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Thermodynamic Properties Of Water Adsorbed On Kaolinite, S. John Bennett

Theses and Dissertations

The object of the work presented in this thesis was to obtain quantitative values of the thermodynamic changes in water upon adsorption by kaolinite. Two methode were used. The first was a determination of the differential heat content and entropy of adsorption. The second method included a thermodynamic evaluation of the B.E.T. "c" constant expressed in terms of the Gibbs standard free energy of adsorption. The experimental data gave satisfactory results in determining the differential and standard thermodynamic functions or free energy, entropy, and heat content of adsorption. The adsorption of water on kaolinite appears to be a van der …

The Decomposition Of Solid Barium Nitrate By Gamma Rays, Lawrence E. Lamar

Chemistry and Chemical Biology ETDs

Very little work has been done on the chemical effects produced during the irradiation of solid materials. Although some research has been reported concerning the action of ultraviolet light on solid nitrates, most of the information in the literature is based upon the use of nuclear radiations.

A Survey Of The Effects Of Changes In PH, Solvent And Salt Concentration Upon The Rate Of The Periodate-Glycol Reaction, Jay E. Taylor, Benadetto Soldano, George A. Hall

Department of Chemistry: Faculty Publications

A quantitative study of the effect of the periodate- glycol complex upon the rate of the periodate-glycol reaction was made in an earlier paper. The data for the present paper were taken before those of the previously published paper and, for the most part, before the importance of the periodate-glycol complex had been recognized. It has not been possible therefore to interpret the present data with the degree of thoroughness of the earlier paper. However, certain very interesting conclusions can be made.
The Effect of Variation of pH.
Effect of Changes in Solvent.
The Effects of Certain Salts.

Various Ways Of Preventing The Formation Of Scale In Sea Water Evaporators, James M. Stanek

Bachelors’ Theses

Previous work carried out at Marquette University has proved that the formation of scale in sea water evaporators can be prevented if such things as dehydrated alfalfa foliage or dehydrated corn, oats, peas, and grass foliage are added to the feed sea water. It has also been proved that the maturity of the plant from which the corn foliage has been stripped varies the scale preventing ability of the foliage, and that the storing of the corn foliage increases its scale preventing ability. The object of this work is to determine what effect the combination of various types of stainless …

Study Of The Complex Products Of Polymerization Of Some Quinones By Esr Spectroscopy, Juana Acrivos, M Blois

Faculty Publications, Chemistry

No abstract provided.

Esr Of Impurities In Mgo, John Wertz, Juana Vivó, B. Musulin

Faculty Publications, Chemistry

SP1. Electron Spin Resonance of Impurities in Magnesium Oxide. John E. Wertz, Juana L. Vivo, and Boris Musulin, University of Minnesota.

Esr Of Defect Centers In Magnesium Oxide, John Wertz, Juana Acrivos

Faculty Publications, Chemistry

B8. Electron Spin Resonance of Defect Centers in Magnesium Oxide.* John E. Wertz and Juana L. Vivo, University of Minnesota.

Phase Equilibrium In The 1-Butene-Water System And Correlation Of Hydrocarbon-Water Solubility Data, T. W. Leland

Journal of the Arkansas Academy of Science

No abstract provided.

Some Optical Properties Of Vapor-Deposited Films Of Arsenic, Antimony, And Bismuth, Zaboj V. Harvalik

Journal of the Arkansas Academy of Science

No abstract provided.

Chromatographic Studies., Richard Thomas Moravek

LSU Historical Dissertations and Theses

No abstract provided.

The Construction Of A Recording Raman Spectrometer And An Analysis Of The Vibrational Spectrum Of Bromobenzene And Its Monodeuterium Isomers., William Ward Daniels

LSU Historical Dissertations and Theses

No abstract provided.

Separation Of Germanium, Lead, Zinc, And Cadmium By Anion Exchange, Franklin Maynard Hill

Masters Theses

"The object of this study was to investigate the ion exchange behavior of germanium and apply the anion exchange technique for the separation of germanium, cadmium, lead, and zinc.

A new interest in germanium has developed because of its recent industrial application as a semi-conductor. Analytical methods for the separation and analysis of germanium in low concentrations have not been perfected. Krause and Johnson, in a recent review, discussed and evaluated a number of methods.

Most of the methods for the analysis of germanium require a preliminary separation. The analytical methods for germanium reported in the literature are troublesome and …

Addition Of Ketene To Ethylene Oxide, John Philip Friedrich

Masters Theses

"The object of this work was to study the reaction between ethylene oxide and ketene, and if possible, to isolate and identify the postulated γ-butyrolactone. Although the results could hardly be described as completely gratifying, they were at least in a sense positive. Many possibilities remain with regard to further modifications of the experimental work on this problem, however it is the author's sincere wish that this investigation will serve some useful purpose in the future"--Introduction, page 4.

Elementary Chemical Calculations, Edward S. Amis

Journal of the Arkansas Academy of Science

No abstract provided.

Possibility Of Weak Alpha Branching In Radium D, B. R. Miccoli, R. R. Edwards, B. L. Robinson, R. W. Fink

Journal of the Arkansas Academy of Science

No abstract provided.

Condensation Reaction Of Terephthaladehyde And Acetophenone, Lloyd J. Mitchell

University of the Pacific Theses and Dissertations

The plant pigments constitute a fascinating group of compounds whose constitution has only recently been partially clarified. Roughly speaking, there are two main groups of pigment: the plastids, associated with the protoplasmic structure of plants, and the anthocyanins, generally found in solution in the cell sap. The term “anthocyanin” is derived from the Greek, “antho” signifying flower and “cyan” meaning blue, and was introduced by the botanist Marquart in 1835 to designate the blue pigments of flowers. It has since been extended to include all of the pigments of this group, the anthocyanin pigments being responsible for the innumerable shades …

The Synthesis Of 2-Methyl-3, 4-Benzpyrene And 2, 8-Dimethyl-3, 4-Benzpyrene, James W. Patton

Chemistry and Chemical Biology ETDs

In 1933 Cook, Hewett and Hieger (1) isolated a carcinogenic hydrocarbon from coal tar thought to be 3,4-benzpyrene (I).

