oxide films on zirconium were duplex layers structure. The internal layerwas ZrO₂ and the external layer ZrO₂·(H₂O)_n. The photocurrent included photogenerated carrier ininternal and external oxide films, as well as internal photoinjection process for electrons from thesubstrate metal into the …

Synthesis Of LiXCoo2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye

Journal of Electrochemistry

The Variations of crystal lattice parameters of Li_xCoO₂ during charge anddischarge have been st ud ied by XRD and AAR spectroscopy. It was found that the Li_xCoO₂ crystalvolume expanded during charge and contracted during discharge. The crystal lattice structure was broken because of the formation of Co₃O₄ when deeply charge.The variation of lattice parameter C₀ value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case. In case of preheating for 20 hours at 700℃ before operating high temperature, the …

Electroreduction Of The Nittobenzene On Titanium Electrode Implanted With Palladium, Zhongda Wu, Xianjun Zhu, Hongsen Wang

Journal of Electrochemistry

The titanium substrates were bombarded with 1×10¹⁷～5×10¹⁷ ions·cm^-2 ofpalladium at the room temperature. The surface composition of implanted electrode and concentration-depth profiles of various elements were measured by AES. The electrored uction processes ofnitrobenzene (NB) in 0.1 mol/L NaOH solution at Pd/Ti electrodes have been investigated by cyclicvoltaivimetry. The results show that the palladium implanted titanium electrodes exhibit a high catalyticactivity in the electroreduction of NB. The NB radical anion, which is the product of one-electronelectroreduction of NB, was detected by ESR in-situ in conjunction with electrochemical methods. Aniline was also detected as a product of …

Electroreduction Of Holmium Ion On Iron Electrde In Molten Cholorides, Qiqin Yang, Guankun Liu, Yuzhi Su

Journal of Electrochemistry

The cyclic voltammetry, open circuit potential-time curve after poteritiostatic electrolysis, current-time curve at potential step, X-ray diffraction and electron probe microanalysiswere used to investigate the electrode process of Ho(Ⅲ) reduced on iron electrode in molten chloridesand the phases of surface alloy layer. The Ho-Fe alloys are formed at first, and then the metallic holmium is deposited when Ho(Ⅲ) is reduced on iron electrode. The charge transfer is reversible. The free energies of formation for the four inter metallic compounds of Ho-Fe system, the diffusion coefficients and diffusion activation energy of Ho in alloyed cathode are determined.

Electrocatalytic Oxidation Of Formaidehyde And Formic Acid On A Pt/SbAd Electrode, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic activity for the oxidation of formaldehyde and formic acid ona Sb-modified platinum (Pt/Sb_ad) was investigated. Results showed that the Pt/Sb_ad electrode was electrocatalytically more active than a Pt electrode in the anodic oxidation of formaldehyde and formicacid. In the case of formaldehyde, an oxidation peak appeared at a potential of ca. 0.7V. During the oxidation of formic acid, a 4-fold increase in the 1st peak current was observed. The Sb-modified platinum electrode was found to be most electrocatalytically active at a coverage of 0.75±0.05. The electrocatalytic activity of the Pt/Sb_ad electrode can be best …

The Study Of The Growth Processes Of The Oxides On Lead Electrodes In Sulfuric Acid Solution, Hesheng Zhai, Xuguang Chen, Jinkua You, Yong Yang, Zugeng Lin

Journal of Electrochemistry

The growth processes of PbO and PbO₂ on lead electrodes have been investigatedby using in-situ methods that are combined with temporary AC resistance measurment technique and in-situ laser scanning photoelectrochemical microscopy. It is found that a linear relationship existsbetween the electrode resistance(R) and^1/2 after the electrode is oxidized at +0.6 V(vs.Hg/H₂SO₄/35% H₂SO₄) for more than 5 min. This result suggests that the growth of PbO is well distributed during the early stage of oxidation. The study by using laser scanning photoelectrochemical microscopy has further proved this point. The results also …