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Full-Text Articles in Probability

Characterization Of The Anomalous Ph Of Aqueous Nanoemulsions, Kieran P. Ramos Oct 2019

Characterization Of The Anomalous Ph Of Aqueous Nanoemulsions, Kieran P. Ramos

Doctoral Dissertations

Aqueous water-in-oil nanoemulsions have emerged as a versatile tool for use in microfluidics, drug delivery, single-molecule measurements, and other research. Nanoemulsions are often prepared with perfluorocarbons which are remarkably biocompatbile due to their stability, low surface tension, lipophobicity, and hydrophobicity. Therefore it is often assumed that droplet contents are unperturbed by the perfluorinated surface. However, in microemulsions, which are similar to nanoemulsions, it is known that either the pH of the aqueous phase or the ionization constants of encapsulated molecules are different from bulk solution. There is also recent evidence of low pH in perfluorinated aqueous nanoemulsions. The current underlying …


Function And Dissipation In Finite State Automata - From Computing To Intelligence And Back, Natesh Ganesh Oct 2019

Function And Dissipation In Finite State Automata - From Computing To Intelligence And Back, Natesh Ganesh

Doctoral Dissertations

Society has benefited from the technological revolution and the tremendous growth in computing powered by Moore's law. However, we are fast approaching the ultimate physical limits in terms of both device sizes and the associated energy dissipation. It is important to characterize these limits in a physically grounded and implementation-agnostic manner, in order to capture the fundamental energy dissipation costs associated with performing computing operations with classical information in nano-scale quantum systems. It is also necessary to identify and understand the effect of quantum in-distinguishability, noise, and device variability on these dissipation limits. Identifying these parameters is crucial to designing …


Allocative Poisson Factorization For Computational Social Science, Aaron Schein Jul 2019

Allocative Poisson Factorization For Computational Social Science, Aaron Schein

Doctoral Dissertations

Social science data often comes in the form of high-dimensional discrete data such as categorical survey responses, social interaction records, or text. These data sets exhibit high degrees of sparsity, missingness, overdispersion, and burstiness, all of which present challenges to traditional statistical modeling techniques. The framework of Poisson factorization (PF) has emerged in recent years as a natural way to model high-dimensional discrete data sets. This framework assumes that each observed count in a data set is a Poisson random variable $y ~ Pois(\mu)$ whose rate parameter $\mu$ is a function of shared model parameters. This thesis examines a specific …