Evaluations Of Two Proposed Mechanisms Of Cation Adsorption By Silicate Minerals, Norman D. Larsen

Theses and Dissertations

Previous work done at the Brigham Young University by Andelin^1, Roberts^2, and Olsen^3, has established the mechanism by which xanthate collectors are adsorbed on molybdenite ores to produce the hydrophobic surfaces necessary for flotation. This thesis is an attempt to better understand the mechanism by which the silicate minerals, which are found in conjunction with the ores, become hydrophyllic and as a result are not floated when in contact with air bubbles. It has been previously established that silicate minerals do adsorb cations on their surfaces^4. The present study has been undertaken to more fully understand the mechanism by which …

A Polarographic Study Of Respiration In A Blue-Green Alga, Samuel Leonard Cooke Jr.

Master's Theses

The study of many aspects of physiology is accomplished by the study of respiration under varied conditions. For this purpose, a simple, rapid, and relatively accurate respirometer would be useful. This project was undertaken to investigate the possibility of adapting previously described polarographic techniques to the measurement of respiration.

Paper Partition Chromatography: A Qualitative Method For Separating The Amino Acid Residue Of Hydrolyzed Hordein, Samuel D. Toner

Bachelors’ Theses

In the search for a new analytical procedure the author became interested in the field of paper chromatography, and especially in its relation to the study of amino acids. The source of amino acids used in this work was selected from the alcohol-soluble hordein fraction of barley. Special attention was given to obtaining more rapid separation of the amino acids on two-dimensional paper chromatograms.

The Exchange Of Antimony Between Antimony Trichloride And Antimony Pentachloride In Carbon Tetrachloride Solution, Franklin Brett Barker

Chemistry and Chemical Biology ETDs

In the investigation of any chemical reaction, the main points of interest are the conditions of equilibrium, the rate at which equilibrium is approached, and the mechanisms by which the reaction occurs. The first of these is determined by the standard free energy change, a thermodynamic quantity which depends only upon the initial and final states of the system. However, two reactions having the same value of the standard free energy change may approach equilibrium at radically different rates, one being practically instantaneous and the other almost infinitely slow. The field of chemical kinetics is concerned with the study of …

Volume 1, Number 2 - May 1954

The Entropy

The Entropy (also published as the Providence College Journal of Physics and Chemistry) was an undergraduate scholarship journal published by the Phi Chi Club of Providence College. (Volume 1, Number 2 - May 1954 - 10 pages in total.)

Semi-Micro Procedure In High School Laboratories, Karl J. Aaberg

Journal of the Minnesota Academy of Science

No abstract provided.

The Content Of Essential Amino Acids In 1950 Alfalfa Hay Grown In Utah Soil Treated With Different Fertilizers, Adriana Lanting Kunkel

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Application of fertilizers to soils to increase production yields has raised questions concerning the effect of fertilizer on chemical composition of plants. With the development of accurate, sensitive microbiological methods for the determination of amino acid in protein, speculations concerning amino acid content have been supplanted by acquisition of facts.

The effect of the different fertilizer applications on alfalfa yield has been discussed by Jones, et al (5). Also, some work has been done to determine the effect different fertilizers might have on the amino acid content of plant material. Some values (1,3,12) have been reported for the amino acid …

Exchange Reactions Of The Transuranium Elements Section 1. Am(Iii)-Am(V)-Am(Vi), Am(Iii)-Am(V), And Am(V)-Am(Vi), Thomas K. Keenan

Chemistry and Chemical Biology ETDs

No exchange work prior to this dissertation has been reported on the americium system. Neptunium exchange is presently being studied by J. C. Hindman and co-workers at the Argonne National Laboratory, but has not been completely reported. Study of uranium exchange, which is still in an unsatisfactory state, has been limited to the U(IV)-(VI) exchange.

Volume 1, Number 1 - January 1954

The Entropy

The Entropy (also published as the Providence College Journal of Physics and Chemistry) was an undergraduate scholarship journal published by the Phi Chi Club of Providence College. (Volume 1, Number 1 - January 1954 - 22 pages in total.)

The Electrolytic Reduction Of Osmium Tetroxide In Perchloric Acid Solution, Donald Lloyd Brunner

University of the Pacific Theses and Dissertations

This is a study involving some of the chemistry of osmium tetroxide in perchloric acid solution. The research was originally instigated from a seminar report on the ruthenium III thiocyanate complex ion which was studied in perchloric acid solution. The seminar report given by Craig Townsend discussed how a spectrophotometric study by Yaffe and Voight (1951) was made of the ruthenium III thiocyanate complex ion, Similar possibilities were recognized as being possible in attacking the problem of an osmium thiocyanate complex or complexed. Some of the chemistry involved in the study of the ruthenium III thiocyanate complex will be discussed …

Studies Of The Reactions In Alcoholic Solution Of Gold(Iii) And Alpha-Naphthylamine., Theo Conner Mccoy

LSU Historical Dissertations and Theses

No abstract provided.

Voltammetry At Constant Current And Its Application To Electrochemical Kinetics., Calvin C. Mattax

LSU Historical Dissertations and Theses

No abstract provided.

A Study Of Some Nitroso Compounds., Cilton Watson Tate

LSU Historical Dissertations and Theses

No abstract provided.